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Home My WebLink About295 Rye Street - Tier II Reports - Fire (3) SOUTH WINDSOR DIVISION P:860-290-2900 295 RYE STREET F:860-291-0263 ® SOUTH WINDSOR,CT 06074 E:deborah.battles@aldi.us February 14, 2018 South Windsor Volunteer Fire Department Attention:Chief Kevin E.Cooney 1175 Ellington Road South Windsor,CT 06074 Dear Chief Cooney; Enclosed is the 2017 Tier II Form,for our facility in South Windsor,Connecticut. Tier II forms will also be submitted to the State Emergency Response Commission,State Emergency Response Commission-Emergency Response and Spill Prevention,and the South Windsor LEPC.If you have any further questions,please contact me at(860)290-2900 extension 117. Sincerely, -- Eric Wemitt Director of Warehousing Aldi, Inc.,South Windsor Division SWN,Warehouse,DBattles,per:14 February 2018 Pagel/1 PAPersonal\Warehouse\Eric Correspondence\Tier 11 Letters 2018\SWVFD.doc Tier Two Reporting Period: January 1 to December 31,2017 Emergency and Hazardous Chemical Inventory Page 1 Specific Information by Chemical Printed: February 14,2018 Facility Name: ALDI Inc. -South Windsor Division FACILITY IDENTIFICATION: ALDI Inc. -South Windsor Division Dept: 295 Rye Street South Windsor, CT 06074 USA County: Hartford Fire District:South Windsor Latitude:41.859994 Longitude:-72.689956 Facility Phone:8608191629 [ ]Ali facility information(not including chemical information)is identical to last year's submission IDENTIFICATION NUMBERS: Dun&Bradstreet:00-694-0423(Retail Grocery Distribution Warehouse) NAICS:445110(Supermarkets and Other Grocery(except Convenience)Stores) Is the facility manned? [x]Manned [ ] Unmanned Maximum No. of Occupants:290 REGULATORY INFORMATION: Subject to Emergency Planning under Section 302 of EPCRA(40 CFR part 355)? [ ]Yes [x] No Subject to Chem.Accident Prevention under Section 112(r)of CAA(40 CFR part 68, Risk Mgmt. Pgm.)?[ ]Yes [x] No CONTACT INFORMATION: Persohn, Bruce Title: Vice President Contact Type 1: Owner/Operator Address: 295 Rye Street, South Windsor, CT, 06074 USA Phones:Work:860-290-2900*125 Email:Bruce.Persohn@aldi.us Wemitt,Eric Title: Dricetor of Warehouse and Logistics Contact Type 1: Emergency Contact Contact Type 2: Fac. Emergency Coordinator Contact Type 3:Tier II Information Contact Address: 295 Rye Street, South Windsor, CT, 06074 USA Phones: 24-hour: 860-819-1629 Mobile-Cell: 860-819-1629 Work: 860-290-2900*117 Email:Eric.Wemitt@aldi.us Butrick, Rick Title: Warehouse Supervisor Contact Type 1: Emergency Contact Contact Type 2: Other Address: 295 Rye Street, South Windsor, CT,06074 USA Phones:24-hour:860-819-1632 Work: 860-290-2900*128 Email:Rick.Butrick@aldi.us Rosa, Pedro Title: Building Mechanic Contact Type 1: Emergency Contact Contact Type 2: Other Address: 295 Rye Street, South Windsor, CT, 06074 USA Tier Two Reporting Period: January 1 to December 31,2017 Emergency and Hazardous Chemical Inventory Page 2 Specific Information by Chemical Printed: February 14,2018 Facility Name: ALDI Inc. -South Windsor Division Phones:24-hour:860-983-4316 Work:860-290-2900*135 Email:Pedro.Rosa@aldi.us CHEMICAL DESCRIPTIONS: ------------------------------------------------------------ CHEM NAME:Ammonia (Anhydrous) CAS: 7664-41-7 EHS: Yes [x] Identical to previous year [ ]TRADE SECRET [x] Pure [ ] Mix [ ]Solid [x] Liquid [x] Gas CHEMICAL COMPONENTS: [x] EHS, CAS: 7664-41-7, Component:Ammonia(Anhydrous), 100%Wt, Max Amt code: 05(5,000-9,999 pounds) PHYSICAL HAZARDS: [x]Explosive [x]Flammable (gases, aerosols, liquids, or solids) [ ]Oxidizer (liquid, solid or gas) [ ]Self-reactive [ ]Pyrophoric (liquid or solid) [ ]Pyrophoric Gas [ ]Self-heating [ ]Organic peroxide [ ]Corrosive to metal [x]Gas under pressure (compressed gas) [ ]In contact with water emits flammable gas [ ]Combustible Dust HEALTH HAZARDS: [ ]Acute toxicity (any route of exposure) [ ]Carcinogenicity [x]Skin corrosion or irritation [ ]Reproductive toxicity [x]Serious eye damage or eye irritation [ ]Specific target organ toxicity (single/repeated exposure) [x]Respiratory or skin sensitization [x]Aspiration hazard [ ]Germ cell mutagenicity [ ]Simple Asphyxiant [ ]Hazard Not Otherwise Classified INVENTORY: [ ] Below Reporting Thresholds Max Amt: 9900 pounds Max Daily Amt code: 05(5,000-9,999 pounds) Avg Amt: 9900 pounds Avg Daily Amt code: 05(5,000-9,999 pounds) Max quantity in largest container:9900 pounds No. of days on-site: 365 STORAGE LOCATIONS: [ ] Confidential Container Type: Tank inside building Pressure: Less than ambient pressure Temp: Less than ambient temp./not cryog Location:Above ground tank inside the building (closed system ammonia compressor high side in the ammonia room Amount: 9900 pounds Container Type:Tank inside building Pressure: Greater than ambient pressure Temp: Less than ambient temp./not cryog Location:Above ground tank inside the building (closed system high pressure receiver tanks in the ammonia room Amount: 9900 pounds Container Type:Tank inside building Pressure: Greater than ambient pressure Temp: Less than ambient temp./not cryog Location: Above ground tank inside the building (closed system ammonia compressor low side in the ammona room Amount: 9900 pounds Container Type: Tank inside building Pressure: Greater than ambient pressure Temp: Less than ambient temp./not cryog Location:Above ground tank(closed system ammonia evaporator penthouses on west rooftop Amount: 9900 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [ ]Trucks [ ]Tank Trucks [ )Rail Car [ ]Tank Car [ ] Pipeline [ ] Barge [x] Other(Specify) Specify other:Ammonia is used to refrigerate the building. Ammonia is not shipped and does not leave the building Frequency of Shipment:0 per Maximum capacity per single vessel: 0 Max Shipment Qty(Ibs): 0 Tier Two Reporting Period: January 1 to December 31,2017 Emergency and Hazardous Chemical Inventory Page 3 Specific Information by Chemical Printed: February 14,2018 Facility Name: ALDI Inc. -South Windsor Division Ave Qty(lbs): 0 Physical State in Transit: Comments(please provide both the primary and alternate routes of travel):Ammonia is used in the refrigeration system and does not leave the buildng Carrier:Not Applicable ------------------------------------------------------------ CHEM NAME: Lead(Lead Acid Battery) CAS: 7439-92-1 EHS: Yes [ J Identical to previous year [ ]TRADE SECRET [ ]Pure [x]Mix [ ] Solid [xj Liquid [ ]Gas CHEMICAL COMPONENTS: [x]EHS, CAS:7439-92-1,Component: Lead(Lead Acid Battery),60%Wt, Max Amt code: 10(100,000-499,999 pounds) [x]EHS, CAS: 7664-93-9,Component: Sulfuric Acid(Lead Acid Battery), 30%Wt, Max Amt code: 10(100,000-499,999 pounds) PHYSICAL HAZARDS: [x]Explosive [x]Flammable (gases, aerosols, liquids, or solids) ( ]Oxidizer (liquid, solid or gas) [x]Self-reactive [ ]Pyrophoric (liquid or solid) [ ]Pyrophoric Gas [ ]Self-heating [ ]Organic peroxide [ ]Corrosive to metal [ ]Gas under pressure (compressed gas) [ ]In contact with water emits flammable gas [ ]Combustible Dust HEALTH HAZARDS: [x]Acute toxicity (any route of exposure) [ ]Carcinogenicity [x]Skin corrosion or irritation [ ]Reproductive toxicity [x]Serious eye damage or eye irritation [ ]Specific target organ toxicity (single/repeated exposure) [ ]Respiratory or skin sensitization [ ]Aspiration hazard [ ]Germ cell mutagenicity [ ]Simple Asphyxiant [ ]Hazard Not Otherwise Classified INVENTORY: [ ] Below Reporting Thresholds Max Amt: 192720 pounds Max Daily Amt code: 10 (100,000-499,999 pounds) Avg Amt: 192720 pounds Avg Daily Amt code: 10(100,000-499,999 pounds) Max quantity in largest container: 1800 pounds No. of days on-site: 365 STORAGE LOCATIONS: [ ]Confidential Container Type: Battery Pressure: Ambient pressure Temp:Ambient temperature Location: Present in lead acid batteries throughout the facility Amount: 192720 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [x]Trucks [ ]Tank Trucks [ ] Rail Car [ ]Tank Car [ ] Pipeline [ ] Barge [ J Other(Specify) Specify other: Frequency of Shipment:40 per Week Maximum capacity per single vessel:26 Max Shipment Qty(lbs): 1600 Ave Qty(lbs): 400 Physical State in Transit: Solid Comments(please provide both the primary and alternate routes of travel): Pallet jacks are shipped to and from divisional ALDI stores thoughout CT, MA, RI, NY, VT, NH. These pallet jacks are powered by lead acid batteries. The majority of travel is on 184, 1291, 191, 195, 190, Route 5, Rye Street,and Sullivan Ave. Once off the major highways and interstates, local roads are used to deliver product/equipment to the retail store locations. Currently there are 25 stores in CT. All deliveries are performed by Black Horse Carriers. Tier Two Reporting Period: January 1 to December 31, 2017 Emergency and Hazardous Chemical Inventory Page 4 Specific Information by Chemical Printed: February 14, 2018 Facility Name: ALDI Inc. - South Windsor Division Carrier: Black Horse Carriers ------------------------------------------------------------ CHEM NAME: Propylene Glycol CAS: 57-55-6 EHS: No [x] Identical to previous year [ ]TRADE SECRET [ ] Pure [x]Mix [ ] Solid [x] Liquid [ ]Gas CHEMICAL COMPONENTS: [ ]EHS, CAS: 57-55-6, Component: Propylene Glycol, 98%Wt, Max Amt code:06(10,000-24,999 pounds) PHYSICAL HAZARDS: [ ]Explosive [ ]Flammable (gases, aerosols, liquids, or solids) [ ]Oxidizer (liquid, solid or gas) [ )Self-reactive [ )Pyrophoric (liquid or solid) [ ]Pyrophoric Gas [ ]Self-heating [ ]Organic peroxide [ )Corrosive to metal [ ]Gas under pressure (compressed gas) [ ]In contact with water emits flammable gas [ ]Combustible Dust HEALTH HAZARDS: [x]Acute toxicity (any route of exposure) [ ]Carcinogenicity [x]Skin