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Home My WebLink About80 Kimberly Drive - Building Plans & Dra Section VII - Accidental Release Measures (continued) ` recmAons to be TaWe—n in an ng ard Storage 'fake sure all personnel involved in housekeeping and spill clean-up follow good Industrial Hygiene practices and wear proper protective equipment. Section Vlil - Handling/Storage/Transportation Handling Chemical goggles and full face shield must be worn at all times by personnel exposed to or handling Hydrochloric Acid. The use of a NIOSH approved cartridge respirator or a Scott Air-Pak should be used by all personnel exposed. �toiaye - Store containers in a cool, dxy iocation away from direct sunlight, sources of intense heat, or where freezing may occur. Store material in acid-proof container. Keep ccntair_er tigh•:Iy closed when not in •-ise. Keep container away from incompatible materials. All loading, unloading, and storage equipment must be inspected prior to any transfer operations are initiated. eneral Comments Impervious clothing, gloves, footwear and head gear must be worn at all times by personnel exposed to or handling Hydrochloric Acid. Section IX - Exposure Controls/P-rsonal Protection Respiratory Protection(Specify•yre Maintain airborne coatatn_na_e levels below =Asce.a ;;wi?elines. Use with adequate ventilation. Use a nec:-iani.:a.l fa__ o: vent area scrubber. Ventilation I_ocal Exhaust Special -- /1 If PEL exceeded Vent fumes: to appropriate scrubber `Mechanical(General) 'Other If PEL exceeded Not Applicable - Wear neoprene rubber glove:3 to minimize skin cone= _ct. Eye Protecfioin Splash goggles or safety gasses. Face shields are recommended. OtheiPiotecdon -- --- --. ........ _ Use body protection appropriate for task. An apron or other impermeable body protection is suggested. "ull bvc.y chemical pzo•:e<.t_oa is recommended for emergency respo::se proc�_,dur.:�. Appficable Exposure Limits Other than any exposure limits which may be displayed in Section 3, there are no other known exposure limits applicable to :his product cr its components. Section X - Physical and Chemial Properties Boiling Point Specific Gravity(H20=1) 230 F :1.160 - 1.1693 Vapor Pressure(mm Hg) Freezing Point i 50 - 60 mm ..-12 F to -63 F Vapor Density(AIR= ) ;ex.-A _ N.A. 9.671 - 9.748 Solubility in W ater miscible _ Appearance and Oaor Clear/Slightly yellow with a sharp pungent odor J Page 4of7 Section XI - Stability and Reactivity _Stability Unstable Conditions to Avoid lJ Hydrochloric Acid is extremely reactive. Avoid contact with I Stable X metal surfaces and oxidizing agents. Incompatibility(Materials to Avoid) Hydrochloric Acid is chemically stable when properly contained and handled. It is a strong mineral acid and reacts with many me::alg and metal oxides and hydroxides to form the equivalent metal chloride. It reacts with zeolites and other siliceous compounds to form Hydrosilicic Acid; it reac-cs wick carbonates to form Carbon Dioxide and Water. It is oxidized by Oxygen or electrolysis to form Chlorine, a lethal, poisonous gas. It reacts with alkaline compounds to form a neutral salt. It is a hydrolyzing agent for carbohyd---;tes, esters and other compounds. Its reaction with most metals will produce Hydrogen, an explosive gas. violent reactions will result when Hydrochloric Acid Reacts with acetic anhydride, 2-aminoethanol, ammonium hydroxide, calcium phosphide, chlorosulfonic acid, ethylene diamine, ethylene :mine, oleum (f•itning sulfuric acid) , perchloric acid, beta propiolactone, propylene oxide, sodium hydroxide, sulfuric acid, uranium phosphide and vinyl acetate. This listing is not all-inclusive. Hazardous Decomposition or By-products Extreme heat may cause the product to decompose, producing toxic fumes which may _- Anclude chlorine compounds. Hazardous :May Occur Condiii•:.ns:o A:z:d Polymerization Extreme heat and contact with incompatible materials .Will Not Occur X Section XIl - Toxicological information r� Route(s) Entry Inhalator" kin? Ingestion? fes Yes Yes Health Hazards(Acute and Chronic) - . Hydrogen Chloride, both as a gas and in a solution as Hydrochloric Acid, is a corrosive substance and can cause severe and painful burns on contact with any part of the body or =f taken internally. The mucous membranes of the eyes and the upper respiratory tract are especially suscerc_- ':e to the irritating effects of high atmospheric concentrations of Hydrogen Chloride. The gas or vapor is so penetrating and pungent that; when high concentrations do occur, those exposed _ should immediately leave the contaminated area. -Carcinogenicity. NTP? IARC tdoi.ographs? OSHA Regulated?No No No Signs and Symptoms of Exposure _ . Exposure to Hydrochloric acid may cause se:•erz 'urns at the contact points Medical Conditions Generally Aggravated by Exposure - Exposure to fumes may aggri ate dermatitis and breathing disorders. J - Page 5 of 7 Section XII - Toxicological Information (cont.) Toftology Inhalation Date �iydrogen Chloride Human LCLo - 1300 ppm/30 min _JJ Rat LC,,, - 4701 ppm/30 min Oral (mbbM LD.,,, - 500 mg/kg - Mutagenic Effects - _ Inhalation: 100 ppm/24 hrs (Chromosome damage) Oral: : 100 ppm (Chromosome damage) _ Parental: 20 mg (Cytogenic effects) Section XIII-Ecologic::,!Informat;31 Ecological oracity Animals exposed to hydrochloric acid solution will experience tissue damage, burns and may be killed. Plants contaminated with h•dr�)vhloric acid solutions of low pH may be adversely effected or destroyed. High con.zantrations have been shown to be detrimental to aquatic life. A release into a body of water will kill fish and other aquatic life. OtHdir l=cological Information Hydrochloric acid is stable and found naturally in the environment. All work practices should be aimed at eliminating environmental ronra.mination. Chemical Fate'nfonnation "'- Hydrochloric acid is naturally occurring in the environment. Other Regulatory Information No other regulatory information is availabl.: on :;his product. Section XIV - Transportation Information Regulated ateria Hydrochloric Acid is de-`-_ned aD haza:_ous br the US Do--- and Transport Canada DOMESTIC SHIPPING. INFORMATION Proper Shipping Name Hazard Clas_ification ;Hydrochloric Acid Corrosive UNMA Identification Hazard Class UN 1799 Class 8 DOT Labels Required Packaging Croup ; Corrosive II IN':ERNATIONAL SH_TPP:ENG !NFORMATION roper Shipping Name Hazard Ciassificadon .Hvdrochloric Acid Corrosive UNWA Identification Haard Class :JN 1789 Class 8 Labels Required F a.;naging:a.cup Corrosive II Section XV - Other Information Created y WDS Revivion Number Product Safety - 4/20/99 Revision # 005 Topc Substances Control Act -Superfund Amendment&Reiuth6diation Act,Title III Acute &- TSCA listed 7647-01-0 Hazard Categories HEALTH: Chronic Emergency Planning&Community Right to Know EHS - Threshold Quantity: None 3HYSICAL: None _ Ts product Regulated Under 1990 Clean Ai:Art, Coec Procuct Contain,or is Manufactured with,CFCs? NO No -Reportable Quantity:.. NSF Uatr.g RQ - 5000 lbs Scale & Corrosion control at maximum 40 mg/1 NFPA 3 - 0 - 0 - Acid 3 - 0 - 0 - X _ Ts This Product Regulated Under the EPA's Risk Management Piana- No, Hydrochloric Acid Solution under 3. a is not regulated. Nofth American Emergency Response Guide Soot JD # 1789 Guide #157 1996 Revision Page 6 of 7 Disclaimer of Liability )he data contained herein is furnished gratuitously and independent of any sale of any product. It is supplied only for your investigation and possible independent verification. While the data is believed to be correct, Reagent Chemical and Research Inc. makes no representation as to the accuracy of any data contained herein. In no event shall Reage :: "hem=cal and Research, Inc. be responsible for any damages of any nature whatsoever directly or indirectly resulting from the publication, use or reliance ur-)n any data contained herein. Data Sheets are available frr other Reagent Ch-mmwcal and Research, Inc. products. You are urged to obtain data shae:s for all products you buy, process, use or distribute and you ;..re encouraged to ad-visa anyone working with or exposed to such products of zhe zformatio:: contained in the applicable data sheets. The data in this document is yj_4 out any representation or warranty, express or iwfilied, regar3:.ng its accLra,71 or correctness. No warranty either expressed or implied of merchant ability o.: fitness or of any nature is made with respect to any product referred to here_ri., ncagert Chemical and Research Inc. does not assume respoasibiliry and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the products rercrred herein. Page 7 of 7 S+r- COL tracAtng r>ew frontiers � ZJ 331001 Acetone Material Safety Data Sheet SECTION 1 PRODUCT AND COMPANY IDENTIFICATION. Trade name Acetone Synonyms 2-propanone,Dimethyl ketone,Ketone propane,beta-Ketopropane. Manufacturer/Supplier SASOL CHEMICALS NORTH AMERICA LLC (An affiliate of Sasol North America Inc.) Address 900 Threadneedle,Houston,TX 77079 Telephone CHEMTREC North America Transportation Emergency(24-hr) (800)424-9300 CHEMTREC World Wide (703)527-3887 Other Emergencies(24-hr) (337)494-5142 MSDS and Product Information(8:00am-4:30pm CST) (281)588-3491 Health and Safety Information(8:00am-4.00pm CST) (281)588-3492 SECTION 2 COMPOSITION AND INFORMATION ON INGREDIENTS Components CAS-No. Weight% Acetone 67-64-1 99.9 See Section 8 for Exposure Guidelines and Section 15 for Regulatory Classifications. SECTION 3 HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Appearance Clear,colorless Liquid Odor Pungent Precautions DANGER! EXTREMELY FLAMMABLE LIQUID AND VAPOR MAY CAUSE EYE,SKIN AND RESPIRATORY IRRITATION. Keep away from heat and flame. Do not get in eyes,on skin,or on clothing. Wash thoroughly after handling. Keep container closed. Use only with adequate ventilation. Environmental Do not flush into surface water or sanitary sewer system. Non-toxic to aquatic fife. precautions Readily biodegradable. POTENTIAL HEALTH EFFECTS Distributed by HUBBARD-HALL INC. Eyes Irritali'm to eyes. data w.mwny.CT OM 26s17e1-2171 @ In n.n,RC MW 66v472-9M 1111 METALS TESTING MAP W*dn n, �a01066 07SM413f7 77 - WHMtgOon,MA 01867 6761B86-0D77 it r Rai FEMED 13 lDATE l Version date:01/18/2M Version 1.2 Print bate: 01/12&M ' Page 1 of 7 SaSO .. reaching new frontiers Acetone Skin Repeated or prolonged contact can cause redness,irritation and scaling of the skin (dermatitis). Normal care and personal hygiene should prevent skin effects. The product may be absorbed through the skin. Inhalation Irritation of the nose and throat,dizziness,and headache. Ingestion Aspiration(breathing)into lungs,caused while vomiting,may result in severe pulmonary injury. Depression of central nervous system can occur. Ingestion may cause gastrointestinal irritation,nausea,vomiting and diarrhea (See Section 11 for Toxicological Information) SECTION 4 FIRST AID MEASURES Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Sidn contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. When symptoms persist or in all cases of doubt seek medical advice. Wash contaminated clothing before re-use. Inhalation Remove to fresh air. If breathing is irregular or stopped,administer artificial respiration. If breathing is difficult,give oxygen. Call a physician immediately. Ingestion If swallowed,call a physician or poison control center immediately. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. SECTION 5 FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES Flash point -20°C closed cup -4 OF Autoignition 465'C 869 OF temperature Flammable limits in Lower explosion Ilmit: 2.6%M air%by volume Upper explosion limit: 12.8%M Fire and explosion Vapours may form explosive mixture with air. Flash back passible over considerable distance. Use water spray to disperse the vapors. NFPA Class IB flammable liquid. Extinguishing media Use water spray,alcohol-resistant foam,dry chemical or carbon dioxide. Fire fighting Self-contained breathing apparatus(SCBA)and structural firefighter's protective clothing instructions will provide limited protection. I Version date:01/18/2006 Version 1.2 Pont date: 01/12/2006 Page 2 d 7 SaSOL -'1 readit eta fron ic., /j Acetone Further information Keep containers and surroundings cool with water spray. Beware of vapours accumulating to form explosive concentrations.Vapours can accumulate in low areas. SECTION 6 ACCIDENTAL RELEASE MEASURES Steps to be taken in Evacuate personnel to safe areas. Remove all sources of ignition. Contain and collect case of spill or leak spillage with non-combustible absorbent material,(e.g.sand,earth,diatomaceous earth, vermiculite)and place in container for disposal according to local/national regulations (see Section 13). Do not flush into surface water or sanitary sewer system. SECTION 7 HANDLING AND STORAGE Safe handling advice Ensure all equipment is electrically grounded before beginning transfer operations. StoragerTransport Ambient. pressure Further information Keep away from heat and sources of ignition. l on storage conditions J SECTION 8 EXPOSURE CONTROLWERSONAL PROTECTION ENGINEERING MEASURES Air contaminant levels should be controlled below the PEL or TLV for this product(see Exposure Guidelines). Mechanical ventilation may be necessary if working with this product in enclosed areas and/or at elevated temperatures. Use explosion-proof equipment. PERSONAL PROTECTIVE EQUIPMENT Eyes When contact with liquid is possible,use a face shield and/or chemical splash goggles. Otherwise use safety glasses with side shields or goggles. Skin Wear suitable protective clothing,gloves and eye/face protection. Inhalation Respiratory protection is normally not required except in emergencies or when conditions cause excessive airborne levels of mists or vapors. NIOSH-approved organic vapor air- purifying respirator,self-contained breathing apparatus,or air-supplied respirators where there may be potential for overexposure. Version date:01/ta(2005 Version 1.2 Print date: 01/1212M Page 3 of 7 Sa-SOL raaEA'My ft"jro dW' Acetone EXPOSURE GUIDELINES Components Exposure limit(s) Acetone OSHA PEL 1,000 ppm ACGIH TLV(&hour)500 ppm ACGIH STEL 750 ppm PEL= PermisslWa E)posure Limits TWA-- Time Weighted Average(8 hr.) TLV= Threshold Umlt Value STEL-- Short Tenn Exposure Limit(15 min.) EL= Exotusim Limit WEEL= Workplace Envirorunentol Exposure Level SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Liquid Colour Clear,colorless Odour Pungent Form Liquid Boiling point/range 56.2°C 132.2 OF l Vapour pressure 186.2 mm Hg @ 20°C J Vapor density 2 Solubility(water) Easily soluble. Viscosity 0.4 cSt @ 20°C Melting poinUrange -95.35 OC -139.6 OF Density 0.79 g/cm3 SECTION 10 STABILITY AND REACTIVITY Conditions to avoid Keep away from heat and sources of ignition. Hazardous Combustion products include carbon dioxide,carbon monoxide and possibly other decomposition unidentified organic compounds. products Incompatability with Can react with strong oxidizers,inorganic acids,and halogens. other materials Hazardous None. polymerization Version date:01/18nox Version 1.2 Print date: 01/12/2M Page 4 of 7 SaSO .. ` � reaeh7rg new frwurers Acetone SECTION 11 TOXICOLOGICAL INFORMATION Eyes Severe irritant bases on standard Draize tests Skin . Acute dermal LD50 (rabbit): 20,000 mg/kg Inhalation Acute 8 hours LC50(rat): 50,100 mg/m3 Ingestion Acute oral LD50(rat): 5,800 mg/kg CARCINOGENICITY This product contains no carcinogenic substances. SECTION 12 ECOLOGICAL INFORMATION Aquatic toxicity Non-toxic to aquatic life. (Trout)96 hours 5,540 mgfl (Goldfish)24 hours 5,000 mgA (Bluegill sunfish)96 hours 8,300 mg/I (Shrimp)24 hours 2,100 mgll (Daphnia)48 hours 10 mg/l Biodegradation Readily biodegradable. SECTION 13 DISPOSAL CONSIDERATIONS Waste code F003(RQ 5,000 Lbs) Disposal methods Dispose of only in accordance with local,state,and federal regulations. Do not contaminate any lakes,streams,ponds,groundwater or soil. Empty containers Empty containers retain product residue(liquid and/or vapor)and can be dangerous.DO NOT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND,OR EXPOSE SUCH CONTAINERS TO HEAT,FLAME,SPARKS,STATIC ELECTRICITY,OR OTHER SOURCES OF IGNITION;THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.Empty drums should be completely drained,triple-rinsed,properly bunged and promptly returned to a drum reconditioner,or properly disposed. SECTION 14 TRANSPORT INFORMATION DOT description Acetone,3,UN 1090, II Version date:01118/2005 version 1.2 Print date: 01/12/2006 Page 5 of 7 saSOL � l �r�►,�w,►�Mren Acetone IATA description Acetone,3,UN 1090, 11 IMDG description Acetone,3,UN 1090,II SECTION 15 REGULATORY INFORMATION U.S. FEDERAL REGULATIONS OSHA classification Flammable liquid,Eye irritant TSCA Inventory Listing Components CAS-No. Acetone 67-64-1 SARA 302 Status Components CAS-No. Weight Contains no chemicals subject to SARA 302 reporting. SARA 3111312 Classification . "Fire hazard","Immediate(acute)health hazard" SARA 313 Chemical Components CAS-No. Weight Contains no chemicals subject to SARA 313 reporting. CERCLA Hazardous Substance Components CERCLA RO Weight% Acetone 5,000 LB 99.9 INTERNATIONAL REGULATIONS Workplace Hazardous Materials Information System(WHMIS)Classification Class B,Division 2:Flammable liquid. Class D,Division 2,Subdivision B:Toxic material. Australian Inventory of Chemical Substances(AICS)Listing Listed on the AICS. Japanese Minister of international Trade and Industry(MITI)Inventory Listing Listed on MITI. Version date:01/18l2005 Version 1.2 Print date: 01112/2M Page 6 of 7 sasOL Acetone Canadian Domestic Substance List(DSL)Inventory Listing Listed on the DSL European Inventory of Existing Commercial Chemical Substances(EINECS)Listing Listed on EINECS. Phillipines Inventory List(PICCS) Listed on PICCS. Korean Inventory List Listed on the ECL China Inventory List Listed on the China inventory. STATE REGULATIONS California Safe Drinking Water Act(Prop 65)Listing Components CAS-No. Contains no chemical subject to Cal'rfomia Prop 65. SECTION 16 OTHER INFORMATION HAZARD RATINGS Health Flammability Rogkft HMIS 1 3 0 NFPA 1 3 0 THE DATA AND INFORMATION CONTAINED HEREIN ARE BEING FURNISHED FOR INFORMATIONAL PURPOSES ONLY,UPON THE EXPRESS CONDITION THAT EACH CUSTOMER SHALL MAKE ITS OWN ASSESSMENT OF APPROPRIATE USE AND APPROPRIATE SHIPPING,TRANSFER AND STORAGE MATERIALS AND PROCEDURES FOR SASOL NORTH AMERICA'S PRODUCTS. ALTHOUGH BASED ON INFORMATION SOURCES WHICH SASOL NORTH AMERICA CONSIDERS ACCURATE AND RELIABLE,SASOL NORTH AMERICA MAKES NO WARRANTY,EITHER EXPRESS OR IMPLIED,INCLUDING ANY WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE,REGARDING THE VALIDITY OF THIS INFORMATION,THE INFORMATION SOURCES UPON WHICH THE SAME ARE BASED,OR THE RESULTS TO BE OBTAINED,AND EXPRESSLY DISCLAIMS LIABILITIES FOR DAMAGES OR INJURIES RESULTING FROM THE USE THEREOF. _J Version data:01/18/2005 Version 1.2 Prini date: 01/12/2M Page 7 d 7 ACEIIC ACID GLACIAL httpJ/wwwjftkerc0IWn s/A0326.htm 94 M+w Emwyet"roUphone;$004041161 CWMTM-1-6064244M IMSDS material.Sa AW SNOW �m'�In�40°i Auwds U.E.and caetsda Chfindt o_7034r1P 41W From Malinckradt Baker,Inc. j 1 mallinckrodt J. �Rod SchoDI Lan* � �[ CHFMCA1.S � e gQn�rnum�s#�t� Phl111p9t rg.1�1J o e pas i► re of ohsrt aE.a r 3.a ifMbh+M a a,Qi�,�06(C.tilt,�trf ffi63d�ilE NIlOtYilS�bFl114'J@{$. Aft non-vmw9my quntiom should *Wadto CAMOMss SW v6oa(t•OWSW-263 Im anisla-me. ACETIC ACID GLACIAL MSDS Number: A0326—Effective Date: 05117101 1. Product Identification Synonyms:Acetic acid,methane carboxylic acid, edmoic acid CAS No.: 64-19-7 Molecular Weight: 60.05 Chemical Formula:CH3COOH Product Codes:J.T.Baker: 5355, 5579, 5844, 6903, 9500, 9501,9503,9505, 9507,9508, 9511, 9513, 9515,9522,9524,9526 Mallinckrodt: 2501,2504, 3121, 7711, 8817,H979,H983,V155,V193,V194 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------------ --------- Acetic Acid 64-19-7 99.5 - 100% Yes 3. Hazards Identification Emergency Overview -------------------------- POISON! DANGER! CORROSIVE.LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE.MAY BE FATAL IF SWALLOWED.HARMFUL IF INHALED. 1 of9 3/19/2002 12:52 PM ACEIIC ACID GLACIAL httpJ/www.jthaker.com/mscls/A03261ihn INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE.FLAMMABLE LIQUID AND VAPOR J.T.Baker SAF-T-DATAft ) Ratings(Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating:2-Moderate Flammability Rating: 2-Moderate Reactivity Rating:2-Moderate Contact Rating: 3 -Severe(Corrosive) Lab Protective Equip: GOGGLES&SHIELD;LAB COAT&APRON;VENT HOOD; PROPER GLOVES;CLASS B EXTINGUISHER Storage Color Code: White Stripe(Store Separately) ----------------------------------------------------------------------------------------------------------- Potential Health Effects ---------------------------------- Inhalation: Inhalation of concentrated vapors may cause serious damage to the lining of the nose,throat,and lungs.Breathing difficulties may occur.Neither odor nor degree of irritation are adequate to indicate vapor concentration. Ingestion: Swallowing can cause severe injury leading to death Symptoms include sore throat,vomiting,and diarrhea.Ingestion of as little as 1.0 ml has resulted in perforation of the esophagus. Skin Contact: Contact with concentrated solution may cause serious damage to the skin.Effects may include redness,pain,skin burns.High vapor concentrations may cause skin sensitization. Eye Contact: Eye contact with concentrated solutions may cause severe eye damage followed by loss of sight. Exposure to vapor may cause intense watering and irritation to eyes. Chronic Exposure: Repeated or prolonged exposures may cause darkening of the skin,erosion of exposed front teeth, and chronic inflammation of the nose,throat,and bronchial tubes. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems,or impaired respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air.If not breathing,give artificial respiration.If breathing is difficult,give oxygen. Call a physician. Ingestion: DO NOT INDUCE VOMITING! Give large quantities of water or milk if available.Never give 2 of 9 3/19/200212:52 PM ACEIIC ACID GLACIAL httpj/wwwjilakacom/mWA0326.htm anything by mouth to an unconscious person.Get medical attention immediately. Skin Contact: In case of contact,immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.Wash clothing before reuse.Call a physician. