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Home My WebLink About66 Kimberly Drive - Tier II Reports - Fi L East Hartford,CT Phone:860-289-1100 Fax:860-289-3272 RUSSELL & DAWSON Stamford,CT Fax:203-653-3526 TO: Walter Summers, South Windsor Fire Marshal FROM: Thomas A. Manning, AIA � Thomas A Manning 2012.03.19 18:46:26 -04'00' DATE: 3/19/2012 RE: Metals Testing Company 80 Kimberly Drive South Windsor, Connecticut File No. 12.038 This is in response to your request for a brief narrative regarding code compliance at this project. This is a mixed business and industrial occupancy using hazardous chemicals. received a list of the chemicals, which is attached. I have requested MSDS from the owner. Pending receipt, I have classified the industrial occupancy as H-4 based on the information about the chemicals that I have been able to obtain online. They appear to be primarily corrosive and toxic. Methanol is a flammable liquid, but does not cause classification as H-2 or H-3 in the quantity listed per Table 307.7(1). The employee lounge is classified as accessory Assembly. As an H-4 occupancy, the building is able to take advantage of the area increase for sprinklers in 506.3. With the addition it is well within the allowable area for nonseparated mixed use per 302.3.1, so rated separations are not required per Table 302.3.2. There is a requirement for rated separations in 415.8, but it does not appear to apply to this plan. The mezzanine is partially closed, and the closed portion has an occupant load of 6, well under the 10 permitted by Exception No. 1 to 505.4. The common path of travel to the bottom of the stairs from the most remote corner is 75 feet. Although fully sprinklered, the Exceptions to 1013.3 are not available to H occupancies. The area of the mezzanine is 1240 square feet. It is open to a room 8500 square feet in area, so well within the limitation of 505.2. Mezzanines are permitted in H occupancies. If you have questions, please call. I am usually at(860) 679-4197 during the day. I am working on assignment away from our East Hartford office. You may also contact me by e-mail at thomas.manning@russellanddawson.com or tmanning@uchc.edu. c: file Christopher Dougan, Building Official R:\PROJECTS\A-YR-2012\12.038 Metals Testing-South Windsor,CT\R&D Code Compliance\WS120319 Memo.Doc Website:www.russellanddawson.com Email:info@russellanddawson.com RUSSELL AND DAWSON LLC° 1111 Main Street-East Hartford,CT 06108•TEL:860-289-1100•FAX:860-289-3272 CHIRAG B.THAKER,PRESIDENT•DAN LYMAN RUSSELL,ARCHITECT•ROBERT M.DAWSON,III,PROFESSIONAL ENGINEER NG COMPAMY DELISLE INC.,D/8 A,METALS TESTING COMPANY 80 Kimberly Drive,P.O.Box e9,South Windsor,CT 06074 Jim Simmons Allied Construction Inc. March 2,2012 Mr.Simmons With regards to the new chemical processsing facility for Metals Testing Company,the processes and chemicals currently being conducted and stored at are facility now will be the same in the new facility only on a larger scale. Below is a brief description of the process in new facility: l; Parts received in and sent to chemical processing facility. 2. Parts unpacked/fixtured 3. Parts immersed in alkaline cleaner 4.. Parts immersed in water rinse tank 5. Parts immersed in etching tank 6. Parts immersed in water rinse tank 7. Parts immersed in anodizing tanks/anodized(if applicable to parts) 8. Parts immersed in water rinse tank(if applicable to parts) 9. Parts immersed etching/desmut tanks(if applicable to parts) 10. Parts immersed in water rinse tank 11.Parts immersed in hot deionized water rinse tank/blown dry 1.2.Parts inspected/repacked 13.Parts sent to other departments or back to customer Below is a list of chemicals that will be used and stored in the new-facility.These chemicals will either be in drums from the manufacturer or in our processing tanks in diluted amounts. Chemical Approx Chemical Approx Name Amount Name Amount Acetic Acid 150 gal Methanol 110 al Acetone I 10 gal Nitric Acid 800 Ral Ammonium Bifluoride 300 lbs Phosphoric Acid 10.0 al Aricid-B(Acid Salt) 5000 lbs Soda Ash 200 lbs En re 576(Alk-Cleaner) 2400 lbs Sodium Hydroxide 2000-lbs Ferric Chloride 2400 gal Sulfuric Acid t400 al Hydrochloric Acid' 800 gal Trisodium Phosphate 1000 lbs H drofluoric Acid 200 gal Turco Vitro-Klene(Alk-Cleaner) 120001bs Lime 2000 lbs Anthony Bruno Special Projects Manager ZD East Hartford,CT Phone:860-289-1100 Fax:860-289-3272 ItIJSSEL:.L & DAWSON Stamford,CT Phone;203-653-2335 Fax:203-653-3526 TO: Walter Summers, South Windsor Fire Marshal FROM: Thomas A. Manning, AIA a, Thomas A Manning DATE: 4/9/2012 72012.04.10 09:09:29 -04'00' RE: Metals Testing Company 80 Kimberly Drive South Windsor, Connecticut File No. 12.038 This is to follow up on the occupancy classification of this building based on the attached listing of the types and quantities of chemicals present, and the attached Material Safety Data Sheets (MSDS). Based on the MSDS, the chemicals have been classified as follows: Acetic Acid toxic, corrosive, Class II combustible liquid (flash point 104°F) Acetone irritant, Class IB flammable liquid (flash point-4°F, boiling point 132.2°F) Ammonium Bifluouride toxic, corrosive Aricid-B toxic, corrosive Enprep 576 toxic, corrosive Ferric Chloride toxic, corrosive Hydrochloric Acid toxic, corrosive Hydrofluoric Acid toxic, corrosive Lime (Calcium Hydroxide) irritant Methanol irritant, toxic, Class IB flammable liquid (flash point 51.8°F, boiling point 148.5°F) Nitric Acid toxic, corrosive Phosphoric Acid corrosive Soda Ash (Sodium Carbonate) irritant Sodium Hydroxide corrosive Sulfuric Acid toxic, corrosive Trisodium Phosphate irritant Turco Vitro-Klene corrosive The presence of toxic and corrosive chemicals is consistent with the initial classification as an H-4 occupancy. As Acetic Acid, Acetone, and Methanol in sufficient quantity might raise the classification to H-2 or H-3, I offer the following more detailed analyses. Per Table 307.7(1), up to 120 liquid gallons of Class II combustible liquids may be stored without requiring classification as H-2 or H-3. Per note d, this amount is increased 100 percent when the building is fully sprinklered per NFPA 13. The owner proposes to store 150 gallons of acetic acid, less than the 240 gallons that would require classification as H-2 or H-3. Website:www.russellanddawson.com Email:info@russellanddawson.com RUSSELL AND DAWSON LLC• 1111 Main Street-East Hartford,CT 06108•TEL:860-289-1100•FAX:860-289-3272 1 CHIRAG B.THAKER,PRESIDENT•DAN LYMAN RUSSELL,ARCHITECT•ROBERT M.DAWSON,III,PROFESSIONAL ENGINEER Per T;ihle 307 70) 1-1p to 190 liquid gallons of Class IR combustible liquids may be stored without requiring classification as H-2 or H-3. Per note d, this amount is increased 100 percent when the building is fully sprinklered per NFPA 13. The owner proposes to store 110 gallons each of acetone and methanol, in combination less than the 240 gallons permitted in this fully sprinklered facility without requiring classification as H-2 or H-3. I consulted the Commentary on this issue, and it appears that the maximum quantity of each and every line item is permitted to be present before reclassification is required. I therefore conclude that the H-4 occupancy classification stated on the drawings submitted for permit application is correct, and that use of approved storage cabinets or specific control areas is not required. If you have questions, please call. I am usually at(860) 679-4197 during the day. I am working on assignment away from our East Hartford office. You may also contact me by e-mail at thomas.manning@russellanddawson.com or tmanning@uchc.edu. c: file Christopher Dougan, Building Official R:\PROJECTS\A-YR-2012\12.038 Metals Testing-South Windsor,CT\R&D Code Compliance\WS120409 MSDS.Doc Website:www.russellanddawson.com Email:info@russellanddawson.com RUSSELL AND DAWSON LLC- 1111 Main Street-East Hartford,CT 06108-TEL:860-289-1100•FAX:860-289-3272 2 CHIRAG B.THAKER,PRESIDENT•DAN LYMAN RUSSELL,ARCHITECT•ROBERT M.DAWSON,III,PROFESSIONAL ENGINEER S T� COMPANY DELISLE INC.,DB/A,METALS TESTING COMPANY 80 Kimberly Drive,P.O.Box 69,South Windsor,CT 06074 Jim Simmons Allied Construction Inc. March 2,2012 Mr.Simmons With regards to the new chemical processing facility for Metals Testing Company,the processes and chemicals currently being conducted and stared at are facility now will be the same in the new facility only on a larger scale. Below is a brief description of the process in new facility: 1 Parts received in and sent to chemical processing facility. 2 Parts unpacked/fixtured 3. Parts immersed in alkaline cleaner 4. Parts immersed in water rinse tank 5. Parts immersed in etching tank 6. Parts immersed in water rinse tank 7. Parts immersed in anodizing tanks/anodized(if applicable to parts) 8. Parts immersed in water rinse tank(if applicable to parts) 9. Parts immersed etching/desmut tanks(if applicable to parts) 10. Parts immersed in water rinse tank 11.Parts immersed in hot deionized water rinse tank/blown dry 12.Parts inspected/repacked 13.Parts sent to other departments or back to customer Below is a list of chemicals that will be used and stored in the new facility.These chemicals will either be in drums from the manufacturer or in our processing tanks in diluted amounts. Pre mical Approx Chemical Approx ame Amount Name Amount c Acid 150 al Methanol 110 al tone 110 al Nitric Acid 800 al m Bifluoride 300 lbs Phos horic Acid 100 al (Acid Sal#) 50001bs Soda Ash 200 lbs Aik-Cleaner) 2400 lbs Sodium H droxide 2000 lbs Chloride 2400 al Sulfuric Acid 400 al oric Acid 800 al Trisodium Phosphate 1000 lbs Hydrofluoric Acid 200 al Turco Vitro-Klene(Alk-Cleaner) 2000 lbs Lime 2000 lbs Anthony Bruno Special Projects Manager 3 t • mum Material Safety Data Sheet Better Chemistry. Better Business. Hubbard-Hall Inc Information: 800-331-6871 563 South Leonard Street In case of Emergency:CHEMTREC: (24hr): (800)424-9300 Waterbury,CT 06708 www.hubbardhall.com info@)hubbardhall.com SECTION I- PRODUCT IDENTIFICATION TRADE NAME:Phosphoric Acid 75% PRODUCT CODE:2971012 CHEMICAL NAME: Phosphoric Acid REVISION DATE: December 7,2009 CHEMICAL FAMILY: Mineral Acid SECTION II-HAZARDOUS INGREDIENTS *PHOSPHORIC ACID, 75%, CAS 7664-38-2, CLEAN WATER ACT SECTION 311 HAZARDOUS SUBSTANCES, CERCLA HAZARDOUS SUBSTANCES, SARA TITLE III SECTION 313 TOXIC CHEMICALS, OSHA AIR CONTAMINANTS, OSHA TABLE Z-1-A [REVOKED], DOT HAZARDOUS MATERIALS, DOT HAZARDOUS SUBSTANCES OTHER THAN RADIONUCLIDES AND RADIONUCLIDES, MASSACHUSETTS SUBSTANCE LIST, NEW JERSEY RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST, SPECIAL HEALTH HAZARD, PENNSYLVANIA HAZARDOUS SUBSTANCE LIST, ENVIRONMENTAL HAZARD, CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS, INGREDIENT MUST BE DISCLOSED AT CONCENTRATION OF 1%. EP: CERCLA RQ IS 5000 LB; EPCRA SECTION 313 DE MINIMIS CONCENTRATION IS 1.0%. ACGIH: TWA IS 1 MG/M3; STEL IS 3 MG/M3. OSHA TABLE Z-1: TWA IS 1 MG/M3. OSHA TABLE Z-1 A [REVOKED]: TWA IS 1 MG/M3; STEL IS 3 MG/M3. *THIS SUBSTANCE IS A CHEMICAL SUBJECT TO SARA TITLE III, SECTION 313 REPORTING REQUIREMENTS. NO OTHER INGREDIENTS IN THIS MIXTURE ARE CONSIDERED TO BE HAZARDOUS ACCORDING TO ANY STATE OR FEDERAL REGULATIONS. SECTION III-PHYSICAL DATA BOILING POINT: 135 deg C(275 deg F) FREEZING POINT: 0 degrees F VAPOR PRESSURE: N/A VAPOR DENSITY:N/A SOLUBILITY IN WATER: 100% PH:2@ 10 GM/L APPEARANCE AND ODOR: Liquid SECTION IV-FIRE AND EXPLOSION DATA FLASH POINT(F): N/A FLAMMABLE LIMITS:N/A EXTINGUISHING MEDIA: Product is not combustible. Use water spray, fog, foam, carbon dioxide, dry chemicals or other agents appropriate for the materials in the fire. Firefighters exposed to fire, smoke, fumes, and or products of the combustion should wear full face self-contained breathing apparatus and impervious protective clothing gear such as gloves, hoods,suits and boots. SPECIAL FIRE FIGHTING MEDIA: Evacuate non-essential people from the area of the fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: May decompose and product toxic gas irritating to the respiratory tract and cause breathing difficulty and pulmonary edema. fi .METALS TES T IM.G COMPAMY REVIEWED 6Y1101, 1of3 DATE—_ "/D f � SECTION V-HEALTH HAZARD DATA HMIS:HEALTH: 3 FIRE: 0 REACTIVITY: 1 EFFECTS OF OVEREXPOSURE:Phosphoric acid is an acid corrosive. Exposure to eyes, throat and skin. Liquid or high concentration may cause serious skin bums and may result in severe burns to the eyes. ROUTES OF ENTRY AND EMERGENCY FIRST AID PROCEDURES: SKIN: May produce serious chemical burns. Flush contaminated skin with water and wash with soap and water. Remove all contaminated clothing preferably while under a safety shower. Get medical aid immediately. Discard contaminated clothing and shoes. EYE CONTACT: Corrosive to eyes and may cause corneal ulceration, conjunctivitis, and permanent damage or blindness. Immediately lush eyes with large amounts of water for 15 minutes. Hold eyelids away from eyes to assure through flushing of eyes.Get prompt medical aid. INGESTION: Causes damage to mucous membranes,digestive tract and may lead to ulcerations and secondary infection. Immediately give large amounts of water. Do not induce vomiting, but if vomiting occurs, give fluids again. Do not attempt to induce vomiting or give fluids to an unconscious person. Get prompt medical aid, or call the nearest poison control center. INHALATION: Mist or fumes may cause respiration tract irritation, bronchitis, or even pulmonary edema if concentrated. Remove from contaminated atmosphere. If breathing has stopped, clear the victim's airway and perform artificial respiration. If victim is breathing, oxygen may be administered from a demand type or continuous flow inhalator, preferably with a physician's advice.Keep victim warm and at rest.Get medical aid promptly. SECTION VI—REACTIVITY DATA INSTABILITY: Stable under normal conditions at atmospheric pressures and in normal use. Freezes at lower \ temperatures. INCOMPATIBILITY: Phosphoric acid is a strong acid and a dehydrating agent. May spatter upon contact with water or with chemicals solvents containing water. Reacts violently with bases. Reacts with may metal producing heat and flammable hydrogen gas. DECOMPOSITION: Heating to decomposition point gives off toxic fumes of phosphorus pent oxide. POLYMERIZATION:Will not occur. CONDITIONS TO AVOID: Phosphoric acid is a strong acid and a dehydrating agent. May spatter upon contact with water or with chemicals solvents containing water. Reacts violently with bases. Reacts with may metal producing heat and flammable hydrogen gas. SECTION VII-SPILL OR LEAK PROCEDURES SPILL, LEAK OR RELEASE: In case of spill,wear protective clothing. Evacuate all non-essential people from the area. Soak up small spills with sand, dirt, or absorbent material. Neutralize with soda ash and scoop up and place in clean, dry lined steel containers and carefully label container for eventual disposal. Flush away residue with copious amounts of water. LARGE SPILLS should be diked with dirt,san or other similar material to prevent flowing into streams or sewers. Pump spill into marked containers fir reclamation or disposal. Residue should be neutralized and flush with water as described above.Always notify authorities if spill can produce adverse side effects to area. WASTE DISPOSAL:Waste disposal should be done in accordance with federal, state and local regulations. Incineration should be in equipment designed to handle oxides of phosphorus as combustion products. Submit waste material only to approved chemical disposal service companies. SECTION VIII-SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Use NIOSH approved equipment with full-face piece when airborne appropriate type equipment for given application. VENTILATION: Provide ventilation to minimize exposure. Local exhaust ventilation preferred, SPECIAL: N/A 2 of 3 OTHER: Remove contaminated clothing promptly and launder before reuse. Provide safety shower at any location where skin contact can occur.Wash contaminated skin promptly. PROTECTIVE GLOVES:Wear appropriate impervious gloves and protective clothing to prevent skin contact. Wash contaminated skin promptly. EYE PROTECTION: Wear chemical safety goggles to prevent eye contact. Have eye baths immediately available where contact can occur. OTHER PROTECTIVE EQUIPMENT:Wear face shields and impervious aprons. SECTION IX-SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store away from heat and keep product away from alkalies. Storage tanks should be off approved materials for phosphoric acid and should be vented and diked. 316elc stainless steel is the preferred material for storage, process equipment and shipping containers. OTHER PRECAUTIONS: None SECTION X-TRANSPORTATION REQUIREMENTS PROPER SHIPPING NAME:PHOSPHORIC ACID HAZARD CLASS: 8 DOT GUIDE: 154 ID NUMBER: UN1805 PKG.GROUP: III NOTICE WILE THE INFORMATION AND RECOMMENDATIONS GIVEN ARE BELIEVED TO BE ACCURATE, HUBBARD-HALL INC.MAKES NO WARRANTY,EXPRESS OR IMPLIED,AND ASSUMES NO LIABILITY WITH RESPECT TO USE OF THIS INFORMATION. 3of3 Hera SODIUM CARBONATE (ANHYDROUS) ICSC: 1135 Date of Peer Review: October 2004 Carbonic acid disodium salt Soda ash [EC AS# 497-19-8 Na2CO3 ECS# VZ4050000 Molecular mass: 106.0 # # 011-005-00-2 YPES OF HAZARD/ ACUTE HAZARDS/ FIRST AID/FIRE EXPOSURE SYMPTOMS PREVENTION FIGHTING Not combustible. In case of fire in the FIRE -surroundings:use appropriate extinguishing media. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUSTI Inhalation Cough.Sore throat. Local exhaust or Fresh air,rest. breathing protection. Skin Redness. Protective gloves. Rinse skin with plenty of water or shower. Redness. Pain. Safety goggles. First rinse with plenty of water for several minutes Eyes (remove contact lenses if easily possible),then take to,a doctor. Burning sensation in the Do not eat,drink,or Rinse mouth. Give plenty Ingestion throat and chest. smoke during work. of water to drink. Refer for Abdominal pain. medical attention. SPILLAGE DISPOSAL PACKAGING&LABELLING Sweep spilled substance into sealable containers; if EU Classification appropriate, moisten first to prevent dusting. Personal Symbol:Xi protection:P2 filter respirator for harmful particles.. R:36 S:u 22-26 UN Classification EMERGENCY RESPONSE SAFE STORAGE Dry.Well closed.Separated from incompatible materials.See Chemical Dangers. Prepared in the context of cooperation to qrAmme—between the in rilationa!Pro IPCS % IL Chemical Safety and the Commission of the InteProgramme vim_ j, */ b European Communities©IPCS CEC 2004 Programme on �� Chemical Safety uNEp SEE IMPORTANT INFORMATION ON BACK SODIUM CARBONATE (ANHYDROUS) ICSC; 1135 ' IMPORTANT DATA PHYSICAL STATE;APPEARANCE: INHALATION RISK: WHITE HYGROSCOPIC POWDER A harmful concentration of airborne particles can be CHEMICAL DANGERS: reached quickly especially if powdered. The solution in water is a medium strong base. Reacts EFFECTS OF SHORT-TERM EXPOSURE: violently with acids.Reacts with magnesium, I The substance is irritating to the eyes,the skin and phosphorous pentoxide causing explosion hazard. the respiratory tract. Reacts with fluorine causing fire hazard. EFFECTS OF LONG-TERM OR REPEATED OCCUPATIONAL EXPOSURE LIMITS: EXPOSURE: TLV not established. MAK not established. The substance may have effects on the respiratory tract, resulting in Perforation of the nasal septum. L peated or prolonged contact with skin may cause dermatitis. PHYSICAL PROPERTIES Melting point:851°C Density:2.5 g/cm3 .Solubility in water,g/100 ml at 20°C:30 ENVIRONMENTAL DATA NOTES ADDITIONAL INFORMATION LEGAL NOTICE Neither the CEC nor the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information C IPCS, CEC 2004 See Also: Toxicological Abbreviations O col ' Material Safety Data Sheet NFPA HN6S Personal Protecaft Equipffimm 2 See Section 15. SBCt101f 1.Cir /)kal.Ploduet and Co 'a0 tiOn Faye Number.1 T�emNanemd Sodium hydroxide/ ustic Soda N ems) S11501 S11502 S11503 CAS# 1310-73-2 Maoafactorer SAMIRIAN CHEMICALS INC. RTECS WB4900000 _ 1999 S.BASCOM AVE.,SUITE#51$ TSCA TSCA 8(b)inven0y.Sadurt ' CAMPBELL;CA 95()(}8. .. _ hyrlrooatle Commercial Names)` Caustic soda beads,Sodium hydroodde-Dry,Solid r CI# Not available. Synonym Caustic Soda flakes/pearls/sticks,Soda lye,•lM sodium hydrate Chemiai Name Sodium HytlrarddeEq ROEC�G ENCY 800.4224-9306 Chemical Faway Sh org aticaG Chemical Fornnela NaOH Disbibuted by HUBBARD-HALL INC. Supplier SANpRIAN CliEMCALS INC. Waftfenfyc C.aerm zaanse-zrn 19W S.BASCOM AVE.,SUITE#515 mm.,,sc zsses ssu472-Ml CAWBi3L,CA 95M W.ssmss.b,nN mass 4ia�4rcree vnm,yn,n,r,u near sMresa•aon Section 2Ce"Weshion and inflamution on btgredibift - -.. .. . EWeowvL1x ils Name CAS# TWA(mgh?) S (-gh?) CEH (W)hr) %by Wdght 1)So*;m hydrodde 1310.73-2 2 2 2 100 Toxicological Data Sodhpn hydroxide on Ingredients LD50:40 mal g(hAouse) LDkr. 500 mglkg[Rabbit) SWdon I Hame nTS kbPffflCatADn Potential Aerate Health Effects Very hazardous In Case Of skin CenW(Corrosive, irritant, permeator),Cf eye contact(trrflat,corrosive),or of Inhalation. The amount of tissue damage depends an length or contact and the concentration (sc(utiens).Eye contact can ressut in Corneal damage or blindness. Skin contact can produca severe bums with deep uloeratlarws and pemnanent scarring.Inh"on or dust wo produce lriFatien b gash"testirral Cr respiratory tract,characterized by burning,sneezing and coughing. Severe over-exposure Can produce pulmonary edema(severe,itie threatening king Injury,choking,unconsciousness or death. IrAwmation of the eye is characterized by redness,watering,and itching. Skin I flarematien is characterized by itching,sca ft reddag,or,occasionally,blistering.Ingestion can result in severe pain,burning of the mouth,throat esophagus. vomiting.diarrhea.Collaspe or death. Continued on.NeW Page WISTALS .: .•v�_: :w n- p L rK:¢.f:KY ..?zee..........-•....-.... »;.eMAf_y . :'it•....,w.,-...yam ..r .c,e,..� .,...s,x..-n-..r. .%F Sodium hydroxide 2 Potential Chronic Health CiiRCMOGENIC EFFECTS:None. Effects MVMGENIC EFFECTS: Mutagenie for manxrsalian somatic cats. TERATOGENIC EFFECTS:Not salable. DEVELOPiiIENTAL TOXICITY:None. Repeated exposure of the eyes to a tow level of dust can-produce eye Irritation. Repealed skin exposure can produce local skin destruction, or dermatitis: Repeated inhalation of dust can produce varying degree of respiratory imitation or lung damage.May aggravate eating lung diseases such as asttuna,bronchitis.a nphysema. Section 4 Fhst Aid Reams Eye MAR Check for and remove any contact lenses.Immediately flush eyes with plenty of water far at bast 1511111 Hold eyeft open during flushing.Odd wafter may be used. If Mallon persists,continue flushing. Get medical attention Immediately. Sidn Contact In case of contact,Immediately flush skin with plenty of weber for at least 15 rnirwbas while removing caKamirxabd emollient.Cold and shoes. Co*iue washing until skin does not fed skwv. Cow the' NAP Skin with an emolld water may be used Wash doting before reuse. Thoroughly dean shoes befcxe reuse -Get medical attention immediately. Serious Skin Contact Follow above directions.Flush skin with water for up to 60 minutes. Seek medical attention. Inhalation If ice.remrlove to fresh air. Sit in half upright posm'h'omm.Rest If breadit is difficult,give auygen.Monitor for respirator cfistress.Seek medial attention hurry. Serious InhalaRoe .Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a color,tie,bet or waisfnd. If training Is difficult,administer oxygen. N the victim is not breathing,give artificial respiration. Do not use rrx xAv-to mouth method if victim ingested or Inhaled the substarcce. Induce artificial respiration -• with the aid of a pocket mask equipped with a one-way valve or other proper respiralory nxedasal device. Seek hMedwte medical attention. ingestion Do not induce vomiting. 'mouth and give as riWich water as pcmlble to Mute noWialr Careen dolhing such as,a oollar,tie,belt or waistband. if vmnitbg docurs,have victim lean forward with head down,`rinse - mouth and administer more water.Seek immediate metrical attention. Serious Ingestion Follow above directions. Nmw give anything by moult to an unconscous person.If Mcbm Is not breathing . give artificial respiration. Do riot use mouth-to mouth method ifvictim ingested or inhaled the substance. trndxce arterial respiration with the aid of a pocl*'mask equipped with a am-way valve or alter proper respiratory medical device.Seek kmwdiate meckai attention. Section I Fine and Eft Gdon Dieta Flammability of the Product Non-flaninabla. nit-%affloo Temperature Not applicable. Flub Points None. Flammable Limits NO$ , oducts of Combustion Sodium oxide fumes. Fire Hazards ion Presence of Sodium hydroxide in contact with water and adds may generate enough heat to ignite alfacent combustible Various,Substances materials.Can read with metals such as akiminun,tin,and zinc to form flarmmable hydrogen gas. Explesil0o Hazards in Presence Risks of exµtlosion of the product in presence of mechanical Impact: None. of Varions Substances Risks of explosion of the prat ud in presence of static discharge Not available. Reacts to form explosive product with ammonia and silver.bate Fire Fmgbdng Media Dry chemical.carbon&Wde,water spray,or alcohol resistant loan Do not get water Inside containers.Cool anal Instructions containers with flooding quantities of water and well after fire Is out.Wear fol chemical protective doWN. l tank,ral car,or tank truck is involved in a fire,isolate for 8W metes(112 mile)In all directions.BxrGngulsh fire from maxirnxm distance. Special Remarks on Sodium hydroxide in contact with Ance metal dust will Ignite.Under proper motions of temperabmrs,pressure Fire Hazards and state,it can ignite or read violently with atxetadenyde,ally alcohol,allyt chloride,benzene 1,4 did,dnorime tritualde,1.2 didnoroethylehe,nitroethane,nihcmedwie,rnhaparaftins,nitropropeow,cinnamaldehyde, 2,2-dk hbro-3.14imethylbutane.PhospIm s bated with sodium hydroxide yields a product that may ignite spontaneously In air.See Section 10-Special Remarks on Reactivity. Cmdnued oa Next Page Sodium hydroxide Pape ARsrabe.3 Special Remarks on Explosion Sodium hydroxide reacts to farm explosive products With ammonia+silver mate. 1Barairds Benzene elda d of elyl b ffanfe Mared from SIM alcohol,and benzene sulfa ryl chloride to p ownce of aquesaus sodium hydradde,under vacuum distillation,residue darkened and exploded. Sodium Hydrwafe+krqxn WUMWmfuran.which can cant h peroddes,can raise serious explosbhs Dry mixtures of sodium hydroxide and sodium telrehydraborate Iterate hydrogen explosively at 230-270 deg.C. Sodium Hydrerdde reacts with sodium salt of trkfiloropherwi+maW alcohol+ttichlorobarom+heat to cower an wOosiom Section 6.Accfdenral/Remise Measures Small spM Absorb or cover with dry earth,sand,or other non-combustible material and transfer to waste disposal ocrkairror Errecessaryt Neutralize the residue with a dilute sWullon of grade acid Flush am with water. L+rgc Spill Evacuate am Remove all ignition seuroes and ventilate area.Stop leak if without risk. Do not go water inside contairner.Do not tocsin spilled material. Use water spray to reduce vapors. Prevent entry into surface water, sewers,basements or confined areas:dike lf needed. Notify appropriate government,-ocm9adonal hearth and safety and environmental sutiafthles.Neutralize the residue with a die solution of acetic add. Cal fire department immediately. rely. Section 7.liar ding and Storage Precautions Use with adequate ventilation.Do not breathe dust. Never add water to this product In case of insufficient ve dOli( h,wear suitable respiratory equipmenL Always add sodium hydroxkte b water and provide agitation.Use cold water and sfir in small amount in skw(y.Avoid contact with skin and eyes. Storage• Hygroscopic. Keep container tightly.dosed and dry. Keep container in a coal,well-kentisted arm Do not . store above 23T(73.4TF Keep away from Incompatibles such as m odnang ages*.reducing ago*, muihais,adds,ai *.water and crWrilc materials. -. F w•: w , Seaftn. EVowre Con&O&IW-w11af PrigeCflOn . . '77. - Engineering Controls Use process endosures,veil "On. or otter engirneering ux".to keep airborne keels b6 m recomxmerrded exposlxe&ft. if user operations generate dust.fuine'or_east,use local erdraust v "on to keep exposure to aabome contaminants below the exposure firm.Eye wash and safety showers are necessary. Personal Protection Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approvedicerthfied rasosow or equtvaiemL Glames.Face stnald. Personal Protection in Case of Splash gaggles. Full suit Vapor and dust respirator. Boots. Gloves. A self contained breathing apparabrs a L-V Spin should be used to avoid Inhalation of the product.Chemical protective dotlnig.Suggested protective clothing might not be sufficient consult a specialist BEFORE handling this product Exposure Units STEL•2 (mWffr) from ACGIH CTLV)[United States) TWA:2 CEIL:2 (mghn) firm OSHA(PEL)(United States] CELL 2 (mgim3) firm NIOSH Consult local authorities for actable exposure limits. Section 9 Physical and Monica properties Physical state and appearance Solid. Odor Odorless. Molecular Weight 40 gird Taste Not available. p19(1X sohr/uraty) 13.5[Basic.] Color White. iBoRing Point 1388-C(263OXF) Melting Point 323-C(613.4°F) Critical Temperature Not available. Specific Gravity Z13(Water=1) Vapor