corrosion or irritation [ )Reproductive toxicity [x]Serious eye damage or eye irritation [ ]Specific target organ toxicity (single/repeated exposure) [x]Respiratory or skin sensitization [ ]Aspiration hazard [ ]Germ cell mutagenicity [ ]Simple Asphyxiant ( ]Hazard Not Otherwise Classified INVENTORY: [ ] Below Reporting Thresholds Max Amt: 11999.3 pounds Max Daily Amt code:06(10,000-24,999 pounds) Avg Amt: 11999.3 pounds Avg Daily Amt code: 06(10,000-24,999 pounds) Max quantity in largest container:9537 pounds No. of days on-site: 365 STORAGE LOCATIONS: [ ]Confidential Container Type:Tank inside building Pressure: Ambient pressure Temp: Greater than ambient temperature Location: Cooler Freezer sub-floor heating system Amount: 9537 pounds Container Type:Tank inside building Pressure: Ambient pressure Temp: Less than ambient temp./not cryog Location: HVAC chiller units on the mezzanine Amount: 1213.8 pounds Container Type:Tank inside building Pressure: Ambient pressure Temp: Greater than ambient temperature Location: Sidewalk heating system Amount: 867 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [ ]Trucks [ ]Tank Trucks [ ] Rail Car [ ]Tank Car [ ] Pipeline [ ) Barge [x]Other(Specify) Specify other: Propylene Glycol is used in the building and is not shipped. Frequency of Shipment: 0 per Year Maximum capacity per single vessel:0 Max Shipment Qty(lbs): 0 Ave Qty(lbs):0 Physical State in Transit: Comments (please provide both the primary and alternate routes of travel): Propylene Glycol is used in the cooler/freezer sub-floor, HVAC system,and sidewalk heating system. Propylene Glycol is never shipped. Carrier: NA ------------------------------------------------------------ CHEM NAME: Sulfuric Acid Tier Two Reporting Period: January 1 to December 31,2017 Emergency and Hazardous Chemical Inventory Page 5 Specific Information by Chemical Printed: February 14,2018 Facility Name: ALDI Inc. -South Windsor Division CAS:7664-93-9 EHS: Yes [ ] Identical to previous year [ ]TRADE SECRET [ ]Pure [x] Mix [ ]Solid [x] Liquid [ ] Gas CHEMICAL COMPONENTS: [x]EHS,CAS:7664-93-9,Component:Sulfuric Acid (Lead Acid Battery), 30%Wt, Max Amt code: 10(100,000-499,999 pounds) [x]EHS,CAS:7439-92-1,Component: Lead (Lead Acid Battery),60%Wt, Max Amt code: 10(100,000-499,999 pounds) PHYSICAL HAZARDS: [x]Explosive [x]Flammable (gases, aerosols, liquids, or solids) [x]Oxidizer (liquid, solid or gas) [x]Self-reactive [ ]Pyrophoric (liquid or solid) [ ]Pyrophoric Gas [ ]Self-heating [ )Organic peroxide [ )Corrosive to metal [ ]Gas under pressure (compressed gas) [ ]In contact with water emits flammable gas [ ]Combustible Dust HEALTH HAZARDS: [x]Acute toxicity (any route of exposure) [ ]Carcinogenicity [x)Skin corrosion or irritation ( ]Reproductive toxicity [x]Serious eye damage or eye irritation [ )Specific target organ toxicity (single/repeated exposure) [x]Respiratory or skin sensitization [ ]Aspiration hazard [ )Germ cell mutagenicity [ ]Simple Asphyxiant [ )Hazard Not Otherwise Classified INVENTORY: [ ] Below Reporting Thresholds Max Amt: 108979 pounds Max Daily Amt code: 10(100,000-499,999 pounds) Avg Amt: 108797 pounds Avg Daily Amt code: 10(100,000-499,999 pounds) Max quantity in largest container:791 pounds No.of days on-site: 365 STORAGE LOCATIONS: [ ]Confidential Container Type: Battery Pressure: Ambient pressure Temp:Ambient temperature Location: Present in lead acid equipment batteries throughout the facility Amount: 108797 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [x]Trucks [ ]Tank Trucks [ ]Rail Car [ ]Tank Car [ ] Pipeline [ J Barge [ ]Other(Specify) Specify other: Frequency of Shipment:40 per Week Maximum capacity per single vessel: 26 Max Shipment Qty(lbs): 656 Ave Qty(lbs): Physical State in Transit: Liquid Comments(please provide both the primary and alternate routes of travel): Pallet jacks are shipped to and from divisional ALDI stores thoughout CT, MA, RI, NY,VT, NH. These pallet jacks are powered by lead acid batteries. The majority of travel is on 184, 1291, 191, 195, 190, Route 5, Rye Street,and Sullivan Ave. Once off the major highways and interstates, local roads are used to deliver product/equipment to the retail store locations. Currently there are 25 stores in CT. All deliveries are performed by Black Horse Carriers. Carrier: Black Horse Carriers ------------------------------------------------------------ FACILITY STATE FIELDS: No additional information is required by Connecticut STATE/LOCAL FEES: None. Tier Two Reporting Period: January 1 to December 31,2017 Emergency and Hazardous Chemical Inventory Page 6 Specific Information by Chemical Printed: February 14,2018 Facility Name: ALDI Inc. - South Windsor Division [ ] I have attached a site plan [ ] I have attached a list of site coordinate abbreviations [ ] I have attached a description of dikes and other safeguard measures Certification(Read and sign after completing all sections) I certify under penalty of law that I have personally examined and am familiar with the information submitted in pages one through 6, and that based on my inquiry of those individuals responsible for obtaining this Information,I believe that the s�nformati on is true,accurate,and complete. Eric Wemitt '::� — 2/14/2018 Name and official title of owner/operator OR owner/operator's authorized representative Signature Date signed Tier Two Emergency and Hazardous Chemical Inventory February 14,2018 VALIDATION REPORT Page 1 ------END OF VALIDATION REPORT------ -------ALL FACILITIES PASS VALIDATION CHECK.------ DATASHEEN' -Al SAFETY x Ammonia [Section 1. Identification GHS product identifier : Ammonia Chemical name : ammonia, anhydrous Other means of : ammonia; anhydrous ammonia;Aqueous ammonia;Aqua ammonia identification Product use Synthetic/Analytical chemistry. Synonym ammonia; anhydrous ammonia;Aqueous ammonia;Aqua ammonia SDS# : 001003 Supplier's details Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 Emergency telephone 1-866-734-3438 number(with hours of operation) Section 2. Hazards identification OSHAIHCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : FLAMMABLE GASES-Category 2 substance or mixture GASES UNDER PRESSURE-Compressed gas ACUTE TOXICITY(inhalation)-Category 4 SKIN CORROSION/IRRITATION- Category 1 AQUATIC HAZARD(ACUTE)-Category 1 GHS label elements Hazard pictograms < 100w,> < > < > Signal word : Danger Hazard statements Flammable gas. Contains gas under pressure; may explode if heated. May displace oxygen and cause rapid suffocation. Harmful if inhaled. Very toxic to aquatic life. Precautionary statements General Read and follow all Safety Data Sheets (SDS'S) before use. Close valve after each use and when empty. Use equipment rated for cylinder pressure. Do not open valve until connected to equipment prepared for use. Use a back flow preventative device in the piping. Use only equipment of compatible materials of construction. Approach suspected leak area with caution. Prevention Never Put cylinders into unventilated areas of passenger vehicles. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, sparks, open flames and hot surfaces.- No smoking. Use only outdoors or in a well- ventilated area. Avoid release to the environment. Avoid breathing gas. Wash hands thoroughly after handling. Use and store only outdoors or in a well ventilated place. Date of issue/Date of revision : 1011412014. Date of previous issue :9/29/2014. Version :0.04 1114 Ammonb.. Section 2. Hazards identification Response Collect spillage. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. IF SWALLOWED: Immediately call a POISON CENTER or physician. Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. Wash contaminated clothing before reuse. Immediately call a POISON CENTER or physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or physician. Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Eliminate all ignition sources if safe to do so. Storage : Store locked up. Protect from sunlight. Protect from sunlight when ambient temperature exceeds 520C/1250F. Store in a well-ventilated place. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : In addition to any other important health or physical hazards,this product may displace classified oxygen and cause rapid suffocation. [Section 3. Composition/information on ingredients Substance/mixture : Substance Chemical.name : ammonia,anhydrous Other means of : ammonia; anhydrous ammonia;Aqueous ammonia;Aqua ammonia identification CAS numberlothgr identifiers CAS number : 7664-41-7 Product code : 001003 Ingredient name % CAS number ammonia, anhydrous 100 7664-41-7 There are no additional ingredients present which,within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section B. Section 4. First aid measures Description of necessary first aid measures Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Date ofissue/Date of revision :1 011 4120 1 4. Date of previous issue :9/29/2014. Version :0.04 2114 Ammodia Section 4. First aid measures Skin contact Get medical attention immediately. Call a poison center or physician. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Continue to rinse for at least 10 minutes. Chemical bums must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Ingestion : As this product is a gas, refer to the inhalation section. Mog-A irnportgnt symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye damage. Contact with rapidly expanding gas may cause bums or frostbite. Inhalation : Harmful if inhaled. May give off gas,vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact : Causes severe burns. Contact with rapidly expanding gas may cause burns or frostbite. Frostbite : Try to warm up the frozen tissues and seek medical attention. Ingestion : May cause burns to mouth,throat and stomach. As this product is a gas, refer to the inhalation section. Over-exposure signs/gymptoms Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains Indication of immediate medical attention and special f`reatment needed, if necessary Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Protection of first-alders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing Use an extinguishing agent suitable for the surrounding fire. media Unsuitable extinguishing None known. media Date of issue/Date of revision :10/1412014: Date of previous issue :912912014. Version :0.04 31141 Ammonia Section 5. Fire-fighting measures Specific hazards arising Contains gas under pressure. Flammable gas. In a fire or if heated, a pressure from the chemical increase will occur and the container may burst,with the risk of a subsequent explosion. This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. ' Hazardous thermal Decomposition products may include the following materials: decomposition products nitrogen oxides Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Contact supplier immediately for specialist advice. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is impossible,withdraw from area and allow fire to bum. Fight fire from protected location or maximum possible distance. Eliminate all ignition sources if safe to do so. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA)with a full face-piece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions. protective equipment and emer_gency_arocedures For non-emergency Accidental releases pose a serious fire or explosion hazard. No action shall be taken personnel involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Shut off all ignition sources. No flares,smoking or flames in hazard area. Do not breathe gas. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For emergency responders : If specialised clothing is required to deal with the spillage,take note of any information in Section 8 on suitable and unsuitable materials. See also the information in"For non- emergency personnel'. Environmental precautions : Ensure emergency procedures to deal with accidental gas releases are in place to avoid contamination of the environment. Inform the relevant authorities if the product has caused environmental pollution(sewers,waterways,soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Methods pnd materials for containment and cleaning up Small spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Large spill : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note:see Section 1 for emergency contact information and Section 13 for waste disposal. Section 7. Handling and storage Precautions for safe handling Protective measures : Put on appropriate personal protective equipment (see Section 8). Contains gas under pressure. Do not get in eyes or on skin or clothing. Do not breathe gas. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Date of issue/Date of revision :1011412014. Date of previous issue :91292014. Version :0.04 4114I Ammonia Section 7. Handling and storage Protect cylinders from physical damage;do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is occupational hygiene handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area. including any Store away from direct sunlight in a dry,cool and well-ventilated area, away from incompatibilities incompatible materials (see Section 10). Store locked up. Eliminate all ignition sources. Keep container tightly closed and sealed until ready for use. Cylinders should be stored upright,with valve protection cap in place, and firmly secured to prevent-falling or being knocked over.Cylinder temperatures.should not exceed 52°C (125 OF). Section 8. Exposure controls/personal protection Control parameters Occunational exposure limits Ingredient name Exposure limits ammonia, anhydrous ACGIH TLV(United States, 6/2013). STEL:24 mg/m315 minutes. STEL:35 ppm 15 minutes. TWA: 17 mg/m3 8 hours. TWA:25 ppm 8 hours. NIOSH REL(United States,412013). STEL:27 mg/m315 minutes. STEL: 35 ppm 15 minutes. TWA: 18 mg/m9 10 hours. TWA: 25 ppm 10 hours. OSHA PEL(United States, 212013). TWA: 35 mg/m3 8 hours. TWA: 50 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). STEL: 27 mg/m315 minutes. STEL: 35 ppm 15 minutes. Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or controls other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Environmental exposure Emissions from ventilation or work process equipment should be checked to.ensure controls they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Individual rp otegtion measures Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Date of issuelDafe of revision :10/i4I2014. Dafe of previ ous issue :912912014.. Version :0.04 5/14 •Ammonia Section 8. Exposure controls/personal protection Eye/face protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible,the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Skin protection Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances,the protection time of the gloves cannot be accurately estimated. Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity,wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory protection : Use a properly fitted,air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Section 9. Physical and chemical properties Appearance Physical state : Gas. [Compressed gas.] Color : Colorless. Molecular weight 17.03 g/mole Molecular formula H3-1N Boiling/condensation point -33*C(-27.4°F) Melting/freezing point -77.7°C (-107.9°F) Critical temperature 132.85'C (271.1°F) Odor Pungent. Odor threshold Not available. pH : Not available. Flash point : Not available. Burning time : Not applicable. Burning rate : Not applicable. Evaporation rate : Not available. Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: oxidizing materials. Lower and upper explosive Lower: 15.4% (flammable) limits Upper:25% Vapor pressure : 114.1 (psig) Vapor density : Q.59 (.Air= 1) Specific Volume (ft 3/Ib) : 22.7273 Gas Density (lb/ft 3} : 0.044 Date of issue/Date of revision : 1011412014. Date of previous issue :9/292014. Version :0.04 6114 Ammonia Section 9. Physical and chemical properties Relative density : Not applicable. Solubility : Not available. Solubility in water : 540 gA Partition coefficient: n- : Not available. octanoi/water Auto-ignition temperature : 6510C (1203.8°F) Decomposition temperature : Not available. SADT : Not available. Viscosity Not applicable. Physicalichemical SPECIFIC GRAVITY(AIR=1): @ 70OF(21.1°C) =0.59 properties comments PH:Approx. 11.6 for 1 N Sol'n.in water Section 10. Stability and reactivity Reactivity : No specific test data related to reactivity available for this product or its ingredients. Chemical stability : The product is stable. Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur. reactions Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut,weld, braze, solder,drill, grind or expose containers to heat or sources of ignition. Incompatibility with various : Extremely reactive or incompatible with the following materials: oxidizing materials. substances Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced. Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Information on toxicological effects Acute toxicity Product/ingredient name Result Species Dose Exposure ammonia, anhydrous LC50 Inhalation Gas. Rat 7338 ppm 1 hours lrritaationiCorrosion Not available. Sensitization Not available. Nlutauenicity Not available. Carcinogenicity Not available. Date of issuelDate of revision :1011412014. Date of previous issue :912912014. Version :0.04 1114 Ammonle Section 11. Toxicological information Reproductive toxicity Not available. Teratogenicity Not available. Specific target organ toxici single exposurel Not available. Specific target gr an toxic (rel2eatgd exposurel Not available. .Aspiration hazard Not available. Information on the likely : Not available. routes of exposure Potential acute health effects Eye contact : Causes serious eye damage. Contact with rapidly expanding gas may cause bums or frostbite. Inhalation : Harmful if inhaled. May give off gas,vapor or dust that Is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. Skin contact : Causes severe bums. Contact with rapidly expanding gas may cause bums or frostbite. ingestion : May cause burns to mouth,throat and stomach. As this product is a gas, refer to the inhalation section. Sym tlLams mated tq the physical chemical and toxicological characteristics Eye contact : Adverse symptoms may include the following: pain watering redness Inhalation : No specific data. Skin contact : Adverse symptoms may include the following: pain or irritation redness blistering may occur Ingestion : Adverse symptoms may include the following: stomach pains Delayed and immediate effects anti also chronic effects from short and long term exposure Short term exposure Potential immediate : Not available. effects Potential delayed effects : Not available. Long term exposure Potential immediate : Not available. effects Potential:delayed effects : Not available. Potential chronic health effects Not available. Date ofissue/Date ofrevision : 1011412014. Date of,orevious issue :912912014. Version :0.04 8114 I Ammonia Section 11 . Toxicological information General : No known significant effects or critical hazards. Carcinogenicity : No known significant effects or critical hazards. Mutagenicity : No known significant effects or critical hazards. Teratogenicity : No known significant effects or critical hazards. Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Numerical measures of toxicity Acute toxicity estimates Not available. Section 12. Ecological information TgxIcljX Product/ingredient name Result Species Exposure ammonia, anhydrous Acute EC50 29.2 mgA Marine water Algae-Ulva fasciata-Zoea 96 hours Acute LC50 2080 pg/I Fresh water Crustaceans-Gammarus pulex 48 hours Acute LC50 0.53 ppm Fresh water Daphnia-Daphnia magna 48 hours Acute LC50 300 pg/I Fresh water Fish-Hypophthalmichthys nobilis 96 hours Persistence and degradabilily Not available. Gioaccumulative potential Not available. Mobility in soil Soil/water partition Not available. coefficient(Koc) Other adverse effects No known significant effects or critical hazards. Section 13. Disposal considerations Disposal methods The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Empty Airgas-owned pressure vessels should be returned to Airgas. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. Date of issue/Date of revision : 1011412014, Date of previous issue :91292014, Version :0.04 9114 Ammonia Section 14. Transport information DOT TDG Mexico 1MDG IATA UN number UN1005 UN1005 UN1005 UN1005 UN1005 UN proper AMMONIA, AMMONIA, AMMONIA, AMMONIA, AMMONIA, shipping name ANHYDROUS ANHYDROUS;OR ANHYDROUS ANHYDROUS ANHYDROUS ANHYDROUS AMMONIA Transport 2.2 2.3 (8) 2.2 2.3(8) 2.3(8) hazard class(es) > <!> 4;4� z z Packing group - - - Environment No. No. No. Yes. No. Additional Reportable quantity Explosive Limit and The marine pollutant The environmentally information 100 Ibs/45.4 kg Limited Quantify Index mark is not required hazardous substance Package sizes shipped 0 when transported in mark may appear if in quantities less than sizes of s5 L or s5 kg. required by other the product reportable ERAP Index transportation quantity are not subject 3o00 regulations. to the RQ(reportable Passenger and Cargo quantity)transportation passenger Carrying AtrcraftQuantity requirements. Shi Index ndex limitation:0 Forbidden Forbidden Cargo Aircraft Only Limited gugntity Quantity limitation: Yes. Passenger Carrying Forbidden Road or Rail Index Packaging instruction Forbidden Passenger aircraft Quantity limitation: Special provisions Forbidden. Cargo aircraft Quantity limitation: Forbidden. Special provisions 13,T50 "Refer to CFR 49 (or authority having jurisdiction)to determine the information required for shipment of the product." Special precautions for user : Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. Transport in bulk according : Not available. to Annex 11 of MARPOI_ 73178 and the IBC Code Dafe of issuelDate of revision :1011412014. Date of previous issue :9/29/2014. Version :0.04 10114 Ammonia ,I Section 15. Regulatory information U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined United States inventory (TSCA 8b):This material is listed or exempted. Clean Water Act(CWA) 311: ammonia, anhydrous Clean Air Act(CAA) 112 regulated toxic substances: ammonia, anhydrous Clean Air Act Section 112 : Not listed (b)Hazardous Air Pollutants(HAPs) Clean Air Act Section 602 : Not listed Class I Substances Clean Air Act Section 602 : Not listed Class 11 Substances DEA List I Chemicals : Not listed (Precursor Chemicals) DEA List 11 Chemicals : Not listed (Essential Chemicals) SARA 30M 4 Composition/inforrngtion on ingredients SARA 302 TPQ SARA 304 RQ Name % EHS (Ibs) - (gallons) (lbs) (gallons) ammonia, anhydrous 100 Yes. 500 - 100 - SARA 304 RQ : 100 Ibs/45.4 kg SARA 311/312 Classification : Fire hazard Sudden release of pressure Immediate(acute)health hazard Composition/information on ingredients Name % Fire Sudden Reactive Immediate Delayed hazard release of (acute) (chronic) pressure health health hazard hazard ammonia, anhydrous 100 Yes. Yes. No. Yes. No. SARA 313 Product name CAS number % Form R-Reporting ammonia, anhydrous 7664-41-7 100 requirements Supplier notification ammonia, anhydrous 7664-41-7 100 SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. estate reguiptiong Massachusetts This material is listed. New York This material is listed. View Jersey : This material is listed. Pennsylvania This material is listed. Date of issue/Date of revision : 1011412014. Date of previous issue :9/292014. Version^:0.04 11114 , ,Ammonia Section 15. Regulatory information Canada inventory : This material is listed or exempted. International regulations International lists : Australia inventory(AICS):This material is listed or exempted. China inventory(IECSC):This material is listed or exempted. Japan inventory:This material is listed or exempted. Korea inventory:This material is listed or exempted. Malaysia Inventory(EHS Register):This material is listed or exempted. New Zealand Inventory of Chemicals (NZIoC):This material is listed or exempted. Philippines inventory(PICCS):This material is listed or exempted. Taiwan inventory(CSNN): Not determined. Chemical Weapons : Not listed Convention List Schedule I Chemicals Chemical Weapons : Not listed Convention List Schedule If Chemicals Chemical Weapons : Not listed Convention List Schedule Ill Chemicals Canada WHMIS (Canada) : Class A: Compressed gas. Class B-1: Flammable gas. Class D-IA: Material causing immediate and serious toxic effects (Very toxic). Class E: Corrosive material CEPA Toxic substances:This material is listed. Canadian ARET:This material is not listed. Canadian NPR[:This material is listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances:This material is not listed. Quebec Designated Substances:This material is not listed. Section 16. Other information Canada Label requirements : Class A: Compressed gas. Class B-1: Flammable gas. Class D-IA: Material causing immediate and serious toxic effects (Very toxic). Class E: Corrosive material Hazardous Material Information System (U.S.A.) 3 .......... . , 2 Caution: HMISO ratings are based on a 0-4 rating scale,with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMISO ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMISO ratings are to be used with a fully implemented HMISO program. HMISO is a registered mark of the National Paint&Coatings Association (NPCA). HMISO materials may be purchased exclusively from J. J. Keller(800) 327-6868. The customer is responsible for determining the PPE code for this material. National Fire Protection Association (U.S.A.) fJate of issueJDate of revision : 1011412014. Date of previous issue :912912014. Version :0.04 12114 F mmonia Section 16. Other information Flammability Health 40!! Instability/Reactivity Special Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright©1997, National Fire Protection Association, Quincy, MA 02269.This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright©2001,National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,which would be used as a guideline only.Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. HiAtou Date of printing : 10/14/2014. Date of issue/Date of : 10114/2014. revision Date of previous issue : 9/29/2014. Version : 0.04 Key to abbreviations : ATE=Acute Toxicity Estimate BCF= Bioconcentration Factor GHS= Globally Harmonized System of Classification and Labelling of Chemicals IATA= International Air Transport Association IBC=Intermediate Bulk Container IMDG= International Maritime Dangerous Goods LogPow= logarithm of the octanol/water partition coefficient MARPOL 73178 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol"= marine pollution) UN = United NationsACGIH—American Conference of Governmental Industrial Hygienists A1HA—American Industrial Hygiene Association CAS—Chemical Abstract Services CEPA—Canadian Environmental Protection Act CERCLA—Comprehensive Environmental Response, Compensation, and Liability Act (EPA) CFR—United States Code of Federal Regulations CPR—Controlled Products Regulations DSL—Domestic Substances List GWP—Global Warming Potential IARC—International Agency for Research on Cancer ICAO—International Civil Aviation Organisation Inh—Inhalation LC—Lethal concentration LD—Lethal dosage NDSL—Non-Domestic Substances List NIOSH—National Institute for Occupational Safety and Health TDG—Canadian Transportation of Dangerous Goods Act and Regulations TLV—Threshold Limit Value TSCA—Toxic Substances Control Act WEEL—Workplace Environmental Exposure Level WHMIS—Canadian Workplace Hazardous Material Information System References Not available. P Indicates information that has changed from previously issued version. Date of issue/Date of revision : 1011412014. Date of previous issue :91292014. Version :0.04 13114 Ammohi -- Section 16. Other information Notice to reader To the best of our knowledge,the information contained herein is accurate.However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist. Date o1 issue/Date of revision : 1011412014. Date of previous issue :91292014. Version :0.04 14 1 U- S SAFETY DATA SHEET . ro 1. Identification Product identifier Propylene Glycol Other means of Identification Catalog number 1576708 Chemical name 1,2-Propanediol Recommended use Specified quality tests and assay use only. Recommended restrictions Not for use as a drug.Not for administration to humans or animals. Manufacturer/Importer/Supplier/Distributor information Company name U.S.Pharmacopeia Address 12601 TWnbrook Parkway Rockville MD 20852-1790 US Telephone RS Technical Services 301-816-8129 Website www.usp.org E-mail RSTECH@usp.org Emergency phone number CHEMTREC within US& 1-800-424-9300 Canada CHEMTREC outside US& +1 703-527-3887 Canada 2. Hazard(s) identification Physical hazards Not classified. Health hazards Skin corrosionfirritation Category 2 Serious eye damage/eye irritation Category 2B OSHA hazard(s) Not classified. Label elements