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes,lifting lower and upper eyelids occasionally.Get medical attention immediately. 5. Fire Fighting Measures Fire: Flash point: 40C(104F)CC Autoignition temperature:427C(801F) Flammable limits in air%by volume: lel:4.0;uel: 16.0 Flammable Liquid and Vapor! Explosion: Above flash point,vapor air mixtures are explosive within flammable limits noted above.Vapors can flow along surfaces to distant ignition source and flash back Contact with strong oxidizers may cause fire.Reacts with most metals to produce hydrogen gas,which can form an explosive mixture with air. Fire Extinguishing Media: Water,dry chemical,foam or carbon dioxide.Water spray may be used to keep fire exposed containers cool. Special Information: In the event of a fire,wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Water may be used to flush spills away from exposures and to dilute spills to non-flammable mixtures.Water diluted acid can react with metals to form hydrogen gas. 6. Accidental Release Measures Ventilate area of leak or spill.Remove all sources of ignition.Wear appropriate personal protective equipment as specified in Section 8.Isolate hazard area.Keep unnecessary and unprotected personnel from entering.Use water spray to dilute spill to a nonflanunable mixture.Contain and recover liquid when possible.Collect liquid in an appropriate container or absorb with an inert material(e.g.,vermiculite,dry sand,earth),and place in a chemical waste container.Use non-sparking tools and equipment.Do not use combustible materials,such as saw dust.Do not flush to sewer! US Regulations(CERCLA)require reporting spills and releases to soil,water and air in excess of reportable quantities.The toll free number for the US Coast Guard National Response Center is(800)424-8802. J.T.Baker NEUTRASORBO or TEAM®'Low Na+'acid neutralizers are recommended for 3 of 9 3/19/200212:52 PM ACETIC ACID GLACIAL hupJ/—jdrakerc0mbs&A0326.hhn spills of this product. 7. Handling and Storage Protect against physical damage. Store in a cool,dry well-ventilated location,away from any area where the fire hazard may be acute.Outside or detached storage is preferred. Separate from incompatibles.Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas.Use non-sparking type tools and equipment, including explosion proof ventilation.Protect from freezing. Store above 17C(63F).Containers of this material may be hazardous when empty since they retain product residues(vapors,liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -OSHA Permissible Exposure Limit(PEL): 10 ppm(TWA). -ACGIH Threshold Limit Value(TLV): 10 ppm(TWA); 15 ppm(STEL). Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits.Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,preventing dispersion of it into the general work area. Please refer to the ACGIH document,Industrial Ventilation,A Manual of Recommended Practices,most recent edition,for details. Personal Respirators(NIOSH Approved): If the exposure limit is exceeded,a full facepiece respirator with organic vapor cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,whichever is lowest.For emergencies or instances where the exposure levels are not known,use a full-facepiece positive-pressure, air-supplied respirator.WARNING:Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Sldn Protection: Wear impervious protective clothing,including boots,gloves,lab coat,apron or coveralls,as appropriate,to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible.Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties 4 of 9 3/19/200212:52 PM ACEIIC ACID GLACIAL httpV/www jtbaka.w,,Vm,&A0326lWn Appearance: Clear,colorless liquid. Odor: Strong,vinegar-like. Solubility: Infinitely soluble. Density: 1.05 pH: 2.4(1.OM solution) %Volatiles by volume @ 21C (70F): 100 Boiling Point: 118C(244F) Melting Point: 16.6C(63F) Vapor Density(Air--I): 2.1 Vapor Pressure(mm Hg): 11 @ 20C(68F) Evaporation Rate(BuAc=1): 0.97 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage.Heat and sunlight can contribute to instability. Releases heat and toxic,irritating vapors when mixed with water.Acetic acid contracts slightly upon freezing which may cause the container to burst Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated to decomposition.May also release toxic and irritating vapors. Hazardous Polymerization: Will not occur. Incompatibilities: Acetic Acid is incompatible with chromic acid,nitric acid,ethylene glycol,perchloric acid, phosphorous trichloride,oxidizers,sodium peroxide,strong caustics,most metals(except aluminum),carbonates,hydroxides,oxides,and phosphates. Conditions to Avoid: Heat,flame,ignition sources,freezing,incompatibles 11. Toxicological Information 5 of 9 3/19/200212:52 PM ACEIIC ACID GLACIAL httpJ/wwwjftkercom/mscls/A0326.hhn Oral rat LD50: 3310 mg/kg; skin rabbit LD50: 1.06 g/kg;inhalation mouse LC50: 5620ppm/1-hr, investigated as a mutagen,reproductive effector. --------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen--- Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- ------------- Acetic Acid (64-19-7) No No None 12. Ecological Information Environmental Fate: When released into the air,this material may be moderately degraded by reaction with photochemically produced hydroxyl radicals.When released into air,this material is expected to have a half-life between 10 and 30 days.When released into water,this material is expected to readily biodegrade.When released into the water,this material is expected to have a half-life between 1 and 10 days. Standard dilution BOD5/TOD=58%When released into the soil,this material is expected to readily biodegrade.This material is not expected to significantly bioaccumulate.This material has an estimated bioconcentration factor(BCF)of less than 100. Environmental Toxicity: This material is expected to be slightly toxic to aquatic life.The LC50/96-hour values for fish are between 10 and 100 mg/l. For glacial acetic acid: EC50(wheat fumigation)=23.3 mg/m3/2-hr,effect:leaf injury LC50(shrimp)= 100-300 mg/l/48-br LC50(fathead minnow)=88 mg/l/96-br This material may be toxic to aquatic life. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility.Processing,use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.Dispose of container and unused contents in accordance with federal,state and local requirements. 14. Transport Information Domestic(Land,D.O.T.) ----------------------- 6 of 9 3/19/200212:52 PM ACETIC ACID GLACIAL ht1 J/www jftk,.MWmsds/A0326.Wm Proper Shipping Name:ACETIC ACID,GLACIAL(WITH MORE THAN 80%ACID,BY MASS) Hazard Class: 8, 3 UN/NA: UN2789 Packing Group: U Information reported for product/size:450LB International(Water,I.M.O.) ----------------------------- Proper Shipping Name:ACETIC ACID,GLACIAL(WITH MORE THAN 80%ACID,BY MASS) Hazard Class:8, 3 UN/NA: UN2789 Packing Group: 11 Information reported for product/size:450LB 15. Regulatory Information --------\Chemical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia ----------------------------------------------- ---- --- ----- --------- Acetic Acid (64-19-7) Yes Yes Yes Yes --------\Chemical Inventory Status - Part 2\--------------------------------- --Canada-- Ingredient Korea DSL NDSL Phil. ----------------------------------------------- ----- --- ---- ----- Acetic Acid (64-19-7) Yes Yes No Yes --------\Federal, State & International Regulations - Part 1\---------------- -SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. ----------------------------------------- --- ----- ---- -------------- Acetic Acid (64-19-7) No No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA- -TSCA- Ingredient CERCLA 261.33 8 (d) Acetic Acid (64-19-7) 5000 No No Chemical Weapons Convention: No TSCA 12 (b) : No CDTA: No SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: Yes (Pure / Liquid) Australian Hazchem Code:2P Poison Schedule:S6 7 of 9 3/19/200212:52 PM ACETIC ACID GLACIAL httpJ/—jibakercoanisds/AO326.htrn WHnIIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations(CPR)and the MSDS contains all of the information required by the CPR 16. Other Information NFPA Ratings:Health:3 Flammability: 2 Reactivity: 0 Label Hazard Warning: POISON! DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE.MAY BE FATAL IF SWALLOWED.HARMFUL IF INHALED. INHALATION MAY CAUSE LUNG AND TOOTH DAMAGE.FLAMMABLE LIQUID AND VAPOR. Label Precautions: Do not get in eyes,on skin,or on clothing. Do not breathe vapor or mist. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep away from heat, sparks and flame. Label First Aid: In case of contact,immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.Wash clothing before reuse.If swallowed,DO NOT INDUCE VOMITING.Give large quantities of water.Never give anything by mouth to an unconscious person.If inhaled,remove to fresh air.If not breathing,give artificial respiration.If breathing is difficult,give oxygen.In all cases get medical attention immediately. Product Use: Laboratory Reagent. Revision Information: No changes. Disclaimer: Mallinckrodt Baker,Inc.provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy.This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product.Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.MALLINCKRODT BAKER,INC.MAKES NO REPRESENTATIONS OR WARRANTIES,EITHER EXPRESS OR IMPLIED,INCLUDING WITHOUT LMMATION ANY WARRANTIES OF MERCHANTABILITY,FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY,MALLINCKRODT BAKER,INC.WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. 8 of 9 3/19/200212:52 PM ACETIC ACID GLACIAL hupJ/www j#3akcr con m MA032&Wm Prepared by: Environmental Health&Safety Phone Number: (314) 654-1600(U.S.A.) 9 of 9 3/19/2002 12:52 PM 06/01/2002 23:38 7591942 HUBBARD HALL ING F'AUL LIZ of/o3/2008 11:01 FAX NEBO MINERAL jaoo3/on7 Material Safety Data Sheet 1/, 'y/OD," WEGO CHZMICAL tit MMRAL CORP 239 dreat Neck Road Ghat Neely NY 11021 Phone.(516)487 3510;email:sOnSwegechem.com Data of P station: Ammonium B fluoride Seaton X - Chemical Product and ColaipanI IIdentifical( m —� ...�. ,�. roduct/Chemical Name:Ammonium of fluoride Chemical Formula:NH,HFa AS Number.1341.49-7 Other Assignations:acid ammonium fluoride,ammonium acid fluoride,ammonium hydrogen bifluorkle, mmoniam h;idrogah Wooride,ammonium hydrogen fhtori c Derivation:Produced by reaction of ammonium hydroxide with bydrofluoda said aced subsequent orysts1i stion. en erel Use:As a obmtical reagent,ctuffiror for brewery,deity,and other equipment,"sour"i n lautuk.= ;cloth,mord ant for uminum;in manuibeture ofmagnesD m and mapesium alloys,lab production of hydrogen fluoride,elea spieling,pro cming Ilium,cWhing glass,and to acidify welts, mergency Telepbone: 1-800a34-9:100(Cgemtrec) Section?.- Cons 9ition/I OMfltioli on Ip edielkttL ingraitiontRame CAS Number r z:iN ECs/zLwcs %tot or'5 i vol Ammonium B illuoride 1341.49.7 215476.4 100 OSHA PEi.• ACGIH TLv N1OSN REV 8-brTWA.2.5 mg/m' TWA:2,5 mplie 10-hr'1 WA:2.5 mg/mr Jl DFG(Germany)MAX* WLH Level* Peak Exposurt L all., TWA:M mg1h ,total dust Soo mg/mu I Z5 ms/m3,30 min;everag, value,2/ehif t Category 11:3abstances with ayatemie a fleets Dlstrlbulee bj HUSBARI1-HALL INC. Half-life:2 b to shift length SOMM.II171 I� �J E� hewn.BG QGOti 0"47RI MI W. "OP 41WI47-OM °°'W 11M7 P7uoeemn Section 3-Hazards XdentiSleation >ct r? Emergenq Overview+ H 3 Ammonium biDuarlde existr u white,odorless crystals.It is highly toxic;locally because of it F 0 corrosive action and systemically because of Ira conversion to bydragen fluoride and fluoride it A 0 absorpilou.Fluoride tin is a direct cellular poison which interferes with calcium and magnento I P11E1 balances.Chronic exposure alp result in Iluorosis(see below.It Is noncombustible-Exposure I 1 iS,o a moisture forms hydrofluoric acid which is capable of itching glass,cement,a W many unetnb. Potential Health Effects Primary Entry Routes:inhalation,skin and eye contact,ingestion. Target Ornas:Eye,skin,teeth and bonus,kidneys,central nervous system(CMS). Acute Ef fecto lahalsdon7 May cause irritation(possibly severe)ofthe respiratory tract.Respiratory stimulation occurs fu t,followed ty cpressed respirations.Deane may ocetir from respiratory paraiyslL Eye,Direct contact can cause corrosive ocular burns. Skin:Contsm is irritating and may c:WW an umeaual,large,pustular skin rash that appear similar to ballot ling of the sl'ie.It skin is moist,formation of hydrotluaric acid am canoe serious burns.These bum do not appear sodowr a fast,but me:/ penwlate all the way to the bone. Ingeatiome Symptoms include digestive tract irritation or ca. ion,nausea end vomiting(possibly bloo-t,?), loody diarrh m bdominal pain,muscle weakness and spasms,dehydration,comrolslons,progressive CN6 depression(fetig e,coma,and pirexory arrest,even lo absence of circulaEohy failure),cardiac artydhmias,and excessive potassium and c cium in the blood. 1 aroinogettie t IARC,NTP,and OSHA do not list Ammonium Bitluorid[e ar a1 carcinogen, Medical Conditions Aggravated by Lout Term Exposure:Kidney or bone disorders. 3 lob/ft/103U;L LJ:Sri 13yly4'L HU0JJAKU HALL INN r Aur- CJ.J Wo3/2oOG 11:01 FAX WEG0 MINERAL a0(14/007 1 Ammonium DiAuoride 2 J Chronic Effects:Repeated or proloar.d exposure to and absorption of the Eumids ion ro cause)ddtte;,►d conga ad well U flnorosis(brittle bones,calcified ligarnrats,and anemia). -- Section 4-First Aid Measures Iabalationv Remove exposed person to fresh air and support breathing as needed. Eye Conack Do nor allow victim to sub or peep eyes tightly shut.Gently lift eyelids and flash immedim ly and eotitlrruously with flooding amounts orwata uuW lraasported to an emergency medical Facility.Consult a pinysfcian in nediately. Skin Contact;Quiddy remove contwxinated clothing.Rinse with flooding amounts of water for at laan 1 min.After rinsing, massage in a 2.S%calcium giueonart.gel until pain is relieved.If pain persists,calcium gluconate iajnxi- to may be nicessuy. Consult a physician. Ingestion:Never give anything by mouth to an unconscious or convulsing peraen.Contact a poison coda I center.Unl ens the poison control center advises otherwine,have the conscious and ales person drink 1 to 2 gleseas ofww--r c dilute.The decision induce vomiting is debatable.Its corrosive nature may indicate gastric lavege or binding oftbe fluoride to with milk c alcium ghtconate,or calcium lactate. Otber.Toxic dose is ostimtucd at 5 to 10 nWf kg of fhaoside;30 mL of a I.%solution in a 10 kg child-20 alift fluoride. A terJbw aid,get appropnare fad pas wft,or eonrnwalgr nredwa♦'arrppore Note to Physicians;Administration ofatttaeids(magnesium and aluts n tm)is suggested.Seiatres may w Are Diazepam but can ultimately be corrected by electrolyte vmbiihation.Monitor EKG,electrolytes,and vital aigus.High coucei rations of fluoride ion may be prevent In urine after akin conusi.SueraWre may be helpful In protecting the upper 01 tract flrolrrr v id injury.C( ault with a poison control center on current recommendations. Special Prmautlons/l'recadaree;ftenacy personnel should protect against secondary eonneamination. Section 5-InyetBaliting_Messures Flash Point: Noncombustible NFPA Burning Rate: () Autolphion Temperaturc Noncombustible LEi-None reported. 3 0 UEL.-Note reported. -- Flammability ClaaslrwAtion:non flntnmable 1Extiegufahiag Media:Do not apply waW to adjacent foes because possible contact with ammonium bi0u ride will libctate hydrogen fluoride gas capable of etching glaaa,cernettt;and many metals. Unusual Pare or Explosion Haaarde;None reported Hazardous Combustion Produea:Inolude ammonia,nftrogen oxide.and fluorine gases. Fire-Fighting Instructions:Do not release runoff from fire o001;01 methods to sewers or waterways. Fire-Fighting Equipment:Booeuse fire may Droduce toxic thermal decomposMoA products,wear a self:v itained breathing apparetua(SCBA)with a fail fkcepiece operated in pressarademand or positive-presam mode. Section 6-Accidental Release Measures _ Spill Mock Promdurm Notify safety personnel,isolate and veadlate area,deny entry,and stay upwind Small Spahr:To avoid dust generation,carefully scoop We container or vacuum(with appropriate filter 1.l unp snap aqv residue (use a dilute solution of sodium bionbotnts to neutralize residue). 1Larp Spills Con taintneat:For large spills,flush to containment area for reclamation or disposal.Do not release hw)a mars or waterways. Cleanup;Neutralize with sodium bicarbonate,soda ash,slaked lime,or crushed limestone:. Regulatory Requirements:Follow applicable OSHA regular=(29 CFR 1910-120). Section 7-Handling and Storage _ Handling Precautions:Do not use in moiatlhumid areas. Storage Requirements;Store In plash:,rubber,or paraffined contain m Do not use metal containers braes se of poulb v corrosion and generation of flammable hydrogen gas(occurs when ammonium bifluoride is exposed to mot ure and many metals). Store in a cool,dry,well-ventilated area away from incompatibles(See. 10).Keep coruabw tightly cJoasd. Section 8l-Exposure Controls/Personal Protection Engin"Ir ng Controls:Enclose process in wherever passible to prrmut dum from entering wont areas, ventilation:Provide genetal or local exhaust va ntilation system"m maintain airborne concentrations ations belo%% ]SHA PEU 1 (Sec.2).Looa1 exhaust vrxrnladon is P7*hU d because It prevents contaWeant dispersion into the work 4m n by controlf ng it at / IC5 6AtltCC. Page 2 of 5 �� 06/01/2002 23:38 7591942 HUbBARD HALL 1NU t Aur U4 01403/2006 11;D1 FAX WE50 MINERAL ®0)5/007 l 3 Ammonium Bil'lttot'ide / A11111i11iurative Controls:Consider rMlacement amd periodic medical exams of exposed workers with a rphssis on the C SS, kidneys,skin,and bones. Respiratory protection:Seek prefeantonal advice prior to respirstor selection and use.Follow OSHA res kuwregulafons (29 CFR 1910.134)and,if necessary,wear a MBHAMOSH-approved reapbVor.Select respirator bet-ad ►n its suftabi lily to provide adequate worker protection Apr gin working cond1dons,level orairborne contamination,W.'Ir unce of suf licicat oxygen.For emergency or nonroutim.operations(cleaning spills,reactor vessel&or storage tanks),wear n SCBA. Wa►r►ingf Air purifying rupfrators do xm proNer workers in oxygen-dCldenr aDwmpherar:If rmspitatim ire used,OSHA requires a written resphloty protection prttp=that includes at least:medical certification,training,it-, sting,periodic environmental monitoring,maintenance,inspection,cleaf,and mveniaM sanitary storage uses_ Protective ClotbiRg/Equipment:Wear chemically protective glovea,boots,aprons,and gaundem to prey it prolonged or repeated skin contact,Wear protective eyeglasses or chemical safety goggles,per OSHA eye and faec•pt section rep WIWI (29 CFR 1910,133).Contact lenaes are not eye protective devices.Appropriate eye protection must be wt n Instead of,or in conjunction with contact lenses. Safety Stations:Make emergency eye'nash stabone.safety/gylck-dreneb sb,owers,and washing facilities a aileble in work area. Contaminated Equipment:Separate sonteMinated work clothes from stare clothes.Launder before ra"lu Remove thlt metedai from your shoes and clean personal protective equipmeta: Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this wait fat,especially before eating,drinking.smoking,using the toilet,or applying cosmetics. Section 9-Physical and Chemical Propy iee _ Physical State:Solid Water Solubility:41.5 Wt%at 77°F'(2 5° Di forms a Appearance and Odor.white,odorless,orthorhombic hydrofluoric sold solution. crystals.Hygroscopic ifhumidity is>S096. Other Solubilities: 1.73 wt%in edmoL a 771?(25•C) Vapor Ptessuret 77 mm Hg at 7?OF(7?°C) Bolling Point:463.1 OF(239.5°C) Vapor Density(Atr=1r Frecdog/MrAing Point 256.28 OF(124.6 'C) Formula Weight: viscosity: Density/Specitk Gravity(H20-i,at IC): 1.5 Relrsetive Index.- 1.390 PH(5%solution):3.5 Suril.ce Tension: Section 10-Stability and Reaedvity _ Stability:Ammonium Bifluoride is stable at roost temperatm in closed oontainers under normal storuWaa a d handling a Witions, In presence of moisture,it will etch glaia,semen%and most metals.It may gencrate flammable hydrogen g i if exposed to maimn and metal at the same time. Polymerisation:Huardous polymerization caimot ocw. Chemical tacompatlbllitksr include mwter,Bolds,and oxidizers. Conditions to Avoid:Exposure to incompatibles. Hazardous Decomposition Prodoeb:Thermal oxidative deo mrposition of Ammonium Bifluoride can pro nee fluorine.nitrogen oxide,end unanonia gases. Section 11-Toxicological Information Toxicity Doti: Rye Effects: Acute Oral 91feetse Skin Ef acts: Rat,oral.LDSo:60 m&g Chronic Meets- Cardnogenieity: Mutallardrily: 'l'erntogetaielty: See Nlt)Sll, RUGS(BQ920M0,solid);(BQ920500o,aohWon)ibr tonne toxicity daa. Section 12-Ecolwjcal Infolrmation Ecoloxicity: 7Ynca vWgar4 TLm=2W ppm/96 hr. Enviroamentad Vale, l:nAmumeotul Degradation:Ammani am bifluoride is biodegtedeable and will not accumulate in the k od :hair. �1 Faso 3 of 5 06/01/2002 23:38 7591942 HUBBARD HALL INC PAGE 05 QIY03/2008 11:02 FAX 9EQ0 MINERAL @ 00/007 Ammonium 111 1neride 4 Section 13-I&M921 Colasiderattons Disposal:Contact your supplies or a licensed eotlttacw for detailed recommendations.Follow a"UcAttle Weal,ante,and local regulations. Container Cleaning and Disposal:Triple rinse conmieors and treat rinse water the same as other atnmon un hifluori6t*sue. Section 14-Transport Information DDT Trm apotia4on Data(49 CFR 172.101). Shipping Name: Ammonium Pad aglingAtithorisations Quantity 1Limitatfnnt Hydrogendifivoride,solid a)Exe9floust 173.154 a)Powesiger,Aim* ,or Railcar; 15 kg Shipping Symbols. b)lion-bulk Packaging:173.212 0)Cargo AlrcnR Di r.SO kg 'Hazard Class:a e)Bulk Packaging: 173.240 M No.:UN1727 Vessel Stowage Regd -Monte Packing Croup:II a)Vessel Stowagc A Ubd:Corrosive b)Other:2S,26,41) Special Providotts(171.102):N34, N34,T15 .