Pressure 1 mm of Hg at 73V C. Vapor Density Not avallable: Volatility Not available. Con>3inued on Next-Page Sodium hydroxide Pago iltaasber 4 Odor Threshold Not available. Water/oti Dial Codr. virtually,0 iomieity(M water) Not available- Disperskm Properties See salubrity in water. Solubility Easily soluble in cold water. Section 10.StaWdy and Reactitiily Daft Stability The product is stable under nomral conditions. Iustabli ty Temperature Not avaPh"a Cond'it,'oms of Imtabillty inoo rVAWe materials,moisture,moist air bcompatibility with various Avoid contact WM organic ambarials,acids,water,flanw able liquids,organic halogens.arnphoterie nletaFs and substances mlro corrtpaunds.Reac M with taddmng agents reducing agents.See Special Remarks an ReacMy. Cerrodvity Corrosive to al rninurn,tin,zinc,copper and most alloys in which they are present C oche to steel at temperatures above 140'C. Special Remarks on Hygnoscopta Much heat is evolved when scid material is dissolved in water. Therefore odd water and caubat Reactivity - rcicusthe used for.this process. , 4 }So*ff ft roride scl bmand octand+ddbgr w4 unng a warts-W cf a.reacxlon n of o*m anti dihoran 1 in Y roQM is very exatherttdc,a.mrd explosion being noted on one occassian. $. ' Raac(iv�Anater all-raneral acids.aN ac s.a _ orgarniF: afdet►jrdes,cargarnates, orygirr.hak>�ens t - =keSoiies,aoCd`chlarides,strong bases,oxidizing agents reducing age its.flarnrrraWaPoilds,powdered metals E meWS,metal campadnds,nitrides.nitrites,nitro corn Pounds.acetic anhydride chVrohydrin,chlecosulfo k; . ^r aad,.etltylene cyanohydrin,glyoxal,hydrasulfuric acid,ofeuni,propiolactone,acykxxtrrle;RhosMic ro= pentoxide,Chloroathand,Ch►oolbMI-Inediand,t*ahydrdxrate.cyanogen wide, 1,2,4.5 tef aciftobenzene,cinnameldehyde, tormatdehyde hydroxide. m ..Produces hydrogen gas when it reacts with sodium tetrahydroborate or certain metals such as Annnum,tin,zinc. Can form spontaneously ffanumble clu naicals upon contact with 1.2-dichicroalhylans.twhioreehylene,or . lonoetitane.Can produce carbon moncedde cgarrcbntad with solutions of sugars,such as truetose,lactose Special Remarks on. Very corrosive to aluminum and other instals in presence of moistm Corrosh* Polyaserfintiom Will not occur However,can violently induce polynWzalon with acetaldehyde,ecrdein and acrylonrrle. Section It.Toxfoological Monnradon Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals 1.D50:40 mglkg(Mouse) LDla SM mglkg PRabbit) Chronic Effects on Humans MUTAGENiC EFFECTS: Mutagenic for nnarrsnaiarn somatic cells. Other Toodc Effects an See Section 3-Eudrerrlely hao ardous is case of inhalation(lung corrosive). Humans Very hazardous in ease of skin contact(convolve,iritant,perrrmtor),of eye contact(corrosive).of ingestion,. Special Remarks on Highly bowie to aquatic ife. Toxicity to Animals Special Remarks on May affect genetic material. Investigation as a mutagen(cytogenetic analysis) Chronic Effects on Humans Special Remarks on other Irtmnediately dangerous to Me or health at 10 mgl m3 Toxic Effects on Humans Cont`inuedon!Next Page Sodium hydroxide PA90 Blunter:s Acute Potential Health Eftcts: Skin: May be harmful if absorbed through skin. Causes severe skin irritation and bums. May cause deep perneba ulcers of the skin. Eyes: Causes severe eye irriraltm and bums. May cause cdnerrucat cor4u ndmijis and comeal darpge kdralstim: Hannfui if inhaled. Cauca severe irritation of the respiratory tract and mucous membranes with coughing,burns,breathing ddrm ty,and possl*coma. Irritation may lead the chemk:al prowwriiis and Pulmonary edema. Causes chenioal bums to the respiratory tact and mucous membranes. IrKiNtion: May be fatal if swallowed. May cause severe and permanent damage to the digestive tract. Causes severe gastrointestinal tract irritation and burns. May cause perforation of the digestive tract Causes same pork+,nausea,vomiting,crwrhea,and shock. May cause corrosion and,perrnarnent destructiom of the esophagus and digestive tract. Secilon 12 Ecolog CW Wbrmaftn EcoWdeity LC100: 180 ppm24 hr at 25'C[Cyprkvis Carpio];125 ppmM6 hr[fLm Mosquito fish[; 99 mg4146 hr[TLrnt Biuegffl BOOS and COD Not availeWe. odnets.ofBtodegradad- Degrades readily by reacting with natural mton dodde.ilorming sodcum carbonate. Torfdty r�)wodacts The product itself and its products of degnadalion are not toodc. of Special Reaarks 00 the Not avaltabkL y; P!oducts of Biodegradation. . dtlsr�fior�s �;, . s act-vbposai If this product becomies a waste t could meet the criteria--of a hazardous waste as defined y'h ..., !9y tile Resource Cornservatien Recovery Act(RCRA)40 CFR 261.Before d should be dderrrl�ti a waste meets the criteria of a hazardous waste.Consuft local,state,federal for speafic Harmful to aquatic we at low carxxr4ratior.Do not contaminate domestic or InVation water supplies or bodies of water. F f4.�T,rwpert MbMIWOn ation Class&Corrosive material :Sodium hydroxide,sold UNNA:1823 PG:uions for Air transort IATAiICAO-Class 6,UN 18M,PG I1 w) Section 1&Other-Regulatorybdbmiation and Pictograms Federal and State IEirnois toode substances disclosure to errnpbyee act Sodium hydroxide Regrlatioas Illinois ctrerrdcal safety act Sodium hydro dde New Yak release reporting list Sodium hydroxide, Rhode Island RTK hazardous substances:Sodium hydroodde Minnesota: hydroxid RTK Sodium e rordde Massadpaetts RTK:Sodium hydroxide New Jersey:Sodium hydradde LOUISOne spill repor ft Sodium hydroxide California Director's List of Hazrdous Substances:Sodium hydroxide TSCA 8(b)inventory:Sodium hydroxide CERCLA:Hazardous substances.:Sodium hydroxide:1000 lbs.(453.6 kg) Caifornia Proposition 65 Ooes not require warning under CA Prop 65. Warsrmt Corned on Next Page Sodium hydroxide Piye fYYraber.6 Omer R ftmkfi as OSHA:Hazardous by definition of Hazard Corrmunicaban Standard(29 CFR 1910.1200). EINECS:This product is on the European Inventory of E*ft C nmerciai Chemical Substances. SARA Section 311 and 312:The product is to be reported under the krimediate(Acute)and Reactive Health HazaRls DSL:This product is on the Domestic Substances List.of Canada. On the Air Contaminants.Regulatory List and the Registered Pesticide List. Otter Classifiation WBIMIS(Goads) CLASS E:Corrosive sofd. DSCL(EEC) R35.Causes severe bums. S26-In case of oorrtaa with eyes,rinse lmrrreira0elir with plenty of water and seek medical advice. 528-After contact with skin,wash IMmedi, * with pier*of water ,MT/39-Wear sta7able protective dolhirg, gloves and well"protection. S313-in case of kisufficient vengatim,wear writable respiratory equipment. S45-in case of accident or 9 you fed urwak seek medial advice immediately(show Ore label where possit b). HMIS(U.S.A.) 3 National Fire Protection Inr p Association(U S.A.) 2 mare' r POISM YAMS(Canada) (Pktograms) 44. DSCL(Europe) (Pictograms) TDG(Canada) Mctograms) - ,'!� ADR(Europe) gictograms) Y Protective Equipment Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certriied respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Continued on Kext Pepe Sodium hWmxide Pace Nrerrbec 7 Splash gaggles. Section 16 Odw hawnaiibn Code WIND Referewes Hazardous Substances Data Bank,U.S.National Ubrary of Meftw,Bethesda.Mffybrxl.toeafet.lrYrr.nM gov. Intemallonal Chemical Safety Cards,National Institute for Occupational Safety and Health.Cinch rali.OH. www.cdc.gov/nIosh OSHA,U.S.Deparftnent of Labs;Washington D.C.,www.osho.gov. Marwtadurees,Material Safety Data Sheet MSDS Sokttiorrs,www.msds corn Spedalzed k>Fomration Services,U.S.National Lbrary d Medicine,Department of Health and Human Servicm diernAs.ol nALgov. Chemical Carcinogenesis Research information System,U.S.National Library of Meddne.Beftsda.W418-1. tDmetrim.nih.gov. S1 .. Cor►adieiattous s. Note .. ».. . _ Vaiidated by Debbie Andres on&13&05 t i CALL 12O 9962010 =) Noftc to Reader chmiefib xW POW URLM w how*ani sh"be and N"eardsw nits A6rerla! arr Sisss(�1 spyl&s w4 r d1s a�sk�K asraelGq aL tf,itr�rlru tr e+rolL�nixff►.airrna�s.;.$ikspirrYper.Kars.era�a�raMfa�,tr+yr'Iw�reMuKsr.rws�nt.:NlsalirAlSAT hsWbsdk�ro5rrapgrrJe�Lj�rrlerrrwlr .., alb+1r�►/K+swlPnea�wrdare+swar�2�rer�E�ipsrrjxra If7�disAlSDstrbssalwTtare�tullarjr�drlsse/�Ble.Sur6ryrC+�i�fastr/.amswer . rx: sisussglav aaor!= oke wnuwdkff im J 1 Distributed by HUBBARD-HALL INC. yo 7100 I NorFalco Inc. W. ., C,O, ,ri Vl1 °�� Z`IS� - Safety Data Sheet NorFalco Sales Inc. W.�W. A 41e o- 0%SULFURIC ACID SECTION 1.IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade Name 77%-100%Sulfuric Acid Product Code None Manufacturers/Distributors NorFalco Inc.,6000 Lombardo Center,The Genesis Big,Suite 650 Seven Hills,OH 44131 NorFalco Sales Inc.,6755 Mississauga Road,Suite 304,Mississauga,Ontario L5N 7Y2 Information Contact Andrd Auger,Administration Assistant Product information 1-905-542-6901(Mississauga) Phone Number(Transportation Emergency) Canada 1-877-ERP ACID(377-2243) Phone Number(Transportation Emergency) U.S.A.1-80042449300 CHEMTREC Phone Number(Medical Emergency) 1418-656-8090 Phone Number(Emergency) CANUTEC 1-613-996-6666 Synonyms Dihydrogen Sulfate;Oil of Vitriol;Vitriol Brown Oil;Sulphuric Acid. Acide suifruique(French) Name/Chemical Formula Sulfuric Acid /H2SO4 Chemical Family Acid Utilization Chemical industries;Water treatment;Fertilizer;Pulp and Paper. Manufacturers CEZinc on behalf of Noranda Income Limited Partnership,Salaberry-de-Valleyfield(Quebec)Canada J6T 614 Xstmta Copper,Home Smelter,Rouyn Noranda(Quebec) J9X 5B6 Xstrata Zinc,Brunswick Smelting,Belledune,New Brunswick EOB I GO Xstmta Copper,Kidd Metallurgical Division,Timmins,Ontario P4N 7K1 Xstrata Nickel,Sudbury Operations,Falccobridge,Ontario POM ISO SECTION 2.HAZARDS IDENTIFICATION WHMIS(Canada) CLASS D-IA:Very toxic material causing immediate and serious effects (@G CLASS E:Corrosive material Labelling(EEC) C Corrosive 0 _l Other hazards Danger. Extrernely corrosive. Causes severe bums and eye damage. Mist : Causes respiratory irritation. Harmful if inhaled.Har redid or fatal if swallowed. - Environmental hazards Strong acid.Highly toxic to plants and to aquatic organisms. SECTION 3.COMPOSITION/INFORMATION ON INGREDIENTS Name CAS No Percentage(%) EC No R Phrases' Sulfintc(Acid) 7664-93-9 77%to 100% 231.639-5 R35 60 Deg Technical 7664-93-9 77.7 231.639-5 R35 66 Deg or 93%Technical 7664-93-9 93.2 231-639-5 R35 1.835 Electrolyte 7664-93-9 '93.2 231-639 5 R35 98%Technical 7664-93-9 98 231-639-5 R35 99%Technical 7664493.9 99 231-639-5 R35 100%Technical 7664-93-9 too - 231.639-5 R35 Water 7732-18-5 0-22 231-791-2 Note 1:See section 15 for the complete wording of risk phrases. SECTION 4.FIRST-AID MEASURES Eye Contact Remove contact lenses if present Immediately flush eyes with plenty of water,holding eyelids open for at least 15 minutes.Consult a physician.If medical treatment must be delayed,repeat the flushing with tepid water or soak the affected area with tepid water to help remove the last traces of sulfuric acid.Possibility of conjonctiviris,severe irritation,severe bums,permanent eye damage. Skin Contact Remove contaminated clothing and shoes as quickly as possible protecting your hands and body. Place under a deluge shower for 15 minutes. Flush exposed skin gently and thoroughly with running water(Pay particular attention to:Folds, crevices,creases,groin). Call a physician if irritation persists. May irritate skin,cause burns (Highly corrosive)and possibility of some scarring. Wash contaminated clothing before reusing.While the patient is being transported to a medical facility,continue the application of cold,wet compresses.If medical treatment must be delayed,repeat the flushing with tepid water or soak the affected area with tepid water to help remove the last traces of sulfuric acid. Creams or ointments SHOULD NOT be applied before or during the washing phase of treatment. Inhalation Take precautions to avoid secondary contamination by residual acids. Remove the person to fresh air. If not J breathing,give artificial resp ation.Difficult breathing:Give oxygen.Get immedi edical attention.Possibility EE •gp-.iR a,t � +y.rf'.'^F i'\5...+ r: •�".c"f f 1Ra':a`�i Hs...-'3 ` '•-i:i to;.L..S vet c, T'°�'9 i 2010 1/6 o NorFalco Inc. NorFalco Sales inc. 77%-100%SULFURIC ACID of damage to the upper respiratory tract and lung tissues.Maintain observation of the patient for delayed onset of pulmonary oedema.May cause irritation to the upper respiratory tract:Coughing,sore throat,shortness of breath. ingestion DO NOT INDUCE VOMITING.Conscious and alert person:Rinse mouth with water and give h to 1 cup of water or milk to dilute material.Spontaneous vomiting:Keep head below hips to prevent aspiration;Rinse mouth and give %z to I cup of water or milk. UNCONSCIOUS person DO NOT induce vomiting or give any liquid. Immediately obtain medical attention. Notes to Physicians Continued washing of the affected area with cold or iced water will be helpful in removing the last traces of sulk acid Creams or ointments should not be applied before or during the washing phase of the treatment. SECTION 5.FIRE-FIGHTING MEASURES Flash Point Not available Flammable Limits Not available Auto-lgaidon Temperature Not available Products of Combustion Releases of sulfur dioxide at extremely high temperatures. Fire Hazard Not flammable Explosion Hazard Reacts with most metals,especially when dilute:Hydrogen gas release(Extremely flammable,explosive).Risk of explosion if acid combined with water, organic materials or base solutions in enclosed spaces(Vaccum tnreks, tanks). Mixing acids of different strengths/concentrations can also pose an explosive risk in an enclosed space/container. Extinguishing media ERG(Emergency Response Guidebook):Guide 137 When material is not involved in fire,do not use water on material itself Small An:Dry chemical or COz.Move containers ftvan fire area if you can do it without risk. Large Are: Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply:knock down vapors only. Fire involving Tanks or Car/Trailer Loads: Cool containers with flooding quantities of water until well after fire is out.Do not get water inside containers.Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.ALWAYS stay away from tanks engulfed in fire. Protective equipment Evacuate personnel to a safe area.Keep personnel.removed and upwind of fire.Generates heat upon addition of water,with possibility of spattering. Wear full protective clothing.Runoff from fire control may cause pollution. Neutralize run-off with lime,soda ash,etc.,to prevent corrosion of metals and formation of hydrogen gas.Wear self-contained breathing apparatus if fitmes or mists are present. SECTION 6.ACCIDENTAL RELEASE MFASr RES Measures Review Fire and Explosion Hazards and Safety Precautions before proceeding with clean up. Stop flow if possible.Soak up small spills with dry sand,clay or diatomaceous earth. Methods Dike large spills,and cautiously dilute and neutralize with lime or soda ash,and transfer to waste water treatment system.Prevent liquid from entering sewers,waterways,or low areas. If this product is spilled and not recovered, or is recovered as a waste for treatment or disposal,the Reportable Quantity(U.S.DOT)is 1000 IN(Based on the sulfuric acid content of the solution spilled).Comply with Federal, State,and local regulations on reporting releases. Protective equipment Review Fire Fighting Measures and Handling (Personnel Protection).sections before proceeding with clean- up.Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. SECTION T.HANDLING AND STORAGE Handling DO NOT get in eyes, on skin,or on clothing. Avoid breathing vapours or mist. Wear approved respirators if adequate ventilation cannot be provided Wash thoroughly after handling. Ingestion or inhalation :Seek medical advice immediately and provide medical personnel with a copy of this SDS.NEVER add water to acid Conditions for storage Sulfiuic acid must be stored in containers or tanks that have been specially designed for use with sulfuric acid.DO NOT add water or other products to contents in containers as violent reactions will result with resulting high heat, pressure and/or generation of hazardous acid mists. Keep containers away from heat, sparks, and flame. All closed containers must be safely vented before each opening.For more information on sulfuric acid tanks,truck tanks and tank cars including safe unloading information go to www.norfalcocom. 2010 1J6 NorFalco Inc. NorFalco Sales Inc. 77%-100%SULFURIC ACID SECTION 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters _ACGIH(U.S.A.)2009 OSHA(U.S.A.) ;Name CAS# TLV-TWA(mg1m3) PEL TWA(mg/m') _Sulfuric(Acid) 7664-93-9 0.2(thoracic fr.) 1 60 Deg Technical 7664-93-9 0.2(thoracic fr.) I _66 Deg or 93%Technical 7664-93-9 0.2(thoracic fr) 1 1.835 Electrolyte 7664-93-9 0.2(thoracic fr.) 1 98%Technical 7664-93-9 0.2(thoracic fr.) 1 99%Technical 7664-93-9 0.2 thoracic fr.)1 100%Technical 7664-93-9 0.2(thoracic fr.) 1 Water 7732-18-5 Not established Not established ACGIH:American Conference ofaovernmenmllmhcsMa/Hygienrsxs OSM:Oceapalianal Safety and Health Adminatranan. Note: Sulfuric(Add :Exposure limits maybe different in other jurisdictions.NIOSH REL-TWA(510 hours):1 mg/m3;IDLH:15 mg/m3. Consul[local authorities for aceviable exposure limits. Engineering Controls Good general ventilation should be provided to keep vapour and mist concentrations below the exposure limits. Individual protection Chemical splash goggles;Full-length face shield/chemical splash goggles combination;Acid-proofgauntlet gloves, apron, and boots ; Long sleeve wool, acrylic, or polyester clothing; Acid proof suit and hood ; Appropriate NIOSH respiratory protection. In case of emergency or where there is a strong possibility of considerable exposure,wear a complete acid suit with hood,boots,and gloves.If acid vapour or mist are present and exposure limits may be exceeded,wear appropriate NIOSH respiratory protection. SECTION 9.PHYSICAL AND CHEMICAL PROPERTIES Physical State and Appearance Liquid(Oily;Clear to turbid) Odour Odourless -`� Molecular Weight 98.08 Colour Colourless to light grey PH(lab soln/water) <I Volatility <1(Butyl Acetate=l.0) Boiling Point 193aC to 327 aC(379aF to 621°,l @ 760 rain Hg Vapour Density 3.4 Melting Point -35aC to I IOC(-31aF to 520F) Dispersion Yes(Water) Vapour Pressure <0.3 nun Hg @ 250C(77 OF) Solubility Yes(Water) <0.6 ram Hg @ 380C(100 OF) GRADE Boning Point Freezing Point Specific Gravity DEG aC DEG OF DEG'C DEG OF 60 DEG TECHNICAL 193 380 -12 t0 1.706 66 DEG or 93%TECHNICAL 279 535 -35 -31 1.835 1.835 ELECTROLYTE 279 535 -35 -31 1.835 98%TECHNICAL 327 621 -2 29 1.844 _ - 99%TECHNICAL _ _ 310_ 590 4 40_ 1.842 T00='/o TECHNICAL 274 4 526 _ 11 S 1 1.839 - - SECTION 10.STABILITY AND REACTNtTY Stability Yes(Under normal conditions of ambiant temperature) Reactivity Reacts violently with water,organic substances and base solutions with evolution of heat and hazardous mists. Conditions to avoid Sources of ignition,Heat:Possibility of decomposition Release of toxic gases and vapours(Sulfur oxides SO2, S03) Polymerization Polymerization will not occur. Materials to avoid Vigorous reactions with :Water;alkaline solutions;Metals,metal powder;Carbides; Chlorates;Fulminates; nitrates;Picrates;Strong oxidizing,reducing,or combustible organic materials.Hazardous gases are evolved on contact with chemicals such as cyanides,sulfides,and carbides. Corrosi-My Yes SECTION 11.TOXICOLOGICAL INFORMATION Routes of Entry Ingestion. Inhalation.Skin and eye contacts. Carcinogenicity Strong inorganic acid mists containing sulfuric acid(Occupational exposures):PROVEN (Human,Group 1, ,ARC) ;SUSPECTED(Human,Group A2,ACGIH);Group X(NTP) ;Classification not applicable to sulfuric acid and sulfuric acid solutions. Mutagenicity Cytogenic analysis:Ovaries 4 mmol/L(Hamster).(RTECS). 2010 3/6 NorFalco Inc. NorFalco Sales Inc. -1 a- o SULFURIC ACID J Teratogeniclty Not terstogenic(Mice,rabbits). Acute toxicity ORAL(LD50) : 2 140 mg/kg(Rat);INHALATION(LC50,2 hours):510 mg/m3(Rat) ; 320 mg/m3(Mouse). (RTECS). Acute Effects May be fatal if inhaled or ingested in large quantity.Liquids or acid mists:May produce tissue damage:Mucous membranes(Eyes,mouth,respiratory tract).Extremely dangerous'by eyes and skin contact (Corrosive). Severe irritant for eyes :Inflammation(Redness,watering„itching).Very dangerous in case of inhalation(Mists)at high concentrations:May produce severe irritation of respiratory tract(Coughing,shortness of breath,choking). Chronic Effects Target organs for acute and chronic overexposure(NIOSH 90-117):Respiratory system,eyes,skin,teeth. Add mists : Overexposure to strong inorganic mists containing sulfuric acid : Possibility of laryngeal cancer (HSBD,IARC).Possibility of irritation of the nose and throat with sneezing,sore throat or runny nose.Headache, nausea and weakness.Gross overexposure:Possibility of irritation of nose,throat,and lungs with cough,difficulty breathing or shortness of breath. Pulmonary edema with cough, wheezing, abnormal lung sounds, possibly progressing to severe shortness of breath and bluish discoloration of the skin.Symptoms may be delayed.Repeated or prolonged exposure to mists may cause:Corrosion of teeth. Contact(Sldn) : Possibility of corrosion, burns or ulcers. Contact with a 1 % solution:Possibility of slight irritation with itching,redness or swelling. Repeated or prolonged exposure(Mist) :Possibility of irritation with itching,burning,redness,swelling or rash. Contact(Eye) : Possibility of corrosion or ulceration(Blindness may result). Repeated or prolonged exposure (Mist) :Possibility of eye irritation with tearing,pain or blurred vision. Ingestion: Immediate effects of overexposure:Burns of the mouth,throat,esophagus and stomach,with severe pain,bleeding,vomiting,diarrhea and collapse of blood pressure.Damage may appear days after exposure. Toxicity Persons with the following pre-existing conditions warrant particular attention Sulfuric(Acid):Laryngeal irritation. Eating drinking and smoking must be prohibited in areas where this material is handled and processed Wash hands and face before eating,drinking and smoking. SECTION 12.ECOLOGICAL INFORMATION Ecotoxicity Aquatic toxicity:Slightly to moderately toxic. Biuegill Sunfish(LC50;48 hours) :49 mg/I(Tap water, 20°C,conditions of bioessay not specified). J (HSBD). Flounder(LC50;48 hours):100-330 n%q(Aerated water,conditions of bioessay not specified).(HSBD). Toxicity to Animals Toxicity to aquatic life increases with lowering pH.At pH lower than 5,only a few fish species can survive and at pH lower than 4,aquatic life is rare. EYE:Concentrated compound is corrosive.10%solution: Moderate eye irritant. SKIN:Concentrated compound is corrosive.10%solution: Slight skin irritant. Single and repeated exposure:Irritation of the respiratory tract;Corrosion of the respiratory tract;Lung damage;Labored breathing;Altered respiratory rate;Pulmonary oedema.Repeated exposure:Altered red blood cell count. Mobility(Soil) Easy soil seeping under rain action Persistence and degradability Sulfate ion:Ubiquitous in the environment.Metabolized by micro-organisms and plants. Bioaccumuladon Sulfate ion : Ubiquitous in the environment. Metabolized by micro-organisms and plants without bioaeemrralation.. Biodegradation Products Not available Biodegradation Products(Toxicity) Not applicable Remarks on Environment Due to the product's composition,particular attention must be taken for transportation and storage.Protect from rain because the run-off water will become acidic and may be harmful to flora and fauna BOD5 and COD Not available SECTION 13.DISPOSAL CONSIDERATIONS Disposal methods Cleaned-up material may be an hazardous waste on Resource Conservation and Recovery Act(RCRA)on disposal due to the corrosivity characteristic. DO NOT flush to surface water or sanitary sewer system Comply with Federal,State,and local regulations.If approved,neutralize and transfer to waste treatment system. SECTION 14.TRANSPORT INFORMATION TDG(Canada) CLASS 8 Corrosives PIN UNI830 SULFURIC ACID PG II Special Provisions(Transport) None_ DOT(U.S.A.)WO(Maritime) Proper Shipping Name SULFURIC ACID l Hazard Class 8 UN No 1830 2010 416 NorFalco Inc. NorFalco Sales Inc. e- o ULFURIC ACID DOT/IINO Label CORROSIVE Packing Group It Reportable Quantity 1000 lbs(454 kg) Shipping Containers Tank Cars,Tank Trucks,Vessel ERG Guide 137 SECTION 15 REGULATORY INFORMATION Labelling(EEC) EU(Directive 67/548/EEC): Sulfuric(Add):C Corrosive(Pictogram) Annex I Index number:016-020-00.8;EU Consolidated Inventories:EC Number 231-639-5 C>15% C;R35;S2,26,30,45. Risk Phrases(EEC) R35-Causes severe burns Safety Phrases(EEC) S26-In case of contact with eyes,rinse immediately with plenty of water and seek medical advice S30-Naver add water to this product S36/37/39-Wear suitable protective clothing,gloves and e)ctfwc protection S45- In case of accident or if you feel unwell,seek medical advice immediately(show the label where CEPA DSL(CANADA) CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) : On the Domestic Substances last (DSL);Acceptable for use under the provisions of CEPA. Sulfuric Acid is a Class B Drug Precursor under Health Canada's Controller Drug and ubtstances get and Precursor Con&olRRegulations. Regulations(U.S.A.) CERCLA Section 103 Hazardous substances(40 CFR 302.4);SARA Section 302 Extremely Hazardous Substances(40 CFR 355) : Yes; SARA Section 313.Toxic Chemicals (40 CFR 372.65); US: TSCA Inventory:listed: Sulfuric(Add)(Final RQ): 1 000 pounds(454 kg) Sulfuric Acid is subject to reporting requirements of Section 313,Title III ofthe Superfund Ammdinents and Reauthorization Act of 1986, (SARA),40 CFR Part 372. Certain companies must report emissions of Sulfuric Acid as required under The Comprehensive Environmental Response Compensation and Liability Act of 198Q(CERCLA),40 CFR Part 302 For more information call the SARA Hotline 800424-9346. Strong Inorganic Acid Mists Containing Sulfuric Acid:Chemical listed effective Mardi 14,2003 to the State of California,Proposal 65 U.S. FDA Food Bioterrorfsm Reeulations : These regulations apply to Sulfuric Acid when being distributed,stored or used for Food or Food Processing. TSCA(EPA,Toxic Substance Control Act)Chemical Inventory(40 CFR710):Listed Sulfuric(Add) Classifications HCS(U S.A.) Corrosive liquid NFPA(National Fire Protection Association)(U.S.A.) fall-WO Special_-- ' Special Hazard ACID — --NPC tad SECTION IS.OTHER INFORMATION References -TLVs and BEIs(2009).Based on the Documentation of the Threshold Limit Values for Chemical Substances and Physical Agents&Biological Exposure Indices.ACGIH,Cincinnati,OH—httpY/www.acgih.org -CCOHS (2009)-Canadian Centre for Occupational Health and Safety-http•1/www.ccohs.ca/ -CSST(2009)-Commission de la Santd et de la Sdcurite du Travail(Qudbec).Service du rdpettoire toxicologique- httpJ/wwwxeptox.csst.gc.ca/ -ERG(2008).Emergency Response Guidebook,U.S.Department of Transportation,Transport Canada,et le Secretariat of Communications and Transportation of Mexico - -HSDB(2009)-Hazardous Substances Data Bank.TOXNETV Network of databases on toxicology,hazardous chemicals,and environmental health.NLM Databases&Electronic Resources,U.S. National library of Medicine,NHI,8600 Rockville Pike, Bethesda,MD 20894-httpJ/toxnet.nhmrih.gDvlcgi-bin/sis/htmlgen?HSDB -ESIS:C&L(Classification and Labelling),substances or preparations in accordance with Directive 67/548/EEC(substances)and 1999/45/EC(preparations), -ESIS:EINECS(European Inventory of Existing Commercial chemical Substances)O.J.C 146A,15.6.1990 -ESIS:EINECS corrections published in O.J.C 54/13 01-03.2002,2002/C54/08. -IARC-Monographs on the Evaluation of Carcinogenic Risks to Humans(collection)-httpY/www-cie.iwo.fr/ -Merck Index(1999). Merck&CO.,Inc,12th edition 2010 516 i NorFalco Inc. NorFalco Sales Inc. o- o ULFURIC CID -NIOSH U.S.(2009)-Pocket Guide to Chemical Hazards-httpl/www.cdc.gov/niosh/npg/ -Patty's Industrial Hygiene and Toxicology,3rd Revised Edition -Reglement sur les produits controlds(Canada) -RTECS(2009).Registry of Toxic Effects of Chemical Substances,NIOSH,CDC -Toxicologic industrielle&intoxication professionnelle,3e 6dition,Lauwerys -TSCA(2009)-U.S.EPA Toxic Substance Control Act,Chemical Inventory.System of Registries(Solt),Substance Registry Services,httpd/iaspub.epa.gov/son intemet/registry/substreg/searchandretrieve/substancesearcWsearciLdo Glossary CSST . :Commission de la Santo et de la Securit6 du Travail(Qudbec). HSDB :Hazardous Substances Data Bank. LARC :International Agency for Research on Cancer. NIOSH :National Institute of Occupational Safety and Health. NTP :U.S.National Toxicology Program. RTECS :Registry of Toxic Effects of Chemical Substances Note For fiuther infmrnation,see NorFalco Inc.Sulfuric Acid v Storage and Handling Bulletin». Because of its corrosive characteristics and inherent hazards,Sulfuric Acid should not be used in sewer or drain cleaners or any similar application; regardless of whether they are formulated for residential,commercial or industrial use.NorFalco will not knowingly sell sulfuric acid to individuals or companies who repackage the product for sale as sewer or drain cleaners,or any other similar use. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. For additional information,please visited our website: .rww.norfalcoxom Written by:Groupe STEM Consultants/NorFalco Sales Inc. Complete revision:2010-01-24 Partial review:None Previous complete revision:2009-01-24 Verified by: Guy Desgagnds and Eric Kuraitis,Technical Representative-Sulfuric Acid Request to: Andr6 Auger,Administration Assistant Tel.:(905)542-6901 extension 0 Fax:(905)542-6914/6924 NorFalco Sales Inc.,6755 Mississauga Road,Suite 304,Mississauga,Ontario L5N 7Y2 Notice to Reader Although reawnable precautions have been token in the preparation of the data contained herein,it it offered solely for your information,considerallon and investigation.NorFalco Sales Inc emndr no ivarramy and assumes no responsibility for the accuracy of the content and ewremly disclaims all habilily for reliance thereon.This material safety data sheet provides guidelinu for the soe handling and processing of this product•,it does not and cannot advise an all possible situations,therefom your spec#?c use of this product should be evaluated to deie mine Ifadditton l precautions are required Individuals exposed to this product should read and understand Air information and be provided pertinent training prior to working with this product. 2010 6/6 n p t 20 2008 17. 04 HP LASERJET FRX P. 1_ 5 i Methanol M EfA tiX .,rMiW'I.r.•fr.vN MATERIAL SAFETY DATA SHEET ThIS Aliiterfa/Safety Date Sheet comp►lea W th the Canadian Controlled product Regulations and the Unhod States Oacupatlonaf Safety and Health Adminlstret/on(OSHA) hazard cornmun/catlon standard. 1. Product and.Supplier Identification —� Product: Methanol(CH30H) Non-Emergency Tel.0 (604)661-2000 Synonyms; Methyl alcohol,methyl Emergency Tel,#: 1-600.4245300 hydrate,wood spirit,methyl (CHEMTREC) (Canadc and US) hydroxide Product Use: Solvent,fuel,feedstock Company Methanex Corporation, Note;CHEMTREC number to be laved only in ldendflcatlon; 1800 waterfront Contra, the event of chemical emergencies involving a 200 Burrard Street, spill,leak,We,exposure or sodden:involving Vancouver,B.C. chemlcais. V0C 3M1l Importer; Methanex Methanol Company Mutts 1160—15301 Dallas Parkway Addison,Texas 75001 Telephone:(972)7024900 2. Compooltion Component %(w/w) EXpoaureLimite LOw LC, Methanol 99.100 AC©IH TLV TWA.,200 ppm,skin 6628 mglkg 64000 ppm (CAS 67,-5e-1) STEL:250 ppm,skin notation (qrelirat) (Inhalation/rot) OSHA PEL;200 ppm TLV Basis,critical effects; 20 m1/4 neuropalhy,vision, central nervous system (derr.?au --- —__ 1 rabbit Exposure limits may vary from time to time and from one jurledlotlon to another.Check with local regulatory agency for the Axposure Ilmlts In your aroe. Disfributed by HUBBARD-HALL INC. METALS TESTING COMPANY INX4 s ,sM OIt11� aiNtJoa►amr 7 4 DATE` - \ Methanex Corporation -1- Octobtr 13,200 Oct 20 2008 17: 04 HP LRSERJET FAX r Methanol MaAH X 3. Hazards identification Routes of Entry: Skin Contact:Moderate Eye Contact:Moderate Ingestion:Major innalatlon:Major Enacts of Short Term(Acute)Exposure: Inhalation:Inhalation of high airborne concentrations can also Irrlete mucous membranes,cause headaches,sleepiness,nausea,confusion,loss of consciousness,digestive and visual disturbances and even death.NOTE:Odour threshhold of methanol is several times h Igher than the TLV-TWA Depending upon severity of poisoning and the promptness of treatment,survivors may recover completely or may have permanent blindness,vision disturbances and/or nervous System effects.Concentrations in air exceeding 1000 ppm may cause Irrltallon of the mucous membranes. Skin Contact: Methanol Is moderately Irritating to the skin.Methanol can be absorbed through 1he skin and harmful effects have been reported by this route of entry.Effects are slmlalr to those desoribed In'Inhalatlen" Eye Contact;Methanol Is a mild to moderate eye Irritant. Hign Vapour concentration or liquid COnteot with eyea causes Irritatlon,tearing and burning. Ingestion:Swellowing even small amounts of methanol could potentially cruse blindness or death.Effect,of sub lethal doses may be nausea,headache,abdominal pain,vorniting and visual l clieturbances ranging from blurred vision to light sensitivity. J Effects of Long Tenn(Chronic)Exposure.,Repeated exposure by inhalation or absorption may cause systemic poisoning,brain disorders,Impaired vision and blindness.Inhalation may worsen conditione such as emphysema or bronchitis.Rapeatod skin oonteot may cause dermal Irritation. dryness and cracking. Madloal Conditions Aggravated By Exposu►at Emphysema or bronchitis. 4. First Aid Measures Note,ErnefgerlcY stsslsfertce may also be available from the kcaf poison own2l centre. Eye Contact.,Remove contact lenses d worn. In case of contact,Immediately flush eyes with Plenty Of clean running water for at least 15 minutes,lifdng the upper and lower eyelids oacaslonally,Obtaln medical attention. Skin Contact: In Case of contact, remove conlaminated clothing.In a shower,wash affected ar*as with 50813 and water for at least 15 minutes.Seek medical attention It irrltstlon occurs or Persists.Wash clothing before reuse, Inhalation:Remove to fresh air,setters or assist breathing if necessary. Ootaln medical attention. Ingestion: swallowing methanol ie potentially Ufa threatening.Onset of symptoms may be delayed for 18 to 24 hours after digestion,If Conscious and medical old Is not Immvdlateiy Mothanex Corporation -2- Ootooer 13, 2005 Oct 20 2008 17: 04 HP LHSERJET FAX P. 3 1 Methanol MET" X available,do not Induce vomiting,In actual or suspected cases of Ingestion transport to medical facility immediately. NOTE TO PHYSICIAN:Acute exposure to methanol,either through Ingestion or breathing high airborne concentrations can result In symptoms appearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to CNS,eyes and gastrointestinal tract. Because of the initial CNS's effects of headache,vertigo,lethargy and confuslon,there may be an impression of ethanol Intoxication. Blurred vision,decreased acuity and photophobla are common complaints. Treatment wtih Ipecac or lavage Is indicated in any patient presenting within two hours of ingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure Of severlty then serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration with appropriate hospitals is recommended. 5. Fire Fighting Measures Flash point: 11 OC TCC Autolgnitton temperature; 385°C(NFPA 1678),470°C(Kirk-•Othmer 1981; Explosive Limit: Ullmann 1975) Lower Ex p 6%(NFPA, 1978) upper Explosion Limit: 36%(NFPA. 1878),38.6%(Ullmann, 1975) Sensitivity to Impact; LOW Sensitivity to 8tade Discharge: Low HasardOui Combustion Products: Toxdc sages and vapours:oxides of carbon and Extinguishing Media, Small fires:D chemical,formaldehyde. Large fires:Wryetar spray, FFF(R)(Aqu,water eous Film Forming Foam(alcohol resistant))type with either a 3%or 5%foam proporllonlhg system. Fire Fighting Instructlons: Methanol turns with a clean clear flame that Is almost Invlslble In oayllght,Stay upwindl Isolate and restrict area aacoeaa.COnOentralions of greater that 25% methanol In water can be ignited.Use Me water spray or fog to oontmi fire spread and cool adjacent structures or coritalners.Contain fire control water for later disposal. Fire fighters must wear full falca,positive pressure,self-contained breathing apparatus or airline and appropriate protective clothing.Protective fire fighting structural clothing Is not effective protection from mothonol. Do not walk through spilled product. NATIONAL FIRE PROTECTION ASSOCIATION(NFPA)HAZARD INDEX; HEALTH:1 FLAMMABILITY.3 REACTIVITY:0 6. Accidental Release Measures Overview: Flammable liquid which can bum without a visible flame.Reieai6e can cause an Immediate risk of fire and explosion.Eliminate all Ignition sources,stop leak and use absorbent materials. If necessary,contain spill by diking.Fluorocarbon alcohol realste.-It foams maybe applied to spill to diminish vapour and fire hazard. Maximize methanol taco very for recycling or re-use.Restrict access to ores until completion of cleanup.Ensure cleanup Is conducted by Methenex Corporation .3- October 13, 2005 Oct ZO 2008 17: 04 HP LRSERJET FAX p. 4 1 Methanol MET Nix trained personnel only.Was adequate personal protection and remove all:3GurceS of ignition, Notify all govemmental agencies as required by law, Personal Protection.Fu11 face,positive pressure self-contained breathing apparatus or airline, and protective clothing must be worn.Protective fire fighting structural clothing is not effective Protection from methanol. Environmental Precautions:Biodegrades easily in water Methanol in fresn or sah water may have serious effects on aquatic life.A study on methanol'stoxic efltacts on sewage sludge bacteria reported little effect on digestion at 0.1%while 0.6%methanol retarded digestion. Methanol will be broken down to carbon dioxide and water, Remedial Measures:Flammable liquid.Release can cause an Immediate fire/explosion hazard. Eliminate all sources of Ignition,stop leak and use absorbent materials.Collect liquid with explosion proof pumps.Do notwalk through spill product as It may be on fna and not visible. Large Spills:If necessary, contain spill by diking.Fluorocarbon alcohol resiri*tant foams may be applied to spill to diminish vapour and fire hazard,Maximize methanol recovery for recycling or reuse.Collect liquid with explosion proof pumps. Small SPille:Soak up spill with non-combustible absorbent material.Recover methanol and dilute with water to reduce fire hazard.Prevent spilled methanol from entering sewers,confined spaces, drains,or waterways.Restict access to unprotected personnel.Full.Put material In suitable, covered,labeled containers.Flush area with water, 7. Handling and Storage Handling Proosduras: No smoking or open flame In storage,use or handling areas. Use 1 explosion proof electrical equipment.Ensure proper eiectricei grouding proi:edures are in place. Storage:Store In totally enclosed equipment,designed to avoid ignition and human contact, Tanks must be grounded,vented,grid should have vapour emission controls.Tanks must be diked.Avoid storage with Incompatible materials,Anhydrous methanol is non-corrosive to most metals at ambient temperatures except floc lead,nickel,morlel,cast Iron and high silicon Iron. Coatings of copper(or copper alloys),zinc(including golvenlzed steel),or aluminum are unsuitable for Storage.These materials may be attacked slowly by the metlaanoi.Storage tanks mance of welded oonstructlon arc normally satisfactory.They should be designed and built In Confor with good engineering practice for the material being stored.While plesycs Can be used for short term storage,i11GY are generally not rocommended for longterm srorsge C1r6 to deterioration effects and the subsequent risk of contamination. Corrosion rates for several construction materials: c0.508 mrn/yeor Coot Iron,monei,lend,nickel c0.051 mmlyear High silloon Iron Some attack Polyethylene Satisfactory Neoprene,phenolic reslne,polyesters,natural rubber,butyl rubber Resistant Polyvinyl chloride,unplaNkized S. Exposure Controls, Personal Protection Engineering Controls:In confined areas,local and general ventilation should be provided to maintain airborne concentrations beloew pormissable exposure limits.Venillallon systems mull be designed according to approved engineering otandards, Methanex Corporation -4- October 13, 2005 Oct 20 2008 17: 04 HP LASERJET FAX P. 5 Methanol METH EX M.,...1M[.IYDlgtif Respiratory Pmtsotlons NIOSH approved supplied air respirator when airborne concentrations exceed exposure limits. Skin protection,Butyl and nitrile rubbers are recommended for gloves. Check with manufacturer.Wear chemical resistant pants and Jackets.preferably of butyl or nitrtie rubber. Check with manufacturer. Eye and Face Protection:Face shield and chemical splash goggles when tranarerring is taking place. Footwear:Chemical resistant,and as specified by the workplace. Other:Eyewash and showers should be located near work areas.NOTE:PPE must not be considered a long-term solution to exposure control,PPE usage must be accompanied by employer programs to property select,Maintaln,dean,fit and use.Consult acompetent Industrial hygiene resource to determine hazard potential and/or the PPE manufacturers to ensure eadaquate protection. 9. Phyelcal and Chemical Properties Appearance:Liquid,clear,colourless Bolling Point: 64.7°C @ 101.3 kPa Odour:Mild characteristic alcohol odour Critical Temperature: 239.4°C Odour Threshold:dctedion.4.2.5960 ppm Relative Density:0.791 (geometric maen)IGO ppm Evaporation Rate:4.1 (n-butyl acetate ml) recognition:63—am ppm (geometrlc moan)600 ppm Panition Coefficient:Log .0.82 PH:Not applicable 4 P(Oct)( ) Vapour Pressure: 12.6 We Q 200C 8oiub111ty In other Liquids: Soluble in all ttiolubllltyt Completely soluble proportions In other alcohols.eaters, Vapour DeneKyt 1.105 4116°C katones,Millers and moot other organic Freezing Point:-97.3 oC solvents 10. Stability and Reactivl Chemical Stability: Yes Incompatlblllty: Yes.Avoid contact with strong oxidlzera.strong mineral or organic acids, and strong bases,COMOOt with these materials may cause a violent or explosive reaction. May be corroelve to lead,aluminum,magneslum,and Platinum. Conditions of Reactluity: Presence Of I1100nlpatible materiale and ignition sources. Hazardous becornposldon Productsi Formaldehyde,carbon dioxide,and carbon monoxide. Hazardous Polymerisation:Will not odour, Methanex Corporation -5- October 13, 2005 Oct 20 2008 17: 04 HP LASERJET FAX p, g l Methanol MkTFI A" 11. Toxicological Information LOW: 6628 mg/kg(oral/rat),20 mUkg(darmal/rabbit) 1.0", E woo ppm(rat) Acute xposure: Sea Section 3 Chronic Exposure: Sea Section 3, Exposure Limits; See Section 2. Irritancy; See Section 3. Sensitization; No Carcinogenicity; Not listed by IARC,NTP,ACGIH,or OSHA or,a Carcinogen. Terstogenleltyl No Reproductive toxicity. Reported to cause birth defects In rate exposed to 20,000 ppm Mutegenicity; Instdfloisnt data Synergle tic Products. None Known 12 Ecological Information Environmental toxicity: Methanol in fresh or saltwater may have Serious affects on aquatic life. A study an methanol's toxic effects on sewage sludge bacteria reported pufd effect on digestion at 0.1%while 0.5%methanol retarded digestion.Methanol will be broken dow-t Into carbon dioxide and water,. l Biodegradability.,Btodegradee easily In water. 93- Dis oral p Considerations R"ew federal,provincial or state,and local government requirements prior to disposal,Store material for disposal ea indicated in Section 47,Handling and storage, 019100eal by Controlled Incineration or by secure Isnd rill may be acoeptsbie. 14. Transport Information Transport of Dangerous Goods(TOG and GLR): Methanol,Class 3re.1), UN1230,P.G.It Limited quantity;:,1 litres United States Department of Transport(49CFR): Methanol,Class 3 UN 1230, P.G.11. (Gomesda only) (RQ 3000 Ibs/2270 ke) Limited Quantity;!;1 litres International Air Transport Association(IATA): Methanol,Class 3(6.1),UN1230,P,G,II Packaging Instruction:305, 1 litre maximum per package, International Madilrrw Organization(IMO); Methanol,Class 3(9.1),UN1230,P.G.It, Flash Point A 12°t; EmS No.F-E,8-0 Stowspe Ceiegory W,Clear of living quarters' 1 Methanex Corporation -e- October 13.2005 Oct 20 2008 17: 04 HP L.ASERJET FAX p, 7 Mathancl hIETH X •rW,nih M.i[.prr, 15. Re®ulatory information CANADIAN P OERAL ISEGULATIObM CEPA,DOMESTIC SUBSTANCES LIST: Listed WHMIS CLASSIFICATION: 132,D1A uEMD STATES REGULATIONS; 29CFR 1910.1200(OSHA); Hazardous 40CFR 110417(EPA): Hazardous 40CFR 355,Appendices A and B: Sub)eot io Emergency Planning and Notification 40CFR 372(SARA Title III): Listed 40CFR 302(CBRCLA): Listed 16. Other Information Preparation Date:October 13,2005 Prepared by:Kel-Ex Agenclee Ltd.,P.O.Box 52201.Lynnmour RPO,North Vancouver,6,C.,V7J 3V5 Disclaimer The Information above Is believed to be accurate and represerta the best Inforn*atlon currently available to us. Users should make their own investigatIons to determine -the:sultabllity of the Information for their particular purposes. This document is Intended as a guide to the appropriate precautionary handling or the matarlal by a properly tMiAW person using this product, Methanex Corporation and Its subsidiaries make no representations or warranties, either express or implied,including wlO vut limitation any warranties of merohantabillty,fitness fnr a particular purpose with respect to the information set forth herein or the product to which the Infnnnatlon refers. Accordingly. Methan ex Corp.will not be responsible for damages resulting from use of or reliance upon this Information. Revisions:None Methenex Corporation .7. October 13,2005 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF430/IDH No. 698364 * * * Section 1 - Chemical Product and Company Identification Product Trade Name TURCO VITRO-KLENE Manufacturer Information Henkel Surface Technologies Contact Phone:(248)583-9300 Henkel Corporation 32100 Stephenson Highway Chemtrec Emergency#(800)424-9300 Madison Heights,MI 48071 * * * Section 2 - Composition / Information on Ingredients CAS# Component Percent 6834-92-0 Sodium metasilicate 30-60 1310-73-2 Sodium hydroxide 10-30 Mixture Sodium phosphate,tribasic 1-10 7722-88-5 Tetrasodium pyrophosphate 1-10 Proprietary Rosin soap 1-10 * * * Section 3 - Hazards Identification Emergency Overview: DANGER—CORROSIVEI Contact with this material will cause burns to the skin,eyes and mucous membranes. Avoid breathing dusts. Eye Contact: Contact with the eyes can cause severe burns and permanent eye damage. Skin Contact: Contact with the skin or mucous membranes will cause severe burns and possible ulceration. Ingestion: Not a likely route of entry. Ingestion may produce bums to the lips,oral cavity, upper airway,esophagus and possibly the digestive tract. Inhalation: Inhalation of dusts of this product may cause severe irritation and bums to the respiratory tract. Medical Conditions Aggravated by Exposure: Pre-existing eye,skin and res irato disorders. * * * Section 4 - First Aid Measures Eye Contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Skin Contact: For skin contact flush with large amounts of water while removing contaminated clothing. Discard any shoes or clothing items that cannot be decontaminated. if irritation persists,get medical attention. Ingestion: If the material is swallowed, get immediate medical attention or advice—Do not induce vomiting. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. Inhalation: Move person to non-contaminated air. If not breathing,give artificial respiration, preferably mouth-to-mouth. If breathing is difficylt give oxygen. Seek medical attention. * * * Section 5 - Fire Fighting Measures => METALS TESTING Lqp Pagel of 6 Issue Date: 10/13/06 Revision: 1.0114 IEWEWM BY / Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF430/IDH No. 698364 Flash Point: Not applicable Method Used: Not applicable Flammability Not applicable Classification: Upper Flammable Not applicable Lower Flammable Not applicable Limit(UFL): Limit(LFL): Fire & Explosion Hazards: This material will not burn. Extinguishing Media: Use any media suitable for the surrounding fires. Fire-Fighting Instructions: Fire fighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Fire fighters should avoid inhaling any combustion products. * * * Section 6 - Accidental Release Measures Containment Procedures: Stop the flow of material, if this is without risk. Contain the discharged material. Block any potential routes to water systems. Isolate area. Keep unnecessary personnel away. Clean-Up Procedures: Sweep up or gather material and place in appropriate container for disposal. Flush area with water to remove trace residue. Dis ose of collected material according to regulation. * * * Section 7 - Handling and Storage Handling Procedures: Do not get this material in your eyes, on your skin, or on your clothing. Use this product with adequate ventilation. Do not breathe dust from this material.Wash thoroughly after handling. Do not reuse the empty container. Considerable heat is generated when water or acid is added,therefore when making solutions always add the l caustic to the water or acid with.constant stirring. If caustic substance or solution becomes concentrated in one _J area, or if added too rapidly or if added to hot or cold water a rapid temperature increase can result in dangerous boiling water and/or splashing or may cause immediate violent eruption. Storage Procedures: Kee the container ti2htly closed and in a cool,well-ventilated place. * * * Section 8 - Exposure Controls / Personal Protection Exposure Guidelines: A: General Product Information Follow all applicable exposure limits. 13: Component Exposure Limits Sodium hydroxide (1310-73-2) ACGIH: 2 mg/m3 Ceiling OSHA: 2 mg/m3 TWA NIOSH: 2 mg/m3 Ceiling Tetrasodium pyrophosphate (7722-88-5) NIOSH: 5 mg/m3 TWA Engineering Controls: Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. PERSONAL PROTECTIVE EQUIPMENT As prescribed in the OSHA Standard for Personal Protective Equipment(29 CFR 1910.132),employers must perform a Hazard Assessment of all workplaces to determine the need for,and selection of, proper protective equipment for each task performed. Eyes/Face Protective Equipment: Wear chemical goggles. Page 2 of 6 Issue Date: 10/13/06 Revision: 1.0114 :i.'r�; . Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF4301 IDH No. 598364 Skin Protection: Use impervious gloves. Use of impervious apron and boots are recommended. Respiratory Protection: If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided. Work Practices: Eyewash fountains and emergency emergen2y showers are required. * * * Section 9 - Physical & Chemical Properties Physical State: Solid,granular mixture Appearance: Brown Odor: Vapor Pressure: Not applicable Vapor Density: Not applicable Boiling Point: Not applicable Melting Point: Not established Specific Gravity: Not applicable pH: (5%solution)->12.0 Viscosity: VOC: Not applicable Solubility Water: Soluble Percent Volatile: Not applicable * * * Section 10 - Chemical Stability & Reactivity Information Chemical Stability: Stable under normal conditions. Conditions to Avoid: Avoid contact with water.Avoid dispersion of dust in air.Avoid contact with acids. Incompatibility: This product reacts with acids. Decomposition Products: None identified. Hazardous Polymerization: Will not occur. * * * Section 11 - Toxicological Information Acute Toxicity: A: General Product Information Sodium hydroxide is an alkaline corrosive that results in severe irritation and bums to the eyes,skin, respiratory system,and gastrointestinal system.Sodium hydroxide has been implicated as a cause of cancer in humans. However,this may be a secondary effect of the tissue destruction and scar formation caused by sodium hydroxide. Embryotoxicity in rats may be attributed to an alteration of pH in the amniotic fluid rather than the sodium hydroxide itself. 13: Component Analysis -LD50/LC50 Sodium metasilicate(6834-92-0) Oral LD50 Rat:600 mg/kg Sodium hydroxide(1310-73-2) Dermal LD50 Rabbit: 1350 mg/kg Sodium phosphate,tribasic(Mixture) Oral LD50 Rat: 3100 mg/kg; Dermal LD50 Rabbit: >7940 mg/kg Tetrasodium pyrophosphate(7722-88-5) Oral LD50 Rat:4 g/kg Page 3 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name:TURCO VITRO-KLENE ID: 238863DLF430/IDH No.598364 Carcinogenicity: A: General Product Information No information available for the product. B: Component Carcinogenicity None of this products components are listed by ACGIH, IARC,OSHA, NIOSH, or NTP. Chronic Toxicity No information available for the product. Epidemiology: No information available for the product. Neurotoxicity: No information available for the product Mutagenicity: No information available for the product Teratogenicity: No information available for the product Other Toxicological Information: None available. * ** Section 12 - Ecolo icaI Information Ecotoxicity: A: General Product Information No data available for this product. B: Component Analysis -Ecotoxicity-Aquatic Toxicity Sodium metasilicate (6834-92-0) `\ Test&Species Conditions /1 96 Hr LC50 Brachydanio repo 210 mg/L[semi- static] 96 Hr EC50 Daphnia magna 216 mg/L Sodium hydroxide (1310-73-2) Test&Species Conditions 96 Hr LC50 Oncorhynchus mykiss 45.4 mg/L[static] Sodium phosphate,tribasic (Mixture) Test&Species Conditions 48 Hr LC50 Leuciscus idus 1650 mg/L Environmental Fate: No data is available concerning the environmental fate, biodegradation or bioconcentration for this product. * * * Section 13 - Disposal Considerations US EPA Waste Numbers & Descriptions: A: General Product Information Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. B: Component Waste Numbers No EPA Waste Numbers are applicable for this products components. Disposal Instructions: Dispose of waste material according to Local, State, Federal,and Provincial Environmental Regulations. Page 4 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF430/IDH No. 598364 * * * Section 14 - Transportation Information US DOT Information Shipping Name: Please refer to the container label for transportation information. * * * Section 15 - Regulatory Information US Federal Regulations A: General Product Information This product is considered hazardous under 29 CFR 1910.1200(Hazard Communication). B: Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313(40 CFR 372.65)and/or CERCLA(40 CFR 302.4). Sodium hydroxide (1310-73-2) CERCLA: 1000 lb final RQ;454 kg final RQ Sodium phosphate,tribasic (Mixture) CERCLA: 5000 lb final RQ(listed under Sodium phosphate,tribasic);2270 kg final RQ(listed under Sodium phosphate,tribasic) SARA 3111312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactive: No State Regulations A: General Product Information No additional information available. 1 B: Component Analysis-State The following components appear on one or more of the following state hazardous substances lists: Comp,onent I CAS# I CA I FL I MA I MN NJ PA Sodium hydroxide 1310-73-2 1 Yes No Yes I Yes Yes Yes Sodium phosphate,tribasic Mixture I Yes I No I Yes No Yes Yes Tetrasodium pyrophosphate 7722-88-5 Yes I No I Yes I Yes Yes Yes Other Regulations A: General Product Information All components are on the U.S. EPA TSCA Inventory List. B: Com onent Analysis-Invento Component CAS# TSCA DSL EINECS Sodium metasilicate 6834-92-0 Yes Yes Yes Sodium hydroxide 1310-73-2 Yes Yes Yes Sodium phosphate,tribasic Mixture Yes Yes Yes Tetrasodium pyrophosphate 7722-88-5 Yes Yes Yes Rosin soap Proprietary Yes Yes Yes C: Component Analysis-WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List Component CAS# Minimum Concentration Sodium metasilicate 6834-92-0 1 % Sodium hydroxide 1310-73-2 1 % Tetrasodium pyrophosphate 7722-88-5 1 % * * * Section 16 - Other Information Page 5 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238863DLF430/IDH No. 698364 NFPA Ratings:Health:3 Fire:0 Reactivity: 1 Hazard Scale: 0=Minimal 1 =Slight 2=Moderate 3=Serious 4=Severe HMIS Ratings: Health:3"Fire:0 Reactivity: 1 Hazard Scale: 0=Minimal 1 =Slight 2=Moderate 3=Serious 4=Severe *=Chronic hazard Key/Legend EPA=Environmental Protection Agency;TSCA=Toxic Substance Control Act;ACGIH=American Conference of Governmental Industrial Hygienists; IARC=International Agency for Research on Cancer, NIOSH=National Institute for Occupational Safety and Health; NTP= National Toxicology Program; OSHA=Occupational Safety and Health Administration; NFPA=National Fire Protection Association; HMIS=Hazardous Material Identification System;CERCLA=Comprehensive Environmental Response, Compensation and Liability Act; SARA=Superfund Amendments and Reauthorization Act The information presented herein is believed to be factual as it has been derived from the works and opinions of persons believed to be qualified experts; however, nothing contained in this information is to be taken as a warranty or representation for which Henkel Surface Technologies bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Contact: Product Safety and Regulatory Affairs Contact Phone: (248)583-9300 This is the end of MSDS# 238853DLF430/IDH No. 598364 ,J _.J Page 6 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet - � 239 Great Neck Road Great Neck,NY 11021 Phone: (516)487 3510; email: sales@wegoehem.com Date of Revision:8/2007 TRISODIUM PHOSPHATE Section 1 - Chemical Product and Company Identification Produet/Chemical Name:Trisodium Phosphate dodecahydrate Chemical Formula:Na3P0442H2 O CAS Number:10101-89-0 Other Designations: TSP;trisodium orthophosphate;sodium phosphate,tribasic;tertiary sodium phosphate;trisodium phosphate Derivation:Prepared by combining proper proportions of phosphoric acid and soda ash to form disodium phosphate,then adding caustic soda. General Use:Used in softening water,tanning leather,manufacturing paper,clarlt ing sugar,in detergent mixtures,photographic developers,food additives,buffers,emulsifiers,dietary supplements,boiler water compounds,and industrial cleaners. Emergency Telephone:1-800424-9300(Chemtree) Section 2 - Composition/Information on Ingredients ingredient Name CAS Number EINECS/ELINCS %wt or%vol Trisodium Phosphate dodecahydrate 10101-89-0 231-509-8 100 Trace Impurities; OSHA PEL ACGIH TLV NIOSH REL NIOSH In ient TWA STEL TWA STEL I TWA I STEL IDLH Trisodium 5 mg/m3 none estab. none estab. none estab. none estab. none estab. none estab. Phosphate Section 3-Hazards Identification ***** Emergency Overview***** HMIS MAY CAUSE EYE INJURY.CAUSES SKIN IRRITATION. MAY BE HARMFUL IF H 1 F 0 SWALLOWED. R 2 Potential Health Effects PPEt Primary Entry Routes:Inhalation,ingestion or skin contact. tom.g Target Organs:Skin,digestive tract. Acute Effects Inhalation:May cause irritation of the respiratory tract with burning pain in the nose and throat,coughing,wheezing,shortness o breath and pulmonary edema. Eye:May cause severe eye irritation.May result in comeal injury. Skin:May cause severe irritation and possible burns. Ingestion:May cause severe gastrointestinal tract irritation with nausea,vomiting and possible burns. Carcinogenicity:IARC,NTP,and OSHA do not list Trisodium Phosphate as a carcinogen. Medical Conditions Aggravated by Long-Term Exposure: Chronic Effects:Prolonged or repeated eye and skin contact causes irritation.Injury to the esophagus from scarring may occur.Alkali exposures may necessitate irrigation for extended duration. Section 4 -First Aid Measures Inhalation:Remove from exposure to fresh air immediately.Ifnot breathing,give artificial respiration.If breathing is difficult, give oxygen.Get medical aid. Eye Contact:Prolonged or repeated eye and skin contact causes irritation. Skin Contact:Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.Get medical attention if irritation develops or persists. 