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Home My WebLink About295 Rye Street - Tier II Reports - Fire (2) SOUTH WINDSOR DIVISION - P:860-290-2900 ! I 295 RYE STREET F:860-291-0263 - ® SOUTH WINDSOR,CT 06074 E:realestate.swn@aldi.us February 24, 2014 South Windsor LEPC,CT Attention:Matthew Galligann Fire Headquarters 1540 Sullivan Avenue South Windsor,CT 06074 Dear Mr.Galligann; Enclosed is the 2013 Tier II Form,for our facility in South Windsor,Connecticut. Tier If forms will also be submitted to the State Emergency Response Commission,State Emergency Response Commission- Emergency Response and Spill Prevention,and the South Windsor Volunteer Fire Department.If you have any further questions,please contact me at(860)290-2900 extension 117. Sincerely, --- Eric Wemitt Director of Warehousing Aldi,Inc.,South Windsor Division SWN,WAREHOUSE,DBattles,per:24 February 2014 Page 1/1 PAPersonal\Warehouse\Eric Correspondence\Tier 11 Letters 2014\SW LEPC.doc Tier Two Reporting Period: January 1 to December 31,2013 Emergency and Hazardous Chemical Inventory Page 1 Specific Information by Chemical Printed: February 24,2014 Facility Name: ALDI Inc. -South Windsor Division FACILITY IDENTIFICATION: ALDI Inc.-South Windsor Division Dept: 295 Rye Street South Windsor,CT 06074 USA County: Hartford Latitude:41.859994 Longitude:-72.689956 Facility Phone:860-819-1629 [ ]All facility information(not including chemical information)is identical to last year's submission IDENTIFICATION NUMBERS: Dun&Bradstreet:00-694-0423(Grocery Warehouse Distribution) NAICS:445110(Grocery Warehouse Distribution) Is the facility manned? [x]Manned [ ]Unmanned Maximum No.of Occupants: 127 REGULATORY INFORMATION: Subject to Emergency Planning under Section 302 of EPCRA(40 CFR part 355)? [ ]Yes [x]No Subject to Chem.Accident Prevention under Section 112(r)of CAA(40 CFR part 68, Risk Mgmt. Pgm.)?[ ]Yes [x]No CONTACT INFORMATION: Persohn,Bruce Title: Vice President Contact Type 1: Owner/Operator _— -- Address- 2G-5BXe-Street. Sou%—W1n_dsQC CT_ 60 074 _ USA Phones:Work:860-290-2900*125 Email:Bruce.Persohn@aldi.us Wemitt,Eric Title: Director of Warehouse Contact Type 1: Emergency Contact Contact Type 2: Emergency Contact Contact Type 3: Tier 11 Information Contact Address: 295 Rye Street, South Windsor, CT,06074 USA Phones: Mobile-Cell:860-819-1629 24-hour:860-819-1629 Work:860-290-2900*117 Email:Eric.Wemitt@aldi.us Supervisor,Warehouse Title: Warehouse Supervisor Contact Type 1: Emergency Contact Contact Type 2:Other Address: 295 Rye Street,South Windsor, CT,06074 USA Phones:24-hour:860-819-1632 Work:860-290-2900*132 Email:swn@aldi.us Black Horse Carriers,Gary Andrews Title: Terminal Manager Contact Type 1: Emergency Contact Contact Type 2:Other Address: 295 Rye Street,South Windsor, CT, 06074 USA Phones:24-hour:860-734-6581 Work:860-290-2900*211 Tier Two Reporting Period: January 1 to December 31,2013 Emergency and Hazardous Chemical Inventory Page 2 Specific Information by Chemical Printed: February 24,2014 Facility Name: ALDI Inc. -South Windsor Division Email:Gary.Andrews@blackhorsecarriers.com Rosa, Pedro Title: Mechanic Contact Type 1: Emergency Contact Address: 295 Rye Street,South Windsor, CT,06074 USA Phones:24-hour:860-983-4316 Work:860-290-2900*135 Email:swn@aldi.us CHEMICAL DESCRIPTIONS: ----------------------------------------------------------- CHEM NAME:Ammonia (Anhydrous) CAS:7664-41-7 [ ] Identical to previous year [ ]TRADE SECRET [x] Pure [ ] Mix [ ]Solid [x]Liquid [x]Gas [x]EHS CHEMICAL COMPONENTS: [x]EHS,CAS:7664-41-7,Component:Ammonia(anhydrous), 100%Wt,Max Amt code:05(5,000-9,999 pounds) PHYSICAL&HEALTH HAZARDS: [ ] Fire [x]Sudden Release of Pressure [ ] Reactivity [x] Immediate(acute) [ ]Delayed(chronic) INVENTORY: [ ] Below Reporting Thresholds Max Amt:9900 pounds Max Daily Amt code:05(5,000-9,999 pounds) Avg Amt:9900 pounds Avg Daily Amt code:05(5,000-9,999 pounds) Max quantity in largest container:9900 pounds No.of days on-site:365 STORAGE CODES&STORAGE LOCATIONS: [ ]Confidential Container Type:Tank inside building Pressure: Less than ambient pressure Temp:Less than ambient temp../not cryog Location:Closed system ammonia compressor high side in ammonia room Amount:9900 pounds Container Type:Tank inside building Pressure: Less than ambient pressure Temp:Less than ambient temp./not cryog Location:Closed system high pressure receiver tanks in ammonia room Amount:9900 pounds Container Type:Tank inside building Pressure: Greater than ambient pressure Temp: Less than ambient temp./not cryog Location:Closed system ammonia compressor low side in ammonia room Amount:9900 pounds Container Type:Tank inside building Pressure: Greater than ambient pressure Temp: Less than ambient temp./not cryog Location:Closed system low pressure receiver tanks in ammonia room Amount:9900 pounds Container Type:Tank inside building Pressure: Greater than ambient pressure Temp: Less than ambient temp./not cryog Location:Closed system ammonia evaporator penthouses on west rooftop Amount:9900 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [ ]Trucks [ ]Tank Trucks [ ]Rail Car [ ]Tank Car [ ]Pipeline [ )Barge [x]Other(Specify) Specify other:Ammonia is not shipped out of the facility Frequency of Shipment:0 per Maximum capacity per single vessel:0 Max Shipment Qty(lbs):0 Ave Qty(lbs): 0 Physical State in Transit: Comments(please provide both the primary and alternate routes of travel):Ammonia is used as the refrigerant for our refrigeration system. The chemical is never shipped to any of our store locations. Carrier:Not Applicable Tier Two Reporting Period: January 1 to December 31,2013 Emergency and Hazardous Chemical Inventory Page 3 Specific Information by Chemical Printed:February 24,2014 Facility Name: ALDI Inc. -South Windsor Division ----------------------------------------------------------- CHEM NAME: Lead(Lead Acid Battery) CAS:7439-92-1 [ ] Identical to previous year [ ]TRADE SECRET [ ] Pure [x]Mix [x]Solid [ J Liquid [ ]Gas [x]EHS CHEMICAL COMPONENTS: [x] EHS,CAS:7439-92-1,Component: Lead(Lead-Acid Battery),60%Wt,Max Amt code: 10(100,000-499,999 pounds) [x]EHS,CAS:7664-93-9,Component:Sulfuric Acid(Lead-Acid Battery),30%Wt,Max Amt code:08(50,000-74,999 pounds) PHYSICAL&HEALTH HAZARDS: [ ]Fire [ ]Sudden Release of Pressure [ ]Reactivity [x]Immediate(acute) [x]Delayed(chronic) INVENTORY: [ ] Below Reporting Thresholds Max Amt: 158960 pounds Max Daily Amt code: 10(100,000-499,999 pounds) Avg Amt: 158960 pounds Avg Daily Amt code: 10(100,000-499,999 pounds) Max quantity in largest container: 1800 pounds No.of days on-site:365 STORAGE CODES&STORAGE LOCATIONS: [ ]Confidential Container Type:Battery Pressure: Ambient pressure Temp:Ambient temperature Location: Present in Lead-Acid equipment batteries Amount: 158960 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [x]Trucks [ ]Tank Trucks [ ]Rail Car [ J Tank Car [ ]Pipeline [ ]Barge [ ]Other(Specify) Specify other: Frequency of Shipment: 14 per Week Maximum capacity per single vessel:26 Max Shipment Qty(lbs): 1600 Ave Qty(lbs):400 Physical State in Transit:Solid Comments(please provide both the primary and alternate routes o trave : e s ip pallet jacks w is are powere " y e6 a -acid----"-- batteries to our retail stores throughout Connecticut, Massachusetts,Rhode Island, New York, New Hampshire,and Vermont. On average two pieces of equipment are shipped to our stores daily. The majority of travel is on 184, 1291. 