� Section 15-LKMIatog Information _ US FEDERAL TSCA CAB#1341.49-7 Is listed on the TSCA inventory. CAU 7732-1 B-S is listed on the TSCA inventory. Health&Safety Reporting List None of the chemicals are on the Heath do Safety Repotting Lief. Chemical Tat Mules \1 None of the chemicals in this product are undo a Chemical Tess Rule. J Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Signifant New Use Role None of the chemicals in this material have a SNUR under TSCA. SARA CERCLA Hazardous Substanew and correspondingRQs CASH 1341-4967:100 lb final RQ;45.4.kg final RQ SARA Section 302 Extremely Hasartioes substances None of the chemicals in this product have a TPQ. SARA Coda CAS#1341.49-7;acute,chronic. Section 313 No chernieals are reportable under Section 313. Clean Air AM This material does not contain arty hazardous air pollutants.This material does not contain any Class I CU a depletors. This material does not contain any Class 2 Ozone depleton. Clean Water Act: CAS#1341-49-7 is listed se a Hazardous Substance tr ibe CWA.None ofthe chemicals in this product re tinted as flniodry Pollutants under 1he CWA.Notre of the chemicals in this product we listed as Toxic Pollutahm under the C, `A. OSHM Name of the chemicals in this product are considered highly hazardous by OSHA» STATE CASs 1341.49-7 can be found on the fo3krA g state right to know lists:CQUbmia,Now Jersey,Pennsylva I-A,Masracbtecns. CAS#7732-19-5 is not present on state lists fain CA,PA,MN,MA,FL,or NJ. CRltfornia No Significant Risk Level:None of The chemicals in this product as Usted. Burvpean4lattrtnttional Aegulatiens European Labeling In Accordance*&.b EC Directives Usurd Symbols: Risk Phrases: Pate 4 of 5 06/01/2002 23:38 7591942 HUBBARD HALL INC PAGE 06 O V03/2008 11:02 FAX WEGO MINERAL it ouq/007 l g Ammonium Billlimide R 25 Toxic tfawallowea, ` R 34 Causm burns. SnIcAy Phrases: S 22 Do not breathe dust. S 26 In case of contsat with eyes,tin a,innnediately with plenty ofwslet and seek medical advioe. 8 37 Weer suitable gloves, S 45 In case of accident or if you feel%mwell,seek medical advice immediately(show the label where possible). WOK(Water Danger/Protection) CAN 1341-49-7: 1 CAS#7732-18-5:No information available. Canada-DSI.MDSL CASO 1341.49-7 is listed on Canada's DSL List. CASO 7732-18-5 is listed on Cannde's DSL List. Canada-WUMIS This product has a WHML4 classification of D!B,E- Canadian ingredient Disclosure List CASO 1341.49.7(listed as Fluorides,inorganic)is listed on tfte Canadian Ingredient Disclorm List Section 16.Other LtlYormation Disclaimer.All information,recommandadons and suggestions appearing herein are Based upon aourceo b lieved to be reliable: However.it is the users responsibility to determine the safety,toxicity and suitability for its own use oftbh nodum WEGO CHEMICAL&MINERAL CORP.DOES NOT ASSUME ANY LIABILM ARISING OUT OF THE US 3 BY OTHERS OF THIS PRODUCT. Page S of East Hartford,CT IZD Phone:860-289-1100 Fax:860-289-3272 i2 U S S E L L & DAWSON Stamford,CT ARCHITECTURE & UNGtNbElt LNG Phone:203-653-2335 Fax:203-653-3526 TO: Walter Summers, South Windsor Fire Marshal FROM: Thomas A. Manning, AIA Thomas A Manning 2012.04.10 09:09:29 -04'00' DATE: 4/9/2012 RE: Metals Testing Company 80 Kimberly Drive South Windsor, Connecticut File No. 12.038 This is to follow up on the occupancy classification of this building based on the attached listing of the types and quantities of chemicals present, and the attached Material Safety Data Sheets (MSDS). Based on the MSDS, the chemicals have been classified as follows: Acetic Acid toxic, corrosive, Class II combustible liquid (flash point 104°F) Acetone irritant, Class 113 flammable liquid (flash point-4°F, boiling point 132.2°F) Ammonium Bifluouride toxic, corrosive Aricid-B toxic, corrosive Enprep 576 toxic, corrosive Ferric Chloride toxic, corrosive Hydrochloric Acid toxic, corrosive Hydrofluoric Acid toxic, corrosive Lime (Calcium Hydroxide) irritant Methanol irritant, toxic, Class IB flammable liquid (flash point 51.8°F, boiling point 148.5°F) Nitric Acid toxic, corrosive Phosphoric Acid corrosive Soda Ash (Sodium Carbonate) irritant Sodium Hydroxide corrosive Sulfuric Acid toxic, corrosive Trisodium Phosphate irritant Turco Vitro-Klene corrosive The presence of toxic and corrosive chemicals is consistent with the initial classification as an H-4 occupancy. As Acetic Acid, Acetone, and Methanol in sufficient quantity might raise the classification to H-2 or H-3, I offer the following more detailed analyses. Per Table 307.7(1), up to 120 liquid gallons of Class II combustible liquids may be stored without requiring classification as H-2 or H-3. Per note d, this amount is increased 100 percent when the building is fully sprinklered per NFPA 13. The owner proposes to store 150 gallons of acetic acid, less than the 240 gallons that would require classification as H-2 or H-3. Website:www.russellanddawson.com Email:info@russellanddawson.com RUSSELL AND DAWSON LLC• 1111 Main Street-East Hartford,CT 06108•TEL:860-289-1100•FAX:860-289-3272 1 CHIRAG B.THAKER,PRESIDENT•DAN LYMAN RUSSELL,ARCHITECT•ROBERT M.DAWSON,III,PROFESSIONAL ENGINEER Per Table 307.7(1), up to 120 liquid gallons of Class IB combustible liquids may be stored without requiring classification as H-2 or H-3. Per note d, this amount is increased 100 percent when the building is fully sprinklered per NFPA 13. The owner proposes to store 110 gallons each of acetone and methanol, in combination less than the 240 gallons permitted in this fully sprinklered facility without requiring classification as H-2 or H-3. consulted the Commentary on this issue, and it appears that the maximum quantity of each and every line item is permitted to be present before reclassification is required. I therefore conclude that the H-4 occupancy classification stated on the drawings submitted for permit application is correct, and that use of approved storage cabinets or specific control areas is not required. If you have questions, please call. I am usually at (860) 679-4197 during the day. I am working on assignment away from our East Hartford office. You may also contact me by e-mail at thomas.manning@russellanddawson.com or tmanning@uchc.edu. c: file Christopher Dougan, Building Official R:\PROJECTS\A-YR-2012\12.038 Metals Testing-South Windsor,CT\R&D Code Compliance\WS120409 MSDS.Doc Website:www.russellanddawson.com Email:info@russellanddawson.com RUSSELL AND DAWSON LLC• 1111 Main Street-East Hartford,CT 06108•TEL:860-289-1100•FAX:860-289-3272 2 CHIRAG B.THAKER,PRESIDENT•DAN LYMAN RUSSELL,ARCHITECT•ROBERT M.DAWSON,III,PROFESSIONAL ENGINEER =S�*- MEULS 1EM-111ti G aw DELISLE INC.,D/B/A,METALS TESTING COMPANY 80 Kimberly Drive,P.O.Box 69,South Windsor,CT 06074 TEL:(860)289-8225 FAX:(860)289-5970 Jim Simmons Allied Construction Inc. March 2,2012 Mr.Simmons With regards to the new chemical processing facility for Metals Testing Company,the processes and chemicals currently being conducted and stored at are facility now will be the same in the new facility only on a larger scale. Below is a brief description of the process in new facility: l. Parts received in and sent to chemical processing facility. 2. Parts unpacked/fixtured 3. Parts immersed in alkaline cleaner 4. Parts immersed in water rinse tank 5. Parts immersed in etching tank 6. Parts immersed in water rinse tank 7. Parts immersed in anodizing tanks/anodized(if applicable to parts) 8. Parts immersed in water rinse tank(if applicable to parts) 9. Parts immersed etching/desmut tanks(if applicable to parts) 10. Parts immersed in water rinse tank 11.Parts immersed in hot deionized water rinse tank/blown dry 12.Parts inspected/repacked 13.Parts sent to other departments or back to customer Below is a list of chemicals that will be used and stored in the new facility.These chemicals will either be in drums from the manufacturer or in our processing tanks in diluted amounts. Chemical Approx Chemical Approx Name Amount Name Amount Acetic Acid 150 gal Methanol 110 gal Acetone 110 gal Nitric Acid 800 gal Ammonium Bifluoride 300 lbs Phosphoric Acid 100 gal Aricid-B(Acid Salt) 5000 lbs Soda Ash 200 lbs Enprep 576(Alk-Cleaner) 2400 lbs Sodium Hydroxide 2000 lbs Ferric Chloride 2400 gal Sulfuric Acid 400 gal Hydrochloric Acid 800 gal Trisodium Phosphate 1000 lbs H drofluoric Acid 200 gal Turco Vitro-Klene(Alk-Cleaner) 2000 lbs Lime 2000 lbs Anthony Bruno Special Projects Manager 3 E Material Safety Data Sheet Better Chemistry. Better Business. Hubbard-Hall Inc Information: 800-331-6871 563 South Leonard Street In case of Emergency: CHEMTREC: (24hr): (800)424-9300 Waterbury,CT 06708 www.hubbardhall.com info(ahubbardhall.com SECTION I-PRODUCT IDENTIFICATION TRADE NAME:Phosphoric Acid 76% PRODUCT CODE:2971012 CHEMICAL NAME: Phosphoric Acid REVISION DATE: December 7,2009 CHEMICAL FAMILY: Mineral Acid SECTION II-HAZARDOUS INGREDIENTS *PHOSPHORIC ACID, 75%, CAS 7664-38-2, CLEAN WATER ACT SECTION 311 HAZARDOUS SUBSTANCES, CERCLA HAZARDOUS SUBSTANCES, SARA TITLE III SECTION 313 TOXIC CHEMICALS, OSHA AIR CONTAMINANTS, OSHA TABLE Z-1-A [REVOKED], DOT HAZARDOUS MATERIALS, DOT HAZARDOUS SUBSTANCES OTHER THAN RADIONUCLIDES AND RADIONUCLIDES, MASSACHUSETTS SUBSTANCE LIST, NEW JERSEY RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST, SPECIAL HEALTH HAZARD, PENNSYLVANIA HAZARDOUS SUBSTANCE LIST, ENVIRONMENTAL HAZARD, CANADIAN WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS, INGREDIENT MUST BE DISCLOSED AT CONCENTRATION OF 1%. EP: CERCLA RQ IS 5000 LB; EPCRA SECTION 313 DE MINIMIS CONCENTRATION IS 1.0%. ACGIH: TWA IS 1 MG/M3; STEL IS 3 MG/M3. OSHA TABLE Z-1: TWA IS 1 MG/M3. OSHA TABLE Z-1 A [REVOKED]: TWA IS 1 MG/M3; STEL IS 3 MG/M3. *THIS SUBSTANCE IS A CHEMICAL SUBJECT TO SARA TITLE III, SECTION 313 REPORTING REQUIREMENTS. NO OTHER INGREDIENTS IN THIS MIXTURE ARE CONSIDERED TO BE HAZARDOUS ACCORDING TO ANY STATE OR FEDERAL REGULATIONS. SECTION III-PHYSICAL DATA BOILING POINT: 135 deg C(275 deg F) FREEZING POINT:0 degrees F VAPOR PRESSURE: N/A VAPOR DENSITY: N/A SOLUBILITY IN WATER: 100% PH:2@ 10 GM/L APPEARANCE AND ODOR:Liquid SECTION IV-FIRE AND EXPLOSION DATA FLASH POINT(F): NIA FLAMMABLE LIMITS: N/A EXTINGUISHING MEDIA: Product is not combustible. Use water spray, fog, foam, carbon dioxide, dry chemicals or other agents appropriate for the materials in the fire. Firefighters exposed to fire, smoke, fumes, and or products of the combustion should wear full face self-contained breathing apparatus and impervious protective clothing gear such as gloves, hoods,suits and boots. SPECIAL FIRE FIGHTING MEDIA: Evacuate non-essential people from the area of the fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: May decompose and product toxic gas irritating to the respiratory tract and cause breathing difficulty and pulmonary edema. 1 METALS TESTING C0t1 P 'Y' 1 l/ ! REVIEWED BY 1 of 3 SECTION V-HEALTH HAZARD DATA HMIS: HEALTH: 3 FIRE: 0 REACTIVITY: 1 EFFECTS OF OVEREXPOSURE: Phosphoric acid is an acid corrosive. Exposure to eyes, throat and skin. Liquid or high concentration may cause serious skin bums and may result in severe burns to the eyes. ROUTES OF ENTRY AND EMERGENCY FIRST AID PROCEDURES: SKIN: May produce serious chemical bums. Flush contaminated skin with water and wash with soap and water. Remove all contaminated clothing preferably while under a safety shower. Get medical aid immediately. Discard contaminated clothing and shoes. EYE CONTACT: Corrosive to eyes and may cause comeal ulceration, conjunctivitis, and permanent damage or blindness. Immediately lush eyes with large amounts of water for 15 minutes. Hold eyelids away from eyes to assure through flushing of eyes.Get prompt medical aid. INGESTION: Causes damage to mucous membranes,digestive tract and may lead to ulcerations and secondary infection. Immediately give large amounts of water. Do not induce vomiting, but if vomiting occurs, give fluids again. Do not attempt to induce vomiting or give fluids to an unconscious person. Get prompt medical aid, or call the nearest poison control center. INHALATION: Mist or fumes may cause respiration tract irritation, bronchitis, or even pulmonary edema if concentrated. Remove from contaminated atmosphere. If breathing has stopped, clear the victim's airway and perform artificial respiration. If victim is breathing, oxygen may be administered from a demand type or continuous flow inhalator, preferably with a physician's advice. Keep victim warm and at rest.Get medical aid promptly. SECTION VI—REACTIVITY DATA INSTABILITY: Stable under normal conditions at atmospheric pressures and in normal use. Freezes at lower -� temperatures. INCOMPATIBILITY: Phosphoric acid is a strong acid and a dehydrating agent. May spatter upon contact with water or with chemicals solvents containing water. Reacts violently with bases. Reacts with may metal producing heat and flammable hydrogen gas. DECOMPOSITION: Heating to decomposition point gives off toxic fumes of phosphorus pent oxide. POLYMERIZATION:Will not occur. CONDITIONS TO AVOID: Phosphoric acid is a strong acid and a dehydrating agent. May spatter upon contact with water or with chemicals solvents containing water. Reacts violently with bases.Reacts with may metal producing heat and flammable hydrogen gas. SECTION VII-SPILL OR LEAK PROCEDURES SPILL, LEAK OR RELEASE: In case of spill,wear protective clothing. Evacuate all non-essential people from the area. Soak up small spills with sand, dirt, or absorbent material. Neutralize with soda ash and scoop up and place in clean, dry lined steel containers and carefully label container for eventual disposal. Flush away residue with copious amounts of water. LARGE SPILLS should be diked with dirt, san or other similar material to prevent flowing into streams or sewers. Pump spill into marked containers fir reclamation or disposal. Residue should be neutralized and flush with water as described above.Always notify authorities if spill can produce adverse side effects to area. WASTE DISPOSAL: Waste disposal should be done in accordance with federal, state and local regulations. Incineration should be in equipment designed to handle oxides of phosphorus as combustion products. Submit waste material only to approved chemical disposal service companies. SECTION VIII-SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: Use NIOSH approved equipment with full-face piece when airborne appropriate type equipment for given application. VENTILATION: Provide ventilation to minimize exposure. Local exhaust ventilation preferred, SPECIAL: N/A 2of3 OTHER: Remove contaminated clothing promptly and launder before reuse. Provide safety shower at any location where skin contact can occur.Wash contaminated skin promptly. PROTECTIVE GLOVES:Wear appropriate impervious gloves and protective clothing to prevent skin contact. Wash contaminated skin promptly. EYE PROTECTION: Wear chemical safety goggles to prevent eye contact. Have eye baths immediately available where contact can occur. OTHER PROTECTIVE EQUIPMENT:Wear face shields and impervious aprons. SECTION DC-SPECIAL PRECAUTIONS HANDLING AND STORAGE: Store away from heat and keep product away from alkalies. Storage tanks should be off approved materials for phosphoric acid and should be vented and diked.316elc stainless steel is the preferred material for storage, process equipment and shipping containers. OTHER PRECAUTIONS: None SECTION X-TRANSPORTATION REQUIREMENTS PROPER SHIPPING NAME: PHOSPHORIC ACID HAZARD CLASS: 8 DOT GUIDE: 154 ID NUMBER: UN1805 PKG.GROUP: III NOTICE WHILE THE INFORMATION AND RECOMMENDATIONS GIVEN ARE BELIEVED TO BE ACCURATE, HUBBARD-HALL INC.MAKES NO WARRANTY,EXPRESS OR IMPLIED,AND ASSUMES NO LIABILITY ` WITH RESPECT TO USE OF THIS INFORMATION. 3 of 3 Home SODIUM CARBONATE (ANHYDROUS) ICSC: 1135 Date of Peer Review: October 2004 Carbonic acid disodium salt_ Soda ash CAS# 497-19-8 Na2CO3 RTECS# VZ4050000 Molecular mass: 106.0 UN# EC# 011-005-00-2 TYPES OF HAZARD/ ACUTE HAZARDS/ PREVENTION FIRST AID/FIRE EXPOSURE SYMPTOMS FIGHTING Not combustible. In case of fire in the FIRE surroundings:use appropriate extinguishing media. EXPLOSION EXPOSURE PREVENT DISPERSION OF DUST! Inhalation Cough.Sore throat. Local exhaust or Fresh air,rest. breathing protection. Skin Redness. Protective gloves. Rinse skin with plenty of water or shower. Redness. Pain. Safety goggles. First rinse with plenty of water for several minutes Eyes (remove contact lenses if easily possible),then take to a doctor. Burning sensation in the Do not eat,drink,or Rinse mouth.Give plenty Ingestion throat and chest_ smoke during work. of water to drink. Refer for Abdominal pain. medical attention. SPILLAGE DISPOSAL PACKAGING&LABELLING Sweep spilled substance into sealable containers; if EU Classification appropriate, moisten first to prevent dusting. Personal Symbol:Xi protection: P2 filter respirator for harmful particles. R:36 S:JL--22--26 UN Classification EMERGENCY RESPONSE SAFE STORAGE --iDry.Well closed.Separated from incompatible materials. See Chemical Dangers. Prepared in the context of cooperation between the International Programme on IPCS V 0) d Chemical Safety and the Commission of the International ,1 European Communities©IPCS, CEC 2004 Programme on -�- Oy�f► p Chemical safety UN +'P SEE IMPORTANT INFORMATION ON BACK SODIUM CARBONATE (ANHYDROUS) ICSC: 1135' IMPORTANT DATA PHYSICAL STATE;APPEARANCE: INHALATION RISK: WHITE HYGROSCOPIC POWDER A harmful concentration of airborne particles can be CHEMICAL DANGERS: reached quickly especially if powdered. The solution in water is a medium strong base. Reacts EFFECTS OF SHORT-TERM EXPOSURE: violently with acids.Reacts with magnesium, The substance is irritating to the eyes,the skin and phosphorous pentoxide causing explosion hazard. the respiratory tract. Reacts with fluorine causing fire hazard. EFFECTS OF LONG-TERM OR REPEATED OCCUPATIONAL EXPOSURE LIMITS: EXPOSURE: Tl_V not established. MAK not established. The substance may have effects on the respiratory tract, resulting in perforation of the nasal septum. Repeated or prolonged contact with skin may cause dermatitis. PHYSICAL PROPERTIES Melting point:851°C Density:2.5 g/cros Solubility in water,g/100 ml at 20°C:30 ENVIRONMENTAL DATA NOTES ADDITIONAL INFORMATION LEGAL NOTICE Neither the CEC nor the iPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information O IPCS, CEC 2004 See Also: Toxicological Abbreviations ©logool Material Safety Data Sheet NFPA HNC Personal Protective Firallmocut 0 2 See Section 15. Section 1.Chemfed-.Pict and Co idwdW' Wfion Page Nu nbec 1 Common Name/ Sodium hydroxide/ ustic Soda N a� S11501 S11502 S11503 me Trade Na CAN 1310-73-2 Maoefaetorer SAMIRIAN CHEMICALS INC. RTECS W84900000 1999 S.BASCOM AVE-,SUITE#515 TSCA TSCA 8(b)bverfty:Sodom ` CAMPBELI,CA 9 Commercial Name(-*)' Causticsoda beads,Sodium hydreDdde-Dry,Sdid C1# Not synonym Caustic Soda bakes/pearls/sticks!Soda iye,lyae,sodium hydrate IN SASE OF EMEIkGENCY Chemical Name Sodium HydroAde awAf AEC a4hr)80%4244M Chemical Family Strong alkali Chemical Formal. N80H Distributed by HUBBARD-HALL INC. Supplier er Sp1FItiRIAN CHEMICALS INC. Irk x cr aerm zav»sazm 19W S.BASCOM AVE.,SUITE#k515 mm.%sc zaM 8641472-Mi CAWBt3L,CAWIM w.SpWo.a,w+otaee 413r7474rM -- WWWd ^UAot887 979958.0077 Section ZComposidw and/nfomNiftn on btgredrents EWasure7loft Name CAS#{ TwA(mg/m) STEL(m)m) CEH.(■Wkar %by weft 1)SOcSum hydratdde 1310 73 2 2 2 2 100 Texicelogical Data Sodhsn hydradde on ingredients 1.1350:40 mglkg IMouse] LDkx 5W mglkg(Rabblt) Section 3.Hart db kr�'rcafion Potential Aerate Health Effects Very hazardous In Case of skin contact(Corrosive, irritant, penneator), d eye contact(irritant, corrosive),d ingestion,of inhalaecrr. The amount d tissue damage depends an length of contact and the axrcentralim (solutions).Eye cantata can result in corneal darnage or b1ndness. Skin r n Is-t can produce severe burns with deep ulcerations and permanent scarring.inhalation of dust will produce Irilation to gastrointestinal or respkatory tract,characterized by burring,sneezing and coughing. Severe over-exposure can produce pul nonary edema(severe.We threatening lung Injury,choking,unconsaa nness or death. krflarrrrrwdm of the eye is characterized by redress,watering,and Itching. Skin k0armnation is characterized by klcg,scaft reddening,or,occasionally,blistering.Ingestion can result in severe pain,burning of the rrnotdtn,throat esophagrm, vami8rng,diarrhea,collaspe or death_ Continued on.11laaft Page Sodium hydroxide Pap Number.2 Potential Chronic Health CARCINOGENIC EFFECTS:None. Efiects MUTA GENIC EFFECTS: Mutagenic for mammalian somatic cads TERATOGENIC EFFECTS:Not available. DEVELOPMENTAL TOMCiiY:Nano. Repeated Wosure of the eyes to a low level of dust can.produce eye irrftatioi Repeated skin exposure can produce local skin destruction, or dermatitis: Repeated Inhalation of dust can produce varying degree of respiratory iritatm or lung damage.May aggravate aftV lug diseases such as as#wA bronchitis, Section 4.First Aiditeast+itas Eye Contact Check for and rernae any contact lenses.Immediately flush eyes with plenty of water for at least 15 minutes. Hold eyelids open during flushing.Cold water may be toed. If in taHon persists,continue 11tshing. Get medical attention immediately. Skin Contact In case of contact,immmedieft flush skim with plenty of water for at least 15 minutes while remairg aired dothing,Jewelry,and six=. Cmftn washing until skin does not Cow the* Nalp skin an eno9ient ay Cold water maybe used Wash clothing before reuse. The=%=shoes before reuse valh Get mnedieai attention imrrediatey. Serious Sidn Cootaet Follow above directions.Flush skin with water for up to 60 minutes. Seek medical attention. Inhalation 9 inhaled,remove to fresh air. Sit in half up Ig! pOoft, .Rest if breathing Is dT=A give ocygen.Monitar for respiratory distress.Seek medical alteidb irtrnectah*. Serious Inhalation waistband. the victim to a safe area as soon as possible. Loosen tight clothing such as a color.tie,belt or wraistband. if breathing is diflkxdt,administer ocygm H the vfotim is not breathing,give artificial respiration. Do not use r xx*i}-o mouth method N vkAn ingested or unclad the substanom Induce ardfidal respiration with the aid of a pocket mask equipped with a one wW valve or other proper respiratory medic al davibe Soak-ilunedate medical attention. logesdou Do not imduee vo filing. Knse'mouth and give as mkkh water as possible to dguta material:•Loosen gb0wng such as a,oolhar:tie,belt or.waistband. If vbmft 6odn,have victim lean kxward with head dawn,`rase mouth and administer more water.Seek immediate medical attention. Serious ingestion: FdbN above directions. Never give anything by mouth to an unconscious person.IfMctimt is opt breathing " give artlfical respiration. Do n use e rlh-to mouth method if victim ingested or Inhaled the st noe dmsta moire arterial respiration with the aid of a po d mask eq*ped with a one-way valve or other proper respiratory medical device.Seek Immediate medk2d attention. Sectkw a.Fire and EnObdon Data Flasusuability of the Product Non-flammable. Auto-%nW*r Temperature Not applicable. Fush Points None. Flammable Limits Not appkable. Products of Combustion Sodium odds fumes. Fire Hazards in Presence of Serum hydronde in contact with wafter and adds may generate enough heat to ignite adjacent combustible Various Substances materials.Can react with mnetals such as 2km* %tin,and zinc to form flarnmtable hydrogen gas. Explosion Hazards in Presence Risks of oplosfon of the product in presence of mechanical impact: Note. of Various Substances Risks of enksien of the product in presence of static discharge:Not available. Reacts to form v#osive product with anxnatia and steer nitrate Fire Fighting Media Dry chernic a.carbon dmod*water spray,or alcohol resistant foam.Do not get water inside containers.Cad Hord instnctioas containers with flooding quantities of water until well after fire Is out.Wear fun chernical protective clothing. l tank,rant car,or tank truck is involved in a fire,isciate for 800 meters(12 mmNe)in afi directions.E*iguish lire fiom mtaximu n distance. Special Remarks on Sodium hydroxide in contact with Ance metal dust wII ignite.Under proper conditions of temperabive;pressure- Fire Hazards and state,it can ignite or read vieiertUy with acetaldehyde,aly ah:atid,ally)chloide,berms 1.4 dot,chlorine frifluctide,1.2 dichWoethyle me,nitroethane.nitrametimane,nibaperafiis,nitraproparme, ride, Z2.dichbro3.3-dimetit ibutane.Phosoms baled with sodkm hy*cxdde yields a prodtx:t that maY ignite spomtaneousy In air.See Section 10-Special Rernarks an Reactivity. Continued on Next Page Sodium hydroxide Pape Nbmbar:3 Special Remarks an Explosion Sodium hydroodde reacts to four expo"products With murartia+silver nNrate Hazards Benzene extract of alai bye pnepared from slid alcohol,and benzene suffianyl chlaide In presatoe of aquescus sodium hydn:m ,under vacxnun distillation,residue darkened and mploded. Sediuon Hydroxde+frpure tatrehydrduran,which can contain peroxides,can cause serious explosions. Dry n=kn m of sodium hydroodde and sodhxn l etrohydroborate liberate hydrogen explosively at 230-210 deg.C. Sodium Hydraodde reacts with sodim salt of trkddorophend+methyl alcohol+tlWkmbermm.