11 Ingestion:If victim is conscious and alert;give 24 cupfuls of milk or water.Nevergiye anything by mouth to an unconscious person.Get medical aid immediately. It After first aid,get appropriate In-plant,paramedic,or community medical suppori 41vt k TA L S 71=S TI K!PG C O MPA Y 1EV1EVfiED B'f. __ TRISODIUM PHOSPHATE 2 Note to Physicians:Treat symptomattca ly and supportively. Section 5 Fire-Fighting- Measures Flash Point:noncombustible NFPA Burning Rate:N/A O Autoignition Temperature:noncombustible LEL: N/A 2 1 UEL: N/A Flammability Classification:noncombustible Extinguishing Media:Use what is appropriate to the surrounding fire since this material is noncombustible. Unusual Fire or Explosion Hazards:In a fire situation at high temperature,phosphates can emit highly toxic phosphorus oxides(PO,) fumes. Fire-Fighting Instructions:Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment:Because fire may produce toxic thermal decomposition products,wear a self-contained breathing apparatus(SCBA)with a full facepiece operated in pressure-demand or positive-pressure mode. Section 6-Accidental Release Measures Spill/Leak Procedures:Cleanup personnel should wear the necessary personal protective equipment to prevent skin or eye contact and dust inhalation. Small Spills: Vacuum or sweep up material and place into a suitable disposal container. Large Spills Containment:Dilre with inert absorbent material,as needed,to contain and limit spill area.Sweep,vacuum,or scoop the spilled solid,avoiding dust generation,into a suitable disposal container(with secure lid).Do not release into sewers or waterways. Cleanup:Flush residues to drain with plenty of water. Regulatory Requirements:Follow applicable OSHA regulations(29 CFR 1910.120). Section 7-Handling and Storage Handling Precautions:Wash thoroughly after handling.Minimize dust generation and accumulation.Avoid contact with eyes, skin,and clothing.Keep container tightly closed.Avoid ingestion and inhalation. Storage Requirements:Store in a tightly closed container.Store in a cool,dry,well-ventilated area away from incompatible substances. Section 8-Exposure Controls/Personal Protection Engineering Controls:Avoid dust inhalation,body contact,contact with acidic materials,and heating to decomposition. Ventilation:Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec.2).Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Respiratory Protection:Seek professional advice prior to respirator selection and use.Follow OSHA respirator regulations (29 CFR 1910.134)and,if necessary,wear a MSHA/NIOSH-approved respirator.Select respirator based on its suitability to provide adequate worker protection for given working conditions,level of airborne contamination,and presence of sufficient oxygen.For emergency or non-routine operations(cleaning spills,reactor vessels,or storage tanks),wear an SCBA. Warning!Air purging respirators do not protect workers in oxygen-deficient atmospheres If respirators are used,OSHA requires a written respiratory protection program that includes at least:medical certification,training,fit-testing,periodic environmental monitoring,maintenance,inspection,cleaning,and convenient,sanitary storage areas. Protective Clothing/Equipment:Wear chemically protective gloves,boots,aprons,and gauntlets to prevent prolonged or repeated skin contact.Wear protective eyeglasses or chemical safety goggles,per OSHA eye-and face-protection regulations (29 CFR 1910.133).Contact lenses are not eye protective devices.Appropriate eye protection must be worn instead of,or in conjunction with contact lenses. Safety Stations:Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Contaminated Equipment:Separate contaminated work clothes from street clothes.Launder before reuse.Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. �l Page 2 of 4 • TRISODIUM PHOSPHATE 3 Section 9- Physical and Chemical Properties Physical State:solid Water Solubility:soluble Appearance and Odor:white/off white crystals Other Solubilities: /powder/granules-odorless Boiling Point:at 212 OF(100*Q(decomposes) Odor Threshold: Freezing/Melting Point: 163.9 to 170.1 OF(73.3 to 76.7°C) Vapor Pressure: Viscosity: Vapor Density(Air=l): Refractive Index: Formula Weight:380.12 Surface Tension: Density: %Volatile: Specific Gravity(H20=1,at 4°C): 1.62 g/cm3 Evaporation Rate: PH: Section 10-StabUity and Reactivity Stability:Trisodium Phosphate is stable at room temperature in closed containers under normal storage and handling conditions. Polymerization:Hazardous polymerization will not occur. Chemical Incompatibilities:This strong caustic material reacts violently with water and strong acids to generate heat. Conditions to Avoid:Never heat to decomposition. Hazardous Decomposition Products:Thermal oxidative decomposition of Trisodium Phosphate can produce highly toxic fiunes of phosphorus oxides(PO,)and sodium oxide(Na?0). Section 11-Toxicological Information Toxicity Data:* Rabbit,Intravenous,LDj,,: 1580 mg/kg Chronic Effects:no data available Acute Inhalation Effects: Carcinogenicity:no data available Human,inhalation,TCL,,):??ppm Mutagenicity:no data available Acute Oral Effects: Terstogenicity:no data available Rat,oral,LD50:7400 mg/kg "See NIOSH, RTECS (TC9575000),for additional toxicity data Section 12-Ecological Information Ecotoxicity.Aquatic toxicity:151 ppm/96 hr/mosquito fish/TLm/Turbid water,126 ppm/96 hr/daphnia magna/TLm Environmental Fate:no data available Environmental'Degradation:no data available Soil Absorption/Mobility:no data available Section 13-Disposal Considerations Disposal:Scrap material can be used for ncutralzing acid wastes or buried in an approved landfill.If regulations permit,you may flush small amounts to drain with large excess of water.Contact your supplier or a licensed contractor for detailed recommendations.Follow applicable Federal,state,and local regulations. Disposal Regulatory Requirements: Container Cleaning and Disposal Section 14 -Transport Information DOT Transportation Data(49 CFR 172.101):Not Regulated.* *(If shipping package is equal to or exceeds 5000 lbs.,then product is hazard class 9,shipping name:Environmentally Hazardous substance,Solid,n.o.s.(sodium Phosphate,Tribasic);UN3077.) Shipping Name. Shipping Symbols: Hazard Class: ID No.: Packing Group: Label: \ Special Provisions(172.102): Page 3 of 4 TRISODIUM PHOSPHATE 4 ll� Section 15 -Regulatory Information l 1 US FEDERAL TSCA CAS#10101-89-0 is not on the TSCA Inventory.It is a hydrate and exempt from TSCA Inventory requirements (40CFR720.3(u)(2)). Health&Safety Reporting List None of the chemicals are on the Health&Safety Reporting List. Chemical Test Rules None ofthe chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUB under TSCA. SARA Section 302(RQ) CAS#10101-89-0:final RQ=5000 pounds(2270 kg)(Listed under'Sodiu Section 302(TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS#10101-89-0:acute. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class I Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: CAS# 10101-89-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE Sodium phosphate tribasic dode can be found on the following state right to know lists:California,New Jersey,Pennsylvania, Massachusetts. California No Significant Risk Level: None of the chemicals in this product are listed. European/Intemational Regulations Eurdpeatl Labeling in Accordance with EC Directives Hazard Symbols:XI Risk Phrases: R 36/37/38 Irritating to eyes,respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes,rinse immediately with plenty of water and seek medical advice. S 28 After contact with skin,wash immediately with plenty of...(to be specified by the manufacturer). WGK(Water Danger/Protection) CAS#10I01-89-0: 1 Canada None of the chemicals in this product are listed on the DSL/NDSL list. This product has a WHMIS classification of D2B. CAS# 10101-89-0 is not listed on Canada's Ingredient Disclosure List. Section 16- Other Information Disclaimer:All information,recommendations and suggestions appearing herein are based upon sources believed to be reliable: However,it is the users responsibility to determine the safety,toxicity and suitability for its own use of this product. WEGO \l CHEMICAL&MINERAL CORP.DOES NOT ASSUME ANY LIABILITY ARISING OUT OF THE USE BY OTHERS OF y THIS PRODUCT. Page 4 of 4 r MATERIAL SAFETY DATA SHEET ARICIEG B-1019" SECTION I _ - IDENTIFICATION 24 HOUR EMERGENCY ASSISTANCE: HMIS HEALTH 2 41 -452-2008 (EASTERN TIME) 8:OOAM-5:OOPM HMIS FLAMMABILITY 0 800-424-930I (OFF HOURS) CHEMTREC HMIS REACTIVITY 0 HMIS PROTECTION X HEATBATH CORPORATION 107.FRONT STREET PREPARED BY: ..DAV I D NAGY INDIAN ORCHARD, MASS. 01151 . INFORMATION:413-452--2000 DATE-REVISED: 2/2S/99'REV.02 PRODUCT NAME........... ARICIVE-11 B-1019 DESCRIPTION............. Dry acid salt. ' DOT CLASS: CORROSIVE. SOLIDS, N.O.S. (CONTAINS SODIUM HYDROGEN SULFATE), 8, UN 1759, PG III ------------ - ----------------•--------_------------ SECTION 11 - HAZARDOUS INGREDIENTS HAZARDOUS COMPONENT CAS NUMBER PEL(MG/M3) TLV(MG/M3) % SODIUM BISULFATE 7681--38-1 N.E. N.E. 80=90 SODIUM FLUORIDE 7681-49-4 2.5 (F) 2.5 (F) 10-20' SODIUM SULFATE 7757-82-6 N.E. N.E. 1-10 N.E.=NOT ESTABLISHED N.A.=NOT APPLICABLE ------------------------------ -� SECTION III_^TPHYSICAL DATA ---___....---_�___-___ BOILING Point(F).....:........... N.A. SPECIFIC GRAVITY (H20=1)_. 2.46. VAPOR PRESSURE (mm Hg')......N.A. MELTING POINT:.....: N.A.' VAPOR DENSITY (Air=1).......... N.A. EVAPORATION RATE......N.A. SOLUBILITY IN H2O............. Complete. PH...........solution is acidic. APPEARANCE/ODOR....::.Odorless, white powder. SECTION IV - FIRE AND EXPLOSION HAZARD DATA------------------ -- _..----------------------------------------------- FLASH POINT.............. None. FLAMMABLE LIMITS..........None. LOWER FLAME LIMIT..:....: N.A. HIGHER FLAME LIMIT.:..... N.A. IN CASE OF FIRE: Material is nonflammable.'Use extinguishing media appropriate to surrounding conditions. SPECIAL FIREFIGHTING PROCEDURES: . Wear protective clothing with self-contained breathing apparatus: UNUSUAL FIRE HAZARDS: Hazardous fumes may be released under thermal decompositions. Prolonged contact with some metals (i.e. aluminum, tin, zinc etc.) may release flammable hydrogen gas. _•------------------------------------------- SECTION V - REACTIVITY DATA CHEMICAL STABILITY: STABLE CONDITIONS TO AVOID: None. INCOMPATIBLE MATERIALS: strong alkali, cyanides, sulfides, nitrites.. DECOMPOSITION PRODUCTS: oxides of.sulfur under thermal decomposition. HAZARDOUS POLYMERIZATION: W01LL NOT OCCUR j SECTION VI HEALTH---- —_ HAZARD---- DATA __-____ -_ ------- R&TESi OF ENTR inhalation, ingestion. = s` MATERIAL SAFETY DATA SHEET ARICIDE B-1019 HEALTH HAZARDS (ACUTE,CHRONIC) — Contains' FLUORIDES. May cause eye, skin and respiratory tract irritation and skin ulcers. May be harmful or fatal if > swallowed. Avoid contact with eyes, skin or clothing. CARCINOGENICITY: None. NTP?: No IARC?: No OSHA REGULATED?: No SYMPTOMS OF EXPOSURE: eye, skin and respiratory tract irritation. eye, skin and tissue burns. skin ulcers, fluorosis. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not known. FIRST AID: INHALATION: Move victim to fresh air. If not breathing, give artificial respiration. If breathing is diffieult,give oxygen. Get medical attention. EYES: Hold eyelids apart and flush with running water for at least 16 minutes. Get medical attention. SIUN:Wash affected area with plenty of water followed by a solution of 0.1% Benzalkonium chloride. Get medical attention. INGESTION: If conscious, give plenty of water followed by milk or milk of magnesia. Do not induce vomiting. Get medical attention. SECTION VII — PRECAUTIONS/PROCEDURES ------------------- IN CASE OF SPILL: Sweep up material into a chemical waste container. Neutralize spill area with weak alkaline solution. WASTE DISPOSAL METHOD: Neutralize with soda ash or lime and dispose of in accordance with federal, state and local regulations. PRECAUTIONS: Avoid contact with eyes, skin or clothing. Use with adequate ventilation. Wear proper protective clothing when using this product. Wash thoroughly after handling. Store in a cool, dry place. OTHER PRECAUTIONS: Emptied containers of this product may contain hazardous vapors and residue. Clean thoroughly before reusing or discarding. Do not use a welding torch to cut container. Do not use for water or food storage. SECTION VIH — SPECIAL PROTECTION RESPIRATORY PROTECTION: Use NIOSH/MSHA approved respirator if dust, fumes or vapors are excessive. VENTILATION: maintain below PEL,TLV. MECHANICAL EXHAUST....... X PROTECTIVE GLOVES: Rubber. LOCAL EXHAUST............ x EYE PROTECTION: safety goggles, face shield. OTHER PROTECTIVE EQUIPMENT........ apron,boots, full cover work clothes. WORK/HYGIENIC PRACTICES...... wash thoroughly after handling,launder clothes. SECT IX —SARA TITLE III INFORMATION HAZARDOUS — _ — CERCLA--� SECT 302 — SECT 313 SECT.311/312 COMPONENT RQ LBS. TPQ LBS. TOXIC HAZARDS --------------- ------ ------- ------ --------- SODIUM BISULFATE N.A. N.A. NO A SODIUM FLUORIDE 1000 N.A. NO A,B SODIUM SULFATE N.A. N.A. NO A A=IMMEDIATE (ACUTE) HEALTH HAZARD B=DELAYED (CHRONIC) HEALTH HAZARD C=FIRE HAZARD D=SUDDEN RELEASE OF PRESSURE HAZARD E--REACTIVE HAZARD NITRIC ACID, LESS THAN 70% HNO3 MATERIAL SAFETY DATA SHEET NITRIC ACID, LESS THAN 70% HNO3 Section 1: Product and Company Identification. Chemical Interchange Co. Information Telephone: (314)962-9002 2932 S. Brentwood Blvd. Emergency Telephone: (800)325-3980 St.Louis,MO 63144 FAX: (314)962-9409 Nitric Acid,less than 70% HNO3 Chemtrec: (800)424-9300 Acid Reagent Section 2: Composition and Information on Ingredients. COMPOSITION: Nitric Acid(HNO3)with less than 70 percent HNO3 (Hydrogen Nitrate,Aqua Fortis,37 to 42 Degrees Baume Nitric Acid) HAZARDOUS INGREDIENTS: Nitric Acid CAS#7697-37-2 66%to 70% Section 3: Hazards Identification. EMERGENCY OVERVIEW: Colorless to light brown liquid with acrid odor. \ DANGER: Strong oxidizer. Corrosive. /) • Dangerously reactive. • May be fatal if ingested. • Causes severe bums to eyes and skin. • Vapor extremely irritating to respiratory trail. • Spills may cause fire or liberate dangerous gas. WARNING: May cause serious delayed lung injury. POTENTIAL HEALTH HAZARDS. EYE: Can cause severe burns. May cause irreversible eye injury. SKIN: Can cause severe skin irritation and bums. May cause deep,penetrating ulcers of the skin. INGESTION: Causes seven:bums to mouth,throat and stomach. May cause perforation of the digestive tract. May be fatal. INHALATION: Severe irritation or bums of respiratory system,pulmonary edema and lung inflammation. May be fatal if inhaled. May cause coughing,wheezing,and shortness of breath. Serious effects on lung function may be delayed. CHRONIC: Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. METALS 7tES T IN IG r'OMPAl�€ Page 1 of 7 REVIEWED BY 0AT t NITRIC ACID, LESS THAN 70% HNO3 EYE: Immediately flush with water for at least 15 minutes. Contact a physician immediately. SKIN: Immediately flush with large amount of water while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Leather or other materials which may retain traces of acid should be decontaminated and properly disposed. INGESTION: Give large amounts of water. Do not induce vomiting. Contact a physician immediately. INHALATION: Remove to fresh air. Give artificial respiration or oxygen if needed. Contact a physician immediately. Observe for delayed effects. Section 5: Fire Fighting Measures. FLAMMABLE PROPERTIES: Nonflammable. Nitric acid alone is not flammable but it may cause ignition by contact with combustible materials. EXTINGUISHING MEDIA: In case of fire,soak with water. Dry chemical or CO2 fire extinguisher may also be used. Use water spray to cool containers and reduce and knock down vapors. Apply water from as far away as possible. Neutralize small amounts of spilled acid with crushed limestone,soda ash or lime. FIRE AND EXPLOSION HAZARDS: Powerful oxidizing agent. Can react explosively with reducing agents such as metal powders,hydrogen sulfide(1-12S),nitrates and organic materials such as wood or cellulose. HAZARDOUS DECOMPOSITION PRODUCTS: Can release highly toxic oxides of nitrogen. Reaction with organic materials results in evolution of heat and acrid fumes. FIRE FIGHTING EQUIPMENT: Wear self contained breathing apparatus and full body acid protective clothing including rubber boots. Thoroughly decontaminate equipment after use. Section 6: Accidental Release Measures. Evacuate area. Avoid all skin,eye and respiratory exposure. Wear self contained breathing apparatus and full body acid protection including rubber boots to enter spill area. Flush small leaks or spills with large quantities of water. If possible,contain large spills with diking and neutralize with limestone,soda ash or liquid caustic soda. CAUTION: Neutralization can produce vigorous reactions,boiling and fumes. Remain upwind,evacuate downwind. Cleaned-up material may be a RCRA Hazardous Waste under 40 CFR 261. Comply with all federal,state and local regulations for disposal of waste. Page 2 of 7 NITRIC ACID, LESS THAN 70% HNO3 Section 7: Handling and Storage, HANDLING: • Do not get in eyes,on skin or on clothing. • Wear full protective equipment including chemical goggles,or face shield,rubber gloves and boots. • Do not inhale mist or vapor. • Handle only in areas with sufficient ventilation to prevent irritation or wear a respirator. • Do not ingest. • Wash thoroughly after handling. • Keep container closed when not in use. • Do not allow contact with water because of violent reaction. • When diluting,slowly add acid to water with stirring and mixing to avoid spattering,boiling or eruption. Water cannot be safely added to acid. • Emptied container retains vapor and product residue. Observe all safeguards until container is cleaned or reconditioned. STORAGE: • Keep container tightly closed. • Outdoor storage in a cool,dry,corrosion proof area is recommended. • Keep containers out of sun and away from heat. • Isolate from incompatible materials. Section 8: Exposure Controls/Personal Protection. RESPIRATORY PROTECTION: Provide general and local exhaust ventilation to control exposure levels below airborne exposure limits. Local exhaust ventilation is the preferred primary control. Refer to the OSHA Respirator Standard 29 CFR 1910.134 for proper selection and use of personal respirators. SKIN PROTECTION: Wear impervious protective clothing to prevent skin contact,including an impervious apron,rubber boots or full impervious suit when splashing is possible. Provide a safety shower in the immediate vicinity of potential exposure. Refer to OSHA General Requirements for Personal Protective Equipment 29 CFR 1910.132. EYE PROTECTION: Wear chemical safety goggles or full face shield to prevent eye contact. Use only in the proximity of an eye wash station. Refer to OSHA Requirements for Eye and Face Protection 29 CFR 1910.133. EXPOSURE GUIDELINES: OSHA PEL ACGIH-TLV ACGIH-STEL 8hr-TWA 8hr-TWA (15 MIN.) Nitric Acid 2 ppm 2 ppm 4 ppm Nitrogen Dioxide — — 5 ppm Page 3 of 7 NITRIC ACID, LESS THAN 70% HNO3 Section 9: Physical and Chemical Properties. earance:...................Appearance: .........................................Colorless to light brown liquid Odor......................................................................Acrid pH:........................................................................<1 Flashpoint:..............................................................Not Applicable %Solids:................................................................Not Applicable %Volatility:............................................................100% Solubility:...............................................................Completely miscible in water Vapor Density(air=1):.............................................1 Vapor Pressure(mm Hg):..........................................9-10 @ 25 deg C(77 deg F) Evaporation Rate(butyl acetate=1):...........................Approx. 1 Weight%HNO3 56.5% 65.7% 67.2% Specific Gravity @ 60 deg F 1.3651 1.40101 1.4078 Degrees Baume 38 41.5 42 Freezing Point(deg F approx.) -4 -20 -25 Boiling Point(deg F approx.) 243 246 248 Viscosity,cp @ 20 deg C(68 F) 2.0 2.1 2.2 Section 10: Stability and Reactivity. STABILITY: Stable if properly contained and handled. INCOMPATIBILITY: All organic materials and reducing agents. Addition of water to acid must be avoided. HAZARDOUS DECOMPOSITION PRODUCTS: • Oxide of nitrogen fumes with elevated temperatures. • Nitric acid will react with most organic materials with the evolution of heat and large quantities of dense acrid fumes. HAZARDOUS POLYMERIZATION: Has not been reported. Section 11: Toxicological Information. ACUTE: Nitric acid is highly corrosive,fuming and suffocating. Diluted nitric acid can cause inhalation irritation,eye irritation,harden skin epithelium and cause skin irritation. Nitric acid may also severely bum and stain the skin,destroy skin tissue and burn the eyes. Inhalation of nitric acid vapors can destroy lung tissue. Evidence of lung damage may not occur until many hours after initial exposure. Lung damage occurs in the form of edema which may be severe and sometimes fatal. Ingestion of nitric acid causes immediate pain and burning of the mouth, throat and stomach. Symptoms range from nausea,vomiting,and circulatory collapse to death. Individuals with pre-existing diseases of the lungs may have Increased susceptibility to the toxicity of acid inhalation exposure. Page 4 of 7 NITRIC ACID, LESS THAN 70% HNO3 CHRONIC: Continued exposure to nitric acid fumes can erode the teeth and is severely irritating and corrosive to the mucous membranes of the respiratory tract. Nitric acid is not listed as a carcinogen by IARC,NTP,ACGIH, NIOSH or OSHA. TARGET ORGANS: Eyes,mucous membranes,skin and respiratory system. Section 12: Ecological Information. This product should be considered as potentially hazardous to the environment. Avoid contamination of soil,drains and water during handling. Nitric acid is moderately toxic to aquatic organisms. Section 13: Disposal Considerations. This material should be treated as a corrosive hazardous waste in accordance with all applicable regulations. Cleaned-up material may also be a hazardous waste due to corrosivity. This product has a RCRA waste identification of D002- Corrosive as designated in 40 CFR 261.22. The waste of this product is subject to the Land Disposal Restrictions under 40 CFR 268. CAUTION: Neutralization can product vigorous reaction,boiling and fumes. Use extreme caution in dean-up procedures. Section 14: Transportation Infonnation. Shipping Name Nitric Acid(other than red fuming,with not more than 70%nitric acid UN/DOT ID# UN 2031 DOT/IMO Hazard Class 8 Packaging Group II DOT Label/Placard Corrosive Quantity Limits: Passenger Aircraft or Railcar Forbidden Cargo Aircraft 30 Liter Vessel Stowage D Packaging Authorizations: Exceptions None Non-Bulk Packaging 49 CFR 173.158 Bulk Packaging 49 CFR 173.242 DOT Emergency Response Guide Number 157 } Page 5 of 7 NITRIC ACID, LESS THAN 70% HNO3 Section 16n Regulatory Information- CERCLA SUPERFUND,40 CFR 117.302: Under the Comprehensive Environmental Response, Compensation and Liability Act,a release of this product in excess of 1,000 pounds may require reporting to the National Response Center. SARA HAZARD CATEGORY: Under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986(SARA Title III),this product is considered to meet the following categories: Fire Hazard Yes Sudden Release of Pressure No Reactivity Hazard Yes Acute Health Hazard Yes Chronic Health Hazard No SARA 313 INFORMATION: This product contains the following substances subject to the reporting requirements of Section 313 of Tide III of the Superfund Amendment and Reauthorization Act of 1986(40 CFR Part 372): Nitric Acid. CLEAN AIR ACT: This product does not contain any hazardous air pollutants. This product does not contain any Class 1 Ozone depletors. l This product does not contain any Class 2 Ozone depletory. J CLEAN WATER ACT: This product is listed as a Hazardous substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants or Toxic Pollutants under the CWA. OSHA: This material is considered highly hazardous by OSHA. TOXIC SUBSTANCES CONTROL ACT(TSCA) This product is listed on the TSCA Inventory. STATE: CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the State of Califomia to cause cancer or reproductive harm: None. PENNSYLVANIA RIGHT TO KNOW. Hazardous Substances and Special Hazardous Substances on the List which must be Identified are: Nitric Acid. NEW JERSEY: Requires reporting the top five components by percent: Nitric Acid:..........................56%to 70% Water:................................30%to 44% Page 6 of 7 NITRIC ACID, LESS THAN 70% HNO3 1 Section IS: Regulatory Information(cont.) J CANADA: WHIMS: Under the requirements of the Workplace Hazardous Materials Information System,this Material is a controlled substance classified as: Class C—Oxidizing Material Class D—Division 1,Subdivision B;Toxic Material Class E—Corrosive All components are on the Domestic Substances List(DSL). Section 16: Other Information. HAZARD RATINGS: HMIS NFPA 0:Minimal Health 3 3 1:Slight Flammability 0 0 2:Moderate Reactivity 1 0 3:Serious 4:Severe Special Hazard Oxidizer Oxidizer J This MSDS has been prepared in compliance with OSHA Hazard Communication Standard 29 CFR 1910.1200. Although the information and recommendations set forth herein(hereinafter "information")are presented in good faith and believed to be correct as of the date hereof,Chemical Interchange Co.makes no representations as to the completeness or accuracy thereof. information is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. in no event will Chemical Interchange Co.be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representations or warranties,either express or implied or merchantability,fitness for a particular purpose or any other nature are made hereunder with respect to information or the product to which information refers. Revised March 2009 Page 7 of 7 1001007 Gulbrandsen Technologies MATERIAL SAFETY DATA SHEET IDENTIFICATION SUBSTANCE: FERRIC CHLORIDE SOLUTION CAS#: T1054)8-0 Distributed by HUBBARD-HALT.INC. MANUFACTURER: Gubandsen Technologies,Inc. Imin C 2WO 70 85"n-M �y.,,.