s. Signal word Warning Hazard statement Causes skin irritation.Causes eye irritation. Precautionary statement Prevention Wash thoroughly after handling.Wear protective gloves. Response If on skin:Wash with plenty of water.If skin irritation occurs:Get medical advice/attention.Take off contaminated clothing and wash before reuse.If in eyes:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing.If eye irritation persists:Get medical advice/attention. Storage Not available. Disposal Not available. Hazard(s)not otherwise Not classified. classified(HNOC) 3. Composition/information on ingredients Substance Hazardous components Chemical name Common name and synonyms CAS number % Propylene Glycol 57-55-6 100 4_ First-aid measures Inhalation Move to fresh air.Call a physician if symptoms develop or persist. Material name:Propylene Glycol usN sos us 7052 Version#:03 Revision date:10-22-2014 Issue date: 10-24-2005 1/7 Skin contact Remove contaminated clothing.Wash off with soap and plenty of water.If skin irritation occurs: Get medical advice/attention. Eye contact Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing.Get medical attention if irritation develops and persists. Ingestion Call a POISON CENTER or doctor/physician if you feel unwell.Rinse mouth. Most important Irritation of eyes,skin,and mucous membranes. symptomsleffects,acute and delayed Indication of immediate Treatment of overdose should be symptomatic and supportive. medical attention and special Administer activated charcoal as an aqueous slurry,unless contraindicated. treatment needed Perform gastric lavage. For seizures,administer a benzodiazepine intravenously,followed by phenobarbital or propofol if the seizures recur.Monitor for hypotension,dysrhythmias,respiratory depression,and need for endotracheal intubation.Evaluate for hypoglycemia,electrolyte disturbances,hypoxia. For severe metabolic acidosis,administer sodium bicarbonate intravenously. For hypotension,infuse 10-20 mUkg isotonic fluid.Administer dopamine or norepinephrine if hypotension persists. For bradycardia,administer atropine intravenously. Monitor for acidosis,hyperosmolality,and CNS changes.In symptomatic patients,monitor arterial blood gasses and ECG. Hemodialysis may be of benefit. (Meditext) General information Remove from exposure.Remove contaminated clothing.For treatment advice,seek guidance from an occupational health physician or other licensed health-care provider familiar with workplace chemical exposures.In the United States,the national poison control center phone number is 1-800-222-1222.If person is not breathing,give artificial respiration.If breathing is difficult,give oxygen if available.Persons developing serious hypersensitivity(anaphylactic) reactions must receive immediate medical attention. 5. Fire-fighting measures Suitable extinguishing media Water fog.Foam.Dry chemical powder.Carbon dioxide(CO2). Unsuitable extinguishing Do not use water jet as an extinguisher,as this will spread the fire. media Specific hazards arising from No unusual fire or explosion hazards noted. the chemical Special protective equipment Wear suitable protective equipment. and precautions for firefighters 6.Accidental release measures Personal precautions, Keep unnecessary personnel away.Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.Ensure adequate ventilation.Avoid inhalation of vapors. protective equipment and emergency procedures Wear appropriate personal protective equipment. Methods and materials for Absorb spillage with suitable absorbent material.For waste disposal,see section 13 of the SDS. containment and cleaning up Clean surface thoroughly to remove residual contamination. 7. Handling and storage Precautions for safe handling As a general rule,when handling USP Reference Standards,avoid ail contact and inhalation of dust,mists,and/or vapors associated with the material.Clean equipment and work surfaces with suitable detergent or solvent after use.After removing gloves,wash hands and other exposed skin thoroughly. Conditions for safe storage, Store in tight container as defined in the USP-NF.This material should be handled and stored per including any incompatibilities label instructions to ensure product integrity. B. Exposure controls/personal protection Occupational exposure limits US.Workplace Environmental Exposure Level(WEEL)Guides Type Value Form Material 10 mg/m3 Aerosol. Propylene Glycol(CAS TWA 57-56-6) Biological limit values No biological exposure limits noted for the ingredient(s). USP sos us Material name: Propylene Glycol 2/7 7052 Version#:03 Revision date: 10-22-2014 Issue date: 10-24-2005 Appropriate engineering Airborne exposure should be controlled primarily by engineering controls such as general dilution controls ventilation,local exhaust ventilation,or process enclosure.Local exhaust ventilation is generally preferred to general exhaust because it can control the contaminant at its source,preventing dispersion into the work area.An industrial hygiene survey involving air monitoring may be used to determine the effectiveness of engineering controls.Effectiveness of engineering controls intended for use with highly potent materials should be assessed by use of nontoxic surrogate materials.Local exhaust ventilation such as a laboratory fume hood or other vented enclosure is recommended,particularly for aerosol-generating procedures. Individual protection measures,such as personal protective equipment Eyelface protection Safety glasses with sideshields are recommended.Face shields or goggles may be required if splash potential exists or if corrosive materials are present.Approved eye protection(e.g.,bearing the ANSI Z87 or CSA stamp)is preferred.Maintain eyewash facilities in the work area. Skin protection Hand protection Chemically compatible gloves.For handling solutions,ensure that the glove material is protective against the solvent being used.Use handling practices that minimize direct hand contact. Employees who are sensitive to natural rubber(latex)should use nitrile or other synthetic nonlatex gloves.Use of powdered latex gloves should be avoided due to the risk of latex allergy. Other For handling of laboratory scale quantities,a cloth lab coat is recommended.Where significant quantities are handled,work clothing may be necessary to prevent take-home contamination. Respiratory protection Where respirators are deemed necessary to reduce or control occupational exposures,use NIOSH-approved respiratory protection and have an effective respirator program in place (applicable U.S.regulation OSHA 29 CFR 1910.134). Thermal hazards Not available. General hygiene Handle in accordance with good industrial hygiene and safety practice. considerations 9.Physical and chemical properties Appearance Clear,colorless,viscous liquid. Physical state Liquid. Form Liquid. Odor Odorless or practically odorless. Odor threshold Not available. PH Not available. Melting point/freezing point -74.2°F(-59"C) Initial boiling point and boiling 370.76°F(188.2°C) range Flash point 210.00-F(98.89°C)Closed Cup 225.00°F(107.22°C)Open Cup Flammability(solid,gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit-lower 2.6 (%) Flammability limit-upper 12.6 (%) Explosive limit-lower(%) Not available. Explosive limit-upper(%) Not available. Vapor pressure 0.017198 kPa at 25°C Vapor density 2.62(Air= 1) Relative density Not available. Solubility in water Miscible. Partition coefficient -0.92 (n-octanollwater) Auto-ignition temperature 700°F(371.11 °C) Viscosity 48.6 mPa•s at 25°C Other information Chemical family Linear aliphatic derivative. Density 1.03 g/cm3 at 25°C Dynamic viscosity 58.1 mPa.s Dynamic viscosity 68°F(20-C) temperature usP sos us Material name:Propylene Glycol 7052 Version#:03 Revision date: 10-22-2014 Issue date:10-24-2005 3/7 Heat of combustion(NFPA 20.5 kJ/g 30B) Molecular formula C3-1-18-O2 Molecularweight 76.09 g/mol Percent volatile 100% Solubility(other) Miscible with acetone and with chloroform;soluble in ether. Specific gravity 1.036 at 25'C VOC(Weight%) 100% 10.Stability and reactivity Reactivity No reactivity hazards known. Chemical stability Stable at normal conditions. Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Avoid temperatures exceeding the flash point. Incompatible materials Strong oxidizing agents.Strong acids.Reducing agents.Caustics.Aliphatic amines.Isocyanates. Acid chlorides.Acid anhydrides.Chloroformates. Hazardous decomposition Irritating and/or toxic fumes or gases.Emits toxic fumes under fire conditions. products 11.Toxicological information Information on likely routes of exposure Ingestion Based on available data,the classification criteria are not met. Inhalation Due to lack of data the classification is not possible. Skin contact Causes skin Irritation. Eye contact Causes eye irritation. Symptoms related to the Headache.Dizziness.Drowsiness.Seizures.Gastrointestinal disturbances. physical,chemical,and toxicological characteristics Delayed and immediate effects Central nervous system depression.Lactic acidosis.Coma.Cardiovascular collapse. of exposure Hypogiycemla. Medical conditions aggravated Impaired kidney function. by exposure Acute toxicity Product Species Test Results Propylene Glycol(CAS 57-55-6) Acute Dermal LD50 Rat 10 g/kg Inhalation LC50 Rabbit 317 mg/I,2 hours,aerosol Oral LD50 Dog 19 g/kg Guinea pig 18.4 g/kg Mouse 23.9 g/kg Rabbit 18 g/kg Rat 30 g/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes eye irritation. irritation Local effects Eye irritancy assay(Draize) Result: Mild irritancy;fully reversible. Species:Rabbit Test Duration:96 hours Material name:Propylene Glycol _ usP sos us 7052 