191, 190, 195,and route 5. Once off of the major highways and interstates local roads are used to deliver to our stores which currently total 21. All equipment is delivered by Black Horse Carriers Carrier: Black Horse Carriers ---------------------------------------------------------- CHEM NAME: Sulfuric Acid CAS:7664-93-9 [ ] Identical to previous year [ ]TRADE SECRET [ ] Pure [x] Mix [ ]Solid [x]Liquid [ ]Gas [x] EH$ CHEMICAL COMPONENTS: [x] EHS,CAS:7664-93-9, Component:Sulfuric Acid(Lead-Acid Battery),30%Wt, Max Amt code:08(50,000-74,999 pounds) [x]EHS,CAS:7439-92-1,Component: Lead (Lead-Acid Battery),60%Wt, Max Amt code: 10(100,000-499,999 pounds) PHYSICAL&HEALTH HAZARDS: [ ] Fire [ ]Sudden Release of Pressure [x]Reactivity [x] Immediate(acute) [x]Delayed (chronic) INVENTORY: [ ] Below Reporting Thresholds Max Amt:67672 pounds Max Daily Amt code:08 (50,000-74,999 pounds) Tier Two Reporting Period: January 1 to December 31,2013 Emergency and Hazardous Chemical Inventory Page 4 Specific Information by Chemical Printed:February 24,2014 Facility Name: ALDI Inc. -South Windsor Division Avg Amt:67672 pounds Avg Daily Amt code:08(50,000-74,999 pounds) Max quantity in largest container:791 pounds No.of days on-site:365 STORAGE CODES&STORAGE LOCATIONS: [ ]Confidential Container Type:Battery Pressure: Ambient pressure Temp:Ambient temperature Location: Present in Lead-Acid equipment batteries Amount:67672 pounds CHEMICALS IN INVENTORY STATE FIELDS: Connecticut requests the following: Mode of Shipment: [x]Trucks [ ]Tank Trucks [ ]Rail Car [ ]Tank Car [ ]Pipeline [ j Barge [ ]Other(Specify) Specify other: Frequency of Shipment: 14 per Week Maximum capacity per single vessel:26 Max Shipment Qty(lbs):656 Ave Qty(lbs): 164 Physical State in Transit:Liquid Comments(please provide both the primary and alternate routes of travel):We ship pallet jacks which are powered by lead-acid batteries to our retail stores throughout Connecticut,Massachusetts,Rhode Island,New York, New Hampshire,and Vermont. On average two pieces of equipment are shipped to our stores daily. The majority of travel is on 184, 1291. 191, 190, 195,and route 5. Once off of the major highways and interstates local roads are used to deliver to our stores which currently total 21. All equipment is delivered by Black Horse Carriers Carrier: Black Horse Carriers ------------------------------------------------------------ FACILITY STATE FIELDS: No additional information is required by Connecticut STATE/LOCAL FEES: None. [ ] I have attached a site plan --- [ ] I have attached a description of dikes and other safeguard measures Certification(Read and sign after completing all sections) I certify under penalty of law that I have personally examined and am familiar with the information submitted in pages one through 4, and that based on my inquiry of those individuals responsible for obtaining this information,I believe that the sub tbTiS't ,es ate,and complete. Eric Wemitt �_ 2/24/2014 Name and official title of owner/operator r'� OR owner/operator's authorized representative Signature Date signed iviaie ai b et a s -6 meet g - Ammonia AIrga Section 1. Chemical product and company identification Product name : Ammonia Supplier : AIRGAS INC., on behalf of its subsidiaries 259_North Radnor-Chester Road Suite 100 Radnor,PA 19087-5283 1-610-687-5253 Product use : Synthetic/Analytical chemistry. Synonym : anhydrous ammonia;am-fol;ammonia anhydrous;ammoniac(french);ammoniaea (Italian);ammonia gas;ammoniale(german);amoniak(polish);nitro-sil;r717;spirit of hartshom; MSDS# 001003 Date of : 811212008. Preparati on]Revision .In case of emergency . : 1-866-734-3438 . Section 2. Hazards identification Physical state : Gas.[COLORLESS GAS OR COLD, MOBILE LIQUID WITH A STRONG, PENETRATING'ODOR) Emergency overview : DANGER! CAUSES SEVERE RESPIRATORY TRACT, EYE AND SKIN BURNS. HARMFUL IF INHALED. CAN CAUSE TARGET ORGAN DAMAGE- CONTENTS UNDER PRESSURE. Do not puncture or incinerate container. Do not breathe gas. Do not get on skin.or .clothing_ Can cause target organ damage.. Use only with adequate ventilation. Keep container .closed. Do not get in eyes, on skin or on.clothing. Avoid breathing gas. Wash thoroughly^cf'cer-haridiing. Contact with rapidly expanding gases can cause frostbite_ Target organs Causes damage to the following organs:eyes. May cause damage to the following organs: lungs,upper respiratory tract, skin,eye,lens or comea. . Routes of entry. _ Inhalation Dermal Eyes Potential acute health effects Eyes Severely corrosive to.the eyes_ .Causes severe burns. Contact with rapidly expanding gas may cause burns�r fmstbitP Skin :. Severely corrosive to the skin.. Causes severe burns. Contact with rapidly expanding gas may cause burns or frostbite. Inhalation : Toxic by inhalation_ Severely corrosive to the respiratory system. Ingestion. Ingestion is not a normal route of exposure for gases Potential chronic health CARCINOGENIC EFFECTS: Not available_ effects MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available_ Medical conditions Pre-existing disorders involving any target organs mentioned in this MSDS as being at aggravated by over- risk may be aggravated by over-exposure to this product. exposure See toxicological information (section 11) Page: 119 Ammonia Section 3. Composition, information on Ingredients Name CAS number %Volume Exposure limits Ammonia 766"1-7 100 ACGIH TLV(United States,1/2007). STEL-24 m9hn315 minute(s). STEL:35 ppm 15 minute(s). TWA 17 mg/W 8 hour(s)_ TWA 25 ppm 8 hour(s). N1OSH REL(-United States,1212001). STEL:27 mg/m315 minute(s). STEL_35 ppm 15 minute(s):. TWA 18 mg/m310 hour(s). TWA 25 ppm 10 hour(s). OSHA PEL(United States,11/200.6). TWA:35 mg/m3 8 hour(s). TWA:50 ppm 8 hour(s)_ OSHA PEL 1989 (United States,311989). STEL:27 mg/m315 minute(s). STEL:35 ppm 15 minute(s)_ Section 4. First aid measures No action shall be taken involving any personal risk or without suitable training.lf it is suspected that fumes.are still present; the rescuer should wear an appropriate mask or self-contained breathing apparatus.it may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes,occasionally lifting the upper and lower eyelids_ Get medical attention immediately. Skin contact : in case of contact,immediately flush skin with plenty of water for at!:east 15 minutes While removing contaminated clothing and shoes. Wash clothing before*reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Ffostbite Try to warm up the frozen tissues and seek.mediical attention. inhalation : Move exposed.person to fresh air. if not breathing,if breathing is irregular or if respiratory arrest occurs,provide artificial respiration.or oxygen by-trained personnel. Loosen tight clothing such as a collar,-tie, belt or waistband. Get medical attention immediately. ingestion : As this product is a gas, refer to the inhalation section. [S�ectio�n _5_ Fire fighting measures - 'Flammability of the product Non-flammable. Autti49R4e . . Flammable limits : Lower. 