�y Mrnn,sc 20949 BBIM72-0031 2 Main�1GR W MA01M 41=47-07M wrm Clinton,NJ 08809npan,Mwolec7 97arsee-0on PRODUCT INFORMATION: (908)735-5458 TRANSPORTATION EMERGENCY REVISION DATE: W15/2005 (CHEMTREC): (800)4244= SUPERSEDES: 12 2002 INGREDIENTS w�w��w�w�wow INGREDIENT CAS B PERCECjAGE M Water 7732-18--5 55-75 Ferric chloride 7705.08-0 25-45 Ferrous chloride 7758-94-3 0-3 Hydrochloric acid 7647-01-0 0-3 ALL INfiRED1ENTS ARE LISTED ON THE TSCA CHENCAL SUBSTANCE INVENTORY SECTION 313 SUPPLIER 14OTIFWATION: The hydrochiodc acid mentioned above is subject to the reporting nequireamft of Section 313 of the Emergency Planning and Community Right To l(now Act of 1988(40 CFR 372). This notffiic ation must be Included In all MSDS's that are copied and drshlouted for this material. PHYSICAL DATA BOILING POINT: 1060C(2230F) pH: <1 MELTING POINT: -120C(100F)40%Soln. SOLUBILITY IN WATER: Complete SPECIFIC GRAVITY: 1.2-1.5 VAPOR PRESSURE: 40mm Hg Q 350C %VOLATILE: 55-75(ovate f) EVAPORATION RATE: N1W VAPOR DENSITY: Air-1,IWF' MOLECULAR WEIGHT: 162.2 APPEARANCE: Orange4mawn liquid ODOR: Slightly acrid FIRE AND EXPLOSION HAZARDS FLASH POINT: .W9 FLAMMABLE LIMITS IN AIR: UFL•WA LFL:WA(%BY VOLUME) SPECIAL FIRE AND EXPLOSION HAZARDS: None EXTINGUISHING MEDIA: Will not bum;use materials appropriate for l surrounding fine. . SPECIAL FIRE FIGHTING INSTRUCTIONS: Cool ex"ied tanks with water. REACTIVITY STABILITY: Stable DECOMPOSITION: Will not occur POLYMERIZATION: Will not occur INCOMPATIBILITY: Rapidly corrodes most metals(titanium is one exception);may generate flammable, potentially explosive hydrogen gas. Avoid contact with nylon,aluminumJaluminum alloys,carbon steel,stainless steel,and copper/copper alloys. HEALTH HAZARDS EXPOSURE LIMITS:Not specifically regulated as toxic or hazardous by OSHA. The ACGIH TLV for soluble iron salts is 1 mg/m3 as Fe(8 hour time-weighted average). TLV for hydrochloric add is 7.5 mg/m3(belling). Toxic effects in animals from repeated exposure by ingestion include reduced weight gain,elevated serum iron levels,Increased red blood cell counts,and iron deposition in many organs. Tests in bacterial and mammalian cell cultures demonstrate no genetic damage. Animal tests demonstrate no carcinogenicity. Human health effects of overexposure by eye contact may include discoloration of eye tissues,eye irritation and discomfort,tearing and blurring of vision,or eye corrosion with corneal or conjunctival ulceration. Skin contact may cause skin irritation with discomfort or rash,skin bums,or ulceration. Ferric chloride has been infrequently associated with skin sensitization in humans. Overexposure by inhalation may result in Irritation of the upper respiratory passages with coughing. Ingestion may cause corrosive damage to the GI tract. Repeated ingestion of sublethal doses may lead to excessive deposition in the tissues accompanied by pancreatic and liver damage. Ingestion in higher doses may lead to abnormal Over function with nausea or vomiting,reduced \ appetite,abdominal pain,lethargy,tarry stools,diarrhea,fast and weak pulse,hypertension,dehydration, acidosis,and coma. Temporary alteration of the heart's electrical activity may result in irregular pulse, palpitations,or inadequate circulation. If death does not occur immediately,symptoms may dear In a few hours but return within a day with cyanosis,pulmonary edema,shock,convulsions,acidosis,fever,and death. Individuals with pre-existing diseases of the liver may have increased susceptibility to the toxicity of repeated exposures. CARCINOGENICITY: None of the components of this material are Bated as a carcinogen by'IARC,NTP, OSHA,or ACGIH. FIRST AID EYE: Immediately flush eyes for 15 minutes with plenty of water.Call a physician. SKIN: Flush skin with water. Remove contaminated clothing;wash before reuse. INHALATION: Remove to fresh air. if not breathing,give artificial respiration. If breathing is difficult,give oxygen.Call a physician. INGESTION: DO NOT INDUCE VOMITING. Give large quantities of water,then an antacid. Never give anything by mouth to an unconscious individual. Call a physician. PERSONAL PROTECTION Adequate general ventilation should be provided to keep vapor and mists below exposure Omits. Wear safety glasses with side shields. Wear chemical safety goggles if a possibility of material splashing or spraying exists. Where there is possibility of skin contact,use the following as appropriate:gloves impervious to material,apron,boots,hood,pants,and jacket. Wear a NIOSH/OSHA approved respirator with a dust/mist cartridge If there Is potential of exposure to mists in excess of applicable limits. SPILL/LEAK PROCEDURE 2 Review safety precautions before proceeding with cleanup. Use appropriate personal protection equipment. Neutralize spill with lime(calcium hydroxide),limestone(calcium carbonate),or soda ash(sodium carbonate). CAUTION:limestone and soda ash will evolve CO2;ventilation should be provided in enclosed areas. Dike area around spill to prevent spreading,and use absorbent material to pick up spill. CERCLA REPORTABLE DISCHARGE: 1000 lbs. DISPOSAL: Under the Resource Conservation and Recovery Act(RCRA),it Is the responsibility of the user to determine whether a substance should be classified as a hazardous waste at the time of disposal. This is due to the fad that product use,transformation,synthesis,mixtures,eta may change the nature of the product. Dispose of waste in accordance with applicable federal,state,and local laws. SHIPPING INFORMATION DOT PROPER SHIPPING NAME: Ferric chloride solution HAZARD CLASS: Class 8 UN/NA#: UN 2582 DOT LABELS: Corrosive DOT PLACARDS: Corrosive PACKAGING GROUP: III L PROPER SHIPPING NAME: Ferric chloride solution HAZARD CLASS: Corrosive material,8 UN#I: 2582 IMO LABEL: Corrosive PACKAGING GROUP: III REPORTABLE QUANTITY: 1000 lbs. SHIPPING CONTAINERS: Rutter-lined steel tank cars4r a ks;polyethylene drums, bottles STORAGE CONDITIONS: Keep containers dosed TITLE III HAZARD CLASSIFICATIONS ACUTE: Yes CHRONIC: No FIRE: No REACTIVITY: No PRESSURE: No EXTREMELY HAZARDOUS SUBSTANCE: No NFPA/HMIS RATINGS CERCLA HAZARDOUS SUBSTANCE: Yes HEALTH: 3 TOXIC CHEMICAL: No FLAMMABILITY: 0 CANADIAN WHMIS CLASSIFICATION: E REACTIVITY: 0 PPE rating to be supplied by user depending on use conditions. ADDITIONAL INFORMATION AND REFERENCES 3 Gulbrandseii Technologies,'Inc.and its divisions,affiliates and subsidiaries("Gulbmndsen")believe that the information contained in each material safety data sheet("MSDS"),technical data sheet("TDS"),product information brochure andfor information contained herein (including data and statements) is accurate as of the date of publication. The MSDSs, TDSs,product information brochures,and information contained herein are referred to collectively as the"Data Sheets". It is the responsibility of the user to obtain and use the most recent version of the Daft Sheets. Each.Data Sheet relates only to the specific product designated therein and may not be valid where such product is used in combination with any other materials or in any process. Further, since.the conditions and methods of use of the product and information are beyond the control of Gulbrandsen, Gulbmndsen expressly disclaims any and all liability as to any consequential damages or results obtained or arising from any use of the products or the information contained in the Data Sheets. NO WARRANTY OF MERCHANTABIUTY,FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED,IS MADE AS CONCERNS THE DATA SHEETS OR THE RELATED PRODUCTS. No statement made in the Data Sheets or by any employee or agent of Gulbrandsen shall be construed as a permission or recommendation for the use of any product in a manner that might infringe existing patents. No employee, agent, distributar,.or sales representative is authorized to vary the terms of the above paragraph, to make any statements, representations, or warranties inconsistent with the above paragraph, or to provide any information that is at variance with the above paragraph. Ali materials related to the product are subject In all respects to the above paragraph and to the extent that they are inconsistent with the above re h,the terms of the above MMmph shall control. 'N/F=None found 2WA=Not applicable 4 f j MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 1 FERRIC CHLORIDE,ANHYDROUS Product Number:None 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Ferric Chloride,Anhydrous Product Number: data not available Chemical Name/Synonyms: Iron(III)Chloride,solid Chemical Formula: FeC13 Cas Number: 7705-08-0 Manufacturer: PVS Technologies,Inc. 10900 Harper Avenue Detroit,Michigan 48213 telephone: (313)571-1100(for product information and emergencies) fax: (313)571-6765 **FOR TRANSPORTATION EMERGENCY ONLY,24 HOURS EVERYDAY,CALL** **CHEMTREC,1-800-424-9300** 2. COMPOSITIONANFORMATION ON INGREDIENTS Com oU nent CAS Re igistry# %by weight Ferric Chloride 7705-08-0 99 Ferrous Chloride 7758-94-3 <1 Inert Matter not available <1 Hazardous Ingredients: Ferric Chloride,Ferrous Chloride Exposure Limits(ppm): Component OSHA TLV _ ACGIH Ferric Chloride TWA 1 mg/m3 TWA 1 mg/m3 (as soluble iron salt) (as soluble iron salt) Ferrous Chloride TWA 1 mg/m3 TWA 1 mg/m3 (as soluble iron salt) (as soluble iron salt RUTZ-1iCED BY ijL-e'... Document Number.:. Page 1 of 9 '1 Revision No.:. Revision Date: 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number:None 3. HAZARDS IDENTIFICATION Potential Health Effects(Acute and Chronic) INHALATION: Irritation potential requires appropriate personal protective equipment. INGESTION: Ingestion may cause severe liver and/or kidney damage. May also cause damage to the gastrointestinal tract. DIRECT CONTACT: Product is a moderate skin irritant. Can cause irritation or corrosive chemical burns to human tissue. High heat of solution(353 BTU/LB)can cause severe thermal burns if in contact with moist skin or mucous tissue. DIRECT EYE CONTACT: Contact with eyes may cause irritation and may be corrosive and result in permanent visual loss unless removed quickly by thorough irrigation with water. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Caused erythema(a rash)to skin of rabbits. CARCINOGENS(NTP,IARC,or OSHA): No 1 4. FIRST AID MEASURES: INHALATION:If exposed to excessive levels of dusts or fumes,remove to fresh air and get medical attention if cough or other symptoms develop. INGESTION: If swallowed,do NOT induce vomiting. Give victim water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. DIRECT CONTACT: Dust off excess before washing.Wash with soap and water. Get medical attention if irritation develops or persists. DIRECT EYE CONTACT: Immediately flush with water for at least 15 minutes.Hold eyelids apart to ensure complete irrigation of eye/lid tissue. Get immediate medical attention. Document Number.:: Page 9 2 of 9 Revision No:::; Revision Date: .: 1 ° 5/2006' MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number:None 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: Flammability: Product not flammable. Flash Point: not applicable Method used: TCC OXIDIZING PROPERTIES: none AUTOFLAMMABILITY: not applicable AUTOIGNITION TEMPERATURE: not applicable FLAMMABLE LIMITS,%BY VOLUME: Lower flammable limit: not applicable Upper flammable limit: not applicable EXTINGUISHING MEDIA: Use dry chemical or CO2 fire extinguishers. \ CAUTION!! This material heats on contact with water. FIRE FIGHTING INSTRUCTIONS: As in any fire,wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH(approved or equivalent)and full protective gear. Keep unnecessary people away;isolate hazard area and deny entry. Stay upwind; keep out of low areas. Move container from fire area if you can do it without risk. Cool exterior of storage tanks. Stay away from ends of tanks. FIRE AND EXPLOSION HAZARDS: During a fire,irritating and highly toxic gases of hydrogen chloride or chlorine may be generated by thermal decomposition. SENSITIVITY TO MECHANICAL IMPACT/STATIC DISCHARGE: no applicable 6. ACCIDENTAL RELEASE MEASURES Vacuum or sweep up material and place in a disposal container. After removal,flush contaminated area with detergent and water. Avoid runoff into storm sewers and ditches which lead to waterways. Spills of 1000 pounds(454 kilograms)or more must be reported to the National Response Center,(800)424-8802. If water pollution occurs, notify the appropriate authorities. Document Number.: Page 3 of 9 Revision Revision Date: 1 1 No.: 5/2006 J MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 = FERRIC CHLORIDE,ANHYDROUS Product Number:None Emergency Overview Greenish black granular solid. May cause severe liver and/or kidney damage if swallowed. Do not induce vomiting. Can cause irritation or chemical burns to human tissue. Contact with eyes can cause irritation and may even cause permanent visual loss, remove quickly by thorough irrigation with water. Do not use water on fire. Use dry chemical or COZ. Beware of chlorine gas or hydrogen chloride gas at high temperatures. See Sections 3,4,and 5. 7. HANDLING AND STORAGE Store in a dry area. Store away from heat,strong alkalis and alkali metals. Keep containers closed and dry. Protect container from physical damage. See Section 10 for types of packaging material to avoid. Avoid contact with water and minimize contact with moisture. Avoid breathing dust. Avoid contact with skin and eyes. Use gloves when handling. Wash thoroughly after handling;dust off excess before washing. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION:Adequate ventilation and appropriate respiratory protection required. RESPIRATORY PROTECTION: Use NIOSH/MSHA approved,full face respirator with gas canister suitable for inorganic gases/vapors . Consult respirator manufacturer to determine appropriate equipment. SCBA equipment is suitable for higher concentrations or long term exposures. PROTECTIVE GLOVES: Wear impervious rubber gloves. EYE PROTECTION: Wear splash proof chemical safety goggles. Do not wear contact lenses. OTHER PROTECTIVE EQUIPMENT: Wear protective clothing to minimize skin contact. Rubber footwear and apron should be used as appropriate. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. WORK/HYGIENIC PRACTICES: Avoid breathing dust. Use gloves when handling. OTHER PRECAUTIONS: None. Document Number.: Page 4 of 9 Revision No.: Revision Date: 1 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,20M ---� FERRIC CHLORIDE,ANHYDROUS Product Number.None 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: greenish black Odor. none Odor Threshold: not applicable Physical State: granular solid Vapor Pressure(REID): negligible Specific Gravity: 2.8 -2.9 (water=1) Solubility in Water: 50%by weight pH: 1.0 for 2%solution Boiling Point: 305-3170 C or 581 -6030 F Vapor Density: not applicable (Air=1) Evaporation Rate: not applicable (Butyl Acetate=1) Melting Point: 3010 C or 5740 F Coefficient of Water/Oil Distribution: data not available Percent Volatile by Volume(%)at 550 C: negligible Viscosity: data not available %Solids: data not available %VOC: data not available l For information on FLASH POINT,FLAMMABILITY OXIDIZING PROPERTIES, J AUTOFLAMMA.BILITY,and EXPLOSIVE PROPERTIES,please see Section 5. 10. STABILITY AND REACTIVITY GENERAL: This product is stable and hazardous polymerization will not occur. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Material is stable when properly handled. Refer to Section 7. Avoid high temperatures. Avoid potassium and sodium. HAZARDOUS DECOMPOSITION PRODUCTS: Can release toxic chlorine gas at elevated temperatures above 5530 F. Can release toxic hydrogen chloride on contact with water or steam at elevated temperatures. Document Number.:_ Page 5 of 9 Revision No.: Revision Date: 1 ' 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 ---� FERRIC CHLORIDE,ANHYDROUS Product Number:None 11. TOXICOLOGICAL INFORMATION LD50: 1932 mg/kg(oral toxicity,rat) LC50: data not available Immediate Effects: Exposure caused erythema to skin of rabbits. Ingestion causes severe liver and/or kidney damage in humans. Refer to Section 3 for other immediate effects. Carcinogenicity: not applicable 12. ECOLOGICAL INFORMATION Chronic Hazard Level: Mild chronic irritant in 2-5 month studies,trout showed growth decreases and invertebrates effects: reproduction at 12 and 3 ppm,respectively. For daphnids,reduction was 16%at 4.38 ppm Fe. Marine waters should not exceed 0.3 ppm Fe. Chronic Plant Toxicity Limit: 1000 ppm 1 Potential for Accumulation: 1 Concentration factors for iron: marine freshwater plants 50,000 5000 invertebrates 20,000 3200 fish 3000 300 Half-life in total human body=800 days Chronic Aquatic Toxicity Limit: 130 ppm(Daphnia magna) Persistency: Can persist indefinitely Carcinogenicity: not applicable 13. DISPOSAL CONSIDERATIONS Dispose of spilled,neutralized,or waste product,contaminated soil and other contaminated materials in accordance with all local,state and federal regulations. Document Number.: page 6 of 9 Revision No.: Revision Date: 1 5/2006 1 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number:None 14. TRANSPORT INFORMATION DOT(Department of Transportation): Proper Shipping Name: Ferric Chloride Hazard Class: 8 Identification Number: UN1773 Packing Group: III Emergency Response Guide Book Number: 157 Corrosive: skin 15. REGULATORY INFORMATION U.S.Federal Regulations: OSHA: This product is hazardous by definition of Hazard Communication Standard(29 CFR 1910.1200). SARA TITLE III(Superfund Amendments and Reauthorization Act of 1986) Section 302 Extremely Hazardous Substances: Ingredient RO(Reportable uantity) TP none Section 311/312 Hazard and Physical Hazards: Immediate: yes Delayed: no Fire: no Pressure: no Reactivity: no Section 313 Toxic Chemicals: Ingredient %by Weight none CERCLA/SUPERFUND(40 CFR 117,302) InUedient Ferric Chloride,Anhydrous 1000 pounds Notify the National Response Center (1-800424-8802) RCRA: If discarded in its purchased form,this product would be a hazardous waste by Document Number.: page 7 of 9 Revision No.: Revision Date: 1 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 j FERRIC CHLORIDE,ANHYDROUS Product Number:None characteristic. This product contains no Class I or Class H Ozone Depleting Chemicals. DOT: Please refer to Section 14. State Regulations: California data not available Michigan data not available International Regulations: CANADA. WHMIS Hazard Class(es): data not available CEPA: data not available This product has been classified in accordance with the hazard criteria of the CPR jand the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION The following label hazard ratings are recommended for containers of Ferric Chloride, Anhydrous: (Hazard Index Key: 4=severe; 3=serious;2=moderate; 1 =slight;0=minimal) NFPA HMIS Health 2 Health 3 Flammability 0 Flammability 0 Reactivity 0 Reactivity 1 MSDS Status: The entire MSDS has been revised October 22,2001. To the best of our knowledge,the information contained herein is accurate. However,neither PVS Chemicals,Inc.,nor any of its subsidiaries,assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein,we cannot guarantee that these are the only hazards which exist. Consult the manufacturer for further Document Number.: Page 8 of 9 Revision No.: Revision Date: 1 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number.None information. I Document Number.: page 9 of 9 Revision No.: Revision Date: 1 5/2006 - i Hydrofluorw ■� (aqueous solution) Material Safety Data Sheet Chemical: Hydrofluoric acid NFPA: H=4 17=0 1=0 S=None HMIS: H=4 F=0 R=1 PPE=Supplied by user, dependent on conditions ■_ MSDS Number. HF70-0505 Effective Date: 5 May 2005 O Issued by: Solvay Chemicals,Inc.Regulatory Affairs Department Not valid three years after effective date or after issuance of superseding MSDS,whichever is earlier.French or Spanish translations of this MSDS may be available.Check www.solvaychemicals.us or call Solvay Fluorides,LLC to verify the latest version or translation availability. Material Safety Data Sheets contain country-specific regulatory information.Therefore,the MSDS's provided are for use only by customers of Solvay Fluorides,LLC in North America.If you are located in a country other than Canada,Mexico or the United States,please contact the Solvay Group company in your country for MSDS information applicable to your location. 1.1 Product Name: Hydrofluoric acid,70%(aqueous solution) Chemical Name: Hydrofluoric acid Synonyms: Fluorhydric acid,70% HF,Aqueous HF Chemical Formula: HF Molecular Weight: 20 CAS Number 7664-09-3 EINECS Number. 231-634-8 1.2 Recommended Uses: Metallurgy;Glass industry,Chemical industry,Fuel additives, Intermediates 1.3 Supplier. Solvay Fluorides,LLC PO BOX 27328 Houston,TX 77227-7328 3333 Richmond Ave.Houston,Texas 77098 1.4 Emergency Telephone Numbers Emergencies(USA):1-800-424-9300(CHEMTRECO) Transportation Emergencies ONTERNATIONAL/IMARMME):1-703-527-3887(CHEMTRECI Transportation Emergencies(CANADA):1-613-996-6666(CANUTEC) Transportation Emergencies(MEXICO-SETTQ): 01-800-00-214-00(MEX.REPUBLIC) 525-559-1588(Mexico City and metro area) ,a,L.S TI"STING C OMI P MEWED BY T f Solvay yMSDS No.H ,Solvay Revised 05 05 05 Fluorides SOLVAY Responsible Cara Copyright 200505 Solvay FluorkJes,LLC C—dchemhhyat Wort A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. A Subsidiary of Solvay Chemicals, Inc. Page 1/15 www.solvw.solvaychemicals.us 1.ti00.705.8292 Hydrofluoric acid, ■� (aqueous solution) Matelial Safety Data Sheet INGREDIENTS FORMULA WT.PERCENT CAS# ■� Hydrogen Fluoride HF >_70 766439-3 Water H2O balance 7732-18-5 O e . Emergency Overview: 3.1 Route of Entry: Inhalation:Yes Skin:Yes Ingestion:Yes O 3.2 Potential Effects of exposure: • Dangerl Corrosive and toxic product,very hazardous to human health and the environment. • Causes severe bums to eyes,skin,and respiratory tract. • Bums may not be immediately painful or visible.Onset can be delayed up to 24 hours. • Can be absorbed through the skin in fatal amounts. • Risk of cardiac and nervous disorders. • Presents hazards from its ionized fluorine which binds with calcium in the body and can result in hypocalcemia(possible life-threatening lowering of serum calcium). 1 Chronic exposure to the product can cause bone or dental fluorosis. J Reactions with certain metals can generate flammable and potentially explosive hydrogen gas. Inhalation. • Severe irritation of the nose and the throat. • Spasmodic cough and difficulty in breathing. • Risk of chemical pneumonitis(lung irritation)and pulmonary edema(fluid in lungs). • At high concentrations,risk of hypocalcemia(possible life-threatening lowering of serum calcium)with nervous problems(tetany)and cardiac arrhythmia(heart irregularity). • In case of repeated or prolonged exposure; risk of sore throat,nose bleeds,chronic bronchitis,emphysema and erosion of teeth. Eyes: • Also possible hazard by simultaneous inhalation of the product • Bums may not be immediately painful or visible for up to 24 hours. • Severe eye irritation,watering,redness and swelling of the eyelids. • Bums. • Risk of serious or permanent eye lesions or cornea damage and blindness. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005.Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 2115 www.solvaychemicals.us 1.800.765.8292 ■� (aqueous solution) Material Safety Data Sheet Skin contact: • Also possible hazard by simultaneous inhalation of the product. • Bums may not be immediately painful or visible for greater than 8 hours. ■_ • The product can be absorbed through the skin causing destruction of the deep tissue layers including the bone tissue. • Painful irritation,redness and swelling of the skin. • Severe bums,slow healing. • Risk of shock. • If contact with the fingernails,severe pain after several hours. - • Risk of hypocalcemia(possible fife-threatening lowering of serum calcium)depending on the extent of the lesions. Ingestion: • Severe irritations,bums,perforation of the gastrointestinal tract accompanied by shock. • Risk of edema(fluid in lungs)and suffocation. • Nausea,vomiting(bloody),abdominal cramps and diarrhea(bloody). • Cough and difficulty breathing. • Risk of chemical pneumonitis Qung irritation)and pulmonary edema(fluid in lungs) Pill% from product inhalation. • Risk of hypocalcemia(possible life-threatening lowering of serum calcium)with nervous problems(tetany)and cardiac rhythm disorders. • Risk of convulsions,loss of consciousness,deep coma and cardiopulmonary arrest. • Risk of general symptoms having a severe or fatal prognosis. CarcinogeniciW.See section 11.3 SOME General Recommendations: • Consult physician immediately in all cases. • Personal protective equipment(respirator,gloves,etc.)required for rescuers of victims (See section 8). • In case of product splashing into eyes and face,treat eyes first. • Decontaminate the victim first. • Maintain an adequate supply of antidote gel(calcium gluconate). (HANDLE PATIENT AND ALL CONTAMINATED CLOTHING WITH HF RESISTANT GLOVES.) Note:The effect of HF,i.e.the onset of pain,particularly in dilute solutions,may not be felt for up to 24 hours. It is important that workers have immediate access to the antidote(calcium gluconate)both on and off the worksite in order to apply it as soon as possible.Instructions should be given for the worker not to use the gel in the eye and the worker to still seek medical attention regardless of how minor the contact.The calcium combines with the fluoride to form the insoluble calcium fluoride thus preventing the fluoride from entering the Intact skin and causing tissue damage.HF antidote gel(calcium gluconate)is available through Pharmascience of Montreal,Canada[(800)207-4477]and your local pharmacist. i MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay chemicals,Inc. All Rights Reserved. Page 3/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluormc i1 ■� (aqueous solution) Material Safety Data Sheet 4.1 Inhalation: • Remove the subject from the contaminated area as soon as possible.Transport subject lying down,with the head higher than the body,to a quiet,uncontaminated and ■_ well-ventilated location. • Administer oxygen(2.5%calcium gluconate if available,can be oxygen-nebulized with O trained personnel)or cardiopulmonary resuscitation if necessary and as soon as possible.If patient is unconscious,give artificial respiration. Note:Mouth to mouth resuscitation is not recommended. • Keep warm(blanket). - Consult physician in all cases. • Take to a hospital. Eyes: • Flush eyes with running water for 5 minutes,while keeping the eyelids wide open. • Rinse the eyes with a calcium gluconate 1%solution in physiological serum (10 ml of calcium gluconate 10% in 90 ml of physiological serum)for 10 minutes. (Continue a calcium gluoonate drip into eyes...Then drop wise while transporting.) If 1%calcium gluconate.is not available continue flushing with water. • In the case of difficulty opening the lids,administer an analgesiceye wash.Do not use oily drops,ointment,or HF skin bum treatments. y\ • Consult an ophthalmologist or eye specialist and physician immediately in all cases. • Take to a hospital immediately. Skin: • Immediately bring the clothed subject under the shower. • Remove contaminated shoes,socks and clothing,while washing the affected skin with running water for 5 minutes.Double-bag all contaminated clothing for disposal. • Immediately apply calcium gluconate gel 2.5%and massage into the affected area using rubber gloves;continue to massage while repeatedly applying gel until 15 minutes after pain is relieved(see section 16). • Apply water longer(15 minutes)if calcium gluconate is not available. • Alternately,immerse the burned area in a solution of 0.2%iced aqueous Hyamine 1622 (a quaternary ammonium made by Rohm&Haas)or 0.13% iced aqueous Zephiran Chloride(a benzalkonium chloride sold by Sanofi-Synthelabo). • If finger/fingernails are touched,even if there is no pain,dip them in a bath of 5%calcium gluconate for 15 to 20 minutes. • Keep warm(blanket);provide clean clothing. • Consult a physician immediately in all cases of skin contact no matter how minor. • Take to a hospital immediately. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemlcais,Inc. All Rights Reserved. Page 4/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet Ingestion: • Consult a physician immediately in all cases. • Take to a hospital. If the subject is completely conscious: • Rinse mouth with fresh water. O Do not induce vomiting. • When directed by physician,give orally either 1%aqueous calcium gluconate solution, milk or calcium/magnesium containing anti-acid.Such solutions can be beneficial but also may be problematic if they induce vomiting. • If the subject presents nervous,respiratory or cardiovascular disorders, administer oxygen. If the subject is unconscious: • Administer classical resuscitation measures. • Do not give anything by mouth to an unconscious person. 4.2 Medical Treatment/Notes to Physician:(HANDLE PATIENT AND ALL CONTAMINATED CLOTHING WITH HF-RESISTANT GLOVES.) Note:For bums of moderate area(greater than 8 square inches on a normal adult),significant inhalation exposure,and ingestion,systemic effects may occur,and a critical care unit should be 1 considered for the patient to monitor for hypocalcemia,cardiac arrhythmias, hypomagnesemia, and hyperkalemia and possible dialysis. Hypocalcemia may need to be monitored for bums of greater than two square inches and may require systemic administration of calcium gluconate. EKG can be monitored indirectly for effectiveness of treatment for hypocalcemia. Excess calcium can cause heart irregularities. Inhalation: • Pulmonary resuscitation(oxygen therapy). • If necessary,tracheal intubation and positive pressure ventilation. • Treat as soon as possible.Give a 2.5 to 3%calcium gluconate solution by nebulizer in the first 12 to 24 hours. • Prevention or treatment of pulmonary edema and bacterial secondary infection. • Surveillance of cardiac(EKG),respiratory,renal and hepatic functions. • In case of hypocalcemia,I.V.perfusion of 10 ml of a 10%calcium gluconate solution diluted in 1 liter of physiological serum. • Surveillance of hyperfluoremia and possible treatment with hemodialysis. • Do not give stimulants.Patient must remain inactive for at least 24 hours. Eye Contact: • Initiate irrigation with 500 to 1,000 cc of a 1%calcium gluconate solution in normal saline using local anesthetic.Administration by an ocular irrigator is desirable. • Consult an ophthalmologist. • Follow up with 1%calcium gluconate eyedrops as required and ophthalmic steroid solution,as indicated by ophthalmologist. • In addition,medical surveillance as specified for inhalation. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 5/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, o ■� (aqueous solution) Material Safety Data Sheet Skin Contact: • Prevention or treatment for shock. • Apply and massage calcium gluconate gel(2.5%)until pain subsides or 20 minutes have elapsed for 4-6 times a day. • If the exposed surface is larger than 2 in2,administer(in 1,000 cc of Hartman or saline O solution)20 cc of 10%calcium gluconate at a slow rate(60-70 dropstminute). • For second and third-degree bums,or if the pain does not subside within 20 minutes,or bums with concentrated HF(greater than 50%),consider sub-cutaneous microinjections of 2.5%calcium gluconate at a distance of 5 mm around the affected area using a small - gauge needle(#30 stainless). Do not use more than 0.5 ml per cm2 of affected skin �■,.