Version#:03 Revision date: 10-22-2014 Issue date: 10-24-2005 4/7 Local effects Skin irritancy assay Result:Mild to moderate irritancy. Species:Human • Test Duration:7 days Skin irritancy assay(OECD 405) Result:No irritancy. Species:Rabbit Test Duration:72 hours Skin irritancy assay,occluded Result:Minimal irritancy. Species:Human Test Duration:21 days Respiratory sensitization Due to lack of data the classification is not possible. Skin sensitization Due to lack of data the classification is not possible. Germ cell mutagenicity Due to inconclusive data the classification criteria are not met. Mutagenicity Ames test Result:Negative. Cytogenic studies in mice and hamster fibroblasts Result:DNA inhibition. In vivo dominant lethal assay in male rats Result:Negative. In vivo mouse micronucleus test Result:Negative. In vivo rat bone marrow chromosomal aberration assay Result:Negative. In vivo tests in mice Result:Sperm cell chromosomal aberrations. Carcinogenicity Based on available data,the classification criteria are not met. This material is not considered to be a carcinogen by IARC,NTP,or OSHA. 2 mg Dermal carcinogenicity study,applied twice weekly Result:No increase in tumors. Species:Mouse Test Duration: 120 weeks 2500 mg/kg/day Carcinogenicity study,chronic oral exposure Result:No treatment-related increases in neoplasms. Species:Rat Test Duration:2 years Reproductive toxicity Based on available data,the classification criteria are not met. The Center for the Evaluation of Risks to Human Reproduction concluded that propylene glycol is not a reproductive or developmental toxicant in animals,and that human developmental or reproductive risks are of negligible concern. Reproductivity 0-10118 mg/kg/day Reproductivity and development studies -continuous breeding protocol,administered in drinking water Result:No adverse effects on reproduction. Species:Mouse 10000 mg/kg/day Reproductivity and development studies., administered orally during gestation. Result:No adverse effects on pup survival. Species:Mouse 1200-1550 mg/kg Reproductivity and development studies in animals Result:No significant reproductive damage. Specific target organ toxicity- Based on available data,the classification criteria are not met. single exposure Specific target organ toxicity- Based on available data,the classification criteria are not met. repeated exposure Aspiration hazard Based on available data,the classification criteria are not met. 12. Ecological information Ecotoxicity Product Species Test Results Propylene Glycol(CAS 57-55-6) Aquatic Crustacea EC50 Water flea(Daphnia magna) >10000 mg/l,48 hours Material name:Propylene Glycol LISP sosus 7052 Version#:03 Revision date: 10-22-2014 Issue date: 10-24-2005 5/7 Product Species Test Results Fish LC50 Fathead minnow(Pimephales promelas) 710 mg/l,96 hours Persistence and degradability Readily biodegradable. Bioaccumulative potential Not available. Mobility in soil Not available. Other adverse effects Not available. 13. Disposal considerations Disposal instructions Dispose in accordance with all applicable regulations.Under RCRA,it is the responsibility of the user of the product to determine,at the time of disposal,whether the product meets RCRA criteria for hazardous waste. Local disposal regulations Not available. Hazardous waste code Not available. Waste from residues/unused Dispose of in accordance with local regulations.Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner(see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue,follow label warnings even after container Is emptied. 14.Transport information DOT Not regulated as a hazardous material by DOT. IATA Not regulated as a dangerous good. Transport in bulk according to No information available. Annex II of MARPOL 73178 and the IBC Code 16. Regulatory information US federal regulations CERCLAISARA Hazardous Substances-Not applicable. All components are on the U.S.EPA TSCA Inventory List. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard-Yes Delayed Hazard-No Fire Hazard-Yes Pressure Hazard-No Reactivity Hazard-No SARA 302 Extremely No hazardous substance SARA 311/312 Hazardous No chemical Other federal regulations Safe Drinking Water Act Not regulated. (SDWA) Food and Drug Total food additive Administration(FDA) Direct food additive GRAS food additive US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986(Proposition 65):This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s)or region Inventory name On inventory(yeslno)* Australia Australian Inventory of Chemical Substances(AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Cherniral Substances in China(IECSC) Yes Material name:Propylene Glycol usPsosus 7052 Version#1:03 Revision date: 10-22-2014 Issue date:10-24-2005 6/7 Country(s)or region Inventory name On inventory(yes/no)' Europe European Inventory of Existing Commercial Chemical Yes Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances(ENCS) Yes Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States&Puerto Rico Toxic Substances Control Act(TSCA)Inventory Yes 'A"Yes"indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16.Other information, including date of preparation or last revision Issue date 10-24-2005 Revision date 10-22-2014 Version# 03 Further information Not available. Disclaimer USP Reference Standards are sold for chemical test and assay purposes only,and NOT for human consumption.The information contained herein is applicable solely to the chemical substance when used as a USP Reference Standard and does not necessarily relate to any other use of the substance described,(i.e.at different concentrations,in drug dosage forms,or in bulk quantities).USP Reference Standards are intended for use by persons having technical skill and at their own discretion and risk.This information has been developed by USP staff from sources considered reliable but has not been independently verified by the USP.Therefore,the USP Convention cannot guarantee the accuracy of the Information in these sources nor should the statements contained herein be considered an official expression.NO REPRESENTATION OR WARRANTY,EXPRESS OR IMPLIED,INCLUDING THE WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE is made with respect to the information contained herein. Revision Information Hazard(s)Identification:<INDENT>Response Physical&Chemical Properties:Multiple Properties Toxicological Information:Toxicological Property Data Material name:Propylene Glycol USP sos us 7052 Version#:03 Revision date: 10-22-2014 Issue date: 10-24-2005 7/7 �r r��t[raot..c�rar�s GHS SAFETY DATA SHEET I. PRODUCT IDENTIFICATION MANUFACTURER/SUPPLIER CHEMICAL/TRADE NAME 002FCLA Lead Acid Cell. GNB Industrial Power (as used on label) (Antimony),GNB Flooded A division of Exide Technologies Classic,Pacific Chloride,GNB, 3950 Sussex Avenue GNB Tubular,Pacific Chloride, Aurora,IL 60504-7932 Tubular,Tubular-HP,Liberator, KDZ,Titan,GNB Fusion,Exide PRODUCT ID:UN2794 Fusion,GNB Flooded Classic Platinum,Tubular-LM FOR FURTHER INFORMATION CHEMICAL FAMILY/ Electric Storage Battery Primary Contact: CLASSIFICATION Exide MSDS Support(770)421-3485 Secondary Contact: FOR EMERGENCY Joe Bolea(423)989-6377 CHEMTREC(800)424-9300 Fred Ganster(610)9214052 (703)527-3887—Collect 24-hour Emergency Response Contact Ask for Environmental Coordinator H. HAZARD IDENTIFICATION < >< > > +� � --- Signal Word: Danger Category: GHS Codes Description H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H360 May damage fertility or the unborn child. H373 May cause damage to organs through prolonged or repeated Health: STOT RE 2 exposure. Acute Tox.4 H220 Extremely flammable gas(hydrogen) Repr.IA H410 Very toxic to aquatic life with long lasting effects. Skin Corr.1A P260 Do not breathe dust/fume/gas/mist/vapors/spray. Flam.Gas 1 P301/330/331 IF SWALLOWED:rinse mouth.Do NOT induce vomiting. P303/361/353 IF ON SKIN(or hair):Remove/Take off immediately all Aquatic Chronic I contaminated clothing.Rinse skin with water/shower. Aquatic Acute 1 P304/340 IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305/351/338 IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ph sician. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking P260 Do not breathe dust/fume/gas/mist/vapors/spray P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Handling: P403 Store in well-ventilated area P405 Store locked up. P391 Collect spillage P273 Avoid release to the environment P501 Dispose of contents/container in accordance with local/regional/national/international regulation. WARNING:Batteries subjected to abusive charging at excessively high currents for prolonged periods of time without vent caps in place may create a surrounding atmosphere of the offensive strong inorganic acid mist containing sulfuric acid. Reactivity: Organic materials,chlorates,carbides, fulminates,water,powdered metals. Reacts violently with water with evolution of Z99-SDS-FLOODPBSB 2013-09 Pape 1 of 7 heat. Corrosive to metals. Strong oxidizers,hydrogen peroxide,acids. III. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient CASNumber %by Wt. Inorganic compounds of: Lead 7439-92-1 44-57 Antimony 7440-36-0 1.0 Lead Dioxide 1309-60-0 19-26 Non-Hazardous Ingredient N/A 15-22 Electrolyte sulfuric acid 7664-93-9 23-27 Note: Components are for a fully charged lead acid design. Inorganic lead and electrolyte(water and sulfuric acid solution)are the primary components of every battery manufactured by Exide Technologies or its subsidiaries. Other ingredients may be present dependent upon battery type. Polypropylene is the principal case material of automotive and commercial batteries. Electrolyte in this product is non-spill and completely absorbed within a solid matrix. IV. FIRST AID MEASURES Take proper precautions to ensure you own health and safe before attempting to rescue a victim and provide first aid. Inhalation: Electrolyte: Remove to fresh air immediately. If breathing is difficult,give oxygen. Lead compounds: Remove from exposure,gargle,wash nose and lips;consult physician. Shin Contact: Electrol e: Flush with large amounts of water for at least 15 minutes;remove contaminated clothing completely, including shoes,and do not wear again until cleaned. If acid is splashed on shoes,remove and discard if they contain leather. Lead compounds: Wash immediately with soap and water. Lead compounds are not readily absorbed through the skin. Eye Contact: Electrolyte and Lead compounds: Flush immediately with large amounts of water for at least 15 minutes;consult physician immediately. Ingestion: Electrol e: Give large quantities of water;do not induce vomiting;consult physician. Lead compounds: Consult physician immediately. V. FIREFIGHTING MEASURES Flash Point: Not Applicable Flammable Limits: LEL=4.1% (hydrogen gas in air ;UEL=74.2% Extinguishing media: CO2i foam;dry chemical Fire Fighting Procedures: Use positive pressure,self-contained breathing apparatus. Beware of acid splatter during water application and wear acid-resistant clothing,gloves,face and eye protection. If batteries are on charge,shut off power to the charging equipment,but,note that strings of series connected batteries may still pose risk of electric shock even when charging equipment is shut down. Hazardous Combustion Products: In operation,or when on charge,batteries generate and release flammable hydrogen and oxygen gases(hydrogen is highly flammable and oxygen supports combustion). They must always be assumed to contain this gas which,if ignited by burning cigarette,naked flame or spark,may cause battery explosion with dispersion of casing fragments and corrosive liquid electrolyte. Carefully follow manufacturer's instructions for installation and service. Keep away all sources of gas ignition and do not allow metallic articles to simultaneously contact the negative and positive terminals of a battery, VI. ACCIDENTAL RELEASE MEASURES Remove combustible materials and all sources of ignition. Stop flow of material and contain spill by diking with soda ash,etc. Carefully ixture is neutral then collect residue and place in a drum or other suitable container with neutralize spill with soda ash,etc. Make certain m a label specifying"contains hazardous waste"or(if uncertain call distributor regarding proper labeling procedures). Dispose of as hazardous waste. If battery is leaking,place battery in a heavy duty plastic bag. Wear acid resistant boots,face shield,chemical splash goggles and acid resistant gloves.Do not allow discharge of acid to server. Acid must be managed in accordance with approved local, state,and federal requirements. Consult state environmental agency and/or federal EPA. VH. HANDLING AND STORAGE Handling: Single batteries pose no risk of electric shock but there may be increasing risk of electric shock from strings of connected batteries exceeding three 12-volt units. Batteries are non-spillable-potential for exposure to contents only during recycling or if outer casing is cracked or damaged. Storage: Store batteries under roof in cool,dry,well-ventilated areas that are separated from incompatible materials and from activities which may create flames,sparks,or heat. Keep away from metallic objects that could bridge the terminals on a battery and create a dangerous short- circuit. Z99-SUS-FL00DPBSB 2013-09 Page 2 of 7 Charging: g g: There is a possible risk of electric shock from charging equipment and from strings of series connected batteries,whether or not being charged. Shut-off power to chargers whenever not in use and before detachment of any circuit connections. Batteries being charged will generate and release flammable hydrogen gas. Charging space should be ventilated. Keep battery vent caps in position.Prohibit smoking and avoid creation of flames ands arks nearby. Wear face and eye protection when near batteries being charged. VHI.EXPOSURE CONTROLS AND PERSONAL PROTECTION Occupational Exposure Limits(mg/rn) Ingredient: US US US Quebec Ontario EU OSHA ACGIH NIOSH PEV OEL OEL Inorganic forms of: Lead 0.05 0.05 0.05 0.05 0.05 0.15(a) Lead Dioxide 0.05(b) 0.05(b) 0.05(b) 0.05(b) 0.05(b) 0.15(a) Antimony 0.5 0.5 0.5 0.5 0.5 0.5(ad) Electrolyte(sulfuric 1 0.2 1 1 0.2 0.05(c) 'acid/water solution) NOTES: (a) as inhalable aerosol (d) based on OELs of Austria,Belgium,Denmark,France,Germany,Netherlands, (b) as inorganic lead Switzerland,&UK (c) thoracic fraction Engineering Controls(Ventilation): Store and handle in well-ventilated area. If mechanical ventilation is used,components must be acid-resistant. Handle batteries cautiously. Make certain vent caps are on securely. If battery case is damaged,avoid bodily contact with internal components. Wear protective clothing,eye and face protection,when charging or handling batteries. Follow all manufacturers' recommendations when stacking or palletizing. Do not allow metallic materials to simultaneously contact both the positive and negative terminals of the batteries. Use a battery carrier to lift a battery or place hands at opposite corners to avoid spilling acid through the vents. Avoid contact with internal components of the batteries. Hygiene Practices: Wash hands thoroughly before eating,drinking or smoking after handling batteries. Respiratory Protection(rIIOSH/MSHA approved): None required under normal conditions. When concentrations of sulfuric acid mist are known to exceed PEL,use NIOSH or MSHA-approved respiratory protection. i. Skin Protection: None required under normal conditions.If battery case is damaged,use rubber or plastic acid-resistant gloves with elbow-length gauntlet,acid-resistant apron,clothing,and boots. Eye Protection: None required under normal conditions. If battery case is damaged,chemical goggles or face shield. Other Protection: In areas where water and sulfuric acid solutions are handled in concentrations greater than l%,emergency eyewash stations and showers should be provided,with unlimited water supply. IX. PHYSICAL AND CHEMICAL PROPERTIES-ELECTROLYTE Boiling Point@760 219 to 237'F Specific Gravity @ 77T(112O=1) 1.1394 to 1.3028 mm H Melting Point Not A plicable Vapor Pressure mm H 13.5 to 20.8 %Solubility in 100 pH Greater than 1 Water Evaporation Rate Less Than 1 Vapor DensityAIR=1 Greater than i Viscosity Not applicable (Butyl acetate=l) Appearance and Sulfuric Acid: A clear liquid with a %Volatiles by Volume @70°F Not Applicable Odor Threshold sharp,penetrating,pungent odor. A battery is a manufactured article;no apparent odor. Octanol Water Not Applicable Partition Coefficient(K w Note:The properties above reflect 20-40% Sulfuric acid Z99-SDS-F1_00DI1t3SR 2013-09 Pacer.I of 7 X. STABILITY&REACTIVITY DATA Stability: Stable Conditions to Avoid: Prolonged overcharging and overheating current;sparks and other sources of ignition. Incompatibilities: (materials to avoid) Electrolyte: Contact of sulfuric acid with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents,most metals,sulfur trioxide gas,strong oxidizers,and water. Contact with metals may produce toxic sulfur dioxide fumes and may release flammable hydrogen gas. No further concern for mechanical impact Lead compounds: Avoid contact with strong acids,bases,halides,halogenates,potassium nitrate,permanganate,peroxides,nascent hydrogen,carbides,sulfides phosphorus,sulfur and reducing agents. Hazardous Decomposition Products: Electrolyte: Sulfur trioxide,carbon monoxide,sulfuric acid mist,sulfur dioxide,hydrogen sulfide,hydrogen. Lead compounds:Temperatures above the melting point are likely to produce toxic metal fume,vapor,or dust;contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas. Hazardous Polymerization: Will Not Occur XI.TOXICOLOGICAL DATA Routes of Entry: Electrolyte: Harmful by all routes of entry. Under normal conditions of use,sulfuric acid vapors and mist are not generated. Sulfuric acid vapors and mist may be generated when product is overheated,oxidized,or otherwise processed or damaged. Lead compounds:Under normal conditions of use,lead dust,vapors,and fumes are not generated. Hazardous exposure can occur only when product is heated above the melting point,oxidized or otherwise processed or damaged to create dust,vapor,or fume. Acute Toxicity: s Inhalation LDSa: Electrol e: LC50rat: 375 mg/m3;LC50: guinea pig: 510 mg/m Elemental Lead: Acute Toxicity Point Estimate=4500 ppmV(based on lead bullion) Oral LDS0: Electrolyte: rat: 2140 mg/kg Elemental lead: Acute Toxicity Estimate(ATE)=500 mg/kg body weight(based on lead bullion) Inhalation: Electrolyte: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation. Lead compounds:Inhalation of lead dust or fumes may cause irritation of upper respiratory tract and lungs. Ingestion: Electrolyte: May cause severe irritation of mouth,throat,esophagus,and stomach. Lead compounds:Acute ingestion may cause abdominal pain,nausea,vomiting,diarrhea,and severe cramping. This may lead rapidly to systemic toxicity. Acute ingestion should be treated by physician. i Skin Contact: Electrolyte: Severe irritation,burns,and ulceration. Sulfuric acid is not readily absorbed through the skin and is not a dermal sensitizer. Lead compounds:Not readily absorbed through the skin and are not dermal sensitizers. Eye Contact: Electrolyte: Severe irritation,burns,cornea damage,blindness. Lead compounds:May cause eye irritation. i