16% Upper:28% Products of combustion : Decomposition products may include the following materials: nitrogen oxides Fire hazards in the presence : Extremely flammable in the presence of the following materials or conditions: oxidizing. of various substances materials- Fire-fighting media and : Use an extinguishing agent suitable for the surrounding fire. instructions Apply water from a safe distance to cool container and protect surrounding area. If involved in fire, shut off flow immediately if it can be done without risk_ . Contains gas under pressure. In a fire or if heated, a pressure increase will occur and the container may burst or explode. Special protective Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA)with a full face=piece operated in positive pressure mode. Page: 2/9 Ammonia • S ection 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment(section 8). Shut off gas supply if this can be done safely. isolate area until gas has dispersed. Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and sewers. Methods for cleaning up : immediately contact emergency personnel. Stop leak if without risk. Note:see section 1 for emergency contact information and section 13 for waste disposal. Section 7. Handling and storage Handling.. : Use only with adequate ventilation.Wash thoroughly after handling.High pressure gas. Do not:puncture or incinerate container Use equipment rated for cylinder pressure. Close valve after each use and when empty.Do not get in eyes,on skin or:on clothing. Keep container closed:Do not get on skin.or clothing. Protect cylinders from physical damage;do not drag,roll,slide, or drop. Use a suitable hand truck for cylinder movement_ Storage Cylinders should be stored upright,.with valve protection cap in place,and firmly secured to prevent falling or being knocked over. Cylinder temperatures.should not exceed 52°C (125'F)_ Section S. Exposure controls/personal protection Engineering controls . Use only with adequate ventilation_ Use process enclosures,local exhaust ventilation or other engineering controls to keep worker exposure.to airborne contaminants below any recommended or statutory. limits. Personal protection Eyes Safety eyewear complying with an approved standard should be used when.a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Skin Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory :. Use a properly fatted, air-purifying or air-fed respirator complying with.an approved standard if a risk assessment indicates this is necessary. . Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The.applicable standards are(US)29 CFR 1910.1.34 and (Canada)Z94.4-93 Hands _ : .Chemical-resistant,-impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a_risk assessment indicatesthis is necessary. Personal protection it case Self-Contained breathing apparatus(SCBA) should be used to avoid inhalation of the of a large spill product_ Full chemical-resistant suit and self-contained breathing apparatus should be worn only by trained and authorized persons. Product name ammonia, anhydrous ACGIH TLV (United States, 1/2007). STEL: 24 mg/m3 15 minute(s). STEL 35 ppm 15 minute(s). TWA: 1.7 mg/m3 8 hour(s). TWA:25 ppm 8 hour(s). NIOSH REL (United States, 12/2001).. STEL: 27 mg/m' 15 minute(s). STEL: 35 ppm 15 minute(s). TWA: 18 mg/m' 10 hour(s). TWA: 25 ppm 10 hour(s). OSHA PEL (United States, 1112006)- TWA: 35 mg/m3 8 hour(s). -- _= TWA_50pppm 8 hour(s). 6SHA-PEt 1g.'WjUnited tales 31198 ). STEL: 27 mg/ml 15 minute(s). o::i€d Page:319 Ammonia • STEL 35 ppm 15 minute(s). Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Molecular weight 17.04 9/mole Molecular formula H3-N Boiling/condensation point -33.3'C (27.9-F) Melting/freezing point -77.8'C(108'F) Critical temperature 132.4"C(270.3°F) Vapor pressure 114.1 (prig) Vapor density : 0.6 (Air= 1) Specific Volume (ft 3/Ib) :. 22.7273 Gas.Density(Ibfft' 0.044 Section 10. Stability and reactivity Stability and reactivity : The product is stable. Incompatibility with various : incompatible with oxygen and peroxides.Incompatible with some strong acids. substances Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products I not be produced. Hazardous polymerization Under normal conditions of storage and use,hazardous polymerization will not occur. Section 1l.. Toxicological information. Toxictly data Product/ingredient name Result Species Bose Exposure ammonia,anhydrous LC50 Inhalation Mouse 4230 ppm 1 hours Gas. LC50 Inhalation Rat. 2000.ppm. 1 hours Gas, IDLH 300 pprn Chronic effects on humans Causes damage to the following organs:eyes. :May cause damage to the following organs: Lungs;upper respiratory tract,skin,eye,lens or cornea. Other toxic effects an : Hazardous by the following.route of exposure: of skin contact(corrosive), of eye contact humans (corrosive)-,of inhalation (lung corrosive). Specific effects Carcinogenic effects : No-known significant effects or critical hazards- Mutagenic effects : No known significant effects or critical hazards. Reproduction toxicity No known significant effects or critical hazards. [Section 12. Ecological information Ec.otoxicity data Aquatic ecotoxicit Productfingredient name Test Result Species Exposure ammonia, anhydrous Acute LC50 2.6 to 2.88 Fish- Red shiner, 96 hours mg/L Fresh water Rainbow dace- Cyprinella lutrensis Acute LC50 2.33 to 2.53 Fish- Red shiner, 96 hours rng/L Fresh water Rainbow dace- Cyprinella Acute LC50 1.17 mg/L �s ueg11----9�iouis Page:419 Ammonia ' Fresh water Lepomis mac rochirus Acute LC50 0.88 mg1L Fish- 96 hours Fresh water Orangethroat darter- Etheostoma spectabile Acute LC50 0.74 mg/L Fish- 96 hours Fresh water Orangethroat darter_ Etheostoma spectabile - Acute LC50 38..01 to Fish-Inland• 96-hours 54.9 ppm Marine water silverside- Menidia beryllina LARVAE-.2 weeks Acute LC50 27.06 to Fish-Inland 9.6 hours 35.98 ppm Marine water- silverside- Menidia beryllina -LARVAE-1 weeks Acute LC50 20.32 to Fish-Inland 96 hours 26.28 ppm Marine water silverside- Menidia beryllina -LARVAE-1 weeks Acute LC50 