�, surface. • Severe digital burns:slow intra-arterial infusion(over a 4-hour period)of 10 ml of a 10%calcium gluconate solution diluted in 40 ml of physiological serum. LZ • For HF contact on nails,consider splitting the nail and application of calcium gluconate on the nail bed. • Blisters and necrotic tissue should be debrided(blaming:The liquid contained in the blister is corrosive). • Do not use local anesthetics.Resolution of pain is a means to determine effective medical treatment • In addition,medical surveillance as specked in"inhalation"section. Ingestion: • Oxygen therapy via intra-tracheal Intubation. • If necessary,tracheotomy. • Careful gastric lavage after administration of 10 vials of calcium gluconate (to be repeated as frequently as needed). • In case of intense pain,inject an I.M.morphomimetic analgesic drug(piritramide) before taking to hospital. • Prevention or treatment of shock and pulmonary edema. • Digestive endoscopy in all cases. • Treatment of gastrointestinal tract burns and resulting effects. • Surveillance and treatment of hypocalcemia.In case of hypocalcemia,I.V.perfusion of 20 ml of a 10%calcium gluconate solution diluted in 1 liter of physiological serum. • Surveillance of hyperfluoremia and possible treatment with hemodialysis. • Surveillance of cardiac(EKG)and nervous system functions. 5.1 Flash point:Not applicable. 5.2 Auto-ignition Temperature: Non-flammable. 5.3 Flammability Limits:Non-flammable. 5.4 Unusual Fire and Explosion Hazards:See section 10. 1 MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 6/15 www.soivaychemicals.us 1.800.765.8292 Hydrofluoric acid, O ■� (aqueous solution) Material Safety Data Sheet 5.5 Extinguishing Methods Common:Use means appropriate for surrounding fire. Inappropriate extinguishing means:None. 5.6 Fire Fighting Procedures Specific hazards: O Non-combustible/non-flammable but may produce dangerous fumes if involved in fire. • Formation of dangerous gas in contact with water or humid air. • Formation of flammable gas on contact with certain metals(see section 10). - Protective measures in case of intervention: Y� Evacuate all non-essential personnel. T*■ • Intervention only by capable personnel who are trained and aware of the hazards of the product. • In all cases wear self-contained breathing apparatus. • When intervention in close proximity,wear full protective acid-resistant suit. • Protect Intervention team with water spray when approaching the fire. • After intervention,proceed to clean the equipment used in intervention(remove pit clothing carefully,double-bag contaminated clothing and dispose of property and shower thoroughly). Other precautions: • Cool containers exposed to fire. • Depending on wind direction,warn people of danger of inhalation,close doors and windows and get ventilation stopped. • Approach from upwind. • Absorb gas/vapors with water spray. • After the fire,proceed rapidly to clean the surfaces exposed to the fumes in order to limit the damage to the equipment. • As for any fire,ventilate and clean the rooms before reentry. 6.1 Precautions: • Follow the protective measures given in sections 5 and 8. • Isolate area • Approach from upwind. • Ventilate the premises. • Eliminate all sources of ignition,and do not generate flames or sparks. • Keep away materials and products which are incompatible with the product (see section 10). • Disperse gastvapor with water spray. • To avoid excessive fuming,do not apply water directly onto the spillage but upstream or on a runoff. • In case of leaking container,try to reposition it to get the leak in gaseous phase. • Protect intervention team with water spray. • Use bagged lime to form containment. • If safe to do so with proper personal protective equipment, attempt to stop or minimize 1 the leak. J MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 7115 www.soivaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet 6.2 Cleanup methods: • Prevent the product from entering sewers or confined spaces. • Knock-down water is dangerous for the environment and should be diked for containment and later disposal(see section 13). • Neutralize product with alkali(sodium carbonate,lime,...). O 6.3 Precautions for protection of the environment: • Immediately notify the appropriate authorities in case of significant discharge. • Do not discharge into the environment(atmosphere,...). 7.1 Handling: • Carry out industrial operations in closed,but vented,piping circuits and equipment • Handle small quantities under a lab hood. MOL • Operate in a well-ventilated area. • Use only equipment and materials which are compatible with hydrogen fluoride. • Keep away from reactive products(see section 10). • Preferably transfer by pump or gravit)6 7.2 Storage: • Keep in ahermetically-sealed container. • Store in a ventilated,cool area. • Keep away from heat sources. • Keep away from reactive products(see section 10). • Use containment dike around storage containers and transfer installation. 7.3 Specific Uses:See section 1.2. 7.4 Other precautions: • Provide tight electrical equipment,well protected against corrosion. • Follow the protective measures given in section 8. • Warn people about the dangers of the product. 7.6 Packaging: • Steel+PE. • PE. &I Exposure Limit Values: Authorized limit Values ACGIIN-USA(2005) OSHA NIOSH Hydrogen fluoride(as F) TWA 0.5 ppm-TLV PE 3 ppm IDLH 30 ppm TWA 0.38 mg/0-TLV STEL 6 ppm(15min) TWA 2 ppm-ceiling 1.5 mg/m'-ceiling AIHA Emergency Response Planning Guidelines ER1113-1 ERPG-2 ERPG-3 2 ppm 20 ppm 50 ppm ACGIH•and TWO are registered trademarks of the American Conference of Governmental Industrial Hygienists. I MSDS No.HF70-0505 Revised 05-05-05 copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay chemicals,Inc. All Rights Reserved. Page 8/15 www.soivaychemlcals.us 1.800.765.8292 fHydrofluoric acid, O ■� (aqueous solution) Q_ Matelial Safety Data Sheet 82 Exposure Controls: • Maintain employee exposures to levels below the applicable exposure limits. • Follow the protective measures given in section 7. ■� 8.2.1 Occupational Exposure Controls: O 8.2.1.1 Ventilation:Provide local ventilation suitable for appropriate emission control. 8.2.1.2 Respiratory protection: • Use only NIOSH-approved respirators. • Comply with OSHA respiratory protection requirements. Use self-contained breathing apparatus in medium confinement/in insufficient oxygen environments/in case of large uncontrolled emissions/in all circumstances when the mask and cartridge do not give adequate protection. 82.1.3 Hand protection: • Use Protective gloves-HF chemically-resistant;recommended materials:butyl rubber. 82.1.4 Eye protection:Chemical-proof goggles/full face shield obligatory. 8.2.1.5 Skin protection: • HF acid-resistant clothing. • HF chemically-resistant boots if risk of splashing. / 8.3 Other precautions: • Provide shower and eyewash stations. • Wash soiled equipment. • Take off contaminated clothing immediately after exposure. Double-bag and dispose of properly. • Avoid contact with any leather object. • Consult the industrial hygienist or the safety manager for the selection of personal protective equipment suitable for the working conditions. 9.1 Appearance:Liquid. Color:Colorless. Odor:Pungent 9.2 Important Health,Safety and Environmental information: pH:<1;10 mg HFA pH=3.15;100 mg HF/I:pH=2.65. Change of state: Melting point:-700C(-940F). Boiling point:67°C(152°F)at atm. Decomposition Temperature: No data. Flash Point:Not applicable. Flammability:Non-flammable. Explosive Properties:With certain materials(see section 10). MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 9/15 www.solvaychemicals.us 1.800.765.8292 acid,Hydrofluoric o ■� (aqueous solution) Material Safety Data Sheet Oxidizing Properties:Not applicable. Vapor Pressure:176 mbar(132 mmHg)at 20°C(680F). C3■� Relative Density: Specific graviry:1.25 at 20°C(680F). O (H2O=1). Solubility: Water.Very Soluble. Fat:No data. Partition coefficient:Not applicable. Viscosity:No data. Vapor Density(air--1):2.4 at 20°C(680F). Evaporation Rate:No data. Stability:Unstable under certain conditions(see below). 10.1 Conditions to avoid:Negligible. 10.2 Materials and substances to avoid: • Metals:yield hydrogen gas. • Glass:dissolves. • Strong Bases:violent reaction. • Alkalines:violent reaction. 10.3 Hazardous decomposition products:Hydrogen. 10A Hazardous Polymerization:Will not occur. 10.5 Other Information: • Exothermic reaction when mixed in water. • Corrosive action on some metals when moisture exists. • Contact with strong bases or alkaline materials may provoke violent reactions or explosions. • In presence of humidity,contact with metals releases hydrogen. 11.1 Acute toxicity: Inhalation:LC,,1 hour(s),rat,850 to 1070 ppm. Oral:LD100,guinea pig,80mg/kg(2%solution). Dermal:No data. Irritation: • Corrosive. • Reacts with mucous membranes. J MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 10115 www.soivaychemicals us 1.800.765.8292 Hydrofluoric acid, o ■� (aqueous solution) Material Safety Data Sheet Sensitization:No data. Comments: • Corrosive effect for the skin,eyes and respiratory tract. ■C • Chronic exposure may entail dental or skeletal fluorosis. + Risk of effect on the liver and the kidney. O The carcinogenic effect found in animals is not demonstrated in humans. • Risk of toxic effect on reproductive systems. 11.2 Chronic toxicity: - • Inhalation,after prolonged exposure,rat,target organ:respiratory system/eyes/kidney, liver,observed effect(Sodium fluoride). T� • Oral route,after prolonged exposure,rat/mouse,target organ:skeleton/thyroid/testes/ kidney,liver,ca.Img/kg.observed effect(Sodium fluoride). • Ambiguous carcinogenic effect(Sodium fluoride). • Fetotoxic and fertility effects(Sodium fluoride). W • Ambiguous mutagenic effect(Sodium fluoride). 11.3 Carcinogenic Designation:None 12.1 Acute ecotoxicity: • Fish,Salmo gairdned,LC50,96 hour(s),51 mg/I(Fluorides). • Crustaceans,Daphnia magna, ECG,48 hour(s), 97 mg/I. • Conditions:Fresh water(Fluorides). Crustaceans,Mysidopsis bahia,EC5.,96 hour(s),10.5mgA. • Conditions:Salt water(Fluorides). Algae,Scenedesmus sp.EC50,96 hour(s),43 mg/I(Fluorides). 12.2 Chronic ecotoAciiy: • Fish,Salmo gardneri,LC50,21 day(s),3.7 mg/I(Fluorides). • Crustaceans,Daphnia magna, NOEC,21 day(s),3.7 mg/I(Fluorides). 12.3 Mobility: • Air-mobility in aerosol form. • Water-considerable solubility and mobility. • Soil/sediments-adsorption on mineral soil constituents. • Conditions:slightly acid pH(Fluorides). 12.4 Degradation Abrotic: • Air-neutralization by natural alkalinity. • Water/soil-ionization/neutralization of inorganic and organic materials. • Water/soil-complexation/precipitation of inorganic materials. Degradation products:aluminumrron/calcium/phosphate complexes and/or precipitates as a function of pH(Fluorides). Biotic:Not applicable(inorganic compound). J MSDS No.HF70-0505 Revised D5-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Ina All Rights Reserved. Page 11/15 www.solvaychemloals.us 1.800.765.8292 Hydrofluoric acid, O ■� (aqueous solution) Material Safety Data Sheet 12.5 Potential for bioaccumulation: Bioconcentration:log Po/w-Not applicable(ionizable inorganic compound). Accumulation into vegetable leaves(Fluorides). ■� 12.6 Other adverse effects/Comments: • Harmful for aquatic organisms. O • Nevertheless,hazard for the aquatic environment is limited due to product properties: low chronic toxicity. • Product fate is highly dependent on environmental conditions:pH,temperature, oxidoreductive potential,mineral and organic content of the medium,... 13.1 Waste treatment: • Dispose in compliance with local,state and federal regulations. • Contact the producer for recyclingtrecovery suggestions. • Absorb the product in a KOH solution. Possible residual solution.Vapors may be released.Good ventilation is required. • Use lime or,preferably,calcium hydroxide or calcium carbonate to precipitate the fluoride ion in the form of CaF2. 'l 13.2 Packaging treatment: J To avoid treatments,use dedicated containers. Do not rinse containers. • Dispose of the containers in compliance with local,state and federal regulations. 13.3 RCRA Hazardous Waste:lasted; RCRA Waste Number:U134. Mode DOT IMDG IATA UN Number UN 1790 UN 1790 UN 1790 Class 8 8 8 Proper Shipping Name Hydrofluoric acid Hydrofluoric acid Hydrofluoric acid Hazard label(Subsidiary) Corrosive(toxic) Corrosive+toxic Corrosive+toxic Subsidiary risk 6.1 Toxic Toxic Placard Corrosive(toxic) 1790 Subsidiary Placard Poison Packing Group 11 II II Reportable Quantity 100 lbs. MFAG 750 F-mS ERG:157 EMS:8-03 ERG code:8P / MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 12/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, O ■� (aqueous solution) Material Safety Data Sheet National Regulations(US) ■� TSCA Inventory 8(b):Yes. SARA Title III Sec.302t303 Extremely Hazardous Substances(40 CFR 355):Yes. SARA Title III Sec.311/312(40 CFR 370):Yes. Threshold planning quantity.100 lbs. SARA Title III Sec.313 Toxic Chemical Emissions Reporting(40 CFR 372):Yes. - CERCLA Hazardous Substance(40 CFR Part 302) Listed waste:Yes;(U134)Reportable quantity-100 lbs. OUnlisted waste:Yes. Characteristic:D002(Corrosive). Other:Occupational Safety and Health Administration(OSHA)requirements for process safety management must be followed anytime at least 1,000 lbs.of hydrofluoric acid is used or stoned. Refer to 29CFR 1910.119 for specific details. Environmental Protection Agency(EPA)requirements for a Risk Management Plan(RMP)must be followed anytime at least 1,000 lbs.of hydrofluoric acid>50%is used or stored.Refer to l 40CFR68.150 for specific details. State Component Listing: State Comment CA Airborne Contaminants&Emissions Inventory CA Hazardous Substance List CT Hazardous Material Safety IL Chemical Safety Act IL Toxic Substances Disclosure to Employees Act IN Occupational Health&Safety Standards-Air KY Occupational Health&Safety Standards-Air LA Right to Know List LA Spill Reporting MA Oil and Hazardous Materials List MA Right to Know Substance List MN Hazardous Substance List NJ Right to Know Substance List NJ Spill Tax List NJ Toxic Catastrophe Prevention Act NC Exposure Limits for Air Contaminants NY Release Reporting List of Hazardous Substances PA Right to Know RI Right to Know Act MSDS No.HF70-0505 Revised 05-05-05 Copyright 2006,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 13/16 www.solvaychemicais.us 1.800.765.8292 Hydrofluoric acid, O ■� (aqueous solution) Material Safety Data Sheet National Regulations(Canada) Canadian DSL Registration:DSL. ■_ WHMIS Classification: D1A-Very toxic material. E-Corrosive. This product has been classified in amordartce with the hazard criteria of the Controlled Products Reguliations,and the MSDS contairis all the information required by the Controlled Products Regulations Labeling according to Directive 1999/45/EC. Category ID Phrase Symbols T+ Very toxic. C Corrosive. Phrases R 26/27/28 Very toxic by inhalation,in contact with skin and if swallowed. 35 Causes severe bums. Phrases S (1/2) (Keep locked up and out of the reach of children.) 7/9 Keep container tightly closed and in a well-ventilated place. 26 In case of contact with eyes,rinse immediately with plenty of water and seek medical advice. 36/37 Wear suitable protective clothing and gloves. 45 In case of accident or if you feel unwell,seek medical advice immediately(show the label where possible). 16.1 Ratings: NFPA(NATIONAL FIRE PROTECTION ASSOCIATION) Health=4 Flammability=0 Instability=0 Special=None HMIS(HAZARDOUS MATERIAL INFORMATION SYSTEM) Health=4 Fire=0 Reactivity=1 PPE=Supplied by User,dependent on local conditions 162 Other Information: For additional information on handling,storage and packaging see HFIPI:Recommended Practices for the Hydrogen Fluorides Industry.Copies can be purchased through American Chemistry Council at(703)741-5611. The previous information is based upon our current knowledge and experience of our product and is not exhaustive.it applies to the product as defined by the specifications.In case of combinations or mixtures,one must confirm that no new hazards are likely to exist. In any case,the user is not exempt from observing all legal,administrative and regulatory procedures relating to the product, personal hygiene,and integrity of the work environment.(Unless noted to the contrary,the technical information applies only to pure product). To our actual knowledge,the information contained herein is accurate as of the date of this document. However, neither Solvay Fluorides, LLC nor any of its affiliates makes any warranty, express or implied,or accepts any liability in connection with this information or its use.This information is for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process.This is not a license under any patent or other proprietary right.The user alone must MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 14115 www.solvaychemicals.us 1.800.765.8292 acid,Hydrofluoric O ■� (aqueous solution) Material Safety Data Sheet finally determine suitability of any information or material for any contemplated use,the manner of use and whether any patents are infringed.This information gives typical properties only and is not to be used for specification purposes.Solvay Chemicals, Inc.reserves the right to make additions,deletions or modifications to the information at any time without prior notification. O Trademarks and/or other Solvay Fluorides,LLC products referenced herein are either trademarks or registered trademarks of Solvay Fluorides,LLC or its affiliates,unless otherwise indicated. - 16.3 Reason for revision: Supersedes edition:Solvay Fluorides,LLC MSDS HF70-0704 dated 07/15/2004. Purpose of revision:Update ACGIH levels(section 8). 1 MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 15/15 www.solvaychemicals.us 1.800.765.8292 enthone Ja aterial Safety taa Sheet. Material Safety Data Sheet Emergency phone: CHEMTREC Number Flammability I (800)424-9300 Health 0 Instability Reactivity "I Special Personal protection C Section 1. Chemical product and company identification Product name : ENPREPO 576E Product code : 202091 Material uses : Specialty chemicals for the electronics and surface finishing industries. Manufacturer : Enthone Inc Enthone OMI deMexico S.A.de C.V. 350 Frontage Road Norte 59 No.896 l West Haven, CT 06516 Col.Industrial Vallejo / Me)aco,D.F.02300 Phone: (203) 799-4917 Mebco Fax: (203) 799-8179 Phone:52 55 5078 3904 www.cooksonelectronics.com Fax 52 555 567 6326 www,cooksonelectronics.com Tel.local de emergenciesa:080 Tel.de emergencies en transportacion:01 800 0021 400; (55)55591588 Validation date 318/2005. Supersedes Date 4/30/1998 Prepared by Robyn Hescock Section 2. Composition, Information on Ingredients Name CAS number %by weight sodium carbonate 497-19-8 40-50 sodium hydro)ade 1310-73-2 30-40 2-(2-butoxyethoxy)ethanol 112-34-5 5-10 sodium sulfite 7757-83-7 1-5 Any component not listed in Section 2 is non-regulated or present in the product in concentrations below legal disclosure limits All ingredients comply with applicable rules or orders under United States TSCA and Canadian CEPA regulations. METALS TESTINGANJ IE1NEf3 BY0 "'�" CAT - L ". Continued on next page Enthone is a subsidiary of ENPREP 576E Page:V7 Fsection3. Hazards identification Physical state Solid.(Powder.) Odor Pungent. Emergency overview Danger! CAUSES RESPIRATORY TRACT,EYE AND SKIN BURNS. HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. MAY CAUSE ALLERGIC RESPIRATORY REACTION. CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS:BLOOD,KIDNEYS,LUNGS,LIVER,GASTROINTESTINAL TRACT, RESPIRATORY TRACT,SKIN,CENTRAL NERVOUS SYSTEM, EYE,LENS OR CORNEA. POSSIBLE CANCER HAZARD CONTAINS MATERIAL WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA. Do not ingest. Do not get in eyes,on skin or clothing. Do not breathe dust. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Risk of cancer depends on duration and level of exposure. Routes of entry Dermal contact. Eye contact. Inhalation. Ingestion. Potential acute health effects Eye contact Corrosive to eyes. Skin contact Toxic in contact with skin. Corrosive to the skin. Inhalation Corrosive to the respiratory system. May cause sensitization by inhalation. Ingestion Toxic if swallowed. May cause burns to mouth,throat and stomach. 'l Potential chronic health effects Target organs Contains material which may cause damage to the following organs:blood,kidneys, lungs,liver,gastrointestinal tract,upper respiratory tract,skin,central nervous system (CNS),eye,lens or comea. Over-exaosure 2-(2-Butoxyethoxy)ethanol:INHALATION: coughing,breathing difficulty-shortness of signs/symptoms breath and chest tightness/wheezing and pain. INGESTION: Narcotic effect;may cause nervous system disturbances. nausea/vomiting,headache,dizziness/vertigo and drowsiness/fatigue. EYES: blinking,redness or swelling.Risk of serious damage to eyes.Skin:Absorbed through skin. sodium sulfite(2:1):Ingestion:discomfort(gastrointestinal), diarrhea,blood pressure elevation May cause allergic reactions to certain individuals.Eyes:Irritating to eyes, mucosa and skin and may cause bums. Sodium carbonate:If large quantities of this material are swallowed:Causes bums., nausea/vomiting,circulatory collapse,death Sodium hydroxide:Corrosive to eyes and skin.Corrosive on ingestion.Inhalation of aerosol may cause lung oedema. Carcinogenicity Classified 3(Not classifiable for human.)by IARC[sodium sulfite(2:1)]. See toxicological Information(section 11) Section 4. First aid measures First aid Eye contact Provide a readily accessible eyewash facility and quick drench safety shower. Immediately flush eyes with running water for at least 15 minutes,keeping eyelids open. Get medical attention immediately. Skin contact Evacuate the victim to a safe area as soon as possible. Ensure that eyewash stations and safety showers are proximal to the work-station location. In case of contact,immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing jbefore reuse. Thoroughly clean shoes before reuse. Get medical attention. Continued on next page Enthone is a subsidiary of ENPREP 576E Page:317 Use NIOSH approved respirator when air concentration is greater than the TLV or PEL. Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Employers must ensure that employees are properly fitted and trained in the use of respiratory and other personal protection equipment. Employers must assure through industrial hygiene monitoring,engineering control and the selection of proper personel protection equipment that employees working with or around this product are not exposed to contaminant levels above those allowed by OSHA 29 CFR 1910. Inhalation If inhaled,remove to fresh air. If exposed person is not breathing,give artificial respiration or oxygen applied by trained personnel. Get medical attention. Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Neoprene gloves. Natural rubber gloves. Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. If fumes are still suspected to be present,the rescuer should wear an appropriate mask or a self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing,or wear gloves. Wear suitable protective clothing. section 5. Fire fighting measures NFPA Hazard identification : 0 number Flammability Auto-ignition temperature : Not applicable. Flash point : Not applicable. l Flammable limits : Not applicable. Products of combustion : These products are carbon oxides(CO,CO2),sulfur oxides(SO2,S03...). Some metallic oxides. Explosion hazards in : Not available. presence of various substances. Special remarks on : Not available. explosion hazards Fire fighting media and : Use an extinguishing agent suitable for surrounding fires. instructions Special protective : Fire fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus(SCBA)with a full facepiece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment(Section 8). Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and sewers. Methods for cleaning up Do not clean-up or dispose except under supervision of a specialist. Keep unnecessary and unprotected personnel from entering. Follow your company's spill procedures. Avoid contact with eyes,skin and clothing. Wear suitable protective clothing. Do not breathe dust. Be sure to use a MSHAMIOSH approved respirator or equivalent. Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Avoid creating dusty conditions and prevent wind dispersal. Vacuum or sweep up material and place in a designated labeled waste container. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Dispose of according to all 1 federal,state and local applicable regulations. Continued on next page Enthone is a subsidiary of ENPREP 576E Page:4/7 Group Section 7. Handling and storage Handling Do not ingest. Do not get in eyes,on skin or on clothing. Keep container closed. Use only with adequate ventilation. Do not breathe dust. Wash thoroughly after handling. Storage : Keep container tightly closed. Keep container in a cool,well-ventilated area. Incompatibility with various Reactive with oxidizing agents,organic materials,metals,acids. substances: Conditions of instability Not available. Section 8. Exposure Controls, Personal Protection Engineering controls Use only with adequate ventilation. If user operations generate dust,fumes,vapor or mist,use process enclosures,local exhaust ventilation,or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Personal protection Eyes Avoid contact with eyes. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes,mists or dusts. Skin Avoid contact with skin and clothing. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Use a properly fitted,particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Hands Avoid contact with skin. Chemical-resistant,impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Personal protection in case Do not clean-up or dispose except under supervision of a specialist.Keep unnecessary of a large spill and unprotected personnel from entering.Follow your companys spill procedures. Avoid contact with eyes,skin and clothing.Wear suitable protective clothing and eyetface protection. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Avoid breathing vapors of this product.Be sure to use a MSHA/NIOSH approved respirator or equivalent.Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Ingredient name CAS number Exposure limits sodium hydrodde 1310-73-2 ACGIH 7LV(United States,9I2004). CEIL:2 mg/m' Form:All forms MOSH REL(United States,612001). CEIL 2 mg/m9 Fonn:All forms OSHA PEL(United States,611993). 'MIA:2 mgW 8 hour(s).Form:All farms OSHA PEL 1989(United States,311989). CEIL•2 mg/m' Form:All farms Consult local authorities for acceptable exposure limits. Continued on next page Enthone Is a subsidiary of ENPREP 576E Page:517 Cookson roup PLU Section 9. Physical and chemical properties Physical state : Solid.(Powder.) Color : Tan. Odor : Pungent. pH : Basic. Boiling/condensation point : Not available. Melting/freezing point : 851.01°C(1563.8°F)based on data for:Sodium carbonate.Weighted average:595.740C (1104.3°F) Specific gravity : Weighted average:2.08(Water=1) Vapor pressure : Not available. Vapor density : The highest known value is 0.8 to 1 (Air=1) (d-gluconic acid,monosodium salt). Odor threshold : Not available. Evaporation rate : Not available. lonicity(in water) : Not available. Dispersion properties : See solubility in water. Solubility : Soluble in cold water,hot water. Section 10. Stability and reactivity Incompatibility with various : Reactive with obdizing agents,organic materials,metals,acids. substances: \l Hazardous polymerization : Will not occur. Section 11. Toxicological information Toxicity data Ingredient name CAS number Test Result Route Species sodium carbonate 497-19-8 LD50 4090 mg/kg Oral Rat LD50 6600 mg/kg Oral Mouse LDLo 714 mg/kg Oral man sodium hydro)ade 1310-73-2 LDLo 500 mg/kg Oral Rabbit 2-(2-butoxyethoxy)ethanol 112-34-5 LD50 5660 mg/kg Oral Rat LD50 2200 mg/kg Oral Rabbit LD50 2400 mg/kg Oral Mouse LD50 2700 mg/kg Dermal Rabbit sodium sulfite 7757-83-7 LD50 3560 mg/kg Oral Rat LD50 820 mg/kg Oral Mouse LDLo 2825 mg/kg Oral Rabbit IDLH Not available. Chronic effects on humans CARCINOGENIC EFFECTS:Classified 3(Not classifiable for human.)by IARC[sodium sulfite(2:1)]. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.