+hoot to pose an exptosiorL Sedlon&Accidental Rehm*Measurm Smatl spin Absorb or ww with dry earth,san4.or other non oorr le material and transfer to waste disposal oa�faitar If necessay:Neutra(te the residue wth a dilute solution of acdlc acid.Fkhsh am with water. Large son Evacuate area Remove all ig Wm soxaoes and vengate area Stop leak lf without risk. Do not get weler inside Castatner.Do nit touch aplOW rrataiat Use water spray to reduce vapors. Prevent entry into surface water. sewers,basements or confined areas;dike N needed Notify appropriate 9marunent,.o=VWtlonai hoM and safely and er virmnental autrorithies.Neutralize the rasidru with a MO solution of acetic actd. Can fire deportment Immediately. Section 7.Haurdin®and Storm Precautions Use with adequate ventilation.Do not breathe dust. Now add water to this product. In rase d Insulfident verhNadom wear suitable respiratory equpment.Aksrrp add sodium hydroxide Oo water and provide aphelion.Use cold water and stir in small anarnt m slordy.Avoid contact with akin and ayes. Storage• HyWwcqutc. Keep container tigtdy dosed and dry. Keep container in a cock welt-irentlsted am Do not store above 23'C(73. T' Keep sway from Inmrr atbles such as au.dmV agents.reduckv egoists.` mefais,adds,alkalis,water and organic materials. .. a ,•.: „: A SWOOn.8 Exposure a IPkAeclWn iF-.. • Engineering Controls Use process endoeu��mVhilsbon. or otter&Vffm ring i*to keep arbome�bvels bet6w reca mmided eucpasure�Grx. If user operations generAs dust,Mine"ournist,use boat etdneust valor to keep wgxsure to airborne contarnmants below the exposure krk Eye wash and safety showers am necessary. Personal Protection Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approvedlcerhTied nespirmlor or equivalent. Doves.Face shIdd. Personal Protection in Case of Splash goggles. Full sulk. Vapor and dust respirator. Boats. Cloves_ A self contained breeding apparatus a Large Spill should be used to avoid inhalation of the product Chemical protective ciotting.Suggested protective dottkhg m%tit not be sutindent;consult a specialist BEFORE harOM this product l+.xps mre L+mits STEL:2 (mg/mM from ACGIH(fLV)[Unked States] TWA:2 CEIL•2 (mg/m) from OSHA(PE)Prdd sus] CEIL:2 (mglm3) from NIOSH Consult local authorities for acceptable exposure limits. Section 9.Physical and Chemical Properties Physical state and appearance Sold. Odor Odorless. Taste Not available, Maleenlar Weight 4t)g/mole PH(I'G sohrhvater) 13.5[Basic.] Color White. Boiling Pant 1388-C(253OXF) Melting Point 323-C(613.4°F) Critical Temperature Not available. Specific Gravity Z13(Water=1) Vapor Pressure 1 ern of Hg at 73V G Vapor Density Not available. Volatility Not available. Continued on Next Page Sodium hydroxide page M&NMber 4 Odor Thrahokd Not available. WaterM Diet weir. virtually 0 Iooieity(hh Water) Not available. IDispersion Properties See solubility in water. Solubility Easily soluble in cold water. Seatfon110 Sftb tyandReacftilyData Stability The productis stable under normal CcriCRk ts. testal"q T—perature Not available. Comli ions of Inev6ility Inoampatibte.naterials.moisture,moist air Incompatda'Gty with various Avoid contact with orgaic materials,adds.water.flammable liquids,organic halogens,anphotaric rne#als and sabsneees nitro compounds.Reactive with ceddhzng agents,reducing agents See Special Remarks an Readiudy. Cerrosh* Corrosive to aluminum,tin,zinc,capper and most alloys in which they are present Carcelve to steel at tempwahaes above IW C. Special Remarks on RIWWcoM Much heat is evolved when sold material is dissohed in water. Mwefae Cold water and Ce" Reactivity _ m usthte4med for this process. Soc 'ID9fr0Wde soltionand octanok+eHrgranedimng a wuri-w cif a.readlan mbtlte of culme air!dihararhe In i. . iidlrahyrofwuin is very w olhermic,a mild sgiosion b"netted on one accession. ;. s _ Reac(�reaaNliarater,al-nmeral acids.all organ(e.aCie s,afdefWas,cart)arnates, orgaiiiathaloga►s =kei<giies, ciniorides,stnxn bases, ids powdered g aodd¢hrg, rr9 a9 .tlarunaMt metals 1 melds,metal compoulnds,nitrides.nitruiles,rptro cornporurds,acetic anhydride eh"ryndrin chlormuiforft . x', acid;ethykm cyanohydrin,9hraaat,hydrasulfuric acid,deuni,Propidadone.acybrntrle.Phosphorous Pentoxide,chkiroadISI 1,Chloroform-Methanol,*Mydrdxrate,cyanogen azide. 1,2,4,5 tetra:hbrobatzene,cinnarnatdehyde, >rurrnaldehyde hydroxide. m ..Produces hydrogen gas when I reads with sodium tetrahydroborate or certain metals such as skankum 6%zinc. Can form spontaneously flammable chemicals upon contact with 1,2-dichleroethylene,ttichlorodr/mis,or Can produce carbon monoxide upar contad with solutions of sugars,such as inrcb4 lactose Special Remarks on Very arrosive to aluminum and other metals in presence of mashu►e. orr-h* Polymerization WIN not occur.However,can viokntly induce polymerization with acetaldehyde,acrdekn and aaylonk le. SeCBon 11. Toxicokxjkai 6/fonnafion Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Taskity 6o AnWu& LD50:40 mg g[Mouse) Lolo: 500 mgAcg[Rabbit] Chrome Effects on Humeri WITAGENiC EFFECTS: Mutagerk for mammalian somatic cells. Other Todc Effects on See Section 3.Extremely hazardous in case of inhalation(lung corrosive). Humans Very hazardous in case of skin contact(corrosive,Irritant,permeator),of eye contact(corrosive),of ingestion. Special Remarks on Highly toxic to aquatic Ife. Toxicity to Animals Special Remarks on May affect genetic material. investigation as a rnutagen(cytoge nedc analysis) Chronic Effects on Humans Special Remarks on other immediately dangerous to fife or health at 10 nxy m3 Toxie Effects on Humans Con&#ued 9n Merl ft_" Sodium hydroxide Page ttlrrrr66r:S Aarte Potential Hearth Effects: Skin: May be harmful N absorbed through skin. Causes severe skin irritation and bums. May cause deep penetrating ulcers of the skin. Eyes: Causes severe eve*ritatia and bums. May cause chemical oorf tanctivitis and corneal darnge Inhalation: Ham*d 9 inhaled Causes severe irritation of the respiratory trail and mucous membranes with coughing,bums,breathing d'dticulty,and possible canna. Irritation may lead the chemical pneurnoni is and pulmonary edema Causes dtertical bums to the respiratory tract and mucous membranes. Ingestion: May be total d swalmed. May cause severe and perrrra wot damage to the dgestive tract Causes severe gestrantestinal tract Imitation and blurts. May cause perforation of the digestive tract. Causes severe pal+.ram,vornitig,diarrhea,and shock. May cause corrosion and.permara t destruction of the esophagus and digestive tray Section 12 Ecca1 kitormattfon Ecatonicity LC100: 180 ppm24 hr at 25'C ICyprixrs Ca o*,125 WnW hr IfLm 1Aos4kft tisht 99 mg&48 hr[Tim Bkiegffl BODS and COD Not available. odnets.of ModW*11ation Degrades readily by reacting with natural carbon&adds.Wring sodium carbonate. Tosidty of the Products The product itself and its products of degradation are not todc. orBiodegndadan Special Reanrks the Not avallabte w, Prodayls ` .SeT'�,.^ .iiVINFYWa J. fly, '1 7I��t. astr Bisposal If this product becomes a waste ft could meet the cdteda-d a hazardous waste as defined by llie Resource Conservation Recovery Act(RCFt�40 CFR 261.Before .., d should be deterr0'� d t(fe waste meets the l Criteria of a hazardous waste.Consult local,state,federal f9r Spe(�I-reQU�.Hxm Ul to aquatic J We at low conceWatiar;9.Do not contaminate domestic or inigaa m*ater supplies oe bodies of water. Sec>tFon 7I4•Tnt�trisportllri!ton . . . .. DOT ClamW"tlon Class 8 Corrosive material Identification :Sodium hydreodde,sold LWNA:1823 PG:ti Special Provisions for Air transport IATAWAO-Class 8,LIN 1823,PG 11 Traaaport DOT(Pictograms) Section 110OW-Reguiatorybrfonnafion and Odograms Federal and State lands tmdc mbstances disclosure to ernployee act Sodium hydrwdde Reguladoffi Marais chemical safety act Sodium hydrardde New York release reporting fist Sodium hydradde Rhode Island RTK hazardous substances:Sarum hydnxdde Pennsylvania RTK Sodium hydro" Minnesdx Sodium hydrt>odde Massachusetts RTK:Sodium hydrordde New Jersey:Sodium houdde Louisiana spit reporting:Sodium hydraaide Caftnia Director's List d Hazardous Substances:Sodium hydrnedde TSCA 8(b)inventory:Sodium hydroxide CERCLA:Hazard uus substances.:Sodium hydroxide:1000 lbs.(453.6 kg) Cawfaraia Proposition 65 Does not require warning under CA Prop 65. Warniobs Congnued on Nmt Page Sodium hydroxide pap NBerr6er:s Otter OSHA Hazardous by definition of Harad Corrrfwnicatian Standard(29 CFR 1910.1200). EINECS:'Kris product is an the European Inventory of E*ftrrg Commercial Cher icai Substances. SARA Section 311 and 312:The product Is to be reported under ftre I ranediale(Acute)and Reactive Heaifh Ha>2rds DSL:This product is on fie Darh>estic Substances Listof Canada. On the Air Contamirrarrts Regulatory List and the Registered Pesticide List. Otter Cdoas S(Canada) CLASS E:Corrosive solid. rDSCLI(EEC) R35•Causes severe bums. S26 In case of contact with eyes,rinse kvmdWely with plenty of water and seek medical advice: S28-Auer contact with skin,wash knm to* with plenty of water 33SWI39.Wear su7able protective elmWrhg, gimm and eyefface pratgction. S3&In case of Insullident ventliallon,wear su'fabie respiratory awAyna t. S45•In case of accident or if you fed u wk seek medical advice frranediately(show the label where possible). HMIS(tJ S.A.) National Fire ProtedieMM0 n �• r Assoeiation( A.) New" %ndscisztmtd WHMIS(Canada) Olictogirluns) 4ti- DSCL( ) (4doIgnims) TDG(Canada) ADR(Europe) (itrlCtOgrhilrl3) P. Protective Equipment Gam, Syrtx#k apron. Vapor and dust respirator. Be sure to use an approved/cerlfiied respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Continued on Next(loge Sodium hydroxide Pape NUO*er:7 Splash goggles. SecLPon I6 OthwkifommOba Code S11500 Rdereaees Ha¢ardars Substatces Data Bank.U.S.National Library of Meftw,Bethesda.MarAmd.lcemet.rhYnA h pov. InRemallonal Chemical Safety Cards,National kuMuls for Oaarpabonal Safety and Health,Cindnnak,OH. www.cdc.gov/rJwh OSHA,U.S.Departnhent of tabor,Washington D.C.,www-os ha.gov. Mwwbc trees Material Safely Data Sheet MSDS Sot dkm www.msds.com Spedalaed W n vMm Services,U.S.National Library of Medickv Deparbrrert of Health and Hharran Services. dhem.sbAniftgov. Cherrdcal Cardnogenesis Research Information System,U.S.National Library of Medrane,Bethesda,Mayland, tunetrim.nth.gov. i Od—Spedal :. Not able. VsHdaoed by AeMe Aeandr eu`6n3665 - r r CALL I.>QOMU010 = Notice to Reader nr alaea■ayPww unkmew Ards wd AMU of,ere r(A WeUne MWS ww"M S94 Drer S-AW Aem rppr+m am&a Me aONOW apertA VA g0 Nepr6er!s WwiierJl�obrra�oidxeerJwwi«arraaorwMtnl6+rpPauMro�srta�e �tJle�isAS�tsiadbseAcav4raprpW9ryrJewiglrrler�wetYlr ofA-A+rrasipmr•••rp—+rawr..irz.aera.eur ay.sa wrus0rsaRsostre IN!AWIIMra.rr rsmePINkdrsr:rs arr,SM*JW hma..err me#wwmmdWMWjbr do comphowen or acemaq Okv uirNwafkarca J IJA ` Distributed by HUBBARD-HALL INC. -7.71001 NorFalco Inc. W .CTOM 22MM.z,r NorFalco Sales Inc. - Safety Data Sheet 77%-100%SULFUAJC ACID SECTION 1.IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Trade Name 77%-100%Sulfuric Acid Product Code None Manufacturers/Dlstributors NorFalco Inc.,6000 Lombardo Center,The Genesis Big,Suite 650 Seven Hills,OH 44131 NorFalco Sales Inc.,6755 Mississauga Road,Suite 304,Mississauga,Ontario L5N 7Y2 Information Contact Andr6 Auger,Administration Assistant Product information 1-905-542-6901(Mississauga) Phone Number(Transportation Emergency) Canada 1-877-ERP-ACID(377-2243) Phone Number(Transportation Emergency) U.S.A 1-80042449300 CHEMTREC Phone Number(Medical Emergency) 1418-656-8090 Phone Number(Emergency) CANUTEC 1-613-996-6666 Synonyms Dihydrogen Sulfate;Oil of Vitriol;Vitriol Brown Oil;Sulphuric Acid. Acide suifurique(French) Name/Chemical Formula Sulfuric Acid/H2SO4 Chemical Family Acid Utilization Chemical industries;Water treatment;Fertilizer;Pulp and Paper. Manufacturers CEZinc on behalf of Noranda Income Limited Partnership,Sahtbeny-de-Valleyfield(Quebec)Canada J6T 61-A Xstrata Copper,Horne Smelter,Rouyn-Noranda(Quebec) J9X 5B6 Xstrata Zinc,Brunswick Smelting,Belledune,New Brunswick EOB 1 G0 Xstrata Copper,Kidd Metallurgical Division,Timmins,Ontario P4N 7K1 Xstrata Nickel,Sudbury Operations,Falconbridge,Ontario POM ISO SECTION 2.HAZARDS IDENTIFICATION WHMIS(Canada) CLASS D-IA:Very toxic material causing immediate and serious effects CLASS E:Corrosive material Labelling(EEC) C Corrosive _l Other hazards Danger. Extremely corrosive. Causes severe burns and eye damage. Mist : Causes respiratory irritation. Harmful if inhaled.Harmful or fatal if swallowed - Environmental hazards Strong acid Highly toxic to plants and to aquatic organisms. SECTION 3.COMPOSITION/INFORMATION ON INGREDIENTS Name CAS No Percentage(%) EC No R Phrases' Sulfuric(Acid) 7664-93-9 77%to 100% 231-639-5 R35 60 Deg Technical 7664-93-9 77.7 231.639-5 R35 66 Deg or 93%Technical 7664-93-9 93.2 231-639-5 R35 1.835 Electrolyte 7664-93-9 '93.2 231-639-5 R35 98%Technical 7664-93-9 98 231-639-5 R35 —_ 99%Technical 7664-93=9 99 231-639-5 R35 100%Technical 7664-93-9 too- 231.639-5 R35 Water 7732-18-5 0-22 231-791-2 Note 1:See section 15 for the complete wording of risk phrases. SECTION 4.FIRST-AID MEASURES Eye Contact Remove contact lenses if present. Immediately flush eyes with plenty of water,holding eyelids open for at least 15 minutes.Consult a physician.If medical treatment must be delayed,repeat the flushing with tepid water or soak the affected area with tepid water to help remove the last traces of sul bric acid.Possibility of conjonctivitis,severe irritation,severe bums,permanent eye damage. Skin Contact Remove contaminated clothing and shoes as quickly as possible protecting your hands and body. Place under a deluge shower for 15 minutes. Flush exposed skin gently and thoroughly with running water (Pay particular attention to:Folds,crevices,creases,groin).Call a physician if irritation persists. May irritate skin,cause bums (Highly corrosive)and possibility of some scaring. Wash contaminated clothing before reusing.While the patient is being transported to a medical facility,continue the application of cold,wet compresses.If medical treatment must be delayed,repeat the flushing with tepid water or soak the affected area with tepid water to help remove the last traces of sulfuric acid Creams or ointments SHOULD NOT be applied before or during the washing phase of treatment. - ` Inhalation Take precautions to avoid secondary contamination by residual acids. Remove the person to fresh air. If not breathing,give artificial resption.Difficult breathing:Give oxygen.Get immedi�r<te�tedical attention. Possibility '�L..R v r.?Fi�tC C.it fit• }, vTi.•si T` 20I0 1/6 s NorFalco Inc. NorFalco Sales inc. ' 77%-100%,SULFURIC ACID of damage to the upper respiratory tract and lung tissues.Maintain observation of the patient for delayed onset of pulmonary oedema.May cause irritation to the upper respiratory tract:Coughing,sore throat,shortness of breath. ingestion DO NOT INDUCE VOMITING.Conscious and alert person:Rinse mouth with water and give''/s to I cep dwater or milk to dilute material.Spontaneous vomiting:Keep head below hips to prevent aspiration;Rinse mouth and give %x to 1 cup of water or milk. UNCONSCIOUS person DO NOT induce vomiting or give ally liquid Immediately obtain medical attention. Notes to Physklans Continued washing of the affected area with cold or iced water will be helpful in removing the last traces of sink acid Creams or ointments should not be applied before or during the washing phase of the treatment. SECTION S.FIRE-FIGHTING MEASURES Flash Point Not available Flammable Limits Not available Auto-Ignition Temperature Not available Products of Combustion Releases of sulfur dioxide at extremely high temperatures. Fire Hazard Not flammable Explosion Hazard Reacts with most metals,especially when dilute:hydrogen gas release(Extremely flammable,explosive).Risk of explosion if acid combined with water,organic materials or base solutions in enclosed spaces (Vaceum trucks, tanks). Mixing acids of different strengths/concentrations can also pose an explosive risk in an enclosed space/container. Extinguishing media ERG(Emergency Response Guidebook):Guide 137 When material is not involved in fire,do not use water on material itself. Small fin:Dry chemical or CO2.Move containers from fine area if you can do it without risk. Large fire: Flood fire area with large quantities of water, while knocking down vapors with water fog. If insufficient water supply.knock down vapors only. Fire involving Tanks or Car/Trailer Loads: Cool containers with flooding quantities of water until well after fire is out.Do not get water inside containers.Withdraw immediately in case of rising sand from venting safaydevices or discoloration of tank.ALWAYS stay away from tanks engulfed in fire. -� Protective equipment Evacuate personnel to a safe area.Deep personnel.removed and upwind of fire. Generates heat upon addition of water,with possibility of spattering.Wear full protective clothing.Runoff from fire control may cause pollution. Neutralize run-off with lime,soda ash,etc.,to prevent corrosion of metals and formation of hydrogen gas.Wear self-contained breathing apparatus if fumes or mists are present. SECTION 6.ACCIDENTAL RELEASE MEASURES Measures Review Fire and Explosion Hazards and Safety Precautions before proceeding with clean up. Stop flow if possible.Soak up small spills with dry sand,clay or diatomaceotis earth. Methods Dike large spills,and cautiously dilute and neutralize with lime or soda ash,and transfer to waste water treatment system.Prevent liquid from entering sewers,waterways,or low areas. If this product is spilled and not recovered, or is recovered as a waste for treatment or disposal,the Reportable Quantity(U.S.DOT)is 1000 lbs(Based on the sulfuric acid content of the solution spilled).Comply with Federal, State,and local regulations on reporting releases. Protective equipment Review Fire Fighting Measures and Handling (Personnel Protection).sections before proceeding with dean- up.Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. SECTION 7.HANDLING AND STORAGE Handling DO NOT get in eyes, on skin, or on clothing. Avoid breathing vapours or mist. Wear approved respirators if adequate ventilation cannot be provided Wash thoroughly after handling. Ingestion or inhalation :Seek medical advice immediately and provide medical personnel with a copy of this SDS.NEVER add water to acid Conditions for storage Sulfuric acid must be stored in containers or tanks that have been specially designed for use with sulfuric acid DO NOT add water or other products to contents in containers as violent reactions will result with resulting high heat, pressure and/or generation of hazardous acid mists. Keep containers away from heat, sparks, and flame. All closed containers must be safely vented before each opening.For more information on sulfuric acid teaks,truck tanks and tank cars including safe unloading information go to www.norfalco com. 2010 V6 NorFalco Inc. NorFalco Sales Inc. -� 77%-100%SULFURiCACID SECTION 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters _ACGLH(U.S.A.)2009 OSHA(U.S.A.) _Name CAS# TLV-TWA(ma/ne) PEL-TWA(mg/m') Sulfuric(Acid) 7664-93-9 0.2(thoracic fr.) 1 60 Deg Technical 7664-93-9 0.2(thoracic fr.) 1 66 Deg or 93%Technical 7664-93-9 0.2(thoracic fr.) 1 1.835 Electrolyte 7664-93-9 0.2(thoracic fr.) 1 98%Technical 7664-93-9 0.2(thoracic fr.) 1 99%Technical 7664-93-9 0.2(thoracic fr.) 1 100%Technical 7664-93-9 0.2(thoracic fr.) 1 Water 7732-18-5 Not established Not established ACGIH:Am,I—Conference ofGo—nwnral hWrnnial HM4nM OSHA:Ocarpatiand Safety wd Hea(di AdmwuhWkm Note- Sulfuric(Add):Exposure limits maybe different in other jurisdictions.NIOSH REL-TWA(510 hours):1 mglnV;IDLH:15 mg/m3. Consult local authorities for acceptable exposure limits. Engineering Controls Good general ventilation should be provided to keep vapour and mist concentrations below the exposure limits. Individual protection Chemical splash goggles;Full-length face shield/chernical splash goggles combination;Acid-proofgauntlet gloves, apron, and boots ; Long sleeve wool, acrylic, or polyester clothing ; Acid proof suit and hood ; Appropriate NIOSH respiratory protection. (7 �4M*MA In case of emergency or where there is a strong possibility of considerable exposure,wear a complete acid suit with hood,boots,and gloves.If acid vapour or mist are present and exposure limits may be exceeded,wear appropriate NIOSH respiratory protection. SECTION 9.PHYSICAL AND CHEMICAL PROPERTIES Physical State and Appearance Liquid(Oily;Clear to turbid) Odour Odourless -� Molecular Weight 98.08 Colour Colourless to light grey pH(1%soln/water) <1 Volatility <1(Butyl Acetate=1.0) Boiling Point 1930C to 327°C(3790F to 621°Il @ 760 nun Hg Vapour Density 3.4 Melting Point -35°C to I IOC(-31017 to 52°F) Dispersion Yes(Water) Vapour Pressure <0.3 nun Hg @ 250C(77°F) Solubility Yes(Water) <0.6 mm Hg @ 38°C(100 OF) GRADE Benina Point Freezing Point Specific Gravi DEG°C DEC OF DEG'C DEG OF 60 DEG TECHNICAL 193 380 -12 10 1.706 66 DEG or 93%TECHNICAL 279 535 -35 -31 1.835 1.835 ELECTROLYTE 279 535 -35 -31 1.835 98%TECHNICAL 327 621 -2 29 1.844 99%TECHNICAL 310 590 4 _ 40_ 1.842 T60%TECIIIVICAL 274 - 526 — 11 S 1 1.839 - - SECTION 10.STABILITY AND 2REACTIM" Stability Yes(Under normal conditions of ambiant temperature) Reactivity Reacts violently with water,organic substances and base solutions with evolution of heat and hazardous mists. Conditions to avoid Sources of ignition,Heat:Possibility of decomposition.Release of toxic gases and vapours(Sulfur oxides SO2, S03) Polymerization Polymerization will not occur. Materials to avoid Vigorous reactions with :Water;alkaline solutions ;Metals,metal powder;Carbides;Chlorates,Fulminates, nitrates;Picrates;Strang oxidizing,reducing,or combustible organic materials.Hazardous gases are evolved on contact with chemicals such as cyanides,sulfides,and carbides. Corrosivity Yes SECTION 11.TOXICOLOGICAL INFORMATION Routes of Entry Ingestion. Inhalation.Skin and eye contacts. Carcinogenicity Strong inorganic acid mists containing sulfuric add(Occupational exposures):PROVEN (Human,Group 1, IARC) ; SUSPECTED(Human,Group A2,ACGIH) ;Group X(NTP) ;Classification not applicable to sulfuric acid and sulfuric acid solutions. Mutagenicity Cytogenic analysis:Ovaries 4 mmol/L(Hamster).(RTECS). 2010 3/6 NorFalco Inc. NorFalco Sales Inc. -\ 77%-100%SULFURIC ACID /) Teratogenicity Not teratogenic(Mice,rabbits). Acute toxicity ORAL(LD50) : 2 140 mg/kg(Rat);INHALATION(LC50,2 hours) :510 mg/m3(Rat) ; 320 mgW(Mouse). (RTECS). Acute Effects May be fatal if inhaled or ingested in large quantity.Liquids or acid mists:May produce tissue damage:Mucous membranes(Eyes,mouth,respiratory tract).Extremely dangerousby eyes and skin contact (Corrosive): Severe irritant for eyes :Inflammation(Redness,watering,itching).Very dangerous in case of inhalation(Mists)at high concentrations:May produce severe irritation of respiratory tract(Coughing,shortness of breath,choking?; Chronic Effects Target organs for acute and chronic overexposure(NIOSH 90-117):Respiratory system,eyes,skin,teeth. Add mists : Overexposure to strong inorganic mists containing sulfuric acid : Possibility of laryngeal cancer (HSBD,IARC).Possibility of irritation of the nose and throat with sneezing,sore throat or runny nose.Headache, nausea and weakness.Gross overexposure:Possibility of irritation of nose,throat,and lungs with cough,difficulty breathing or shortness of breath. Pulmonary edema with cough, wheezing, abnormal hmg sounds, possibly progressing to severe shortness of breath and bluish discoloration of the skin.Symptoms may be delayed.Repeated or prolonged exposure to mists may cause-.Corrosion of teeth. Contact(Skin) : Possibility of corrosion, bums or ulcers. Contact with a 1 % solution:Possibility of slight irritation with itching,redness or swelling. Repeated or prolonged exposure(Mist) :Possibility of irritation with itching,burning,redness,swelling or rash. Contact(Eye) : Possibility of contusion or ulceration(Blindness may result). Repeated or prolonged exposure (Mist) :Possibility of eye irritation with tearing,pain or blurred vision. Ingestion: Immediate effects of overexposure :Burns of the mouth,throat,esophagus and stomach,with severe pain,bleeding,vomiting,diarrhea and collapse of blood pressure.Damage may appear days after exposure. Tordeity Persons with the following pre-existing conditions warrant particular attention: Sulfuric(Acid):Laryngeal irritation. Eating, drinking and smoking must be prohibited m areas where this material is handled and processed Wash hands and face before eating,drinkng and smoking. SECTION 12.ECOLOGICAL INFORMATION Ecotoxicity Aquatic toxicity:Slightly to moderately toxic. _J $luegill Sunfish(LC50 ; 48 hours) : 49 mg/l(Tap water, 20°C,conditions of bioessay not specified). J (HSBD). Flounder(LC50;48 hours):100-330 mg/1(Aerated water,conditions of bioessay not specified).(HSBD). Toxicity to Animals Toxicity to aquatic life increases with lowering pH.At pH lower than 5,only a few fish species can survive and at pH lower than 4,aquatic life is rare. EYE:Concentrated compound is corrosive.10%solution: Moderate eye irritant. SKIN:Concentrated compound is corrosive.10%solution: Slight skin irritant. Single and repeated exposure:Irritation of the respiratory tract;Corrosion of the respiratory tract;Lung damage;Labored breathing;Altered respiratory rate;Pulmonary oedema.Repeated exposure:Altered red blood cell count. Mobility(Soil) Easy soil seeping under rain action Persistence and degradability Sulfate ion:Ubiquitous in the environment.Metabolized by micro-organisms and plant& Bloaccumulation Sulfate ion : Ubiquitous in the environment. Metabolized by micro-organisms and plants without biaeecu m lation. Biodegradation Products Not available Biodegradation Products(Toxicity) Not applicable Remarks on Environment Due to the product's composition,particular attention must be taken for transportation and storage.Protect from rain because the run-off water will became acidic and may be harmful to flora and fauna. BOD5 and COD Not available SECTION 13.DISPOSAL CONSIDERATIONS Disposal methods Cleaned-up material maybe an hazardous waste on Resource Conservation and Recovery Ad(RCRA)on disposal due to the contusivity characteristic. DO NOT flush to surface water or sanitary sewer system Comply with Federal,State,and local regulations.If approved,neutralize and transfer to waste treatment system. SECTION 14.TRANSPORT INFORMATION TDC(Canada) CLASS 8 Corrosives PIN UN1830 SULFURIC ACID PG II r` Special Provisions(Transport) None_ r DOT(U.S.A.)tIMO(Maritime) Proper Shipping Name SULFURIC ACID \ Hazard Class 8 /) UN NO 1830 2010 4/6 NorFalco Inc. NorFalco Sales Inc. 77%-100%SULFURIC ACID DOT/I1N0 Label CORROSIVE Packing Group II Reportable Quantity 10001bs(454 kg) Shipping Containers Tank Cars,Tank Trucks,Vessel ERG Guide 137 SECTION 15 REGULATORY INFORMATION Labelling(EEC) EU(Directive 67/548/EEC): Sulfuric(Add):C Corrosive(Pictogram) Annex I Index number:016-020-00-8;EU Consolidated hiventor➢es:EC Number 231-639-5 C>15% C;R35;S2,26,30,45. Risk Phrases(EEC) R35-Causes severe burns Safety Phrases(EEC) S26-In case of contact with eyes,rinse immediately with plenty of water and seek medical advice S30-Nerver add water to this product S36/37/39-Wear suitable protective clothing,gloves and eye/faoe protection S45- In case of accident or if you feel unwell,seek medical advice immediately(show the label where _..possible), CEPA DSL(CANADA) CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) : On the Domestic Substances list (DSL);Acceptable for use under the provisions of CEPA. Sulfuric Acid is a Class B Drug Precursor under Health Canada's Controlled Drugs and Substances Act and Precursor Control Regulations. Regulations(U.S.A.) CERCLA Section 103 Hazardous substances(40 CFR 302.4);SARA Section 302 Extremely Hazardous Substances(40 CFR 355) : Yes; SARA Section 313, Toxic Chemicals (40 CFR 372.65); US:TSCA Inventory:listed: Sulfuric(Add)(Final RQ): 1 000 pounds(454 kg) Sulfuric Acid is subject to reporting requirements of Section 313,Title III of the Seg erfmdAmendments and Reauthorization Act of 1986(SARA).40 CFR Pat 372. Certain companies must report emissions of Sulfuric Acid as required under The Comnrehensiye 1 AnyironaMM Response.Compensation and Liability Act of 1980 fCERCLA) 40 CFR Part 302 - For more information call the SARA Hotline 800-424-9346. Strong Inorganic Acid Mists Containing Sulfuric Acid:Chemical listed effective March 14,2003 to the State gfC Ubmia.Proposal 65, U.S. FDA Food BWerrorism Regulations : These regulations apply to Sulfuric Acid when bang distributed,stored or used for Food or Food Processing. TSCA(EPA,Toxic Substance Control Act)Chemical Inventory(40 CFR710):Listed Sulfuric(Add) Classifications HCS(U.S-A-) Corrosive liquid NFPA(National Fire Protection Association)(U.S.A.) � -.�R . � � Special Hazard ACID WNW SECTION 16.OTHER INFORMATION References -TLVs and BEls(2009).Based on the Documentation of the Threshold Limit Values for Chemical Substances and Physical Agents&Biological Exposure Indices.ACGIH,Cincinnati,OH-httpl/www.acgULorg -CCOHS (2009)-Canadian Centre for Occupational Health and Safety-httpJ/www.ccohs.ca/ -CSST(2009)-Commission de la Stnte et de la Sdourite du Travail(Qu&ec).Service du rdpertoire toxicologique- httpJ/www.Mtox.c sst.gc.ca/ -ERG(2008).Emergency Response Guidebook,U.S.Department of Transportation,Transport Canada,et le Secretariat of Communications and Transportation of Mexico -HSDB(2009)-Hazardous Substances Data Bank.TOXNM Network of databases on toxicology,hazardous chemicals,and environmental health.NLM Databases&Electronic Resources,U.S. National Library of Medicine,NHI,8600 Rockville Pike, Bethesda,MD 20894-http://tomoLnlmnih.gov/cgi-bin/sis/htinlgen?HSDB -ESIS:C&L(Classification and Labelling),substances or preparations in accordance with Directive 67/548/EEC(substances)and 1999/45/EC(preparations), -ESIS:EINECS(European Inventory of Existing Commercial chemical Substances)O.J.C 146A,15.6.1990 -ESIS:EINECS corrections published in O.J.C 54113 01.03.2002,2002/C54/08. \ -IARC-Monographs on the Evaluation of Carcinogenic Risks to Humans(collection)-httpJ/www-cic.iarc.fr/ -Merck Index(1999). Merck&CO.,Inc,12th edition 2010 516 NorFalco Inc. NorFalco Sales Inc. - '� 77%-100%SULFURIC ACID -NIOSH U.S.(2009)-Pocket Guide to Chemical Hazards-http!/www.cdc.gov/niosh/upgf -Pattys Industrial Hygiene and Toxicology,3rd Revised Edition -Reglement sur les produits contr6les(Canada) -RTECS(2009).Registry of Toxic Effects of Chemical Substances,NIOSH,CDC -Toxicologic industrielle&intoxication professionnelle,3e edition,Lauwerys -TSCA(2009)-U.S.EPA Toxic Substance Control Act,Chemical Inventory.System of Registries(Solt),Substance Registry Services,httpJ/iaspub.epa.gDv/sot intemet/registry/substreg/searchandretrievetsubstancescench/swnh.do Glossary CSST :Commission de la Sant6 et de la S6curit6 du Travail(Quebec). HSDB :Hazardous Substances Data Bank. IARC :International Agency for Research on Cancer. NIOSH :National htstitute of Occupational Safety and Health. NTP :U.S.National Toxicology Program. RTECS :Registry of Toxic Effects of Chemical Substances Note For further information,see NorFalco Inc.Sulfuric Acid«Storage and Handling Bulletin». Because of its corrosive characteristics and inherent hazards,Sulfuric Acid should not be used in sewer or drain cleaners or any similar application; regardless of whether they are formulated for residential,commercial or industrial use.NorFalco will not knowingly sell sulfuric acid to individuals or companies who repackage the product for sale as sewer or drain cleaners,or any other similar use. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. For additional information,please visited our website: -ww,norfh1co.cotn Written by:Groupe STEM Consultants/NorFalco Sales Inc. Complete revision:2010-01-24 Partial review:None Previous complete revision:2009-01-24 Verilled by: Guy Desgagn6s and Eric Kuraitis,Technical Representative-Sulfuric Acid Request to: Andr6 Auger,Administration Assistant Tel.:(905)542-6901 extension 0 Fax:(905)542-6914/6924 NorFalco Sales Inc.,6755 Mississauga Road,Suite 304,Mississauga,Ontario L5N 7Y2 Notice to Reader Although reasonable precaudem have been taken in the preparation of the data contained herein,it is offered solely for your informathm,consideration and tuvwhgation.N"Falco Saks lnavaeuds no warranty and assumes no responsibility for the accuracy of the content and egrressly disclaims all liability for reliance thereon.An material safety data sheet provides guideibus for the safe handing mtd processing of this product•,is does not and cannot advise an all passible situations,therefom your spectfrc use of thin product should be evaluated to determine ifadditional precautions are required Individuals exposed to this product dhould read and understand this information aul be provided pertinent training prior to wonting with this product. 2010 6/6 t 20 2008 17: 04 HP LRASEERJET FAX r Paw. CA •,x__. 40 V Methanol MET •M.s'II.t..'fnrvN MATERIAL SAFETY DATA SHEET This Msterla/Safety Date Sheet complies wkh the Canadian CanfrWied Product Reeuladons and the UnJted States OcagwWonaf Safety and Health Adm/nlstration(OSHA) hazard communlcat/on standard. 1. Product and.Supplier Identification Product: Methanol(CH'OH) Non-Emergency Tel.# (604)661-2600 Synonyms: Methyl alcohol,methyl Emergency Tel.0: 1-600-424-9300 hydrate,wood spirit,methyl (CHEMTREC) (Canadv and US) hydroxide Product Use; Solvent,fuel,feedstock Company Methonex Corporation, Note;CHEMTREC number to be urged only In Identification; 1900 Waterfront Contra, the event of chemical emergencies involving a 200 Burrard Street, spill,leak,fire,exposure or accidane involving Vancouver,B.C, chemicals. VGC 3M1 Importer: Methanex Methanol Company Suits 1160-,16301 Dallas Parkway Addison,Texas 75001 Telephone:(972)702-0909 2. Composition Component %(w/w) ExposureLimite LDw LC,a Methanol 99.100 ACOIH TLV TWA:200 ppm,skin ms mgft 64WO ppm CAS 67-56-1 Ste-=�ppm,skin notation ( OSHA PEL;200 ppm (orelrrat) (Inhalation/rot) TLV Bask,critical effects; Y0 m114 neuropathy,vision, certtrel laem,au --� ----^^ terrors system rabbit •Exposure limits may vary from time to time and from one jurisdiction to another.Check with local regulatory agency for the exposure limits In your area. Disidbuted by HUBBARD-HALL INC. METALS rI=STING COMpAN}r �"okso"M �;l;';; REVIEWED BY w-*"P.MA 01017�e n&'%&ne WMigro,,IAA OIt1/ 01l1Bfilf1077 DATE- / ---....� `\ Methanex Corporation -1- October 13,2006 Oot 20 2008 17: 04 HP LRSERJET FHX P. 2 r I Methanol MATH �x 3. Hazards identification Routes of Entry: Skin Contact Moderate Eye Contact:Moderate Ingestion:Major inhalation:Mayor Effeets of Short Term(Acute)Exposure: Inhalation:Inhalation of high airborne concentrations can also innate mucous membranes,cause headaches,sleepiness,nausea,confusion,loss of consciousness,dlgesUvo and vlsuai disturbances and even death.NOTE;Odour threshhold of methanol Is several times h Igher than the TLV-TWA. Depending upon severity of poisoning and the promptness of treatment survivors may recover completely or may have permanent blindness,vision disturbances and/or nervous System effects.Concentrations In air exceeding 1000 ppm may cause Irrltallon of the mucous membranes. Skin Contact: Methanol Is moderately Irritating to the skin.Methanol can be absorbed through the skin and harmful effects have been reported by this route of entry.Effects are slmlair to those dosorlbed In'Inhalation" Eye Contact:Methanol Is a mlld to moderate eye irritant. High vapour coneentration or liquid contact with eyes causes Irritation,tearing and burning. Ingestion:Swallowing even small amounts of methanol could potentially cause blindness or _ death. Effects of sub lethal doses may be nausea,headache,abdominal pain.vomiting and visual 1 disturbances ranging from blurred vision to light sensitivity. J Effects of Long Terns(Chronic)Exposure:Repeated exposure by inhalation or absorption may cause systemic poisoning,brain disorders,impalMd vision and blindness.Inhalation may worsen conditions such as emphysema or bronchitis.Repeated skin Contact may cause dermal Irritation. dryness and cracking. Medical Conditions Aggravated By Exposure.,Emphysema or bronchitis_ 4. First Aid Measures —� Note.Emergency ass/sfeme may also be available from tho/ooarpason 02ntrd centre. Eye Contact.,Remove content lenses Nworn.In ease of contact,Immediately nuah eyes with plenty of clean running water for at least 15 minutes,lifting the upper and lower eyelids occasionally.Obtain medical attention. Skin Contact: in case of contact, remove contaminated clothing.In a shower,wash affected areas with 502p and water for at least 15 minutes.Seek medical attention 11 irritation occurs or persists.Wash clothing before reuse, Inhalation:Remove to fresh air,restore or assist breathing if necessary, Ootaln medical attention. Ingestion: Swallowing MGM211101 i9 potentially Ufa threatening.Onset of symptoms may be delayed for 19 to 24 hours after digestion,if conscious and medical old is not immediately ` Methanex Corporation -2- October 13, 2005 Oct 20 2008 17304 HP LRSERJET FAX 1 Methanol M Ei" X •..vu,w a-:,nrw available,do not Induce vomiting,in actual or suspected cases of Ingestion transport to medical facility Immediately. NOTE TO PHYSICIAN:Acute exposure to methanol,Blither through Ingestion or breathing high airborne concentrations can result in symptoms appearing between 40 minutes and 72 hours after exposure. Symptoms and signs are usually limited to CN3,eyes and gastrointestinal tract. Because of the Initial CNS's eflecla of headache,vertigo,lethargy and confusion,there may be an impression of ethanol intoxication. Blurred vision,decreased acuity and photophobla are common complaints. Treatment with Ipecac or tavage Is indicated in any Patient preaenting within two hours of ingestion. A profound metabolic acidosis occurs in severe poisoning and serum bicarbonate levels are a more accurate measure of severity than serum methanol levels. Treatment protocols are available from most major hospitals and early collaboration with approprlato hospitals is recommended. 5. Fire Fighting Measures Flesh point: 11°C(TCC) Autolgnitlon temperature; 389°C(NFPA 1978),470°C(Kirk•.Othmer 1881i Ullmann 1975) Lower Explosive Limit: 8%(NFPA, 1978) Upper Explosion Llmtt: 36%(NFPA. 1978),38.8%(Ullm211n, 1975) 84naltivity to Mapect; LOW Sensitivity to Made Discharge: LOW Hazardous Combustion Products: Toxic Vases and vapours:oxides of carbon and formaldehyde. Exttnigulshing Media, Small fires:Dry chemical,CO2,water spray Large fires:Water spray,AFFF(R)(Aqueous Film Forming Foam(alcohol reslatant))type with either a 3%or 5%foam proportioning System. Fire Fighting Instructlonst Methanol burns with a clean dear dame that Is almost Invisible In daylight,Stay upwind!Isolate and ract►Iot area access.Conoentralions of greater that 25% methanol In Water can be ignited.Use Me water spray or fog to control fire spread and cool adjacent abucturea or containers.Contain firs control water for later disposal. Fire fighters must wear full face,positive pressure,self-contained breathing apparatus or airline and a9ppropri2te protective clothing.Protective fire fighting structural arfottling is not effective protection from methanol. Do not walk through spilled product. NATIONAL FIRE PROTECTION ASSOCIATION(NFPA)HAZARD INDEX: HEALTH:1 FLAMMABILITY:3 REACTIVITY:0 6. Accidental Release Measures Overview: Flammable Ii uld which can burn without a visible flame.Relearns can cause an Immediate risk of fire and explosion.ElIMInate all ignition sources,stop leaf;and use absorbent materials.If necessary,contain spill by diking.Fluorocarbon alcohol reslativit foams maybe applied to spill to diminish vapour and fire hazard. MeximlZe methanol reoo•/ery for recycling or re-use.Restrict access to area until completion of cleanup.Ensure cleanup Is conducted by Mefhapnsx Corporation .3- October 13, 2005 Oct 20 2008 17: 04 HP LRSERJET FAX p. 4 _ Methanol MET ♦wNM,aM LiYMgnf trained personnel only.Wear adequate personal protection and remove all sources of ignition. No"all governmental agencies as required by law, Personal Protection:Full face,positive pressure self-contained breathing apparatus or airline, and protective clothing must be worn.Protective fire fighting structural clothing la not effective Protection from methanol. Environmental Precautions:Biodegrades easily in water Methanol in fresh or salt water may have serious effects on aquatic life.A study on methanol'@ toxic efffeate on sewage sludge bacteria reported little effect on digestion at 0.1%white 0.6%methanol retarded digestion. Methanol will be broken down to carbon dioxide and water. Remedial Measures:Flammable liquid.Release can cause an immediate flre/exploolon hazard. Eliminate all sources of Ignition,stop leak and use absorbent materials.Collect liquid with explosion proof pumps.Do notwalk through spill product as it may be on fir and not visible. Large Spills:IF necessary, contain spill by diking.Fluorocarbon alcohol resliftant foams may be applied to spill to diminish vapour and fire hazard,Ma)drNze methanol recovery for recycling or rouse.Collect liquid with explosion proof pumps. Small Spilie:Soak up spill with non-combustible absorbent material.Recover methanol and dilute with water to reduce fire hazard.Prevent spl led methanol from entering sewers,confined spaces, drains,or waterways.Restiet access to unprotected personnel.Full.Put mitterial In suitable, covered,labeled containers.Flush area with water. 