3.55-to 4.24 Fish-Inland 96 hours ppm Marine water silverside= Menidia beryllina -LARVAE-1 weeks - Acute LC50 2.01 to 2.64 Fish-Inland 96 hours ppm Marine water silverside- v'l^cn a be:,;ll:nz -1 weeks Acute LC50 4180 to Daphnia-Water 48 hours 6030 ug/L Fresh water flea-Daphnia magna Acute LC50 4.130 to Daphnia-Water 48 hours 5100.ug/L Fresh water flea-Daphnia pulex Acute LC50 2710 to Daphnia-Water 48 hours 8670 ug/L Fresh water flea- Ceriodaphnia reticulata. Acute LC50 2500 ug/L. Crustaceans- 48 hours Fresh water Aquatic sowbug- Asellus aquaticus 8to10mm Acute LC50 14530 to Crustaceans- 48 hours 20600 ug/L Marine water San paulo shrimp - Penaeus paulensis-Zoea Acute LC50 11310 to Crustaceans- 48 hours 15480 ug/L Marine water Kuruma shrimp- . Penaeus japonicus-Zoea - Acute LC50 8590 to Crustaceans- 48 hours 9640 ug/L Marine water San paulo shrimp Penaeus - - h:id !A Page_5/9 Ammonia Acute LC50 5210 to Crustaceans- 48 hours 6040 ug/L Marine water Redtail prawn- Penaeus penicillatus- Zoea Acute LC50 31260 ug/L Crustaceans- 48 hours Marine water Redtail prawn- Penaeus penicillatus-3.58 to4.75cm-0.4 to 0.69 g Acute LC50 25400 ug/L Daphnia-Water 48 hours Fresh water flea-Daphnia magna Acute LC50 4980 to Crustaceans- 48 hours 9070 ug/L Marine water Kuruma shrimp- Penaeus japonicus- Nauplh Acute LC50 22790 to Crustaceans- 48 hours 32200 ug/L Marine water Kuruma shrimp- Penaeus japonicus-Post- larvae Acute LC50 16010 to. Crustaceans- 48 hours. 21460 ug/L Marine water Kuruma shrimp- Penaeus japonicus-Mysis Acute LC50 14860 to . Crustaceans- 48 hours 19140 ug/L Marine water Redtail-prawn- Penaeus penicillatus- Zoea Products of degradation : Products of degradation nitrogen oxides(NO, NOz etc.). Environmental fate a Not available. Environmental hazards : No known significant effects or critical hazards. Toxicity to the.environment Not available. ]Section 13_ Disposal considerations Product removed.from the"cylinder must be disposed of in accordance with appropriate Federal,State,local dispose of locally. Section 14- Transport information Regulatory UN nu.mb.er. Praper shipping Class Packing group Label Additional information narn-e information DOT Classification UN1005 AMMONIA, 2.2 Not applicable(gas)- Reportable. ANHYDROUS uanti 100 lbs. (45.4 kg) Limited quantity Yes. Packaging instruction Passenger aircraft tiUiii< i 'j - Page- 619 ' Ammonia limitation: Forbidden. Cargo aircraft Quantity limitation: Forbidden. S ecial provisions 4,T50,•N87 TDG Classification UN1005 AMMONIA, 2.2 Not applicable (gas). Explosive ANHYDROUS;OR Limit and ANHYDROUS Limited AMMONIA Quanft Index 0 ERAP Index 3000 Passenger Carrvio ship Index Forbidden Passenger Canvina Road or Rail Index Forbidden P3'i�zicc UNIC05 AMMONIA, 2.2 ;Not applicable (gas). - Classification ANHYDROUS Section.15. Regulatory information United States U.S. Federal regulations united States inventory(TSCA 8b).This material is listed or exempted- SARA 302/ ex reme y azar. ous substances. SARA 302/304 emergeney planning and notification: ammonia, anhydrous SARA 302/3041311/312 hazardous chemicals: ammonia, anhydrous SARA 3111312 MSDS distribution- chemical inventory-hazard identification: ammonia, anhydrous: Sudden release of pressure, Immediate (acute) health hazard Clean Water Act (CWA)307: No products were found.. Clean Water Act(CWA)311: ammonia, anhydrous Clean Air Act (CAA) 112 accidental release prevention: ammonia, anhydrous Clean Air Act (CAA).112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: ammonia, anhydrous SARA 313 Product name CAS number -Concentration Form FZ - Reporting Ammonia 7664-41-7 100 requirements Supplier notification : Ammonia 7664-41-7 100 . --Sf�f�ik�l-3.rx�xtiatit>�=r�s{-��-be_d �e-herf:fror-r-s_#Ire Iv7S�35:-anrl-any-�-o:py±:nc�:an�t_r�da�tri:bction of.tkre�Ul_S:QS�h_al1 -- - --- includec�attached to c es� FFre fNFSBS Bui d t.i - Page_ 719. Ammonia State regulations Connecticut Carcinogen Reporting:This material is not listed. Connecticut Hazardous Material Survey:This material is not listed. Florida substances:This material is not listed. Illinois Chemical Safety Act:This material is not listed. sclosure to Employee Act:This material is not listed- Illinois Toxic Substances Di Louisiana Reporting:This material is not listed. Louisiana Spill:This material is not listed. Massachusetts Spill:This material is not listed. Massachusetts Substances:This material is listed. Michigan Critical Material:This material is not listed_ Minnesota Hazardous Substances:This material is not listed. New Jersey Hazardous Substances:This material is listed. New Jersey Spill:This material is not listed. New Jersey Toxic Catastrophe Prevention Act:This material is not_listed: New York Acutely Hazardous Substances:This material is material sted.is listed- New York Toxic Chemical Release Reporting: This Pennsylvania RTK Hazardous Substances:This material is listed: Rhode Island Hazardous Substances:This material is not listed. Canaria anadIS{Canada) : Class A:Compressed gas. Class B-1: Flammable gas. toxic Class D-1A:Material causing immediate and serious toxic effects(Very ) Class E:Corrosive-material CEPA Toxic substances:This material'is not listed. Canadian ARET:This material is not fisted. Canadian NPRI:This material is listed. Alberta.Designated Substances:This material is notlisted. Ontario Designated Substances:Thismater'ial is not listed. Quebec Designated Substances:This material is not listed. . Fection 16. Other informat-� ion United- States • CAUSES SEVERE RESPIRATORY TRACT,EYE AND SKIN BURNS Label requirements HARMFUL iF INHALED_ CAN CAUSE TARGET ORGAN DAMAGE. CONTENTS UNDER PRESSURE. Canada Label requirements .Class A: compressed gas. Class B-1: Flammable gas: Class D-1 A: MaTerral-cdastnQ immedrate and seriousaoxic effects (Very toxic}. Class E: Corrosive material Hazardous Material 3 information System (U.S.n,) . 1 y x`ry''°3�«• ..^�_,, ,,��'a sue;:-� .. - O National Fire Pr.otectio.l = Flammability Association ,U.S-A.} 0 insiability Special Page:8/9 Ammonia Notice to reader . knowledge,the information contained herein is accurate.However,neither the above-named e best of our Toth completeness of the supplier,.nor any of its subsidiaries,assumes any liability whatsoe ver for the accuracy or comp information contained herein. Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution_Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist_ Page_9/9 MATERIAL SAFETY DATA SHEET Form#s5302oRevised;61I&W Su W/o Chemical Trade Name fas used on label)• Chemical Famfly/Classltication• Lead-Acid Battery Electric Storage Battery Manufacturer's Name/Addtiess: Telephone: E'ji For information and emergencies,contact EnerSys' P.O.Box 14145 Reeadadinngg,PA Environmental,Health&Safety Dept.at 610-209-1996 l PA le Road 24-Hour Ernereencw Response Contact: 19612-4145 CHI M IREC DOMFiS itgC; 800-424-9300 CHEMTREC II I,;703-527-3877 Components AirExposttreLimits(ugi CAS Number Approxynate%by OSHA. ACGIH NXpgg Wt.Or Vol. Inorganic Lead Compound: Lead 7439-92-1 60 50 l50 I00 *Antimony 7440-36-0 2 500 500 *Arsenic 7440-3&2 0,2 10 200 *Calcium 7440 70-2 0.2 — — *Tin 7440-31-5 0.2 2000 2000 — Electrolytts(Sulfuric Add) 7664-93-9 1 10-30 1000. 