[sodium sulfite(2:1)]. Contains material which may cause damage to the following organs:blood,kidneys, lungs,liver,gastrointestinal tract,upper respiratory tract,skin,central nervous system (CNS),eye,lens or comea. Continued on next page Enthone is a subsidiary of ENPREP 576E Page:&7 Cookson Group PLC California prop.65 WARNING:This product contains chemical(s)known to the state of California to cause cancer,birth defects or other reproductive harm:propylene oxide;Ethylene oxide; 1,4-dioxane WARNING:This product contains chemical(s)known to the state of California to cause reproductive harm(female):Ethylene oxide California prop.65(no significant risk level):Ethylene oxide;1,4-dioxane California prop.65(acceptable daily intake level): Ethylene oxide WARNING:This product contains chemical(s)known to the state of California to cause cancer.:propylene oxide;Ethylene oxide; 1,4-dioxane Enthone has not conducted specific studies on the toxicity of this product. Section 12. Ecological information Ecotoxicity data Inaredient name Species Period Result sodium carbonate Lepomis macrochirus(LC50) 96 hour(s) 300 mg/I Lepomis macrochirus(LC50) 96 hour(s) 320 mgA Pimephales promelas(LC50) 96 hour(s) <850 mg/I l 2-(2-butoxyethoxy)ethanol Lepomis macrochirus(LC50) 96 hour(s) 1300 mg/I ? Enthone has not conducted specific studies on the ecotoxicity or enviromental fate of this product. [s-ection13. Disposal considerations Waste disposal Waste must be disposed of in accordance with federal,state and local environmental control regulations. Consult your local or regional authorities. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name information DOT Classification UN1823 SODIUM HYDROXIDE, 8 II Not available. SOLID,MIXTURE(Sodium E�RGro# ) Section 16. Regulatory information United States U.S.Federal regulations All ingredients comply with applicable rules or orders under United States TSCA and Canadian CEPA regulations. TSCA 12(b)annual export notification: No products were found. TSCA 12(b)one time export:No products were found. Clean air act(CAA)112 accidental release prevention:propylene oxide;Ethylene oxide Clean air act(CAA) 112 regulated flammable substances:No products were found. Clean air act(CAA)112 regulated toxic substances:propylene oxide;Ethylene oxide Continued on next page Enthone is a subsidiary of ENPREP 576E Page:7/7 Product name CAS number Concentration SARA 313 2-(2-butoxyethoxy)ethanol 112-34-5 5-10 State regulations WARNING:This product contains chemical(s)known to the state of California to cause cancer,birth defects or other reproductive harm:propylene oxide;Ethylene oxide; 1,4-dioxane WARNING:This product contains chemical(s)known to the state of California to cause reproductive harm(female):Ethylene oxide California prop.65(no significant risk level):Ethylene oxide;1,4-dioxane California prop.65(acceptable daily intake level):Ethylene oxide WARNING:This product contains chemical(s)known to the state of California to cause cancer.:propylene oxide;Ethylene oxide; 1,4-dioxane WHNS(Canada) Class D-2A:Material causing other toxic effects(VERY TOXIC). Class E:Corrosive solid. All ingredients in this product are found on the CEPA DSL. Section 16. Other information Definition of Terms ACGIH American Conference of Governmental Industrial Hygienists Ceiling Maximum exposure limit defined by OSHA CAS Chemical Abstract Service [ARC International Agency for Research on Cancer NIOSH National Institute for Occupational Safety and Health ` NTP National Toxicology Program OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit REL Recommended Exposure Limit RTK Right to Know SARA Superfund Amendments and Reauthorization Act STEL Short Term Exposure Limit TLV ACGIH Threshold Limit Value TLV C ACGIH Threshold Limit Value,Ceiling TRADE SECRET Claimed as allowed under 29CFR§1910.1200 TSCA Toxic Substances Control Act PPE Personal Protection Equipment CEPA Canadian Environmental Protection Act DSL Domestic Substance List NDSL Non-Domestic Substance List NSN New Substance Notification Rules Disclaimer This Material Safety Data Sheet may be used to comply with OSHA's Hazard Communication Standard, 29CFR§1910.1200. This Material Safety Data Sheet may also be used to comply with the requirements of Workplace Hazardous Materials Information System,of the Controlled Products Regulations,under the Hazardous Products Act. Enthone furnishes the data contained herein in good faith at customer's request without liability or legal responsibility for same whatsoever,and no warranty or guarantee,express or implied,is made with respect to such data;nor does Enthone grant permission,recommendation,or inducement to infringe any patent whether owned by Enthone or others.The data is offered solely for your information and consideration.Since conditions of use are beyond Enthone's control,user assumes all responsibility and risk. Cookson Electronics IcC REAGENT Material Safety Data Sheet C REAGENT CHEMICAL&RESEARCH, INC. —May be used to co SHA's Hazard Communication Standard -_ - 9 CFR 1910.1200.Standard must be CHEMICAL consulted for specific requirements. REVISED DATE: 1/1/2006 VALID UNTIL 1/1/2011 IDENTITY Note:Blank spaces are not permitted.Uany item is not appticabk,or no Hydrochloric Acid, 2 0" Baume informadon Is avellaW,the space must be marked to indicate that. Section I - Product Information Product Name CAS# Distributed by HUBBARD-HALL INC. Hydrochloric Acid ,7647-01-0 ..._....___.............. ___ ._ watmhuy,Cr O8705 20W5Q171 SynonYrrt _ --�Chern'ical Formula Innsn,SC 20349 0Bu4r,4031 Muriatic Acid HCl W.swkgrw .MA 01009 413r747.0706 -----.. . _ ............. . _ W"nglon,MA 01BU 9INS&0077 -..._.._.._.... .._ I . .. ._.. ...._.._. Cemical Nameh Chemical Fsn,ily Hydrochloric Acid Solution ;Inorganic Acid Section II - Manufacturers Information Manufacturers Name :Addrese Reagent Chemical & Research, Inc. 124 River Road Middlesex, NJ 08846 Emergency Contact Country ___-- Robert Dritschel United States E enc Tele hone . '- 1 —nurg Y P Emergency Telephone#2 1-409-962-5769 jCHEMTREC 1-800-424-9300 Section III - Ingredients/Regulatory Information Substance Description Percent CAS# ._...__....................................».........._......................................_.._._................_._...................._.......--•----..._................_....._.........................................._._............................. Hydrogen Chloride 31.45 33.30 7647-01-0 Water 66.70 - 68.55 7732-18-5 EaPOSURI's LIMITS/REGULATORY INFORMATION ubstance PEL TLP .,TEL '.:'WA CEILING ryd—r.o.gen Chloride C-7 mg/m3 C-5 npm 50 ppm N/D PPm Water N D N/D N/D N/D N/D N/D Not Determined C = Ceiling Level Section IV - Hazards Identification Appearance&Odor Statement o°Hazards Clear/Pale Yellow Liquid/Pungent Odor _ Severe and painful burns upon contact Primary Route of Exposure _ _... Skin, eye and inhalation contact are the pri-mary routes of exposure to this product Inhalation acute Exposure Effects Inhalation of excessive concentrations of Hydrogen Chloride vapors immediately produces severe irritation of the upper respiratory tract; resulting in coughing, burning of the throat, and a choking sensation. Reactions encountered in man have usually been limited to inflammation occasional ulceration of the nose, throat and larynx. If inhaled deeply, edema of the lungs may occur. Skin Contact Acute Exposure Effects -- _.._. Concentrated solutions are destructive to clothing and on contact with skin, causes severe burns unless promptly washed off. Repeated skin contact with dilute solutions may lead to the development of dermatitis. Exposure to the concentrated vapors of Hydrogen Chloride may also result in burns and dermatitis. . . o Page 1 of 7 -�� MEWED By - - — — DAT- Section IV - Hazards Identification (continued) Eye Contact Acute Exposure Effects mf the eyes with _.._ .. _. .... Hydrogen _..C-hior-ide, either as a vas or in solution, rape y causes severe irritation and painful burns of the eyes and eyelids. If the acid is not quickly removed by thorough irrigation with water, there may be prolonged or permanent visual impairment or total loss of sight. - Ingestion-Acute Exposure Effects - When concentrated Hydrochloric Acid is swallowed, it causes severe burns of the mucous membranes of the mouth, esophagus and stomach. The lips and mouth usually turn white, and later brown. There is pain in the throat and stomach, difficulty in swallowing, intense thirst, nausea and in severe cases, collapse and unconsciousness. Fire and Explosion Hazards Non-flammable, but Hydrochloric Acid reacts with all metals, except gold and platinum, with rapid evolution of Hydrogen which is flammable and explosive in air. Firefighters exposed to Hydrochloric Acid vapors should wear Scott Air-Pak, or equivalent. Hydrogen Chloride vapors are extremely irritating to the respiratory tract and may cause breathing difficulty. Carcinogenicity ---� IARC -No OSHA ...No ACGIH ._No Section V - First Aid Measures General If a known exposure occurs or is suspected, immediately initiate the recommended rocedures below. Simultaneously contact a physician, or the nearest Poison Control Center. Inform the person contacted of the type and extent of exposure, describe the victim's symptoms and follow the advice given. For additional information, call_ day or night, Reagent Chemical (405) 962-5769 or Chemtrec (800) 424-9300. I6hala8o6�� • • ..... . . -. . Remove from contaminated atmosphere. Tf breathing has ceased, clear the victim's airway and start mouth-to-mouth artificial respiration, which may be supplemented by the use of a bag-mask respirator, or a manually-triggered, oxygen supply capable of delivering 1 liter/second or more. If the victim is breathing, oxygen may be administered from a demand-type or continuous-flow inhalator, preferably with a physician's advice. Contact a physician immediately. Eye Contact - Immediately flush the eyes with large quantities of running water for 15 minutes. Hold the eyelids apart during the- flushing o ensure -inning of the entire surface of the eyes and lids with water. DO NOT attempt to :.eut.ralize with chemical agents. Obtain medical attention as soon as possible. Oi_'_s o- ointments should not be used. Continue the flushing for an additional 15 minutes if the physician is not available. l -lar 2 of 7 Section V - First Aid Measures (continued) m Contact �mme lately remove contaminated clothing under a safety shower. Flush all affected areas with large amounts of water for 15 minutes. DO NOT attempt to neutralize with chemical agents. Obtain medical advice. Ingestion DO NOT induce vomiting. Immediately give large quantities of water or milk, if available. If vomiting does occur, give fluids again. Never give anything by mouth to an unconscious person. Call a physician of the nearest Poison Control Center. Medical Conditions Generally Aggravated by Exposure - Hydrogen Chloride will aggravate breathing disorders Note to Physician- Attending Physician should treat exposed patients symptomatically Section Vl - Fire Fighting Measures Flash Point Flash Method N.A. 'N.A. Extinguishing Method _. .. �_.._._.. -- _ • _ __---_-- ... .. .. Not Applicable — ----_...._. - -...... - _._......__.. _. .._... . Unusual Fre and Eicplosion Hazards Non-flammable, but Hydrochloric Acid reacts with metals. Special Fv t'ghting Procedures�- Non-flammable, but Hydrochloric Acid reacts with all metals, except gold and platinum, with rapid evolution of Hydrogen which is flammable and explosive in air. Firefighters exposed to Hydrochloric Acid vapors should wear Scott Air-Pak, or quivalent. Hydrogen Chloride vapors are extremely irritating to the respiratory -tract and may cause breathing difficulty. Section VII - Accidental Release Measures Steps to be Taken in Case Material is Released or Spilled — Spills or discharges into the environment involving large quantities of Hydrochloric Acid should be controlled and cleaned-up according to a pre-determined, affirmative written Spill Prevention and Control Program. For assistance in developing a SPCP contact your nearest Reagent Saes Office. Spills should be handled immediately by neu=ralization and dilution of the spilled product by the use of Soda Ash (Sodium Carbonate), Lime (Calcium Hydroxide) , or Limestone (Calcium Carbonataj with large amounts of water. For an interior (inside a closed space) spill be aware that the use of Soda Ash, Lime and Limestone will evolve heat and carbon dioxide and that ample ventilation must be provided. Waite Disposal Under Federal RCRA, it is the responsibility of the user of products to determine, at the time of disposal, w:.ether the product falls under RCRA as a hazardous waste. This is because product uses, trans fornaticns, mixtures, etc. may render the resulting end-product hazardous. �oniainet i5iiposal • '• """ Containers should be cleaned of residual p::od-.;c:. before disposal. Empty containers �hould be disposed of is ac.;ordance with all applicable laws and regulations. Page 3rf7 Section VII - Accidental Release Measures (continued) recautions to be Taken in Handling a, ,torage Yam— personnel inV01ved in-housekeeping and spill c can-up follow goo Industrial Hygiene practices and wear proper protective equipment. Section Vill - Handling/Storage/Transportation Handing Chemical goggles and full face shield must be worn at all times by personnel exposed to or handling Hydrochloric Acid. The use of a NIOSH -approved cartridge respirator or a Scott Air-Pak should be used by all personnel exposed. toiage " ' Store containers in a cool, dxy iocation awayy from direct sunlight, sources of intense heat, or where freez_ng may occur. 3tcre material in acid-proof container. Keep contair_er tigh•=1y clos.-:d when nct in '-se. Keep container away from incompatible materials. All leading, unloading, and storage equipment must be inspected prior to any transfer operations are initiated. eneral Comments Impervious clothing, gloves, footwear and head gear must be worn at all times by personnel exposed to or handling Hydrochloric Acid. Section IX - Exposure Controls/P-irsonal Protection Respiratory Protection(Specify.y`e Maintain airborne contatn_na:e levels below 1 s-:e �widelines. Use with adequate ventilation. Use a raecaani•_al fa__ o: vent araa *.:a acrubber. Ventilation 'Local Exhaust Special -- If PEL exceeded Vert fume: to appropriate scrubber Jl _.. _ Mecfianical(General) 'Other If PEL exceeded Not Applicable Skirt Fiblection - - Wear neoprene rubber glove:; to minimize skin con:=__ct. Eye Protection Splash goggles or safety gasses. Face shields are recommended. Othei Pi6iiction __ ._. ... ........ Use body protection appropriate ror task. :•.n apron or other impermeable body protection is s::ggezzed. ` ll b,,s-y chemica:. pzo�:ac.t_;,n is recommended for emergency respo::se procedur,.�:. Applicable Exposure Limits Other than any exposure limits which may be displayed in Section 3, there are no other known exposure limits applicable to this product cr its components. Section X - Physical and Chemical Properties Baling Point Specific 3ravity(1120=1) 230 F _ '1.160 - 1.1693 Vapor Pressure(mm Hg) Freezing Point SO - 60 mm -12 F to -63 F Vapor Density(AIR _ N.A. 9.671 - 9.748 Solubility in W ater miscible Appearance and Oeor Clear/Slightly yellow with a sharp pungent odor Page 4 of 7 Section XI - Stability and Reactivity Stability Unstable Conditions to Avoid Hydrochloric Acid is extremely reactive. Avoid contact with (Stable X metal surfaces and oxidizing agents. . _ ... - _ Incompatibility(Materials 10 Avoid) Hydrochloric Acid is chemically stable when properly contained and handled. It is a strong mineral acid and reacts with many me::als and metal oxides and hydroxides to form the equivalent metal chloride. It reacts with zeolites and other silicious compounds to form Hydrosilicic Acid; it reaccs wick carbonates to form Carbon Dioxide and Water. It is oxidized by Oxygen or electrolysis to form Chlorine, a lethal, poisonous gas. It reacts with alkaline compounds to form a neutral salt. It is a hydrolyzing agent for carbohyd-:tes, esters and other compounds. Its reaction with most metals will produce Hydrogen, an explosive gas. Violent reactions will result when Hydrochloric Acid Reacts with acetic anhydride, 2-aminoethanol, ammonium hydroxide, calcium phcsphide, chlorosulfonic acid, ethylene diam_ne, echylene :mine, oleum (f-aming sulfuric acid), perchloric acid, beta propiolactone, propylene oxide, sodium hydroxide, sulfuric acid, uranium phosphide and vinyl acetate. This listing is not all-inclusive. Hazardous Decomposition or By-products - Extreme heat may cause the product to decompose, producing toxic fumes which may Anclude chlorine compounds. Hazardous ;May Occur Conddi.;ns to A;v.d Polymerization Extryme heat and contact with incompatible materials .Will Net Occur _ — X Section XII - Toxicological information ~� Route(s) Entry. Skin? ngestion. fes Yes Yes Health Hazards(Acute and Chronic) Hydrogen Chloride, both as a gas and in a solution as Hydrochloric Acid, is a corrosive substance and can cause severe and painful burns on contact with any part of the body or if taken internally. The mucous membranes of the eyes and the upper respiratory tract are especially suscet;c_o::e to the irritating effects of high atmospheric concentrations of Hydrogen Chloride. The gas or vapor is so penetrating and pungent chat: when hiqh concentrations do occur, those exposed should immediately leave the contaminated area. "'Carcinogenicity. NTP? IARC Monographs? OSHA Regulated! No A'C NO Signs and Symptoms of Exposure _ Exposure to Hydrochloric acid may cause severz burns at the contact points Medical Conditions Generally Aggravated by Exposure -'- Exposure to fumes may aggravate der-matins and breathing disorders. I - Page 5 of 7 Section XII - Toxicological Information (cont.) oxico y Inhalation Date y rogen Chloride Human LCLo - 1300 ppm 30 min Rat LC.,„ - 4701 ppm/30 min Oral (rabbit? - LD.,,, - 900 mg/kg FAutagenic Effects Inhalation: 100 ppm/24 hrs (Chromosome damage) Oral: : 100 ppm (Chromosome damage) Parental: 20 mg (Cytogenic effects) Section XIII-Ecologica!Informat;31 Ecological Toxicity— Animals exposed to hydrochloric acid solution will experience tissue damage, burns and may be killed. Plants contaminated with h •dr-):•rioric acid solutions of low pH may be adversely effected or destroyed. High con-:entrations have been shown to be detrimental to aquatic life. A release into a body of water will kill fish and other aquatic life. Ot er l=cological Information - Hydrochloric acid is stable and found naturally in the environment. All work practices..- .should should be aimed at eliminating environmental cont a.-Anation. Chemical Fate Information — Hydrochloric acid is naturally occurring in the environment. Other Regulatory Information --No other regulatory -information is available; on ::his product. Section XIV - Transportation Info-rmation Regulated ateria Hydrochloric Acid is de`_.ned as haza:-ous b;- she US Do-z and Transport Canada DOMEESTIC SHIPPING. INFORMATION '"Proper Shipping Name Hazard Classification ;Hydrochloric Acid Corrosive - - UN/NA Identification Hazard Class UINT 1739 Class 8 DOT Labels Required ,Packaging Croup ; Corrosive .II rN'ERVIATIONAL SHIPPING INFORMATION -Pro Shi n' Name _.. Per PPi 9 •Hazard Classification .Hvdr.-)ch'loric Acid Corrosive UN/NA Identification Haard Class - JN 1789 Class 8 Labels Required F a,;R in u ag 9.;.a p Corrosive ;II Section XV - Other Information Created y e&-ion Number Product Safety - 4/20/99 Revisicn # 005 Toxic Substances Control Act Superfund Amendment&Re6uUi6fliation Act,Title Ill "' Acute & ' TSCA listed 7647-01-0 Hazard Categories HEALTH: Chronic Emergency Planning&Community Right to Know -- EHS - Threshold Quantity: None 3HYSICAL: None is product Regulated Under 1990 Clean Ai:Ae.-V Coac Procuct Contain,or is Manufactured with,CFCs? "No No Riportable Quantity:•• NS-L'at:r.g RQ - 5000 lbs SCa.le & Corrosion control at maximum 40 mg/l NFPA ;r:! 3 - 0 - 0 - Acid 3 - 0 - 0 - X Ts This Product Regulated Under the EPA's Risk Management Piana"No, Hydrochloric Acid Solution under 3. o is not regulated. .Worth American Emergency Response Guide Boon " D # 1789 Guide #157 1996 Revision Page 6 of 7 Disclaimer of Liability ne data contained erein is furnished gratuitously and independent of any sale _ �of any product. It is supplied only for your investigation and possible independent verification. While the data is believed to be correct, Reagent Chemical and Research Inc. makes no representation a3 to the accuracy of any data contained herein. In no event shall Reagent: "hem--cal and Research, Inc. be responsible for any damages of any nature whatsoever directly or indirectly resulting from the publication, use or relianr_e itr%nn any data contained herein. Data Sheets are available f3r other reagent C;em_'cal and Research, Inc. products. You are urged to obtain data sheazs for all products you buy, process, use or distribute and you c.re encouraged to ad-visa anyone working with or exposed to such products of zhe informatim- contained in the applicable data sheets. The data in this document is prow de,: w_*'thout any representation or warranty, express or itrfilied, reg;:rd:.na its -ccL at:y or correctness. No warranty either expressed or implied of merchant ability o.: fitness or of any nature is made with respect to any product referred to here_n. ncagent Chemical and Research Inc. does not assume respoasibiliry and expressly disclaims liability for loss, \damage or expense arising out of or in any way connected with the handling, )storage, use or disposal of the products rcrCrred herein. I Page 7 of 7 SaSOL 14��10Q1 Acetone Material Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION- Trade name Acetone Synonyms 2-propanone,Dimethyl ketone,Ketone propane,beta-Ketopropane. Manufacturer/Supplier SASOL CHEMICALS NORTH AMERICA LLC (An affiliate of Sasol North America Inc.) Address 900 Threadneedle,Houston,TX 77079 Telephone CHEMTREC North America Transportation Emergency(24-hr) (800)424-9300 CHEMTREC Work!Wide (703)527-3887 Other Emergencies(24-hr) (337)494-5142 MSDS and Product Information(8:00am-4:30pm CST) (281)588-3491 Health and Safety Information(8:00am-4.00pm CST) (281)588-3492 SECTION 2 COMPOSITION AND INFORMATION ON INGREDIENTS Conlaonents CAS-No- Weight% 1 Acetone 67-64-1 99.9 J See Section 8 for Exposure Guidelines and Section 15 for Regulatory Classifications. SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Appearance Clear,colorless Liquid Odor Pungent Precautions DANGERI EXTREMELY FLAMMABLE LIQUID AND VAPOR MAY CAUSE EYE,SKIN AND RESPIRATORY IRRITATION. Keep away from heat and flame. Do not get in eyes,on skin,or on clothing. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Environmental Do not flush into surface water or sanitary sewer system. Non-toxic to aquatic life. precautions Readily biodegradable. POTENTIAL HEALTH EFFECTS Distributed by HUBBARD-HALL INC. Eyes Initalign t0 eyes. 171 iw�se oioee s -Z-0ml �lETA4,.kS TESTING MAP , ,MA01867 n l Version date:01/18MM Version 1.2 Print date: 01/12/2M Page 1 of 7 SaSOL -` ac,ag orwrmnuvry / Acetone Skin Repeated or prolonged contact can cause redness,irritation and scaling of the skin (dermatitis). Normal care and personal hygiene should prevent skin effects. The product may be absorbed through the skin. Inhalation Irritation of the nose and throat,dizziness,and headache. Ingestion Aspiration(breathing)into lungs,caused while vomiting,may result in severe pulmonary injury. Depression of central nervous system can occur. Ingestion may cause gastrointestinal irritation,nausea,vomiting and diarrhea. (See Section 11 for Toxicological Information) SECTION 4 FIRST AID MEASURES Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. When symptoms persist or in all cases of doubt seek medical advice. Wash contaminated clothing before re-use. Inhalation Remove to fresh air. If breathing is irregular or stopped,administer artificial respiration. If breathing is difficult,give oxygen. Call a physician immediately. Ingestion If swallowed,call a physician or poison control center immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. SECTION 5 FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash point -20°C closed cup -4 OF Autoignition 465'C 869 OF temperature Flammable limits in Lower explosion limit: 2.6%(V) air%by volume Upper explosion limit: 12.8%M Fire and explosion Vapours may form explosive mixture with air. Flash back possible over considerable distance. Use water spray to disperse the vapors. NFPA Class IB flammable liquid. Extinguishing media Use water spray,alcohol-resistant foam,dry chemical or carbon dioxide. Fire fighting Self-contained breathing apparatus(SCBA)and structural firefighter's protective clothing instructions will provide limited protection. Version date:01/18/2005 Version 1.2 Prfnt date: 01/12/2006 Page 2 of 7 sasOL If -� readft eew frwuiels wqr Acetone Further Information Keep containers and surroundings cool with water spray. Beware of vapours accumulating to form explosive concentrations.Vapours can accumulate in low areas. SECTION 6 ACCIDENTAL RELEASE MEASURES Steps to be taken in Evacuate personnel to safe areas. Remove all sources of ignition. Contain and collect case of spill or leak spillage with non-combustible absorbent material,(e.g.sand,earth,diatomaceous earth, vermiculite)and place in container for disposal according to local/national regulations (see Section 13). Do not flush into surface water or sanitary sewer system. SECTION 7 HANDLING AND STORAGE Safe handling advice Ensure all equipment is electrically grounded before beginning transfer operations. StoragelTransport Ambient. pressure Further information Keep away from heat and sources of ignition. l on storage conditions J SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING MEASURES Air contaminant levels should be controlled below the PEL or TLV for this product(see Exposure Guidelines). Mechanical ventilation may be necessary if working with this product in enclosed areas and/or at elevated temperatures. Use explosion-proof equipment. PERSONAL PROTECTIVE EQUIPMENT Eyes When contact with liquid is possible,use a face shield and/or chemical splash goggles. Otherwise use safety glasses with side shields or goggles. Skin Wear suitable protective clothing,gloves and eye/face protection. Inhalation Respiratory protection is normally not required except in emergencies or when conditions cause excessive airborne levels of mists or vapors. NIOSH-approved organic vapor air- purifying respirator,self-contained breathing apparatus,or air-supplied respirators where there may be potential for overexposure. Version date.01/18/2005 Version 1.2 Print date: 01/1212M Page 3 of 7 saSOL Acetone EXPOSURE GUIDELINES Components Exposure limit(s) Acetone OSHA PEL 1,000 ppm ACGIH TLV(8-hour)500 ppm ACGIH STEL 750 ppm PEL= Permissible Exposure Limits TWA-- Time Weighted Average(8 hr.) TLV= Threshold Limit Value STEL-- Short Tenn Exposure Limit(15 min.) EL-- Excursion Limit WEEL= Workplace Environmental Exposure Level SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Colour Clear,colorless Odour Pungent Form Liquid Boiling poinVmnge 56.2°C 132.2 OF l Vapour pressure 186.2 mm Hg @ 20°C J Vapor density 2 Solubility(water) Easily soluble. Viscosity 0.4 cSt 0 20°C Melting pointfrange -95.35'C -139.6 OF Density 0.79 g/cm3 SECTION 10 STABILITY AND REACTIVITY Conditions to avoid Keep away from heat and sources of ignition. Hazardous Combustion products include carbon dioxide,carbon monoxide and possibly other decomposition unidentified organic compounds. products Incompatability with Can react with strong oxidizers,inorganic acids,and halogens. other materials Hazardous None. polymerization Version date:01/18/20% Version 1.2 Print date: 01/12/2006 Page 4 of 7 aSOL r nq new rpxuers Acetone SECTION 11 TOXICOLOGICAL INFORMATION Eyes Severe irritant bases on standard Draize tests Skin . Acute dermal LD50 (rabbit): 20,000 mg/kg Inhalation Acute 6 hours LC50(rat): 50,100 mg/m3 Ingestion Acute oral LD50(rat): 5,800 mg/kg CARCINOGENICITY This product contains no carcinogenic substances. SECTION 12 ECOLOGICAL INFORMATION Aquatic toxicity Non-toxic to aquatic life. (Trout)96 hours 5,540 mg/I (Goldrush)24 hours 5,000 mg/I (Bluegitl sunfish)96 hours 8,300 mg/I (Shrimp)24 hours 2,100 mg/l (Daphnia)48 hours 10 mg/I Biodegradation Readily biodegradable. SECTION 13 DISPOSAL CONSIDERATIONS Waste code F003(RQ 5,000 Lbs) Disposal methods Dispose of only in accordance with local,state,and federal regulations. Do not contaminate any lakes,streams,ponds,groundwater or soil. Empty containers Empty containers retain product residue(liquid and/or vapor)and can be dangerous.DO NOT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND,OR EXPOSE SUCH CONTAINERS TO HEAT,FLAME,SPARKS,STATIC ELECTRICITY,OR OTHER SOURCES OF IGNITION;THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.Empty drums should be completely drained,triple-rinsed,properly bunged and promptly returned to a drum reconditioner,or properly disposed. SECTION 14 TRANSPORT INFORMATION DOT description Acetone,3,UN 1090,11 Version date:01116/2M Version 1.2 Print date: 01/12/2006 Page 6 of 7 SaSOL feacffbv now pandels Acetone IATA description Acetone,3,UN 1090,II IMDG description Acetone,3,UN 1090,11 SECTION 15 REGULATORY INFORMATION U.S. FEDERAL-REGULATIONS OSHA classification Flammable liquid,Eye irritant TSCA Inventory Listing Components CAS-No. Acetone 67-64-1 SARA 302 Status Components CAS-No. Weight% Contains no chemicals subject to SARA 302 reporting. SARA 311/312 Classification "Fire hazard `Immediate(acute)health hazard" SARA 313 Chemical Components CAS-No. Welaht Contains no chemicals subject to SARA 313 reporting. CERCLA Hazardous Substance Components CERCLA RO Weight% Acetone 5,000 LB 99.9 INTERNATIONAL REGULATIONS Workplace Hazardous Materials Information System(WHMIS)Classification Class B, Division 2:Flammable liquid. Class D,Division 2,Subdivision B:Toxic material. Australian Inventory of Chemical Substances(AICS)Usting Listed on the AICS. Japanese Minister of international Trade and Industry(MITI)Inventory Listing Listed on MITI. J Version date:01/1=DD5 Version 1.2 Print date: 01/12/2(x)6 Page 6 of 7 sasOL Acetone Canadian Domestic Substance List(DSL)Inventory Listing Listed on the DSL European Inventory of Existing Commercial Chemical Substances(EINECS)Listing Listed on EINECS. Phillipines inventory List(PICCS) Listed on PICCS. Korean Inventory List Listed on the ECL China Inventory List Listed on the China inventory. STATE REGULATIONS California Safe Drinking Water Act(Prop 65)Listing Components CA&No. Contains no chemical subject to California Prop 65. SECTION 16 OTHER INFORMATION HAZARD RATINGS Health Flammability Reacti HAMS 1 3 0 NFPA 1 3 0 THE DATA AND INFORMATION CONTAINED HEREIN ARE BEING FURNISHED FOR INFORMATIONAL PURPOSES ONLY,UPON THE EXPRESS CONDITION THAT EACH CUSTOMER SHALL MAKE ITS OWN, ASSESSMENT OF APPROPRIATE USE AND APPROPRIATE SHIPPING,TRANSFER AND STORAGE MATERIALS AND PROCEDURES FOR SASOL NORTH AMERICA'S PRODUCTS. ALTHOUGH BASED ON INFORMATION SOURCES WHICH SASOL NORTH AMERICA CONSIDERS ACCURATE AND RELIABLE,SASOL NORTH AMERICA MAKES NO WARRANTY,EITHER EXPRESS OR IMPLIED,INCLUDING ANY WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,REGARDING THE VALIDITY OF THIS INFORMATION,THE INFORMATION SOURCES UPON WHICH THE SAME ARE BASED,OR THE RESULTS TO BE OBTAINED,AND EXPRESSLY DISCLAIMS LIABILITIES FOR DAMAGES OR INJURIES RESULTING FROM THE USE THEREOF. _J Version date:01A8/2005 Version 1.2 Print date: 01/12/2006 Page 7 of 7 ACERC ACID GLACIAL htq)Vhvww.jd)aker.com/msds/AO326.htn �#.tom��Tst�ptr:#dt4�d MISDS material sawbate shew 7 Nfdf6oitaf tRaipa�ut In Caefrd 0 W&And ftmew From 141agimkroa.Baker,Inc 1lriallb'Eckrodt i t.an� aT.BAI N_Wi- > ,�air€C e- i___ iktii4i st NJ 0@85 k,j CNIM � eareas ► �a �- t lX rf. o + p#t rlrca eE tnrxa r t s ia+vat mkt� cer rid+na Al scan¢�iat y'. tishould ba diroded to tCwtome Swviw(t FSU- ' iw assimame. ACETIC ACID GLACIAL MSDS Number:A0326—Effective Date: 05117/01 1. Product Identification Synonyms:Acetic acid,methane carboxylic acid, edmoic acid CAS No.: 64-19-7 Molecular Weight: 60.05 Chemical Formula:CH3COOH Product Codes:J.T.Baker: 5355, 5579, 5844, 6903,9500,9501, 9503, 9505, 9507,9508, 9511, 9513, 9515, 9522,9524,9526 Mallinckrodt: 2501,2504,3121,7711, 8817,H979,H983,V155,V193,V194 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------------ --------- Acetic Acid 64-19-7 99.5 — 100% Yes 3. Hazards Identification Emergency Overview -------------------------- POISON! DANGER! CORROSIVE.LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE.MAY BE FATAL IF SWALLOWED.HARMFUL IF INHALED. 