7. Handling and Storage ') Handling Pr000dures: No smoking or open flame In storage,use or handling areas. Use explosion proof electrical equipment Ensure proper electrical grouding procedures are in place. Storage:Store In foully enclosed equipment,dealgned to avoid ignition and human contact, Tanks must be grounded,vented,and should have vapour emission controls.Tanks must be diked.Avoid storage with Ineompatlble materials,Anhydrous methanol is non-corrosive to most metaia at ambient temperatures except for lead,nickel,mono[,ceet Iron and high silicon Iron. Coatings of copper(of copper alloys),zinc(including gpivenrzed staen,or aluminum are unsuitable for storage.These materials may be attacked slowly by the methanol,Storage tanks of welded construction are normally satisfactory.They should be designed and built In conformance with good engineering practice for the material being stored.While pleatics Can be used fof short term storage,Moy are generallY not recommended for longterm storage title to deterloratlon effects and the subsequent rink of Contamination. Corrosion rates for several construction materlelgi: c0.506 mmyear Cast Iron,morel,lead,nickel c0.05'1 mmlyear High sHloon Iron Some attack Polyethylene Satlefiectory Neoprene,phenolic resins,polyesters,natural rubber,butyl rubber Resistant Polyvinyl chloride,unplastkrized 8. Exposure Controls,-Personal Protection Engineering Controls:In confined areas,local and general ventilation should be provided to maintain elrboms concentratlons bsloew pormisEable exposure limits.Ventilation systems must be designed according to approved engineering otandarde. \ Methanex Corporation -4- October 13, 2005 Oct 20 2008 17: 04 HP LRSERJET FAX P. 5 _ Methanol MITkif X I u'N ftftwk' r Respiratory Protection:NI08H approved supplied air respirator when airborne concentmilons exceed exposure limits. Skin protection;Butyl and nitrile rubbers are recommended for gloves.Check with manufacturer.Wear chemical resistant pants and Jackets,preferably of butyl or nitrlle rubber. Check with manufacturer. Eye and Face Protection;Face shield and chemical splash gaggles when tranaferrin®is taking place. Footwear:Chemical resistant,and as specified by the workplace. Other:Eyewash and showers should be located near work areas. NOTE:PPE must not be considered a long-term solution to exposure control,PPE usage must be accompanied by employer programs to properly select,maintain,dean,fit and use.Consult a competent Industdal hygiene resource to determine hazard potential and/or the PPE manuracturers to ensure eadequata protection. 9. Phyelcal and Chomlcal Pro ertles Appearance:Liquid,clear,colourless Bolling Point: 64.7°C @ 101.3 kPa Odour:Mild characterlstle alcohol odour GrNieal Temperature! 239.4°C Odour Threshold:4etedion.4.2.5960 ppm Relative Denelty:0.791 (geometric mean)ISO ppm Evaporation Rote:4.1 (n-butyl acetate a1) rec oodon:83—BM ppm (geometric moan)6e0 ppm Partition Coefficient-Log P(oct)=.0.82 —\ pH:Not applicable p Solubility In other Liquids: Soluble in all Vapour Preasurs: 12.8 We Q 20 C proportions In other alcohols,esters, folubllity:Completely soluble Vapour Denettyl 1.106 4116 90 katoneo,ethers and most other organic Freezing Point:-97,3°C solvents 10. Stabillty and Reactivlty Chemical Stablllty; Yes Incompatlblllty: Yes.Avoid contact with strong oxidizers,atrong mineral or organic acids, and strong bases.Contact with these materiels may cause a violent or expio6lve re80110n, May be 00frosive to lead,aluminum,magnesium,and platinum. Conditions of Reactivlty:Presence of incompatible materials and ignition sources. Hazardous becomposldon Producol Formaldehyde,carbon dioxide,and carbon monoAde. Hazardaus Polymerizatlona Will not odour, Methanex Corporation -5- Ootaber 13, 2006 Oct PO 2008 17: 04 HP LRSERJET FADS P. 6 _l J Methanol Ml i NEx •.h,.rr�l.H•r M-im 11. Toxicologic if Information LDS: 5525 mg/kg(oraUret),20 mUkg(demlal/rabbli) ACUb 8 64000 ppm(rat) Exposure: See Section 3 Chronic Exposure: Sao Seehon 3. Exposure Limits: See Section 2. Irritency; See Section 3. Sensitization: No Carcinogenicity: Not listed by IARC,NTP,ACGIH,or OSHA as a Carcinogen. Teratogenloltyl No Reproductive toxicity: Reported to cause bldh defects in rats exposed to 20.000 ppm Mutageniclty: In5uffldant data Synergistic products: None Known 12. Ecological Information Environmental toxicity:Methanol in fresh or salt water may have serloUs affects on aquatic life. A study on methanol'a toxic effects on sewage sludge bacteria reported paid effect on digestion at 0.1%while 0.5%methanol retarded digestion.Methanol will be broken dow-1 Into carbon dioxide and water,. Biodegradability:Biodegrades easily In water. 13. Disposal Consideration s ns Review federal,provincial or state,and local government requirements prior to disposal.Store material for disposal as indicated in Section#7,Handling and Sfomgs. DlOposai by controlled Incineration or by secure land fill may be acceptable. 14. Trani ort Information Transport of Dangerous Goods(TOG and CLR): Methanol,Class 3r6.1). UN1230.P.G.II Limited Quantity,:;1 litres (inked States Department of Transport(49CFR): Methanol,Class 3 UN 1230. P.G.11, (Domestic Only) (RQ 3000 lbs/2270 kg) Llml(ed Quantity; 1 Iltmg International Air Transport Association(IATA): Methanol.Class 3�6.1),UN1230,P.G.11 Packaging Instruclion:305, 1 litre maximum per package, International Madill meOrganization(IMV); Methanol,Class 3(a.1),UN1230,P.O.II, Flash Point.-12°I; EmS No.F-E,8-0 Stowage Category W,Clear of living Quarters 1 Mathanex Corporation -e- October 13. 2005 Oct E0 2008 17: 04 HP LASERJET FAX P. 7 . Methanol M[r" lx •,..,,nth 4-'T'. 15. Regulatory infonnativn CANADIAN FEDERAL REGULATIONS: CEPA,DOMESTIC SUBSTANCES LIST. Listed WHMIS CLASSIFICATION: B2,D1A UNITED STATES REGULATIONS: 29CFR 1910.1200(OSHA): Hazardous 40CFR 116-117(EPA): Hazardous 40CFR 355.Appendices A and e: Subject to Emergency Planning and Notiflcatlon 40CFR 372(SARA Title III): Listed 40CFR 302(CERCLA)- Listed 1S. Other Information Preparation Date:October 13,2006 Prepared by: Kel wx Agenciao Ltd.,P.O.Box 62201.Lynnmour RPO,North Vancouver,B.C.,V7J 3V8 DInclalmer.The Information above is believed to be accurate and represerta the best Informatlon cunently available to us. Users should make their own investigations to determine the.sultablllty of the Information for their particular purposes. This document le Intended as a guide to the appropriate preosutionary handling orthe material by a properly trained person using this product, Methenex Corporation and Its subsidiaries make no representations or warranties, either express or implied,including without limitation any warranllev of merchantability,fitness for a particular purpose with respect to the Information set for01 herein or the product to which the Infonnatlon refera. Accordingly, Msthanex Corp.will not be responsible for damages resulting from use of or reliance upon this Information. Revisions:None Methenex Corporation -7- October 13,2005 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF4301 IDH No.598364 * * * Section 1 - Chemical Product and Company Identification Product Trade Name TURCO VITRO-KLENE Manufacturer Information Henkel Surface Technologies Contact Phone:(248)583-9300 Henkel Corporation 32100 Stephenson Highway Chemtrec Emergency#(800)424-9300 Madison Heights,MI 48071 * * * Section 2 - Composition / Information on Ingredients CAS# Component Percent 6834-92-0 Sodium metasilicate 30-60 1310-73-2 Sodium hydroxide 10-30 Mixture Sodium phosphate,tribasic 1-10 7722-88-5 Tetrasodium pyrophosphate 1-10 Proprietary Rosin soap 1-10 * * * Section 3 - Hazards Identification Emergency Overview: DANGER—CORROSIVE!Contact with this material will cause bums to the skin,eyes and mucous membranes. Avoid breathing dusts. Eye Contact: Contact with the eyes can cause severe burns and permanent eye damage. Skin Contact: Contact with the skin or mucous membranes will cause severe burns and possible ulceration. Ingestion: Not a likely route of entry. Ingestion may produce bums to the lips,oral cavity, upper airway, esophagus and possibly the digestive tract. Inhalation: Inhalation of dusts of this product may cause severe irritation and bums to the respiratory tract. Medical Conditions Aggravated by Exposure: Pre-existing eye,skin and res irato disorders. * * * Section 4 - First Aid Measures Eye Contact: In case of contact with the eyes, rinse immediately with plenty of water for 15 minutes, and seek immediate medical attention. Skin Contact: For skin contact flush with large amounts of water while removing contaminated clothing. Discard any shoes or clothing items that cannot be decontaminated. If irritation persists,get medical attention. Ingestion: If the material is swallowed, get immediate medical attention or advice—Do not induce vomiting. Give one to two glasses of water or milk. Never give anything by mouth to a victim who is unconscious or is having convulsions. Inhalation: Move person to non-contaminated air. If not breathing,give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen.Seek medical attention. * * * Section 5 - Fire Fighting Measures I WETALS TESTING MP R Page 1 of 6 Issue Date: 10/13/06 Revision: 1.0114C 8Y / Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF4301 IDH No.598364 Flash Point: Not applicable Method Used: Not applicable Flammability Not applicable Classification: Upper Flammable Not applicable Lower Flammable Not applicable Limit(UFL): Limit(LFL): Fire & Explosion Hazards: This material will not bum. Extinguishing Media: Use any media suitable for the surrounding fires. Fire-Fighting Instructions: Fire fighters should wear full-face, self contained breathing apparatus and impervious protective clothing. Fire fighters should avoid inhaling any combustion products. * * * Section 6 - Accidental Release Measures Containment Procedures: Stop the flow of material, if this is without risk. Contain the discharged material. Block any potential routes to water systems. Isolate area. Keep unnecessary personnel away. Clean-Up Procedures: Sweep up or gather material and place in appropriate container for disposal. Flush area with water to remove trace residue. Dispose of collected material according to regulation. * * * Section 7 - Handling and Storage Handling Procedures: Do not get this material in your eyes,on your skin, or on your clothing. Use this product with adequate ventilation. Do not breathe dust from this material.Wash thoroughly after handling. Do not reuse the empty container. Considerable heat is generated when water or acid is added,therefore when making solutions always add the caustic to the water or acid with.constant stirring. If caustic substance or solution becomes concentrated in one area, or if added too rapidly or if added to hot or cold water a rapid temperature increase can result in dangerous boiling water and/or splashing or may cause immediate violent eruption. Storage Procedures: Keep the container tightly closed and in a cool,well-ventilated place. * * * Section 8 - Exposure Controls I Personal Protection Exposure Guidelines: A: General Product Information Follow all applicable exposure limits. B: Component Exposure Limits Sodium hydroxide (1310-73-2) ACGIH: 2 mg/m3 Ceiling OSHA: 2 mg/m3 TWA NIOSH: 2 mg/m3 Ceiling Tetrasodium pyrophosphate (7722-88-5) NIOSH: 5 mg/m3 TWA Engineering Controls: Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. PERSONAL PROTECTIVE EQUIPMENT As prescribed in the OSHA Standard for Personal Protective Equipment(29 CFR 1910.132), employers must perform a Hazard Assessment of all workplaces to determine the need for,and selection of, proper protective equipment for each task performed. Eyes/Face Protective Equipment: Wear chemical goggles. 1 Page 2 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE 1D: 238853DLF4301 IDH No.598364 Skin Protection: Use impervious gloves. Use of impervious apron and boots are recommended. Respiratory Protection: If ventilation is not sufficient to effectively prevent buildup of dust, appropriate NIOSH/MSHA respiratory protection must be provided. Work Practices: Eyewash fountains and emergency emergen2y showers are required. * * * Section 9 - Physical & Chemical Properties Physical State: Solid,granular mbdure Appearance: Brown Odor: Vapor Pressure: Not applicable Vapor Density: Not applicable Boiling Point: Not applicable Melting Point: Not established Specific Gravity: Not applicable pH: (5%solution)->12.0 Viscosity: VOC: Not applicable Solubility Water. Soluble Percent Volatile: Not applicable * * * Suction 10 - Chemical Stability & Reactivity Information Chemical Stability: Stable under normal conditions. Conditions to Avoid: Avoid contact with water.Avoid dispersion of dust in air.Avoid contact with acids. Incompatibility: This product reacts with acids. .- Decomposition Products: None identified. Hazardous Polymerization: Will not occur. * * * Section 11 - Toxicological Information Acute Toxicity: A: General Product Information Sodium hydroxide is an alkaline corrosive that results in severe irritation and bums to the eyes,skin, respiratory system,and gastrointestinal system.Sodium hydroxide has been implicated as a cause of cancer in humans. However,this may be a secondary effect of the tissue destruction and scar formation caused by sodium hydroxide. Embryotoxicity in rats may be attributed to an alteration of pH in the amniotic fluid rather than the sodium hydroxide itself. B: Component Analysis -LD50/LC50 Sodium metasilicate(6834-92-0) Oral LD50 Rat: 600 mg/kg Sodium hydroxide(1310-73-2) Dermal LD50 Rabbit: 1350 mg/kg Sodium phosphate,tribasic(Mixture) Oral LD50 Rat: 3100 mg/kg; Dermal LD50 Rabbit: >7940 mg/kg Tetrasodium pyrophosphate(7722-88-5) Oral LD50 Rat:4 g/kg Page 3 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name:TURCO VITRO-KLENE ID: 238863DLF4301 IDH No. 698364 Carcinogenicity: A: General Product Information No information available for the product B: Component Carcinogenicity None of this products components are listed by ACGIH, IARC,OSHA, NIOSH, or NTP. Chronic Toxicity No information available for the product Epidemiology: No information available for the product. Neurotoxicity: No information available for the product Mutagenicity: No information available for the product Teratogenicity: No information available for the product Other Toxicological Information: None available. * * * Section 12 - Ecolo icaI Information Ecotoxicity: A: General Product Information No data available for this product. B: Component Analysis -Ecotoxicity-Aquatic Toxicity Sodium metasilicate (6834-92-0) `\ Test&Species Conditions J 96 Hr LC50 Brachydanio rerio 210 mg/L[semi- static] 96 Hr EC50 Daphnia magna 216 mg/L Sodium hydroxide (1310-73-2) Test&Species Conditions 96 Hr LC50 Oncorhynchus mykiss 45.4 mg/L[static] Sodium phosphate,tribasic (Mixture) Test&Species Conditions 48 Hr LC50 Leuciscus idus 1650 mg& Environmental Fate: No data is available concerning the environmental fate, biodegradation or bioconcentration for this product. * * * Section 13 - Disposal Considerations US EPA Waste Numbers & Descriptions: A: General Product Information Material, if discarded, is not expected to be a characteristic hazardous waste under RCRA. B: Component Waste Numbers No EPA Waste Numbers are applicable for this products components. Disposal Instructions: Dispose of waste material according to Local, State, Federal,and Provincial Environmental Regulations. - 1 Page 4 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238853DLF430/IDH No.598364 * * * Section 14 - Transportation Information US DOT Information Shipping Name: Please refer to the container label for transportation information. * * * Section 15 - Re ulato Information US Federal Regulations A: General Product Information This product is considered hazardous under 29 CFR 1910.1200(Hazard Communication). B: Component Analysis This material contains one or more of the following chemicals required to be identified under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 313(40 CFR 372.65)and/or CERCLA(40 CFR 302.4). Sodium hydroxide (1310-73-2) CERCLA: 1000 lb final RQ;454 kg final RQ Sodium phosphate,tribasic (Mixture) CERCLA: 5000 lb final RQ(listed under Sodium phosphate,tribasic);2270 kg final RQ(listed under Sodium phosphate,tribasic) SARA 3111312: Acute: Yes Chronic: Yes Fire: No Pressure: No Reactive: No State Regulations A: General Product Information No additional information available. lB: Component Analysis-State -- The following components appear on one or more of the following state hazardous substances lists: Component CAS# ICA IFL IMAJIVIN INJ PA Sodium hydroxide 1310-73-2 Yes I No I Yes I Yes I Yes Yes Sodium phosphate,tribasic Mixture Yes No I Yes I No I Yes Yes Tetrasodium pyrophosphate 7722-88-5 Yes No I Yes I Yes I Yes Yes Other Regulations A: General Product Information All components are on the U.S. EPA TSCA Inventory List. B: Com onent Analysis -Inventory Component CAS# TSCA DSL EINECS Sodium metasilicate 6834-92-0 Yes Yes Yes Sodium h droxide 1310-73-2 Yes Yes Yes Sodium phosphate,tribasic Mixture Yes Yes Yes Tetrasodium pyrophosphate 7722-88-5 Yes Yes Yes Rosin soap Proprietary Yes Yes Yes C: Component Analysis -WHMIS IDL The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List: Component CAS# Minimum Concentration Sodium metasilicate 6834-92-0 1 % Sodium hydroxide 1310-73-2 1 % Tetrasodium pyrophosphate 7722-88-5 1 % * * * Section 16 - Other Information l Page 5 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet Material Name: TURCO VITRO-KLENE ID: 238863DLF430/IDH No.598364 NFPA Ratings:Health:3 Fire:0 Reactivity: 1 Hazard Scale: 0=Minimal 1 =Slight 2=Moderate 3=Serious 4=Severe HMIS Ratings: Health:3"Fire:0 Reactivity: 1 Hazard Scale: 0=Minimal 1 =Slight 2=Moderate 3=Serious 4=Severe *=Chronic hazard Key/Legend EPA=Environmental Protection Agency;TSCA=Toxic Substance Control Act;ACGIH=American Conference of Govemmental Industrial Hygienists; IARC=International Agency for Research on Cancer, NIOSH =National Institute for Occupational Safety and Health; NTP= National Toxicology Program; OSHA=Occupational Safety and Health Administration; NFPA=National Fire Protection Association; HMIS=Hazardous Material Identification System;CERCLA=Comprehensive Environmental Response, Compensation and Liability Act; SARA=Superfund Amendments and Reauthorization Act The information presented herein is believed to be factual as it has been derived from the works and opinions of persons believed to be qualified experts; however, nothing contained in this information is to be taken as a warranty or representation for which Henkel Surface Technologies bears legal responsibility. The user should review any recommendations in the specific context of the intended use to determine whether they are appropriate. Contact: Product Safety and Regulatory Affairs Contact Phone: (248)583-9300 This is the end of MSDS# 238853DLF430/IDH No. 598364 J Page 6 of 6 Issue Date: 10/13/06 Revision: 1.0114 Material Safety Data Sheet r WEGO CHEMICAL&MINERAL CORP 239 Great Neck Road Great Neck,NY 11021 Phone: (516)487 3510; email: sales@wegoehem.com Date of Revision:8/2007 TRISODIUM PHOSPHATE Section 1 - Chemical Product and Company Identification Product/Chemical Name:Trisodium Phosphate dodecahydrate Chemical Formula:Na3PO4.12H20 CAS Number: 10101-89-0 Other Designations: TSP;trisodium orthophosphate;sodium phosphate,tribasic;tertiary sodium phosphate;trisodium phosphate Derivation:Prepared by combining proper proportions of phosphoric acid and soda ash to form disodium phosphate,then adding caustic soda. General Use:Used in softening water,tanning leather,manuflicturing paper,elar*Ing sugar,In detergent mixtures,photographic developers,food additives,buffers,emulsifiers,dietary supplements,boiler water compounds,and industrial cleaners. Emergency Telephone:1-800424-9300(Chemtrec) Section 2 - Composition/Information on Ingredients Ingredient Name CAS Number EINECS/ELINCS %cot or%vol Trisodium Phosphate dodecahydrate 10101-89-0 231-509-8 100 Trace Impurities: OSHA PEL ACGIH TLV NIOSH REL NIOSH IngLvdient TWA STEL TWA STEL TWA STEL IDLH Trisodium 5 mg/m3 none estab. none estab. none estab. none estab. none estab. none estab. Phosphate Section 3 -Hazards Identification ***** Emergency Overview ***** H MIS MAY CAUSE EYE INJURY.CAUSES SKIN IRRITATION. MAY BE HARMFUL IF F 0 SWALLOWED. R 2 PPEt Potential Health Effects tsec.g Primary Entry Routes:Inhalation,ingestion or skin contact. Target Organs:Skin,digestive tract. Acute Effects Inhalation:May cause irritation of the respiratory tract with burning pain in the nose and throat,coughing,wheezing,shortness o breath and pulmonary edema. Eye:May cause severe eye irritation.May result in corneal injury. Skin:May cause severe irritation and possible burns. Ingestion:May cause severe gastrointestinal tract irritation with nausea,vomiting and possible burns. Carcinogenicity:IARC,NTP,and OSHA do not list Trisodium Phosphate as a carcinogen. Medical Conditions Aggravated by Long-Term Exposure: Chronic Effects:Prolonged or repeated eye and skin contact causes irritation.Injury to the esophagus from scarring may occur.Alkali exposures may necessitate irrigation for extended duration. Section 4-First Aid Measures Inhalation:Remove from exposure to fresh air immediately.Ifnot breathing,give artificial respiration.If breathing is difficult, give oxygen.Get medical aid. Eye Contact:Prolonged or repeated eye and skin contact causes irritation. Skin Contact:Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.Get medical attention if irritation develops or persists. "11 Ingestion:If victim is conscious and alert,give 24 cupfuls of milk or water.Never giye anything by mouth to an unconscious person.Get medical aid immediately. Afterfirst aid,get appropriate in-plant paramedic,or community medical support 4 METAL 5 'Ems'-1 l`G CO's,MPA � TRISODIUM PHOSPHATE 2 Note to Physicians:Treat symptomatically an supportively. Section 5 Fire-Fighting- Measures Flash Point:noncombustible NFPA Burning Rate:N/A (1 Autoignition Temperature:noncombustible LEL: N/A 2 1 UEL: N/A — Flammability Classification:noncombustible Extinguishing Media:Use what is appropriate to the surrounding fire since this material is noncombustible. Unusual Fire or Explosion Hazards:In a fire situation at high temperature,phosphates can emit highly toxic phosphorus oxides(PO,) flumes. Fire-Fighting Instructions:Do not release runoff from fire control methods to sewers or waterways. Fire-Fighting