1000 1000. Case Material: 5-10 NIA N/A 100 Polypropylene 9003 07-0 Polystyrene 9003-53-6 Styrene Acrylonitrile 9003-54-7 Acrylonitrile Butadiene Styrene 9W3-56.9 Styrene Butadiene 9003 55 8 Polyvinylchioride 9002-86-2 Polycarbonate,Hard Rubber*Polyethylene _ Other: Silicon Dioxide(Gel batteries only) 7631-86-9 20-40 N/A N/A N/A Sheet Molding Compound — N/A N/A N/A (Glass reinforced polyester) Inorganic lead and electrolyte(sulfuric acid)are the primary components of every battery manufactured by EnerSys. Other ingredients may be present dependent upon battery type. Contact your Ene.Sys representative for additonat'infonin n. 11 IN: Electrolyte: Boiling Point: 203-240'F Specific Gravity- 20=1): I.215 to 1.350 Melting Point: N/A Vapor Pressure(mm Mg).- 16 Solubility.inWater: I0090. Vapor Density(AIR=1): Greater than I Epaporation:Rate: .(Butyl.Acetate=.1) I=than 1 %Volatile by Weight: N/AAppearance and Odor: Manufactured article;no apparent odor. Electrolyte is a clear liquid with a sharp,penetrating,pungent odor. Flash Point: N/A Flammable-Limits: IEl =4.1%(1lydrogenGas) UEL=74.2% Extiguisbing Media: CO2;foam;dry chemical Special Fire Fighting Procedures: If batteries are on charge,shut off power.-Use positive pressure,self-contained breathing apparatus. Water applied to electrolyte generates heat and canses Unusual Fire and Explosion Hazards- Highly flammable hydrogen gas is generated during charging and operation of batteries. To avoid risk of fire or explosion;keep sparks or other . sources of ignition away from batteries. Do not allow metallic materials to simultaneously contact negative and positive.terminals of cells and batteries. Follow manufacturers instructions for installation and service. Stability: Stable Conditions To Avoid: Prolonged overcharge;sources of.ignition Incompatibiliti+: (Materials to avoid) Sulfuric Acid: Contact with combustibles and organic materials may cause fire and explosion. Also reacts violently with strong reducing agents, metals,sulfur trioxide gas,strong oxidizers and water. Contact with metals may produce toxic sulfur dioxide fumes and may.release flammable hydrogen gas. Lead Compounds: Avoid contact with strong acids,bases,halides,halogenates,potassium nitrate,permanganate,peroxides,nascent hydrogen and reducing agents. Hazardous Decomposition Products: Sulfuric Acid:Sulfur trioxide,carbon monoxide,sulfuric acid mist,sulfur dioxide,and hydrogen. Lead Compounds: High temperatures likely to produce toxic metal fume,vapor,or dust;contact with strong acid or base or presence of nascent hydrogen may generate highly toxic arsine gas. Page I Form#853020 MATERIAL SAFETY DATA SHEET Revised:611&W MEMBER 2/9/05 -- .Routes of Enirv: Sulfuric Acid: Harnrftri by all routes of entry. Lead Compound Hazardous exposure can occur only when product is heated,oxidized or otherwise processed or damaged to create dust;vapor or fume. Inhalation:- Sulfuric Acid; Breathing of sulfit;ic acid vapors or mists may cause severe respiratory irritation. Lead Compounds; Inhalation of lead dust or fumes may cause irritation of upper inspiratory tract and lungs. Ingestion: Sulfuric Acid: May cause severe irritation of mouth,throat,esophagus and stomach. Lead Compounds:Acute ingestion may cause abdominal pain,nausea,vomiting,diarrhea and severe cramping. This may lead rapidly to systemic toxicity and must be treated by a physician. Sion Contact: Sulfuric Acid:•Severe irritation,bums and ulceration. Lead Compounds: Not absorbed through the skin. )✓ve Contact: Sulfuric Acid: Severe irritation,burns,cornea damage,and blindness. Lead Components May cause eye irritation. Effects of Overexposure-Acute: Sulfuric Acid: Severe skin irritation,damage to cornea,'Upper respiratory irritation. Lead Compounds: Symptoms of toxicity include headache,fatigue,abdominal pain,loss of appetitie,muscular aches and weakness,sleep disturbances and irritability. Effects of Overexposure-Chronic:- Sulfuric Acid: Possible erosion of tooth enamel,inflammation of nose,throat and bronchial tubes.. Lead Compounds: Anemia;neuropathy,particularly of the motor nerves,with wrist drop;kidney damage;reproductive changes in males and females. Carcinogenicity: , Sulfuric Acid:The International Agency for Research on Cancer(1ARC)has classified"strong inorganic acid mist containing sulfuric acid"as a Category I carcinogen,.a substance that is carcinogenic to Humans. Ibis classification does not apply to liquid forms of sulfuric acid or sulfuric acid solutions contained within a battery. Inorganic acid mist(sulfu is acid-mist)is not generated under nomral use of this product. Misuse of the product,such as overcharging,may result in the generation b€sulfuric acid mist. Lead Compounds: Lead is listed as a 213 carcinogen,likely in animals at extreme doses. Proof of carcinogenicity in humans is Iacking at present Arsenic: listed by National Toxicology program(NTP),International Agency for Research on Cancer(1ARC), OSHA and NIOSH as a carcinogen only after-prolonged exposure at high levels. Medical Conidtions Generally Aggravated-by Etoosure• Overexposure to sulfuric acid wrist may cause lung damage and aggravate pulmonary.conditions. Contact of sulfuric acid with skin may aggravate' ' diseases such as'eczema and contact dermatitis.Lead and its compounds can aggravate,some forms of kidney,liver and neurologic diseases. Inhalation: Sulfuric Acid: Remove to fresh air immediately. If breathing is difficult,give oxygen. Lead: Remove from exposure,.gargle,wash nose and lips;consult physician. Ingestion: Sulfuric Acid: Give large quanitities of water,do not induce vomiting;consult physician. Lzad: Consult physician immediately. Skin.. . . u unc Acla: flush with arge amounts of water for at least 15 minutes;remove contaminated clothing completely,including shoes. Lead: Wash immediately with soap and water.. Eves: Sulfuric Acid and Lead: Flush immediately.with large amounts of water for a least 15 minutes;consult physician. Proposition 65: Warning: Battery posts,terminals and related accessories contain lead and lead.compounds,chemicals known to the State of California to cause cancer and reproductive harm. Batteries also contain other chemicals known to the State of California to cause cancer. Wash hands after handling- �Spjll _ Leak Procedures: Stop flow of material,contain/absorbsmall spills with dry sand,earth,and vermiculite. Do�. .