10179 3119/200212:52 PM ACEIIC ACID GLACIAL hupJ/www jtbaketcom/msds/A0326.him INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE.FLAMMABLE LIQUID AND VAPOR J.T.Baker SAF-T-DATAft )Ratings(Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating: 2-Moderate Flammability Rating:2-Moderate Reactivity Rating:2-Moderate Contact Rating: 3 -Severe(Corrosive) Lab Protective Equip:GOGGLES&SHIELD;LAB COAT&APRON;VENT HOOD; PROPER GLOVES;CLASS B EXTINGUISHER Storage Color Code: White Stripe(Store Separately) ----------------------------------------------------------------------------------------------------------- Potential Health Effects ---------------------------------- Inhalation: Inhalation of concentrated vapors may cause serious damage to the lining of the nose,throat,and lungs.Breathing difficulties may occur.Neither odor nor degree of irritation are adequate to indicate vapor concentration. Ingestion: Swallowing can cause severe injury leading to death. Symptoms include sore throat,vomiting,and diarrhea.Ingestion of as little as 1.0 ml has resulted in perforation of the esophagus. Skin Contact: Contact with concentrated solution may cause serious damage to the skin.Effects may include redness,pain,skin burns.High vapor concentrations may cause skin sensitization. Eye Contact: Eye contact with concentrated solutions may cause severe eye damage followed by loss of sight. Exposure to vapor may cause intense watering and irritation to eyes. Chronic Exposure: Repeated or prolonged exposures may cause darkening of the skin,erosion of exposed front teeth, and chronic inflammation of the nose,throat,and bronchial tubes. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems,or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air.If not breathing,give artificial respiration.If breathing is difficult,give oxygen. Call a physician. Ingestion: DO NOT INDUCE VOMITING! Give large quantities of water or milk if available.Never give 2 of 9 3/19/2002 12:52 PM ACERC ACID GLACIAL htq)J/www.jibaker.comlmsds/AO326.htm anything by mouth to an unconscious person.Get medical attention immediately. Sldn Contact: In case of contact,immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.Wash clothing before reuse.Call a physician. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes,lifting lower and upper eyelids occasionally.Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 40C(104F)CC Autoignition temperature:427C(801F) Flammable limits in air%by volume: lel:4.0;uel: 16.0 Flammable Liquid and Vapor! Explosion: Above flash point,vapor-air mixtures are explosive within flammable limits noted above.Vapors can flow along surfaces to distant ignition source and flash back.Contact with strong oxidizers may cause fire.Reacts with most metals to produce hydrogen gas,which can form an explosive mixture with air. Fire Extinguishing Media: Water,dry chemical,foam or carbon dioxide.Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire,wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Water may be used to flush spills away from exposures and to dilute spills to non-flammable mixtures.Water diluted acid can react with metals to form hydrogen gas. 6. Accidental Release Measures Ventilate area of leak or spill.Remove all sources of ignition.Wear appropriate personal protective equipment as specified in Section 8.Isolate hazard area.Keep unnecessary and unprotected personnel from entering.Use water spray to dilute spill to a nonflammable mixture.Contain and recover liquid when possible.Collect liquid in an appropriate container or absorb with an inert material(e.g.,vermiculite,dry sand,earth),and place in a chemical waste container.Use non-sparking tools and equipment Do not use combustible materials,such as saw dust.Do not Rush to sewer! US Regulations(CERCLA)require reporting spills and releases to soil,water and air in excess of reportable quantities.The toll free number for the US Coast Guard National Response Center is(800)424-8802. J.T.Baker NEUTRASORBO or TEAM®'Low Na+'acid neutralizers are recommended for 3 of 9 3/19/200212:52 PM ACETIC ACID GIACIAL htlpJ/www;jibakercomhnsds/A0326.htrn spills of this product. 7. Handling and Storage Protect against physical damage. Store in a cool,dry well-ventilated location,away from any area where the fire hazard may be acute.Outside or detached storage is preferred. Separate from incompatibles.Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas.Use non-sparking type tools and equipment, including explosion proof ventilation.Protect from freezing. Store above 17C(63F).Containers of this material may be hazardous when empty since they retain product residues(vapors,liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit(PEL): 10 ppm(TWA). -ACGIH Threshold Limit Value(TLV): 10 ppm(TWA); 15 ppm(STEL). Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits.Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,preventing dispersion of it into the general work area. Please refer to the ACGIH document,Industrial Ventilation,A Manual of Recommended Practices,most recent edition,for details. Personal Respirators(NIOSH Approved): If the exposure limit is exceeded,a full facepiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,whichever is lowest.For emergencies or instances where the exposure levels are not known,use a full-facepiece positive pressure, air-supplied respirator.WARNING:Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Sldn Protection: Wear impervious protective clothing,including boots,gloves,lab coat,apron or coveralls,as appropriate,to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible.Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties 4 of 9 3/19/M 12:52 PM ACETIC ACID GLACIAL hupY/www jdmker comhnsds/A0326.htm Appearance: Clear,colorless liquid. Odor: Strong,vinegar-like. Solubility: Infinitely soluble. Density: 1.05 pH: 2.4(1.OM solution) %Volatiles by volume @ 21C(70F): 100 Boiling Point: 118C(244F) Melting Point: 16.6C(63F) Vapor Density(Air--1): 2.1 Vapor Pressure(mm Hg): 11 @ 20C(68F) Evaporation Rate(BuAc=1): 0.97 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage.Heat and sunlight can contribute to instability. Releases heat and toxic,irritating vapors when mixed with water.Acetic acid contracts slightly upon freezing which may cause the container to burst. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.May also release toxic and irritating vapors. Hazardous Polymerization: Will not occur. Incompatibilities: Acetic Acid is incompatible with chromic acid,nitric acid,ethylene glycol,perchloric acid, phosphorous trichloride,oxidizers,sodium peroxide,strong caustics,most metals(except aluminum),carbonates,hydroxides,oxides,and phosphates. Conditions to Avoid: Heat,flame,ignition sources,freezing,incompatibles 11. Toxicological Information 5 of 9 3/19/200212:52 PM ACETIC ACID GLACIAL htq)YAvww.jibakff.com/msds(AO326IYm Oral rat LD50:3310 mg/kg; skin rabbit LD50: 1.06 •inhalation mouse LC50: 562 m/1-hr investigated as a mutagen,reproductive effector. --------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen--- Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- ------------- Acetic Acid (64-19-7) No No None 12. Ecological Information Environmental Fate: When released into the air,this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals.When released into air,this material is expected to have a half-life between 10 and 30 days.When released into water,this material is expected to readily biodegrade.When released into the water,this material is expected to have a half-life between 1 and 10 days. Standard dilution BOD5/TOD=58%When released into the soil,this material is expected to readily biodegrade.This material is not expected to significantly bioaccumulate.This material has an estimated bioconcentration factor(BCF)of less than 100. Environmental Toxicity: This material is expected to be slightly toxic to aquatic life.The LC50/96-hour values for fish are between 10 and 100 mg/l. For glacial acetic acid: EC50(wheat firs igation)=23.3 mg/m3/2-hr,effect:leaf injury LC50(shrimp)= 100-300 mg/l/48-hr LC50(fathead minnow)=88 mg/V96-hr This material may be toxic to aquatic life. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility.Processing,use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.Dispose of container and unused contents in accordance with federal,state and local requirements. 14. Transport Information Domestic(Land,D.O.T.) ----------------------- 6 of 9 3/19/200212:52 PM ACEW ACID GLACIAL htq)JAvww jtbaker com/msds/A0326.htm Proper Shipping Name:ACETIC ACID,GLACIAL(WITH MORE THAN 80%ACID,BY MASS Hazard Class:8,3 UN/NA: UN2789 Packing Group:II Information reported for producttsize:450LB International(Water,I.M.O.) ----------------------------- Proper Shipping Name:ACETIC ACID,GLACIAL(WITH MORE THAN 80%ACID,BY MASS) Hazard Class:8, 3 UN/NA:UN2789 Packing Group: II Information reported for product/size:450LB 15. Regulatory Information --------\Chemical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia ----------------------------------------------- ---- --- ----- --------- Acetic Acid (64-19-7) Yes Yes Yes Yes --------\Chemical Inventory Status - Part 2\--------------------------------- --Canada-- Ingredient Korea DSL NDSL Phil. ----------------------------------------------- ----- --- ---- ----- Acetic Acid (64-19-7) Yes Yes No Yes --------\Federal, State & International Regulations - Part 1\---------------- -SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. ----------------------------------------- --- ----- ---- -------------- Acetic Acid (64-19-7) No No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA- -TSCA- Ingredient CERCLA 261.33 8 (d) ----------------------------------------- ------ ------ ------ Acetic Acid (64-19-7) 5000 No No Chemical Weapons Convention: No TSCA 12 (b) : No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: Yes (Pure / Liquid) Australian Hazchem Code:2P Poison Schedule: S6 7 of9 3/19/200212:52 PM ACEIIC ACID GLACIAL http://vvwwjtbakercom/msds/AO326.htm WHnIIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by the CPR 16. Other Information NFPA Ratings:Health:3 Flammability: 2 Reactivity. 0 Label Hazard Warning: POISON! DANGER! CORROSIVE.LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE.MAY BE FATAL IF SWALLOWED.HARMFUL IF INHALED. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE.FLAMMABLE LIQUID AND VAPOR. Label Precautions: Do not get in eyes,on skin,or on clothing. Do not breathe vapor or mist Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat,sparks and flame. Label First Aid: In case of contact,immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.Wash clothing before reuse.If swallowed,DO NOT INDUCE VOMITING.Give large quantities of water.Never give anything by mouth to an unconscious person.If inhaled,remove to fresh air.If not breathing,give artificial respiration.If breathing is difficult,give oxygen.In all cases get medical attention immediately. Product Use: Laboratory Reagent. Revision Information: No changes. Disclaimer: Mallinckrodt Baker,Inc.provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy.This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product.Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.MALLINCKRODT BAKER,INC.MAKES NO REPRESENTATIONS OR WARRANTIES,EITHER EXPRESS OR IMPLIED,INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY,FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY,MALLINCKRODT BAKER,INC.WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. 8 of9 3/19/2002 12:52 PM ACETIC ACID GLACIAL ht4)J/www.jftker.cotWmsds/AO3261itm Prepared by:Environmental Health&Safety Phone Number: (314)654-1600(U.S.A.) 9 Of 3/19/2002 12:52 PM 06/01/2002 23:38 7591942 HUBBARD HALL INC HAUL b1 ' o=f/0/2009 11:01 FAX WESO MINERAL fi0oo3/007 Oq Material Safety Data Sheet l t 7 'WEGO CHEMirCAL&NMRAX,CORP 239 dreat Neck Road Glreat Neely,NY 11021 Phonies(516)487 3510;email:*Wu@wegoehem.com Date of preo!Mg gn:7/2905 , _ Ammonium Bi ueride Section 1 -Chemical Product and Compan Iy dentiifica* m roduct/Chamical Name:Ammoniwtt Rifluoride hemlcal FOrmCia:NH„HFa AS Number.1341-49-7 ther Aasiguatione:acid aminoniurn fluoride,ammonium acid fluoride,ammonium hydrogen bifluorkle, mmonium hydrogen fluoride,ammonium hydrogen fluorlde Derivation:Produced byreaction of ammonittm hydroxide with i ydrofluoric acid and subaegaem orysudli scion. General Use:Asa chemical reagent,aterflisor for brewery,dairy,and other equipment,"sont"in hRmAcrh ,cloth.mordant for aluminum;in manuilmre ofmagnesitrm and mopuium alleys,lab production of hydrogen fluoride,elan opbtirug,processing beryllium,etching Stags,and to aeidif)'wells. Emergency Terepbotar;1-800424-9.1*0(CAamtree) Section 2. Composition/Information on b gredifthL lngWdient Name CAS Number I EINMIELiNCS � %we or od vol Ammonium B ifluorldle 134149.7 21 5.676.4 100 OSHA PEt.' ACGIH T16v- 141105B RELY 8-hrTWA-2.5 mglm' TWA:2.5 mg/m' 10-hrTWA:2.5 mg/mr DFG(Germany MAN* IDI.H Level' Peak Exposure L alt: TWA:2.S mp/at,,total dust Soo mg/mr I2.5 mg/0,30 min averag value,2/shif t Category a:Subspaces with systemic eff u Rrstribulee b} HUBBARD-HAIL INC. Half-life;2 b to shift length e�rrrR „A,,.,a.,,croer®o WWB&2171 "Fluorides,as F- 1 ..eoawK 61M A WA �l 47R ' WW"T,W C'Of7 07NMmo77 Section 3-Haurds Mentificstlion th1a l�i!r Emelrgmq Overview H 3 Ammonium binnaride exists as mite,odorless crystals.It is highly toxic,locally became of it 0 corrosive action and systemicidly because of In emsversion to hydrogen fluoride and fluoridn k t F absorption.Fluoride Ion is a direct cellular poison which interferes with calcium and laagnenla i R 0 Et balances.Chronic exposure cgilt result in Qaorosb(see below).It fs noncombustible-Txp as are t 1g,o_s moisture forms hydrofluoric acid which is capable of etching glass,cement,and malty metals. Potential Health Effects Primary L"ntry Routes:inhalation,skim and eye contact,ingestion_ Target OrEata:Eye,side,teeth and bones,kidneys,central nervous system(CHS), cafe Effects Inhalation:May cause irritation(possibly severe)ofthe respiratory tract.Respiratory stimulation occurs fa 4 followed ty epressed respirations.Death may occur from respiratory paralysis. Eye,Direct contact can cause corrosive ocular burna. Skin.Contact is irritating and may muse an unusual,)arge,pustular skin rash that appears similar to ballot ling of the sUn.If skin is moist,formation of hydralluaric acid can cause serious burns.These burns do not appear sedou.a fiat,but ma:t pcoctrate all the way to die bone. Ingatroa:symptoms include digestivo tract irritation or corrosion,nausea and vomiting(possibly blood;,'), ioody diarrhea, b40MInal pain,muscle weakness and spasms,dehydration,convulsiotts,progressive CN8 depression(fstig e,come,and piratary arrest,even in absence of etrmtlatory failure),cardiac arrytbmiaa,end excessive potassium and c alum in the blood. ardnogen".11ARC,NTP,and OSHA do not list Ammonium Hiflucride as a carcinogen. adical Conditions Aggravated by Loug-Term ltxpomre;Kidney or boas disorders. bb/V1/;MU;4 ;Zd:db l51d1y4•L HU13bAND HALL INN r'14=1 CI.3 01)'09I2066 11:01 FAX WEG0 MINERAL ®004/007 Chronic Effects..Repeated or prolong-d exposure to end absorption of the fluoride ion rain case kidne i dd mage n well as flnoros➢s(brittle bones,calcified ligamenm ad anemia). Section 4-Fiat Aid Measures Iebalationr Remove exposed person to$ash Air and support breathing as mcded. Eye Coned:Do not allow victim to rub or keep eyes tightly shut.Gently lift eyelids and flush immediat ly and contirntously with tloodiag amounts ofwater thmtil iransported to an eelergeney medical facility.Consult a physician in nediately. Skin Contact:QWcUy remove eontmainated clothing.Rinse with flooding amounts of water for at loan I min.After rinsing, massage in a 2.5 9f6 ealeinnh glseonaht:gel until Pala is relieved.If pain persists,eelciurn gtueonate inja:ti u may .be necessary. Consult a physician. Ingestion;Never give anything by mouth to an unconscious or convulsing person.Contact a poison emu l center.Unl ass the poison control center advises odhem&,e,have the comcfous and alert person drink l to 2 glassas of wgrer o dilute.The decision ti induce vomiting ie debatable.Its corrosive nature may indicate gastric knp or binding ofthe fluoride io with elik c afciurn glu000te,orcaleium lactate. Otber:Toxic dose is estimated at 5 to 10 mgtkg offluoride;30 mL Of 1%solution in a 10 kg child-20 )dines fluoride. .IJlerPubr anti,gd pP➢royriale bh�tpm,1,parwrsedte,or c0avrrrrraur(y mtdlral ay pyor4 Note to PAylkiam:Administration ofantscids(magnesium and shm b man)is suggested.Seim=may ref Are Diazepam but can ultimately be corrected by electrolyte SiMbilization.Monitor EKG.electrolyte),and vital Aisne.High cooeci rations of fluoride ion may be present in urine after akin contact.&mralshre may be helpful in protecting the upper G1 tract&ern s id injury.Ctassult with a poison control center on current recommendations. Special Preeaui(ous/Procetlnres: ency personnel should protect against secondary contamination. Section 5.Fire y ..tin Measures Flash Point: Noncombustible NFPA Burning,Rate: Autoignition Tempersturet Noncotnbuatible IT LET.:None reported. 3 0 UEL:None reported. -- Flammability ClaaslPeeAtion;non flammable Extinguishing Media:Do not apply wMar to adjacent fires because possible contact with autmsonntm biftu ride will tits rate hydrogen fluoride gas capable of etching glass,cement,and Wherry metals. Unusual Fire or Expiation TTarsrde;None reported Hazardous Combustion Prodmeta:include ammonia,nitrogen oxide,and fluorine gases. Fim-Fighting Instructions:Da not release runaff from fin colsaol methods to sewars or waterways. Fire-Fighting Equipment:Because fire may produce toxic thermal decomposltsors products,weer a selPa stained breathing apparatua(SCBA)with a hull tkcepieao operated In pressprademand or positive-pressure mode. Section 6-Accidental Release Measures $pill/Leak Procedures:Notify safety personnel,isolate and vadtilam area,deny AM,and stay upwind Small Spills:To avoid duet generation,carefully scoop into eontahw orvacuum(witb approprWc filterN I unp mop an.l residue (use a dilute solution of sodium bicarbonate to neutralize residue). Large Spills Ceneaintnent:For large spills,flush to contatnmeslt am for reclamation or disposal.Do not release imtr)y .refs or v aterways. Cleanup;Neutralize with sodium bicaTbomAte,soda ash,slatted lime,or crushed limestone. Regulatory Requirements:Follow 401icable OSHA regulations(29 CFR 1910.120). Section 7-HandlinLw and Sto a HandI tug Precautions:Do not use in moist wWd areas. Storage Requirements Store In plestjti rubber,or parRff 46d eorstalners.Do not ins metal containers bmcs se of poastb v corrosion and generation of flammable hydrogen gas(occurs when ammonium bifluoride is exposed to trot sire and emy metals). Store in a cool,dry,well-vegtlated area away bom Incompatibles(Sec.10).Keep coruainert;tightly clotted. Section fil-Exposure COntrols/Personal Protection Enginearing Cnntrob:Enclose processes wherever passible to prevent dug from entering work areas. ventilation:Provide general or local exhaust ventilation systems to maintain airborne concentrations bola* 3SHA PEU l (Sec.2).Local exhaust ventilation is purred bW4Use It prevents contaminant dispersion lore the work.arf s by control!ng It at its source. Page 2 of 5 06/01/2002 23:38 7591942 HUBBARD HALL INU VAlat n4 01403/2006 11:01 FAX WEa(l MINERAL 0 0)3/007 3 Admtnlstrative Controls:Consider prep and periodic Meaesl exsuns of exposed workers widt a tp aa�'�e CNS, kidneys,skin,and bona. Respiratory Prowdou;Seek professional advice prior to retphator selection and use.Follow OSHA its kww repimlons (29 CPR 1910.134)and,if nectuary,wear a MSHA/NJOSR gptOved respirator.Select raapilatotf b -&• ►n its sttitabi lity to provida edaquste worker prowation llrrgiven working colldltlonk level Orairborne contamination,any:p: sense of sufficient Oxygen.For emergency or nonroud .operations(cleaning spills,reactor vessels.or storage mks),wear n SCBA. 11'a►,rin8f Air proifjring raspiretors do am proton wonterr!n oxygon.�fcfenr etnroapl ereur if respirator► ux used,OSHA requires a written respiratory protection pte>graat that includes At least:medical certification,tmimin&f 1t., sting,perioclic environmental monitoring,maintenance,intpectfon,clew and e:ollvenietDt,sanitary storage areas_ Protective Clothing/Equipment:Went cbemieally protective glovea,boots,aprons,and gaundeta to prev it prolonged or repeated skin contact Wear protective eyeglasses or chemical safety goggles,per OSHA eye-and faec•pi teaion regu ladans (29 CM 1910.133).Contact lens are not eye protective devlca.Apptoptiato rye protection must be*( n instead of,or in conjunction with contact lenses. Safety 5tatioaa:Make emergency mash stations.safety/ti"-drench showers,and washing facilities a affable in work area, Contaminated Equfpment:Separate=tam'nated work clothes EMM stare clothes.Launder before raw Remove thtt materiel from your shoes and clean parsonl promotive equipmeta: Comments;Never eat,drink;or smoke:in work areas.Practice good personal hygiene after using this man fal,especially before eating.drinking.smoking,using the toilet,or applying cosmetics. Section 9-Physical and Qeilnical Pro fee ' Physical State.Solid Water Solubility;41.S wt%at 77°F(2 a° D;forms a Appearance and Odor.White, odorless,orthorhombic hydrofluoric said solution. crystals.Hygroscopic if humldlty is>5096. Other Solubilides; 1.73 wt%in ethawL a 77 OP(25'C) Vapor PrMilret 77 min Hg at 7?OF(??°C) Bolling Polot:463.1 OF(239.5 IQ vapor Deosity(Air-1); Freesdng/Melling Fauat:25618 OF(124.6 'C) Formula Weight: viscosity: Denelty/Speclik Gravtty(H20-1,at 4'C): 1.5 Refraedve index: 1 J90 PH(S%solution):3.5 Surface Tendon! SOC60h 10-StAbRW and ReactiII Stability:Ammonium Bifluoride is stable at room tempardu o in closed containers under normal stotar.a d handling aDnditions. in presence of meisttue,it will etch glalu,cetrtent;and most metals_It may generate flammable hydrogen g t if exposed to moiatur and metal at the same time. Polytnerixation:Hazardous polymosi:ntion cannot occur. Chemical iaeompatibWtles:include water,coach,and oxidizers. Conditions to Avoid:Ttcposure to incompadblea. hazardous Decomposition Prodnets:Thermal oxidative decomposition of Ammonium Bifluorids can faro uce Sttortae.nitrogen oxide,and ammonia gases. Section 11-Toxicolo 'cal Infotrmadon Toxicity Data.' Eye Effects: Acute Oral 90ctse Skin Elfacf : Rat,oral.LDso:60 m&U Chronic Urettse Carcinogenicity: Mutagealeity: '1 erritWgerd<clty: See N10SR, RMCS(BQ"O0000,solid);(13Q9205000'aokdw)for titans toxicity data. _ Siect�-Ecol2ocsl Information Ecotoxieity.MCC wdgaris,TLm=200 ppm/96 hr. Environmental Fete; l liinviroumetftUl Degradation:/umrnoniwa bfifluodde is biodegredeable and will not aeeumulaae In the fb od :)lain. Fogg 3 of 9 06/01/2002 23:38 7591942 FAJBBARD HALL INC PAGE 05 QIY03/2008 11:02 FAX IIEQl1 MINERAL Q00e/007 Section 13-Aispossi Considerations Disposal:Contact your supplier or a licensed eotittaetor for detailed recommendation.Follow applicable 'aderal,state,and local regulations Container Cleaning sad Disposal:Triple Apse c0nta4er8 MW treat rinse want the same es other atntaon un hifluoridle waste Section 14-Transport Information DDT Trainsparbdion Data(49 CM 172,101): Shipping Name;Ammonium Packaging Atithorketions Quantity Limilatioat Hydmgendifluoride,solid a)Exceptloas:173.154 a)Passenger,Aircral ,or Railcar; 15 kg Shipping symbols b)Non-bnik Packaging:173.212 b)Cargo AlveraR N r.50 kg Hazard Gass:8 c)Bulk Pac"&g:173.240 ID No.:UN1727 Vessel Stowage Rego "Cato Packing Croup:11 a)vessel S4awage:A Litbelt Corrosive b)Other:2S,26,41) Special Provisions(17LI02):N34, N34,T19 'Section 15-Bmlatog Informatioxt US FEDERAL TSCA CAS#1341.49-7 is listed on the TSCA invencaty. CAS#7732-1 A-S is listed on the TSCA inventory. Htalth B&Safcty Reporting List None of the chemicals ate on the Heallb do Safety Reporting Liat, Chemical Test awes 1 None of the chemicals in this product are tmdot a ChwAcal Tess Rule. J Section 12b None of the chemicals are hated under TSCA Section 12b, TSCA Sigalfleapt Now Use Role None of the chemicals in this material have a SNUB under TSCA SARA CERCLA Hazardous Substance and corresponding RQs CAS#1341-49-7:100 lb final RQ;45.4.kg final RQ SARA Section 302 EXtreately Hasartloes Substances None oftbe chemicals in this product have a TPQ. SARA Codes CAS#1341.49-7:acute,chronic. Section 313 No chemicals an reportable under Section 313. Clean Air Aetr This material does not contain any hazardous air pollutants.This material does not contain any Class i Cu a depletots. Phis material does not contain any Class 2 Ozone depletow. Clean Water Act: CAS#1341.49-7 is listed as a Hazardous Substance under the CWA.None ofthe chemicals in this product ra listed as itioriry Pollutants under the CWA.Notre of the chemcals is this product are listed as Toxic Pollutam under the C` 'A. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE CASs 1341.49-7 can be found on the foJtowlpg state right to know lists:Cslllbrnla,New Jersey,Ponnsylva 4 Manacbuaetts. CAS#7732-13-5 is not present on MU lists from CA,PA,NW,MA,PT,,or NJ. California No Significant Risk Level:None of the chemicals in this product are listed. Enro n4uternstional Ae ulations Pu g European Labeling In Accordance wrrb EC Dirsetivea I surd Symbols: Rusk Phrases: Page 4 of 5 06/01/2002 23:38 7591942 HUBBARD HALL INC PAGE 06 O V03/2008 11:02 FAX WE60 MINERAL 1I007/007 5 Ammonium Hi R 25 Toxic ifewallowod. R 34 Caww burns. Safety Phrases: S 22 Do not bmathe dust. S 26 In case of contact with eyes,rinse,immediately with plenty of vmet and seek medical advice. 8 37 Wear suhable gloves, S 45 In ease of ecoident or if you feel%mwell,seek medical advice immediately(show the label when possible). WGK(Water Danger/Proteedon) CASO 134149-7, 1 CASs 7732-18-5:No information avaa'Isbk- Canada-DSEMDSL CASW 1341.49-7 is Barad on Canada's DEL List. CASO 7732-18-5 is Listed on Canndn's 1DSLLfsi. Canada-WUMTS This product has a WHMLS classification of D IS,S. Canadian Tagredient Disclosure List CASO 1341.49.7(fisted as Fluorides.inorganic)is listed on the Canadian IngrWieut Disclosure List. Section 16-Other Information ~_ Disclaimer.All information,recommandadous and auggesdons Appearing herein are based upon tomes b Moved to be reliable: However,it is the users responsibility m detettnine the safety,toxicity aed suitability forks own use ofthh product. w1s,00 CHEMICAL A MINERAL CORP.DOTES NOT ASSUME ANY LIABILITY APOING OUT OF THE U1 3 BY OTHERS OF THIS PRODUCT. Page S of