Synergistic Products: Electrolyte:No known synergistic products Lead compounds: Synergistic effects have been noted with heavy metals(arsenic,cadmium,mercury), nit ooso-N- (hydroxycthyl)ethyl amine,N-(4-fluoro-4-biphenyl)acetamide,2-(nitrosoetlrylamine)ethanol,and benzo a ene. Antimony oxide: No synergistic effects found Additional Information: Medical Conditions Generally Aggravated by Exposure: Overexposure to sulfuric acid mist may cause lung damage and aggravate pulmonary conditions. Contact of electrolyte(water and sulfuric acid solution)with skin may aggravate skin diseases such as eczema and contact dermatitis. Contact of clectrolYte(water some forms and sulfuric acid solution with eyes may damage cornea and/or cause blindness. Lead and its compounds can a Z.99-SDS-PL00D11BSB 2013-09 Page 4 of 7 kidney,liver,and neurologic diseases. Additional Health Data: .All heavy metals,including the hazardous ingredients in this product,are taken into the body primarily by inhalation and ingestion. Most inhalation problems can be avoided by adequate precautions such as ventilation and respiratory protection covered in Section VIII. Follow good personal hygiene to avoid inhalation and ingestion: wash hands,face,neck and arms thoroughly before eating,smoking or leaving the work site. Keep contaminated clothing out of non-contaminated areas,or wear cover clothing when in such areas. Restrict the use and presence of food,tobacco and cosmetics to non-contaminated areas. Work clothes and work equipment used in contaminated areas must remain in designated areas and never taken home nor laundered with personal non-contaminated clothing. This product is intended for industrial use only and should be isolated from children and their environment. MI. ECOLOGICAL INFORMATION Environmental Fate: lead is very persistent in soil and sediments. No data on environmental degradation. Mobility of metallic lead between ecological compartments is slow. Bioaccumulation of lead occurs in aquatic and terrestrial animals and plants but little bioaccumulation occurs through the food chain. Most studies include lead compounds and not elemental lead. Environmental Toxicity: Aquatic Toxicity: Sulfuric acid: 24-hr LC50,freshwater fish(Brachydanio rerio): 82 mg/L 96 hr-LOEC,freshwater fish(Cyprinus carpio): 22 mg/L Lead: 48 hr LC50 modeled for aquatic invertebrates): <1 mg/L,based on lead bullion XIII. DISPOSAL INFORMATION U5 Sulfuric Acid: Neutralize as described above for a spill,collect residue and place in a container labeled as containing hazardous waste.Dispose of as a hazardous waste.If uncertain about labeling procedures,call your local battery distributor or listed contact.DO NOT FLUSH LEAD CONTAMINATED ACID TO SEWER. S ent batteries Send to secondary lead smelter for recycling recygling following applicable federal,state,and local regulations. MV. 'TRANSPORT INFORMATION GROUND—US-DOT/CAN-TDG/EU-ADR/APEC-ADR: Batteries,Wet,Filled with Acid UN 2794,8,PG III Label:"Corrosive" AIRCRAFT—ICAO-IATA: Batteries,Wet,Filled with Acid UN 2794,8 Label:"Corrosive" Reference IATA packing instructions 870 VESSEL—IMO-IMDG: Batteries,Wet,Filled with Acid UN 2794,8 Label:"Corrosive" Reference 1MDG packing instructions P801 Additional Information: - Batteries must be kept upright at all times and packaged as required to prevent short circuits. - Transport may require packaging and paperwork,including the Nature and Quantity of goods,per applicable origin/destination/customs points as-shipped. XV. REGULATORY INFORMATION United States: EPA SARA Title III Section 392 EPCRA Extremely Hazardous Substances(EHS): Sulfuric acid is a listed"Extremely Hazardous Substance"under EPCRA,with a Threshold Planning Quantity(TPQ)of 1,000 tbs. EPCRA Section 302 notification is required if 500 tbs or more of sulfuric acid is present at one site(40 CFR 370.10). An average automotive/commercial battery contains approximately 5 lbs of sulfuric acid. Contact your Exide representative for additional information. Section 304 CERCLA Hazardous Substances: Reportable Quantity(RQ)for spilled 100%sulfuric acid under CERCLA(Superfund)and EPCRA(Emergency Planning and Community Right to Know Act)is 1,000 lbs. State and local reportable quantities for spilled sulfuric acid may vary. Section 311/312 Hazard Cate orization: Z99-SDS-FL00DP6SB 2013-09 Page 5 of 7 EPCRA Section 312 Tier Two reporting is required for non-automotive batteries if sulfuric acid is present in quantities of 500 lbs or more and/or if lead is present in quantities of 10,000 lbs or more. Section 313 EPCRA Toxic Substances: Supplier Notification: This product contains a toxic chemical or chemicals subject to the reporting requirements of section 313 of(Title)III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. Chemical CAS Percent by Weight Lead(Pb) 7439-92-1 44-57 Electrolyte:Sulfuric Acid(H2SO4) 7664-93-9 23-27 Antimony(Sb) 7440-36-0 1.0 Lead Dioxide(PbO2) 1309-60-0 19-26 If you distribute this product to other manufacturers in SIC Codes 20 through 39,this information must be provided with the first shipment of each calendar year. Note:The Section 313 supplier notification requirement does not apply to batteries that are"consumer products". TSCA:Each ingredient chemical listed in Section III of this SDS is also listed on the TSCA Registry. OSHA: Considered hazardous under Hazard Communication Act(29CFR1910.1200) RCRA:Spent lead-acid batteries are not regulated as hazardous waste when recycled. Spilled sulfuric acid is a characteristic hazardous waste;EPA hazardous waste number D002(corosivity). CAA:Exide Technologies supports preventative actions concerning ozone depletion in the atmosphere due to emissions of CFC's and other ozone depleting chemicals(ODC's),defined by the USEPA as Class I substances. Pursuant to Section 611 of the Clean Air Act Amendments(CAAA)of 1990,finalized on January 19, 1993,Exide established a policy to eliminate the use of Class I ODC's prior to the May 15, 1993 deadline. NFPA Hazard Rating for sulfuric acid: Flammability(Red) = 0 Health(Blue) = 3 Reactivity(Yellow) = 2 US State Identification Notifications/Warning Notifications &Warnings: California California Proposition 65 "WARNING:.This product contains lead,a chemical known to the State of California to cause cancer,or birth defects or other reproductive harm." Battery posts,terminals,and related accessories contain lead and lead compounds, chemicals known to the State of California to cause cancer and reproductive harm. Batteries also contain other chemicals known to the State of California to cause cancer. Wash hands after handling. The following chemicals identified to exist in the finished product as distributed into commerce are known to the State of California to cause cancer,birth defects or to cause reproductive harm: 1. Strong inorganic acid mists including sulfuric acid:CAS#: NA;23-27%wt 2. Lead and lead compounds:CASH.7439-92-1;63-83%wt. Consumer Product Volatile This product is not regulated as a consumer product for purposes of CARB/OTC Organic Compound Emissions VOC Regulations,as sold for the intended purpose and into the industrial/commercial supplychain. Country/Organization Identification Notifications/Warning Canada All chemical substances in this product are listed This product has been classified in accordance on the CEPA DSL/NDSL or are exempt from list with the hazard criteria of the Controlled requirements. Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. Refer to the Controlled Products Regulations for product labeling requirements. NPRI and Ontario Regulation 127/01 This product contains the following chemicals subject to the reporting requirements of Canada NPRI and/or Ont.Reg. 127/01: Chemical _CAS# %wt Lead 7439-92-1 63-83 Sulfuric acid 7664-93-9 23-27 Toxic Substances List Lead Z.99-SDS-1L00DPBSB 2013-09 Page 6 of 7 EU European Inventory of Existing Commercial All ingredients remaining in the finished product Chemical Substances(EINECS): as distributed into commerce are exempt from,or included on,the European Inventory of Existing Commercial Chemical Substances. XVI. OTHER INFORMATION DATE ISSUED: Se tember l 1,2013 OTHER INFORMATION: Distribution into Quebec to follow Canadian Controlled Product Regulations(CPR)24(1)and 24(2). Distribution into the EU to follow applicable Directives to the Use, Import/Export of the product as-sold. SOURCES OF INFORMATION: International Agency for Research on Cancer(1987),IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Overall Evaluations of Carcinogenicity:An updating of IARC Monographs Volumes 142,Supplement 7,Lyon,France. Ontario Ministry of Labor Regulation 654/86.Regulations Respecting Exposure to Chemical or Biological Agents. PREPARED BY: GNB INDUSTRIAL POWER A DIVISION OF EXIDE TECHNOLOGIES 3950 SUSSEX AVENUE AURORA,IL 60504-7932 VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROXIMATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET,AND VENDOR SHALL NOT BE LIABLE FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF REASONABLE PROCEDURES ARE FOLLOWED. ALL PERSONS USING THIS PRODUCT,ALL PERSONS WORKING IN AN AREA WHERE THIS PRODUCT IS USED,AND ALL PERSONS HANDLING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS DATA SHEET. THIS INFORMATION SHOULD BE EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN CONTACT WITH THE PRODUCT. WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF,EXIDE TECHNOLOGIES MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,APPLICABLE,AND SUITABLE FOR THEIR PARTICULAR CIRCUMSTANCES. ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT I I Z99-SD S-F LOO D P B S I 12013-09 Page 7 01-7