�mb. ,ibl materials. if possible,carefully neutralize spilled electrolyte with soda ash,sodium bicarbonate,lime,etc. Wear acid-resistant clothing,boots,gloves,and face shield. Do not allow discharge ofunneutralized acid to sewer. Waste Disposal Methods: Spent batteries: Send to secondary lead smelter for recycling. Place neutralized slurry into sealed containers and handle as applicable with state and federal regulations. Large water-diluted spills,after neutralization and testing,should be managed in accordance with approved local,state and federal requirements- Consult state environmental agency and/or federal EPA. _ - -.- _ _ _.. a —. _ ......... Form#M020 AMTERiA.L SAFETY DATA SHEET Revised:61I RW �' � Supetsedes 219105 rKEdr- e and Storage: Store batteries in cool,dry,well-ventilated areas with.impervious surfaces and adequate containment in the event of spills, Batteries should also be stored underroof for protection against adverse weather conditions. Separate from incompatible materials. Store and handle only in areas with adequate water supply and spill control. Avoid damage to containers. Keep away from fire,sparks and heat. Precautionary Labeling: POISON-CAUSES SEVERE BURNS DANGER CONTAINS SULFURIC ACID Ent3neerbl!Controls: Store and handle in well-ventilated.area. If mechanical ventilation is used.components must be acid-resistant. Work Practices: Handle batteries cautiously to avoid spills. Make certain vent caps are on securely. Avoid contact with internal components. W7pmte.ctive clothing when filling or handling batteries. FCbemical rotection:one required under normal conditions: When concentrations of sulfuric acid mist_are known to exceed the PEL,use NIOSH or MSHA-approved spriatorvprotectioves: ubber or glastic acid resistant gloves with elbow-lenth auntlet. • goggles or face shield. Other Protection• Acid-resistant apron. Under severe exposure emergency conditions,wear acid-resistant clothing and boots. Emergency Flushing: In areas where sulfuric acid is handled in concentrations greater them I%,emergency eyewash stations and showers should be provided, with unlimited water supply. NUM NFPA Hazard Ratine for Sulfuric Acid: Flammability(Red) = o Reactivity(Yellow) =2 Health(Blue) =3 Sulfuric acid is water-reactive if concentrated. U.S.DOT• The transportation'of wet and moist charged(moist active)batteries within the continental United States is regulated by the U.S.DOT through.the Code of Federal Regulations,Title 49(CFR49): These regulations classify these types of batteries as a hazardous material. Refer to CFR 49,173.159 for more details pertaining to the transportation of wet and moist batteries. The shipping information is as follows: Proper Shipping Name: Batteries,wet,filled with acid Packing Group: III Hazardous Class: 8 Label/Placard Required: Corrosive. UN Indentification: UN2794 Some EnerSys batteries have been tested and meet the non-spillable criteria listed in CFR 49,173.159(d)(3)(i)and(ii). Non-spillable batteries are excepted from CFR 49 Subchapter C requirements provided that the following criteria are met- 1. The batteries most be protected against short circuits and securely packaged. 2. The batteries and their outer packaging must be plainly and durably marked"NON-SPILLABLE"or"NON-SPILLABLE BATTERY". The exception from CFR 49,Subchapter C translates to no proper shipping name,no.hazardous class,no UN number,no packing group and no hazardous)abels when transporting a non-spillable battery. Contact your EnerSys representative for additional information regarding the classification of batteries. IATA: The international transportation of wet and moist charged(moist active)batteries is regulated by the International Air Transport Association (IATA). These regulations also classify these types of batteries as a hazardous material. The batteries must be packed according to IATA Packing Instruction 800_ The shipping information is as follows: Proper Shipping Name: Batteries,wet,filled with acid Packing Group: III Hazardous Class: 8 Label/Placard Required: Corrosive UN lndentification: UN2794 Some EnerSys batteries have been tested and meet the non-spillable criteria listed in IATA Packing Instruction 806. Non-spillable batteries must be packed according to IATA Packing Instruction 806. The shipping information for non-spillable batteries is as follows: Proper Shipping Name: Batteries,wet,non-spillable Packing Group: ID Hazardous Class: 8 Label/Placard Required: Corrosive UN Identification: UN2800 In addition,some EnerSys non-spillable batteries have been tested and meet the non-regulated criteria listed in IATA special provision A67. "these batteries are expected from all IATA regulations provided that the batteries'terminals are protected against short circuits_ Contact your EnerSys representative for additional information regarding the classification of batteries. -Page 3 Form#M020 MATERIAL SAFETY DATA SHEET Revised:61I&W Sngetsedes 219105 The international transporation of wet and moist charged(moist active)batteries is regulated by the International Maritime Dangerous Goods code(IIv M. These regulations also classify these types of batteries as hazardous material. The batteries must be packed according to By=code pages 8120 and 8121. The shipping information is as follows• Proper Shipping Name: Batteries,wet,filled with acid Packing Group: III Hazardous Class: 8 LabeWlacard Requited: Corrosive UN Indentification: UN2794 Some EnerSys batteries have been tested and meet the non-spillable criteria listed on page 8121. Non-spillable batteries must be packed according to IMDG page 8121. The shinning information for non-spillable batteries is as follows: Proper Shipping Name: Batteries,wet;non-spillable Packing Group: III Hazardous Class: 8 LabeUPlacard Required: Corrosive UN Identification: UN2800 In addition,some EnerSys non-spillable batteries have been tested and meet the non-regulated criteria listed in the IMDG code page.812). These batteries are excepted from all 1MDG code provided that the batteries'tenninais are protected against short circuits. Contact your EnerSys representative for additional information regarding the classification of batteries. RCRA- Spent lead-acid batteries are not regulated as hazardous waste.by the EPA.when recycled,however state and international regulations may vary. CERCLA(Sunerfund)and EPCRA: (a) Reportable Quantity(RQ)for spilled IGO%sulfuric acid under CERCLA(Superfund)and EPCRA(Energency Planning Community Right to Know Act)is I,ODO.lbs. State and local reportable quantities for spilled sulfuric acid may:vary. (b) Sulfuric acid is a listed"Extremely Hazardous Substance"under EPCRA,with a Threshold Planning Quantity(TPQ)of 1,0001bs. (c) EPCRA Section 302 notification is required if 110001bs.or more of sulfuric acid is present atone site. The quantity of sulfuric acid will vary by battery type. Contact your EnerSys representative for additional information. (d) EPCRA Section 312 Tier 2 reporting is required for batteries if.sulfuric acid is present in quantities of 500 lbs.or more and/or if lead is present in quantities of 10,000 lbs.or more. (e) Supplier Notification: This-product contains toxic chemicals,which maybe reportable under EPCRA Section 313 Toxic Chemical Release Inventory{Form R)requirements. If you are a manufacturing facility under SIC codes 20 through 39 the following information is provdied to enable You to complete the reautred reports: Toxic Chemical CAS Number Approximate%by Wt. Lead 7439-92-1 60 Sulfuric Acid 7664-93-9 10-30 *Antimony. 