Equipment:Because fire may produce toxic thermal decomposition products,wear a self-contained breathing apparatus(SCBA)with a full facepiece operated in pressure-demand or positive-pressure mode. Section 6-Accidental Release Measures Spill/Leak Procedures:Cleanup personnel should wear the necessary personal protective equipment to prevent skin or eye contact and dust inhalation. Small Spills: Vacuum or sweep up material and place into a suitable disposal container. Large Spills Containment:Dilre with inert absorbent material,as needed,to contain and limit spill area.Sweep,vacuum,or scoop the spilled solid,avoiding dust generation,into a suitable disposal container(with secure lid).Do not release into sewers or waterways. Cleanup:Flush residues to drain with plenty of water. Regulatory Requirements:Follow applicable OSHA regulations(29 CFR 1910.120). Section 7-Handling and Storage Handling Precautions:Wash thoroughly after handling.Minimize dust generation and accumulation.Avoid contact with eyes, skin,and clothing.Keep container tightly closed.Avoid ingestion and inhalation. Storage Requirements:Store in a tightly closed container.Store in a cool,dry,well-ventilated area away from incompatible substances. Section 8-Exposure Controls/Personal Protection Engineering Controls:Avoid dust inhalation,body contact,contact with acidic materials,and heating to decomposition. Ventilation:Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs (Sec.2).Local exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source. Administrative Controls: Respiratory Protection:Seek professional advice prior to respirator selection and use.Follow OSHA respirator regulations (29 CFR 1910.134)and,if necessary,wear a MSHA/NIOSH-approved respirator.Select respirator based on its suitability to provide adequate worker protection for given working conditions,level of airborne contamination,and presence of sufficient oxygen.For emergency or non-routine operations(cleaning spills,reactor vessels,or storage tanks),wear an SCBA. Warning!Air purJj5dng respirators do not protect workers in oxygen-deficient atmospheres. If respirators are used,OSHA requires a written respiratory protection program that includes at least:medical certification,training,fit-testing,periodic environmental monitoring,maintenance,inspection,cleaning,and convenient,sanitary storage areas. Protective Clothing/Equipment:Wear chemically protective gloves,boots,aprons,and gauntlets to prevent prolonged or repeated skin contact.Wear protective eyeglasses or chemical safety goggles,per OSHA eye-and face-protection regulations (29 CFR 1910.133).Contact lenses are not eye protective devices.Appropriate eye protection must be worn instead of,or in conjunction with contact lenses. Safety Stations:Make emergency eyewash stations,safety/quick-drench showers,and washing facilities available in work area. Contaminated Equipment:Separate contaminated work clothes from street clothes.Launder before reuse.Remove this material from your shoes and clean personal protective equipment. Comments:Never eat,drink,or smoke in work areas.Practice good personal hygiene after using this material,especially before eating,drinking,smoking,using the toilet,or applying cosmetics. Page 2 of 4 TRISODIUM PHOSPHATE 3 Section 9 - Physical and Chemical Pro ernes Physical State:solid Water Solubility:soluble Appearance and Odor:whiteloff white crystals Other Solubilities: /powder/granules-odorless Boiling Point:at 212 IF(100°C)(decomposes) Odor Threshold: Freezing/Melting Point: 163.9 to 170.1°F(73.3 to 76.7 IQ Vapor Pressure: Viscosity: Vapor Density(Air--1): Refractive Index: Formula Weight:380.12 Surface Tension: Density: %Volatile: Specific Gravity(H20=1,at 4°C):1.62 9/cm3 Evaporation Rate: PH: Section 10- Stability and Reactivity Stability:Trisodium Phosphate is stable at room temperature in closed containers under normal storage and handling conditions. Polymerization:Hazardous polymerization will not occur. Chemical Incompatibilities:This strong caustic material reacts violently with water and strong acids to generate heat. Conditions to Avoid:Never beat to decomposition. Hazardous Decomposition Products:Thermal oxidative decomposition of Trisodium Phosphate can produce highly toxic fumes of phosphorus oxides(PO,J and sodium oxide(Naz O). Section 11-Toxicological Information Toxicity Data:* Rabbit,intravenous,LDL.: 1580 mg&g Chronic Effects:no data available Acute Inhalation Effects: Carcinogenicity:no data available Human,inhalation,TCLO:??ppm Mutagenicity:no data available Teratogenicity:no data available Acute Oral Effects: Rat,oral,LD50:7400 mg/kg See NIOSH, RTECS (TC9575000),for additional toxicity data Section 12-Ecological Information Ecotoxicity:Aquatic toxicity:151 ppm/96 hr/mosquito fishfrLnvTurbid water,126 ppm/96 hr/daphnia magaa/TLm Environmental Fate:no data available Environmentai'Degradation:no data available Soil Absorption/Mobility:no data available Section 13-Disposal Considerations Disposal:Scrap material can be used for ttcutralizing acid wastes or buried in as approved landfill.If regulations permit,you may flush small amounts to drain with large excess of water.Contact your supplier or a licensed contractor for detailed recommendations.Follow applicable Federal,state,and local regulations. Disposal Regulatory Requirements: Container Cleaning and Disposal Section 14 -Transport Information DOT Transportation Data(49 CFR 172.101):Not Regulated.* *(If shipping package is equal to or exceeds 5000 lbs.,then product is hazard class 9,shipping name:Environmentally Hazardous substance,Solid,n.o.s.(sodium Phosphate,Tribasic);UN3077.) Shipping Name: Shipping Symbols: Hazard Class: ID No.: Packing Group: Label: Special Provisions(172.102): 1 Page 3 of 4 TRISODIUM PHOSPHATE 4 Section 15 -Regulatory Information US FEDERAL TSCA CAS#10101-89-0 is not on the TSCA Inventory.It is a hydrate and exempt from TSCA Inventory requirements (40CFR720.3(u)(2)). Health&Safety Reporting List None of the chemicals are on the Health&Safety Reporting List. Chemical Test Rules None ofthe chemicals in this product are under a Chemical Test Rule. Section 12b None ofthe chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302(RQ) CAS#10101-89-0:final RQ=5000 pounds(2270 kg)(Listed under'Sodiu Section 302(TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS#10101-89-0:acute. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class I Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act CAS#10101-89-0 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA. STATE Sodium phosphate tribasic dode can be found on the following state right to know lists:California,New Jersey,Pennsylvania, Massachusetts. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols:XI Risk Phrases: R 36/37/38 Irritating to eyes,respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes,rinse immediately with plenty of water and seek medical advice. S 28 After contact with skin,wash immediately with plenty of...(to be specified by the manufacturer). WGK(Water Danger/Protection) CAS#10101-89-0: 1 Canada None of the chemicals in this product are listed on the DSL/NDSL list. This product has a WHMIS classification of D2B. CAS# 10101-89-0 is not listed on Canada's Ingredient Disclosure List. Section 16- Other Information Disclaimer:All information,recommendations and suggestions appearing herein are based upon sources believed to be reliable: However,it is the users responsibility to determine the safety,toxicity and suitability for its own use of this product. WEGO \l CHEMICAL&MINERAL CORP.DOES NOT ASSUME ANY LIABILITY ARISING OUT OF THE USE BY OTHERS OF y THIS PRODUCT. Page 4 of 4 r MATERIAL SAFETY DATA SHEET ARICID,,; B-1019' ______ _ _--_---____-_-__________-___- SECTION I - IDENTIFICATION 24 HOUR EMERGENCY ASSISTANCE:r --=HMIs HEALTH --= 2 413-452-2080 (EASTERN TIME) 8:00AM-5:00PM HMIS FLAMMABILITY 0 800-424-9370 (OFF HOURS) CHEMTREC HMIs REACTIVITY 0 HMIS PROTECTION X HEATBATH CORPORATION 107.FRONT STREET PREPARED BY: ..DAV I D NAGY INDIAN ORCHARD, MASS. 01151 . INFORMATION:413-452-20138 DATE'REVISED: 2/23/98'REV.02 PRODUCT NAME..........:. ARICID'E B-1019 DESCRIPTION............. Dry acid salt. ' DOT CLASS: CORROSIVE. SOLIDS, N.O.S. (CONTAINS SODIUM HYDROGEN SULFATE), 8, UN 1759, PG III . SECTION H - HAZARDOUS INGREDIENTS HAZARDOUS COMPONENT CAS NUMBER PEL(MG/M3) TLV(MG/M3) -�- % - SODIUM BISULFATE 7681-38-1 N.E. N.E. 80=$0 SODIUM FLUORIDE 7681-49-4 2.5 (F) 2.5 (F) 10-20 SODIUM SULFATE 7751-82-6 N.E. N.E. 1-16 N.E.=NOT ESTABLISHED N.A.=NOT APPLICABLE ------------------------ SECTION III -^_PHYSICAL DATA ^___--_�------- -------------------------- BOILING Point(F)................. N.A. SPECIFIC GRAVITY W2O-1O—. 2.46. VAPOR PRESSURE (mm Hg')......N.A. MELTING POINT:.....: N.A.' VAPOR DENSITY ('Air=1).......... N.A. EVAPORATION RATE......N.A. SOLUBILITY IN H2O............. Complete. PH..—...:.solution is acidic. APPEARANCE/ODOR....,:.Odorless, white powder. SECTION' IV - FIRE AND EXPLOSION HAZARD DATA - ----FLASH POINT.............. None. FLAMMABLE LIMITS..........None. LOWER FLAM LIMIT-i....: N.A. HI GHER FLAME LIMIT........ N.A. IN CASE OF FIRE: Material is nonflammable.'Use extinguishing media appropriate to surrounding conditions. SPECIAL FIREFIGHTING PROCEDURES: Wear protective clothing with self-contained breathing apparatus: UNUSUAL FIRE HAZARDS: H6.zardous fumes may be released under thermal decomposition. Prolonged contact with some metals (i.e. alumirium, tin, zinc etc.) may release flammable hydrogen gas. SECTION V - REACTIVITY DATA CHEMICAL STABILITY: STABLE CONDITIONS TO AVOID: None. INCOMPATIBLE MATERIALS: strong alkali, cyanides, sulfides, nitrites._ DECOMPOSITION PRODUCTS: oxides of.sulfur under thersdal decomposition. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR j SECTION VI HEALTH HAZARD DATA===---_____ RD'LiT OF ENTR ;'-' inhalation, ingestion. L MATERIAL SAFETY DATA SHEET ARICIira B-1019 HEALTH HAZARDS (ACUTE,CHRONIC) _ Contains FLUORIDES. May cause eye, skin and respiratory tract irritation and skin ulcers. May be harmful or fatal if swallowed. Avoid contact with eyes, skin or clothing. CARCINOGENICITY: None. NTP?: No IARC?: No OSHA REGULATED?: No SYMPTOMS OF EXPOSURE: eye, skit and respiratory tract irritation, eye, skin and tissue burns. skin ulcers, fluorosis. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Not known. FIRST AID: INHALATION: Move victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult,give oxygen. Get medical attention. EYES: Hold eyelids apart and flush with running water for at least 15 minutes. Get medical attention. SKIN:Wash affected area with plenty of water followed by a solution of 0.1% Benzalkonium chloride. Get medical attention. -INGESTION: If conscious, give plenty of water followed by milk or milk of magnesia. Do not induce vomiting. Get medical attention. SECTION VII -- PRECAUTIONS/PROCEDURES IN CASE OF SPILL: Sweep up material into a chemical waste container. Neutralize spill area with weak alkaline solution. WASTE DISPOSAL METHOD: Neutralize with soda ash or lime and dispose of in accordance with federal, state and local regulations. PRECAUTIONS: Avoid contact with eyes, skin or clothing. Use with adequate ventilation. Wear proper protective clothing when using this product. Wash thoroughly after handling. Store in a cool, dry place. OTHER PRECAUTIONS: Emptied containers of this product may contain hazardous vapors and residue. Clean thoroughly before reusing or discarding. Do not use a welding torch to cut container. Do not use for water or food storage. SECTION VIII - SPECIAL PROTECTION RESPIRATORY PROTECTION:_ Use NIOSH/MSHA approved respirator if dust, fumes or vapors are excessive. VENTILATION: maintain below PEL,TLV. MECHANICAL EXHAUST....... X PROTECTIVE GLOVES: Rubber. LOCAL EXHAUST............ x EYE PROTECTION: safety goggles, face shield. OTHER PROTECTIVE EQUIPMENT......., apron,boots, full cover work clothes. WORK/HYGIENIC PRACTICES...... wash thoroughly after handling,launder clothes. SECT IX _-SARA TITLE III INFORMATION HAZARDOUS CERCLA SECT 302 SECT 313 SECT.311/312 COMPONENT Rq LBS. TPQ LBS. TOXIC HAZARDS SODIUM BISULFATE- N.A. N.A. NO A SODIUM FLUORIDE 1000 N.A. NO A,B SODIUM SULFATE N.A. N.A. NO A A=IMMEDIATE (ACUTE) HEALTH HAZARD B=DELAYED (CHRONIC) HEALTH HAZARD J C=FIRE HAZARD D=SUDDEN RELEASE OF PRESSURE HAZARD E=REACTIVE HAZARD NITRIC ACID, LESS THAN 70% HNO3 CHEMICAL INTERCHANGE CO. ^� MATERIAL SAFETY DATA SHEET NITRIC ACID, LESS THAN 70% HNO3 Section 1: Product and Company Identification. Chemical Interchange Co. Information Telephone: (314)962-9002 2932 S.Brentwood Blvd. Emergency Telephone: (800)325-3980 St.Louis, MO 63144 FAX: (314)962-9409 Chemtrec: (800)424-9300 Nitric Acid,less than 70%HNO3 Acid Reagent Section 2: Composition and Information on Ingredients. COMPOSITION: Nitric Acid(HNO3)with less than 70 percent HNO3 (Hydrogen Nitrate,Aqua Fortis,37 to 42 Degrees Baume Nitric Acid) HAZARDOUS INGREDIENTS: Nitric Acid CAS#7697-37-2 56%to 70% Section 3: Hazards Identification. EMERGENCY OVERVIEW: Colorless to light brown liquid with acrid odor. \ DANGER: Strong oxidizer. Corrosive. /) • Dangerously reactive. • May be fatal if ingested. • Causes severe bums to eyes and skin. • Vapor extremely irritating to respiratory tract • Spills may cause fire or liberate dangerous gas. WARNING: May cause serious delayed lung injury. POTENTIAL HEALTH HAZARDS. EYE: Can cause severe bums. May cause irreversible eye injury. SKIN: Can cause severe skin irritation and bums. May cause deep,penetrating ulcers of the skin. INGESTION: Causes severe bums to mouth,throat and stomach. May cause perforation of the digestive tract. May be fatal. INHALATION: Severe irritation or bums of respiratory system,pulmonary edema and lung Inflammation. May be fatal if inhaled. May cause coughing,wheezing,and shortness of breath. Serious effects on lung function may be delayed. CHRONIC: Repeated inhalation may cause chronic bronchitis. Repeated exposure may cause erosion of teeth. k4ETALS TESTING COMPAI�t Page 1 of 7 _.� g REV1I1,'VEw 81f �/�sj 1 NITRIC ACID, LESS THAN 70% HNO3 Section 4: First Aid Measures. EYE: Immediately flush with water for at least 15 minutes. Contact a physician Immediately. SKIN: Immediately flush with large amount of water while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Leather or other materials which may retain traces of acid Should be decontaminated and properly disposed. INGESTION: Give large amounts of water. Do not induce vomiting. Contact a physician immediately. INHALATION: Remove to fresh air. Give artificial respiration or oxygen if needed. Contact a physician immediately. Observe for delayed effects. Section 5: Fire Fighting Measures. FLAMMABLE PROPERTIES: Nonflammable. Nitric acid alone is not flammable but it may cause ignition by contact with combustible materials. EXTINGUISHING MEDIA: In case of fire,soak with water. Dry chemical or CO2 fire extinguisher may also be used. Use water spray to cool containers and reduce and knock down vapors. Apply water from as far away as possible. Neutralize small amounts of spilled acid with crushed limestone,soda ash or lime. FIRE AND EXPLOSION HAZARDS: Powerful oxidizing agent. Can react explosively with reducing agents such as metal powders,hydrogen sulfide(1-12S), nitrates and organic materials such as wood or cellulose. HAZARDOUS DECOMPOSITION PRODUCTS: Can release highly toxic oxides of nitrogen. Reaction with organic materials results in evolution of heat and acrid fumes. FIRE FIGHTING EQUIPMENT: Wear self contained breathing apparatus and full body acid protective clothing including rubber boots. Thoroughly decontaminate equipment after use. Section 6: Accidental Release Measures. Evacuate area. Avoid all skin,eye and respiratory exposure. Wear self contained breathing apparatus and full body acid protection including rubber boots to enter spill area. Flush small leaks or spills with large quantities of water. If possible,contain large spills with diking and neutralize with limestone,soda ash or liquid caustic soda. CAUTION: Neutralization can produce vigorous reactions,boiling and fumes. Remain upwind,evacuate downwind. Cleaned-up material may be a RCRA Hazardous Waste under 40 CFR 261. Comply with all federal,state and local regulations for disposal of waste. Page 2 of 7 NITRIC ACID, LESS THAN 70% HNO3 Section 7: Handling and Storage. HANDLING: • Do not get in eyes,on skin or on clothing. • Wear full protective equipment including chemical goggles,or face shield,rubber gloves and boots. • Do not inhale mist or vapor. • Handle only in areas with sufficient ventilation to prevent irritation or wear a respirator. • Do not ingest. • Wash thoroughly after handling. • Keep container closed when not in use. • Do not allow contact with water because of violent reaction. • When diluting,slowly add acid to water with stirring and mixing to avoid spattering,boiling or eruption. Water cannot be safely added to acid. • Emptied container retains vapor and product residue. Observe all safeguards until container is cleaned or reconditioned. STORAGE: • Keep container tightly closed. • Outdoor storage in a cool,dry,corrosion proof area is recommended. • Keep containers out of sun and away from heat. • Isolate from incompatible materials. Section 8: Exposure Controis/Pemonal Protection. RESPIRATORY PROTECTION: \ Provide general and local exhaust ventilation to control exposure levels below airborne exposure limits. Local exhaust ventilation is the preferred primary control. Refer to the OSHA Respirator Standard 29 CFR 1910.134 for proper selection and use of personal respirators. SKIN PROTECTION: Wear impervious protective clothing to prevent skin contact,including an impervious apron,rubber boots or full impervious suit when splashing is possible. Provide a safety shower in the immediate vicinity of potential exposure. Refer to OSHA General Requirements for Personal Protective Equipment 29 CFR 1910.132. EYE PROTECTION: Wear chemical safety goggles or full face shield to prevent eye contact. Use only in the proximity of an eye wash station. Refer to OSHA Requirements for Eye and Face Protection 29 CFR 1910.133. EXPOSURE GUIDELINES: OSHA PEL ACGIH-TLV ACGIH-STEL 8hr-TWA 8hr-TWA (15 MIN.) Nitric Acid 2 ppm 2 ppm 4 ppm Nitrogen Dioxide — — 5 ppm Page 3 of 7 NITRIC ACID, LESS THAN 70% HNO3 l Section 9: Physical and Chemical Properties. 1 Appearance:............................................................Colorless to light brown liquid Odor:.....................................................................Acrid pH:........................................................................<1 Flashpoint:..............................................................Not Applicable %Solids:................................................................Not Applicable %Volatility:............................................................100% Solubility:...............................................................Completely miscible in water Vapor Density(air= 1):.............................................1 Vapor Pressure(mm Hg):..........................................9-10 @ 25 deg C(77 deg F) Evaporation Rate(butyl acetate=1):...........................Approx. 1 Weight%HNO3 66.5% 65.7% 67.2% Speck Gravity @ 60 deg F 1.3551 1.40101 lA078 Degrees Baume 38 41.5 42 Freezing Point(deg F approx.) -4 -20 -25 Boiling Point(deg F approx.) 