7440-36-0 2 *Arsenic 7440-38-2 0.2 If you distribute this product to other manufacturers in SIC Codes 20 through 39,this information must be provided with the first shipment of each calendar year. The Section 313 supplier notification requirement does not apply to batteries,which are"consumer products'. * Not present in all battery types. Contact your EnerSys representative for additional information. TSCA Ingredients in EnerSys'batteries are listed in the TSCA Re retry as follows: components CAS Number TSCA Status Electrolyte: Sulfuric Acid(H2SOa) 7664-93.9 Listed Inorganic Lead Compound: Lead(Pb) 7439-92-1 Listed Lead Oxide:(PbO) 13I7-36-8 Listed Lead Sulfate(PbSOi) 7446-14-2 Listed Antimony Sb) 7440-36-0 Listed Arsenic(As) 7440-38-2 Listed Calcium(Ca) 7440-70-2 Listed Tin(Sri) 7440-31-5 Listed CAA- EnerSys supports preventative actions concerning ozone depletion in the atmosphere due to emissions of CFCs and other ozone depleting chemicals(ODC's),defined by the USEPA as Class I substances. Pursuant to Section 61 lof the Clean Air Act Amendements(CAAA) of 1990,finalized on January 19,1993,EnerSys established a policy to eliminate the use of Class-1 ODC's prior.to the May 15,1993 deadline. MATERIAL SAFETY A Division of DATA SHEET - (rc7a5fi:41 RC�i4 , L Product Identification ChemieaVTrade Name(Identity used on label): Chemical Family/Classification: 002FCI A- Lead Acid Cell(Antimony) Electric Storage Battery Company Name. Address: Exide Technolo•ies 829 Parkview Boulevard Division or Department: Lombard;Illinois 60148-3249 GN 3 Industrial Power 8.00.-872-0471 contact Telephone Number: Questions concerning MSDS Mr.Richard Thompson (972)335-2121 x40 Transportation Emergencies:C IENITREC 24 Hours: Within the United States-Toll-free: (900)42449300 Outside the United States-Call collect: 703)527 3887 II. Hazardous Ingredients CAS Exposure Limits MATERIAL %by Weight NUMBER OSHA ACGIIi Lead 51.4 7439-92-1 0.05-mg/M3 0.15 mg/m Electrolyte 19-44% 7664-93-9 1 mg/m3 1 mg/m3 (Sulfuric Acid) Antimony 1.0 7440-36-0 03 mg/m3 0.5 mg/m3 Lead Dioxide 20.8 1-309-60-0 0.05 mg/m3 0.05 mg/m3 (Pb02) Non-Hazardous 8.2 Ingredients NOTE: Components are for a fully charged lead acid cell des! Ill. Physical Data Materials(at normal temperatures): . Appearance and Odor.. Electrolyte Volume of Sulfide Acid-42-71%. Electrolyte is a clear liquid with a sharp, enetratin , un ent odor. of mg Point(at 203°F N/A Specific Gravity(H20=f): Vapor Pressure(min Hg at 20°C): 1.230-1.350 1.0 Vapor Density(AIR=1): Solubility.in Water Greater than 1 1000/0 %Volatiles by Weight: Evaporation Rate(Butyl Acetate=l): N/A Less than 1 PART NUMBER:Z99-MSDS-FLOODPBSB REV:AB Updated August,2001 1 of 4 Flooded Lead Acid Cell(Antimony) ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT. IV. Health Hazard Information Routes of Entry: Sulfuric Acid:Under normal conditions ofuse,sulfuric acid vapors and mist are no geierated..Sulfuric acid vapors and mist maybe generated when product is overheated,oxidized,or otherwise processed or damaged. Lead Compounds:Under normal conditions of use,lead dust,vapors,and fumes are no,generated. Hazardous exposure may occur when product is overheated,oxidized;or otherwise proqessed or damaged to create dust,vapor,or fumes. Inhalation: Sulfuric Acid vapors or mist may cause severe respiratory irritation. Lead dust or fumes may cause irritation of upper respiratory tract or . htu s. Skin Contact: Sulfuric Acid may cause severe irritation,burns and ulceration. Lead Com ounds are not readily absorbed through the skin. Skin Absorption: Sulfuric Acid is not readily absorbed through the skin. Lead Co ounds are not readi. absorbed tmugh the skin. Eye Contact: Sulfuric Acid vapors or mist can cause severe irritation,burns,cornea damage and possible blindness. Lead.Compounds may cause eye irritation. Ingestion: Sulfuric Acid may cause severe irritation of mouth,throat,esophagus and stomach. Lead Compounds may cause abdominal pain, nausea,vomiting,diarrhea and severe cram in , Acute in estion should be treated by p h pcian, SIGNS AND SYMPTOMS OF OVEREXPOSURE Acute Effects: Sulfuric Acid may cause severe skin irritation,bums,damage to cornea and possible blindness and upper iespiratory..irritation. Lead Compounds may cause abdominal: ai 1,nausea,headaches,vomitin . diarrhea,severe cramping and difficulty in sleeping._ . Chronic Effects: Sulfide Acid may lead to scarring of the cornea,inflammation of the nose,throat and bronchial tubes and possible erosion of tooth enamel. Lead Compounds may cause anemia,damage to the kidneys and nervous system. May cause reproductive harm in both males and. females. POTENTIAL.TO CAUSE CANCER . Lead Compounds-Human studies are inconclusive regarding lead exposure and an increased cancer risk The EPA and the International Agency for Research on Cancer(IARC)have categorized lead and inorganic lead compounds as a B2 classification (probableffiossible human carcinogen)based on sufficient animal evidence and inadequate human evidence. EMERGENCY AND FIRST AID PROCEDURES Inhalation: Sulfuric Acid Remove to fresh air immediately_ If breathing is difficult,give oxygen: Lead Compounds-Remove from exposure;gargle,wash nose and eyes and consult physician. Skin: Sulfuric Acid-flush with large amounts of water for at.least 15 minutes,remove any contaminated clothing and do not wear again until cleaned If acid is splashed on shoes,remove and discard if they contain leather. Lead Compounds are not readily absorbed through the skin. Eyes: Lead Compounds-flush immediate! with cool water for at least 15 minutes,.then consult ph sician. Ingestion' Sulfuric Acid-give large quantities of water;DO NOT induce vomiting,then consult physician. Lead Compounds-consult a physician. V. Fire and Explosion Data Flash Point: Flammable Limits: Not a licable. Lower 4_I%(Hydrogen as)U er 74.1% Extinguishing Media: Carbon dioxide(CO2);.foam;dry chemical. I PART NUMBER:Z99-MSDS-FLOODPBSB REV_AB Updated August,2001 2 of 4 Flooded Lead Acid Cell(Antimony) ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT Special Fire Fighting Procedures: If batteries on charge, n of Power. Use positive pressure,self-contained breathing apparatus- Water applied to electrolyte generates tm heat and causes it to latter. Wear acid resistant clotbingr. Unusual Fire and Explosion Hazard: in the cells during normal battery operation or when on.charge(hydrogen is Nighty flammable Hydrogen and oxygen gases are produced and oxygen supports combustion}: These gases enter the air through the vent caps. To avoid risk of fire or explosion,keep sparks and olhcr sources of ignition away from the battery,and ensure that adequate ventilation is provided. Do not allow metallic material to simultaneously contact both the positive and negative terminal of batteries. Follow manufacturers'instructions for installation and o ration. VL Reactivity Data Stability Conditions to Avoid: L7=Unstable ■ = Stable Sparks and other sources of ignition. Prolonged overcharge and overhea . Incompatibility(Material to Avoid): es,and organic materials may cause fire and explosion. Also avoid strong reducing agents, Combination of sulfuric acid with combustibl most metals,carbides,chlorates,nitrates,and picraw. bead Compound: Potassium,carbides,sulfides,peroxides, Nos horns and sulfur. Hazardous Decomposition Products Hazardous Polymerization: Sulfwic Acid: Hydrogen,sulfur dioxide,sulfur trioxide, 0= May.Occur .0=Will Not Occur h en sulfide,and sulfuric acid mist Vn-. Cointrol Measures Engineering Controls: Store and handle lead acid batteries in well ventilated areas. 'Work Practices: Make certain vent caps are on tightly. Follow all manufacturers'recommen Do not allow metallic dations wlen stacking or palletizing. materials to simultaneously contact both the positive and negative terminals of the batteries. Use a battery carrier to lift a battery or lace bands at o osite comers to avoid spilling acid through the vents. Avoid contao with internal components of the batteries. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: None are required under normal conditions. If an overcharge or overheating condition exists and concentrations of sulfuric acid mist are known or suspected to exceed PEI,,use NIOSH or MSHA approved roved respiratory rotection. Eyes and Face: Chemical.splash o les or face shield. Hands,r BodyErta Rubberastic aloves with elbow len untlet. Other Sl CIotipment:Acid resistant roere exposure or emer enc conditions,wean acid resistant clothingand boots. VUJ. Safe Handling Precautions Hygiene Practices: Wash hands thoroughly before eating,drinking or stroking after handling batteries. Protective Measures.to be taken during non-routine tasks including equipment maintenance: Charged batteries can present an electrical azar . SPILL OR LEAK PROCEDURES Protective measures to be taken ifmaterial is released or spilled` Remove combustible materials and all sources of ignition. m Stop flow of material and_contain spill by diking with soda ash(sodiu carbonate)or quick lime(calcium oxide). Carefully neutralize spill with soda ash,etc_ Make certain mixture is neutral Then collect a label specifying"contains hazardous waste"or(if uncertain call distributor residue and place in a drum or other suitable container with regarding proper labeling procedures)_ Dispose of as hazardous.waste. If battery is leaking,place battery in a heavy duty plastic bag. Wear acid resistant boots,faceshield,chemical splash goggles and acid resistant gloves. DO NOT RELEASE UNNEUTRALIZED ACID. REV:AB PART NUMBER:Z99-MSDS-FLOODPBSB g of 4 Flooded Lead Acid Cell(Antimony) Updated August,2001 ANY PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT Waste Disposal Methods: _ labeled as containing ha-Mous Sulfuric Acid. Neuaalwe as f tmcerha afabout Iabelinor a spill, Ilec�residue�call your local n�&tnbutor or contacts listed at be waste- above . DI of as a hazardous waste. DO N4T I L,LI I LEA D CONTAMINg. ATED A�TO SEWER Batteries: Send to lead smelter followin lieable federal,state and iocat remilatiOns, M Other RTGULATdRY jNpORMATION: NFPA Hazard rating for Sulfuric Acid health(glue) = 3 Reacrivi (Yellow} = 2 Flannnabili (Red) = 4 US DOT identification and description for this battery is: Batteries,wet,filled with acid,Class 8,UN 2794,PG Ill. Label: Corrosive Transpomotion Association(IATA)Dangerous Goods Regulations Manual,Packing Instruction For air shipment,see international Air 800. For ocean shipment,see International Maritime Dangerous Goods Code,P.8120. PROPOSITION 65 WARNING essories contain lead and lead compounds,chemicals known to the State of California to cause Battery posts,terminals,and related acc cancer and reproductive harm. Wash hands after handling. Inc National ToxicologyProgram(NTP)and the International Agency for Research on Cancer(IARC)have classified"strong ong inorganic acid mist containing sulfuric acid"as a substance that is carcinogenic to humans. This:classification does not apply to li liquid forms of sulfuric acid to sulfuric acid solutions contained within a battery. Inorganic acid mist(sulfuric acid mist)is not generated.under normal use of this product. Misuse of the product,such as overe. ,ma however result in the eneration of sulfuric acid mist This product contains sulfuric acid(CAS#7664-93-9),an extremely hazardous substance(40 CFR 355.30),that maybe w, subject to e fog,and other reporting requirements of Sections 3021304,311/312 and Section 313(only acid aerosols ianncldu Q CFRpvapors,rts 37Qand 372 airborne forms)of the Superfund Amendments and Reauthorization Act of 1986(SAKA), (Community Right to-Know). This product contains lead(CAS',I.7439-92-1)and lead compounds,chemicals.that may be subject to the reporting requirements of Sections.3111312 and Section 313 of SARA,and 40 CFR Parts 370 and 372(Comtnumi Ri t to-Know). PREPARED BY: ENYIRONMENTAL,SiFETYAND HEALTH DEPARTMENT GNB INDSTRIAL POWER 829 PARKVIEW BOULEVARD LOMBARD,IL 60148-3249 VENDEE AND THIRD PERSONS ASSUME THE RISK OF INJURY PROX21v1ATELY CAUSED BY THE MATERIAL IF REASONABLE SAFETY PROCEDURES ARE NOT FOLLOWED AS PROVIDED FOR IN THE DATA SHEET,AND VENDOR SHALL.NOT BE LIABLE FOR INJURY TO VENDEE OR THIRD PERSONS PROXIMATELY CAUSED BY ABNORMAL USE OF THE MATERIAL EVEN IF REASONABLE PROCEDURES ARE FOLLOWED. ALL PERSONS USING THIS PRODUCT,ALL PERSONS WORKING IN AN AREA WHERE THIS PRODUCT IS USED,AND ALL PERSONS PERSONS USING THIS PRODUCT SHOULD BE FAMILIAR WITH THE CONTENTS OF THIS.DATA SHEET_ THIS INFORMATION.SHOULD BE EFFECTIVELY COMMUNICATED TO EMPLOYEES AND OTHERS WHO MIGHT COME IN S BELIEVED To BE ACCURATE AS OFTHE DATE WHILE THE 1NFORMATIOLOGIES MAKES NO WARRANTY ITH RES HEREIN THERETO AND DISCLAIMS ALL LIABILITY FROM HEREOF,EXIDE TECHNOLOGIES ADVANCE Of RELIANCE APPL ICABLE,CABLEEAND SUITS ARE ABLE FOR THEIR PAR'TICULARED To CONFIRM�CIRCUMSTANCES. THAT THE INFORMATION IS REV:AB PART NUMBER:Z99-MSDS-FLOODPBSB 4 of 4 Flooded Lead Acid.Cell(Antimony) Updated August,2001 AN PHOTOCOPY MUST BE OF THIS ENTIRE DOCUMENT