243 246 248 Viscosity,cp @ 20 deg C(68 F) 2.0 2.1 2.2 Section 10: Stability and Reactivity. STABILITY: Stable if properly contained and handled. INCOMPATIBILITY: All organic materials and reducing agents. Addition of water to acid must be avoided. HAZARDOUS DECOMPOSITION PRODUCTS: • Oxide of nitrogen fumes with elevated temperatures. • Nitric acid will react with most organic materials with the evolution of heat and large quantities of dense acrid fumes. HAZARDOUS POLYMERIZATION: Has not been reported. Section 11: Toxicological Information. ACUTE: Nitric add is highly corrosive,fuming and suffocating. Diluted nitric acid can cause inhalation irritation,eye irritation,harden skin epithelium and cause skin irritation. Nitric acid may also severely bum and stain the skin,destroy skin tissue and bum the eyes. Inhalation of nitric acid vapors can destroy lung tissue. Evidence of lung damage may not occur until many hours after initial exposure. Lung damage occurs in the form of edema which may be severe and sometimes fatal. Ingestion of nitric acid causes immediate pain and burning of the mouth, throat and stomach. Symptoms range from nausea,vomiting,and circulatory collapse to death. Individuals with pre-existing diseases of the lungs may have Increased susceptibility to the toxicity of acid inhalation exposure. Page 4 of 7 NITRIC ACID, LESS THAN 70% HNO3 Section 11: Toxicological Information(cont.) J CHRONIC: Continued exposure to nitric acid fumes can erode the teeth and is severely irritating and corrosive to the mucous membranes of the respiratory tract. Nitric acid is not listed as a carcinogen by[ARC,NTP,ACGIH,NIOSH or OSHA TARGET ORGANS: Eyes,mucous membranes,skin and respiratory system. Section 12: Ecological Information. This product should be considered as potentially hazardous to the environment. Avoid contamination of soil,drains and water during handling. Nitric acid is moderately toxic to aquatic organisms. Section 13: Disposal Considerations. This material should be treated as a corrosive hazardous waste in accordance with all applicable regulations. Cleaned-up material may also be a hazardous waste due to corrosivity. This product has a RCRA waste identification of D002- Corrosive as designated in 40 CFR 261.22. The waste of this product is subject to the Land Disposal Restrictions under 40 CFR 268. CAUTION:Neutralization can product vigorous reaction,boiling and fumes. Use extreme caution in dean-up procedures. Section 14: Transportation Information. Shipping Name Nitric Acid(other than red fuming,with not more than 70%nitric acid UN/DOT ID# UN 2031 DOT/IMO Hazard Class 8 Packaging Group II DOT Label/Placard Corrosive Quantity Limits: Passenger Aircraft or Railcar Forbidden Cargo Aircraft 30 Liter Vessel Stowage D Packaging Authorizations: Exceptions None Non-Bulk Packaging 49 CFR 173.158 Bulk Packaging 49 CFR 173.242 DOT Emergency Response Guide Number 157 Page 5 of 7 NITRIC ACID, LESS THAN 70/o HNO3 Section 15: Regulatory Information. CERCLA SUPERFUND,40 CFR 117.302: Under the Comprehensive Environmental Response, Compensation and Liability Act,a release of this product in excess of 1,000 pounds may require reporting to the National Response Center. SARA HAZARD CATEGORY: Under Sections 311 and 312 of the Superrund Amendment and Reauthorization Act of 1986(SARA Title III),this product is considered to meet the following categories: Fire Hazard Yes Sudden Release of Pressure No Reactivity Hazard Yes Acute Health Hazard Yes Chronic Health Hazard No SARA 313 INFORMATION: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superrund Amendment and Reauthorization Act of 1986(40 CFR Part 372): Nitric Acid. CLEAN AIR ACT: This product does not contain any hazardous air pollutants. This product does not contain any Class 1 Ozone depletors. l This product does not contain any Class 2 Ozone depletors. CLEAN WATER ACT: This product is listed as a Hazardous substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants or Toxic Pollutants under the CWA. OSHA: This material is considered highly hazardous by OSHA. TOXIC SUBSTANCES CONTROL ACT(TSCA) This product is listed on the TSCA Inventory. STATE: CALIFORNIA PROPOSITION 65: This product contains the following chemicals known to the State of California to cause cancer or reproductive harm: None. PENNSYLVANIA RIGHT TO KNow: Hazardous Substances and Special Hazardous Substances on the List which must be Identified are: Nitric Acid. NEW JERSEY: Requires reporting the top five components by percent: Nitric Acid:..........................56%to 70% Water:................................30%to 44% Page 6 of 7 NITRIC ACID, LESS THAN 70% HNO3 Section 1S: Regulatory Information(cont.) CANADA: WHIMS: Under the requirements of the Workplace Hazardous Materials Information System,this Material is a controlled substance classified as: Class C—Oxidizing Material Class D—Division 1,Subdivision B;Toxic Material Class E—Corrosive All components are on the Domestic Substances List(DSL). Section 16: Other Information. HAZARD RATINGS: HMIS NFPA 0:Minimal Health 3 3 1:Slight Flammability 0 0 2:Moderate Reactivity 1 0 3:Serious 4:Severe Special Hazard Oxidizer Oxidizer J This MSDS has been prepared in compliance with OSHA Hazard Communication Standard 29 CFR 1910.1200. Although the information and recommendations set forth herein(hereinafter 'Information")are presented in good faith and believed to be correct as of the date hereof,Chemical Interchange Co. makes no representations as to the completeness or accuracy thereof. Information Is supplied upon the condition that the persons receiving same will make their own determination as to its suitability for their purposes prior to use. In no event will Chemical Interchange Co.be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. No representations or warranties,either express or implied or merchantability,fitness for a particular purpose or any other nature are made hereunder with respect to Information or the product to which information refers. Revised March 2009 Page 7 of 7 lro 007 Guibrandsen Technologies MATERIAL SAFETY DATA SHEET IDENTIFICATION SUBSTANCE: FERRIC CHLORIDE SOLUTION CAS P. 7705-08-0 Distrbuted by HUBBARD-HALL INC. egos 20=54211M MANUFACTURER: Gulbrandsen Technologies, Inc. �— �,Besc 2�e ee,nn-eos+ 2 Main Street ww+ moo+ 4�erreeo78n Clinton,NJ 08M PRODUCT INFORMATION: (WS)735.6458 TRANSPORTATION EMERGENCY REVISION DATE: 08/15PZ005 (CHEMTREC): (S00)424-9300 SUPERSEDES: 12 01MM INGREDIENTS \ INGREDIENT CAS S PERCENTAGE Water 773218-5 55-75 Fefric chloride 77054M 25-45 Ferrous chloride 7755-94-3 0-3 Hydrochloric acid 7847-01-0 0-3 ALL INQREDIEN78 ARE LISTED ON THE TECA CHIEWCAL SUBSTANCE INVENTORY SECTION 313 SUPPLIER NOTIFICATION: The hydrochloric acid mentioned above Is suhjW to the reporting mquiremients of Section 313 of the Emergency Planning and Community Rlgtrt To-Know Act of 1M(40 CFR 372). This notification must be included In all MSDS's that are copied and distributed for this material. PHYSICAL DATA BOILING POINT: 1080C PH: 41 MELTING POINT: -120C(1001`�40%Soin. SOLUBILITY IN WATER: Complete SPECIFIC GRAVITY. 1.2-1.5 VAPOR PRESSURE: 40mm Hg a 350C %VOLATILE: 55-75(water) EVAPORATION RATE: NIFf VAPOR DENSITY: Air-1,N/F' MOLECULAR WEIGHT: 182.2 APPEARANCE: Orange-1xvw n liquid ODOR: 8110 r acrid FIRE AND EXPLOSION HAZARDS FLASH POINT: .NIAF FLAMMABLE LIMITS IN AIR: UFL:WA LFL:WA(%BY VOLUME) SPECIAL FIRE AND EXPLOSION HAZARDS: None EXTINGUISHING MEDIA: Will not bum;use materials appropriate for l surrounding fire. J SPECIAL FIRE FIGHTING INSTRUCTIONS: Cool expsed tanks with water. METALS TF-STING PA- i0y REV7Lv REACTIVITY STABILITY: Stable DECOMPOSITION: Will not occur POLYMERIZATION: Will not occur INCOMPATIBILITY: Rapidly corrodes most metals(titanium is one exception);may generate flammable, potentially explosive hydrogen gas. Avoid contact with nylon,aluminum/aluminum alloys,carbon steel,stainless steel,and copper/capper alloys. HEALTH HAZARDS EXPGSURE LIMITS:Not specifically regulated as toxic or hazardous by OSHA. The ACGIH TLV for soluble Iron salts is 1 mg/m3 as Fe(8 hour time-weighted average). TLV for hydrochloric acid Is 7.5 mg/m3(ceiling). Toxic effects in animals from repeated exposure by ingestion include reduced weight gain,elevated serum iron levels,increased red blood cell counts,and iron deposition In many organs. Tests in bacterial and mammalian cell cultures demonstrate no genetic damage. Animal tests demonstrate no carcinogenicity. Human health effects of overexposure by eye contact may include discoloration of eye tissues,eye irritation and discomfort,tearing and blurring of vision,or eye corrosion with comeal or conjunctival ulceration. Skin contact may cause skin irritation with discomfort or rash,skin bums,or ulceration. Ferric chloride has been infrequently associated with skin sensitization in humans. Overexposure by inhalation may result in Irritation of the upper respiratory passages with coughing. Ingestion may cause corrosive damage to the GI tract. Repeated ingestion of sublethal doses may lead to excessive deposition in the tissues accompanied by pancreatic and liver damage. Ingestion In higher doses may lead to abnormal liver function with nausea or vomiting,reduced l appetite,abdominal pain,lethargy,tarry stools,diarrhea,fast and weak pulse,hypertension,dehydration, J acidosis,and coma. Temporary alteration of the heart's electrical activity may result in Irregular pulse, palpitations,or inadequate circulation. If death does not occur immediately,symptoms may dear In a few hours but return within a day with cyanosis,pulmonary edema,shock,convulsions,acidosis,fever,and death. Individuals with pre-existing diseases of the liver may have increased susceptibility to the toxicity of repeated exposures. CARCINOGENICITY: None of the components of this material are listed as a carcinogen by IARC,NTP, OSHA,or ACGIH. FIRST AID EYE: Immediately flush eyes for 15 minutes with plenty of water.Call a physician. SIGN: Flush skin with water. Remove contaminated clothing;wash before reuse. INHALATION: Remove to fresh air. If not breathing,give artificial respiration. If breathing is difficult,give oxygen.Call a physician. INGESTION: DO NOT INDUCE VOMITING. Give large quantities of water,then an antacid. Never give anything by mouth to an unconscious Individual. Call a physician. PERSONAL PROTECTION Adequate general ventilation should be provided to keep vapor and mists below exposure limits. Wear safety glasses with side shields. Wear chemical safety goggles if a possibility of material splashing or spraying exists. Where there is possibility of skin contact,use the following as appropriate:gloves impervious to material,apron,boots,hood,pants,and jacket. Wear a NIOSH/OSHA approved respirator with a dust/mist cartridge If there is potential of exposure to mists in excess of applicable limits. SPILL/LEAK PROCEDURE 2 Review safety precautions before proceeding with cleanup. Use appropriate personal protection equipment. Neutralize spill with lime(calcium hydroxide),limestone(calcium carbonate),or soda ash(sodium carbonate). CAUTION:limestone and soda ash will evolve CO2;ventilation should be provided in enclosed areas. Dike area around spill to prevent spreading,and use absorbent material to pick up spill. CERCLA REPORTABLE DISCHARGE: 1000 lbs. DISPOSAL: Under the Resource Conservation and Recovery Act(RCRA),it Is the responsibility of the user to determine whether a substance should be classified as a hazardous waste at the time of disposal. This is due to the fact that product use,transformation,synthesis,mixtures,etc.may change the nature of the product. Dispose of waste in accordance with applicable federal,state,and local laws. SHIPPING INFORMATION DOT PROPER SHIPPING NAME: Ferric chloride solution HAZARD CLASS: Class 8 UN/NA#: UN 2582 DOT LABELS: Corrosive DOT PLACARDS: Corrosive PACKAGING GROUP: III L PROPER SHIPPING NAME: Ferric chloride solution HAZARD CLASS: Corrosive material,8 UN N: 2582 IMO LABEL: Corrosive PACKAGING GROUP: III REPORTABLE QUANTITY. 1000 lbs. SHIPPING CONTAINERS: Rubber-lined steel tank carshnx*s;polyethylene drum, bottles STORAGE CONDITIONS: Keep containers dosed TITLE III HAZARD CLASSIFICATIONS ACUTE: Yes CHRONIC: No FIRE: No REACTIVITY: No PRESSURE: No EXTREMELY HAZARDOUS SUBSTANCE: No NFPAMMIS RATINGS CERCLA HAZARDOUS SUBSTANCE: Yes HEALTH: 3 TOXIC CHEMICAL: No FLAMMABILITY: 0 CANADIAN WHMIS CLASSIFICATION: E REACTIVITY. 0 PPE rating to be supplied by user depending on use conditions. ADDITIONAL INFORMATION AND REFERENCES 3 Gulbrabdseh Technologies,'Inc.and its divisions,affiliates and subsidiaries("Gulbrandsen")believe that the information contained In each material safety data sheet("MSDS"),technical data sheet("TDS"),product information brochure and/or information contained herein (including data and statements) is accurate as of the date of publication. The MSDSs, TDSs,product information brochures,and information contained heroin are referred to collectively as the"Data Sheets". it is the responsibility of the user to obtain and use the most recent version of the Data Sheets. Each-Data Sheet relates only to the specific product designated therein and may not be valid where such product is used in combination with any other materials or in any process. Further, since the conditions and methods of use of the product and information are beyond the control of Gulbrandsen, Gulbrandsen mcpressly disdaims any and all liability as to any consequential damages or results obtained or arising from any use of the products or the information contained in the Data Shoots. NO WARRANTY OF MERCHANTABILITY,FITNESS FOR ANY PARTICULAR PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED,IS MADE AS CONCERNS THE DATA SHEETS OR THE RELATED PRODUCTS. No statement made in the Data Streets or by any employee or agent of Gulbrandsen shall be construed as a permission or recommendation for the use of any product In a manner that might infringe existing patents. No employee, agent, distributor,.or sales representative is authorized to vary the terms of the above paragraph, to make any statements, representations, or warranties inconsistent with the above paragraph, or to provide any Information that is at variance with the above paragraph. All materials related to the product are subject in all respects to the above paragraph and to the extent that they are inconsistent with the above paragraph.the terms of the above MMraph shall control. 'N/F=None found ZIV/A=Not applicable J 4 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 1 FERRIC CHLORIDE,ANHYDROUS Product Number.None 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Ferric Chloride,Anhydrous Product Number: data not available Chemical Name/Synonyms: Iron(III)Chloride,solid Chemical Formula: FeC13 Cas Number: 7705-08-0 Manufacturer: PVS Technologies,Inc. 10900 Harper Avenue Detroit,Michigan 48213 telephone: (313)571-1100(for product information and emergencies) fax: (313)571-6765 "FOR TRANSPORTATION EMERGENCY ONLY,24 HOURS EVERYDAY,CALL** **CHEMTREC,1-800-424-9300** 2. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS Registry# %by weight Ferric Chloride 7705-08-0 99 Ferrous Chloride 7758-94-3 <l Inert Matter not available <1 Hazardous Ingredients: Ferric Chloride,Ferrous Chloride Exposure Limits(ppm): Component OSHA TLV _ ACGIH Ferric Chloride TWA 1 mg/m3 TWA 1 mg/m3 (as soluble iron salt) (as soluble iron salt) Ferrous Chloride TWA 1 mg/m3 TWA 1 mg/m3 (as soluble iron salt) (as soluble iron salt METALS T SES T UNIG n�;1,V{c>,„�' :Y by a Document Number.:. Pagel of 9 ' Revision No.:. Revision Date: 1, ::: 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number:None 3. HAZARDS IDENTIFICATION Potential Health Effects(Acute and Chronic) INHALATION: Irritation potential requires appropriate personal protective equipment. INGESTION: Ingestion may cause severe liver and/or kidney damage. May also cause damage to the gastrointestinal tract. DIRECT CONTACT: Product is a moderate skin irritant. Can cause irritation or corrosive chemical burns to human tissue. High heat of solution(353 BTU/LB)can cause severe thermal burns if in contact with moist skin or mucous tissue. DIRECT EYE CONTACT: Contact with eyes may cause irritation and may be corrosive and result in permanent visual loss unless removed quickly by thorough irrigation with water. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Caused erythema(a rash)to skin of rabbits. CARCINOGENS(NTP,IARC,or OSHA): No 4. FIRST AID MEASURES: INHALATION:If exposed to excessive levels of dusts or fumes,remove to fresh air and get medical attention if cough or other symptoms develop. INGESTION: If swallowed,do NOT induce vomiting. Give victim water or milk. Call a physician or poison control center immediately. Never give anything by mouth to an unconscious person. DIRECT CONTACT: Dust off excess before washing.Wash with soap and water. Get medical attention if irritation develops or persists. DIRECT EYE CONTACT: Immediately flush with water for at least 15 minutes.Hold eyelids apart to ensure complete irrigation of eye/lid tissue. Get immediate medical attention. Document Number.:,::, Page 2 of 9 Revision No. Revision.Date: 1 6/2006, MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number:None 5. FIRE FIGHTING MEASURES FLAMMABLE PROPERTIES: Flammability: Product not flammable. Flash Point: not applicable Method used: TCC OXIDIZING PROPERTIES: none AUTOFLAMMABILTTY: not applicable AUTOIGNITION TEMPERATURE: not applicable FLAMMABLE LIMITS,%BY VOLUME: Lower flammable limit: not applicable Upper flammable limit: not applicable EXTINGUISHING MEDIA: Use dry chemical or CO,fire extinguishers. \ CAUTION!! This material heats on contact with water. FIRE FIGHTING INSTRUCTIONS: As in any fire,wear self-contained breathing apparatus pressure-demand,MSHA/NIOSH(approved or equivalent)and full protective gear. Keep unnecessary people away;isolate hazard area and deny entry. Stay upwind; keep out of low areas. Move container from fire area if you can do it without risk. Cool exterior of storage tanks. Stay away from ends of tanks. FIRE AND EXPLOSION HAZARDS: During a fire,irritating and highly toxic gases of hydrogen chloride or chlorine may be generated by thermal decomposition. SENSITIVITY TO MECHANICAL IMPACT/STATIC DISCHARGE: no applicable 6. ACCIDENTAL RELEASE MEASURES Vacuum or sweep up material and place in a disposal container. After removal,flush contaminated area with detergent and water. Avoid runoff into storm sewers and ditches which lead to waterways. Spills of 1000 pounds(454 kilograms)or more must be reported to the National Response Center,(800)424-8802. If water pollution occurs, notify the appropriate authorities. Document Number.: Page 3 of 9 Revision No.: Revision Date: } 1 5/2006 J MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 = FERRIC CHLORIDE,ANHYDROUS Product Number:None Emergency Overview Greenish black granular solid. May cause severe liver and/or kidney damage if swallowed. Do not induce vomiting. Can cause irritation or chemical burns to human tissue. Contact with eyes can cause irritation and may even cause permanent visual loss, remove quickly by thorough irrigation with water. Do not use water on fire. Use dry chemical or COZ. Beware of chlorine gas or hydrogen chloride gas at high temperatures. See Sections 3,4,and 5. 7. HANDLING AND STORAGE Store in a dry area. Store away from heat,strong alkalis and alkali metals. Keep containers closed and dry. Protect container from physical damage. See Section 10 for types of packaging material to avoid. Avoid contact with water and minimize contact with moisture. Avoid breathing dust. Avoid contact with skin and eyes. Use gloves when handling. Wash thoroughly after handling;dust off excess before washing. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION:Adequate ventilation and appropriate respiratory protection required. RESPIRATORY PROTECTION: Use NIOSH/MSHA approved,full face respirator with gas canister suitable for inorganic gases/vapors .Consult respirator manufacturer to determine appropriate equipment. SCBA equipment is suitable for higher concentrations or long term exposures. PROTECTIVE GLOVES: Wear impervious rubber gloves. EYE PROTECTION: Wear splash proof chemical safety goggles. Do not wear contact lenses. OTHER PROTECTIVE EQUIPMENT: Wear protective clothing to minimize skin contact. Rubber footwear and apron should be used as appropriate. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. WORK/HYGIENIC PRACTICES: Avoid breathing dust. Use gloves when handling. OTHER PRECAUTIONS: None. Document Number.: Page 4 of 9 Revision No.: Revision Dater 1 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 -- FERRIC CHLORIDE,ANHYDROUS Product Number:None 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: greenish black Odor. none Odor Threshold: not applicable Physical State: granular solid Vapor Pressure(REID): negligible Specific Gravity: 2.8 -2.9 (water=1) Solubility in Water: 50%by weight pH: 1.0 for 2%solution Boiling Point: 305-3170 C or 581 -6030 F Vapor Density: not applicable (Air=1) Evaporation Rate: not applicable (Butyl Acetate=1) Melting Point: 3010 C or 5740 F Coefficient of Water/Oil Distribution: data not available Percent Volatile by Volume(%)at 550 C: negligible Viscosity: data not available %Solids: data not available %VOC: data not available 11 For information on FLASH POINT,FLAMMABILITY OXIDIZING PROPERTIES, J AUTOFLAMMABILITY,and EXPLOSIVE PROPERTIES,please see Section 5. 10. STABILITY AND REACTIVITY GENERAL: This product is stable and hazardous polymerization will not occur. INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID: Material is stable when properly handled. Refer to Section 7. Avoid high temperatures. Avoid potassium and sodium. HAZARDOUS DECOMPOSITION PRODUCTS: Can release toxic chlorine gas at elevated temperatures above 5530 F. Can release toxic hydrogen chloride on contact with water or steam at elevated temperatures. Document Number.: h8g@ 5 Of 9 Revision No.: Revision Date: 1 : 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 --� FERRIC CHLORIDE,ANHYDROUS Product Number:None 11. TOXICOLOGICAL INFORMATION LD50: 1932 mg/kg(oral toxicity,rat) LC50: data not available Immediate Effects: Exposure caused erythema to skin of rabbits. Ingestion causes severe liver and/or kidney damage in humans. Refer to Section 3 for other immediate effects. Carcinogenicity: not applicable 12. ECOLOGICAL INFORMATION Chronic Hazard Level: Mild chronic irritant in 2-5 month studies,trout showed growth decreases and invertebrates effects: reproduction at 12 and 3 ppm,respectively. For daphnids,reduction was 16%at 4.38 ppm Fe. Marine waters should not exceed 0.3 ppm Fe. Chronic Plant Toxicity Limit: 1000 ppm l Potential for Accumulation: Concentration factors for iron: marine freshwater plants 50,000 5000 invertebrates 20,000 3200 fish 3000 300 Half-life in total human body=800 days Chronic Aquatic Toxicity Limit: 130 ppm(Daphnia magna) Persistency: Can persist indefinitely Carcinogenicity: not applicable 13. DISPOSAL CONSIDERATIONS Dispose of spilled,neutralized,or waste product,contaminated soil and other contaminated materials in accordance with all local,state and federal regulations. Document Number.: page 6 of 9 Revision No.: Revision Date: 1 512006 1 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 j FERRIC CHLORIDE,ANHYDROUS Product Number:None 14. TRANSPORT INFORMATION DOT(Department of Transportation): Proper Shipping Name: Ferric Chloride Hazard Class: 8 Identification Number: UN1773 Packing Group: III Emergency Response Guide Book Number: 157 Corrosive: skin 15. REGULATORY INFORMATION U.S.Federal Regulations: OSHA: This product is hazardous by definition of Hazard Communication Standard(29 CFR 1910.1200). SARA TITLE III(Superfund Amendments and Reauthorization Act of 1986) Section 302 Extremely Hazardous Substances: InUedient RO(Reportable Oua titv) none Section 311/312 Hazard and Physical Hazards: Immediate: yes Delayed: no Fire: no Pressure: no Reactivity: no Section 313 Toxic Chemicals: Ingredient %by Weight none CERCLA/SUPERFUND(40 CFR 117,302) Ingrgdient Ferric Chloride,Anhydrous 1000 pounds Notify the National Response Center (1-800424-8802) RCRA: If discarded in its purchased form,this product would be a hazardous waste by Document Number.: page 7 of 9 Revision No.: Revision Date: 1 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number:None characteristic. This product contains no Class I or Class R Ozone Depleting Chemicals. DOT: Please refer to Section 14. State Regulations: California data not available Michigan data not available International Regulations: CANADA WIMS Hazard Class(es): data not available CEPA: data not available This product has been classified in accordance with the hazard criteria of the CPR ') and the MSDS contains all the information required by the CPR. 16. OTHER INFORMATION The following label hazard ratings are recommended for containers of Ferric Chloride, Anhydrous: (Hazard Index Key: 4=severe; 3=serious;2=moderate; 1 =slight;0=minimal) NFPA HMIS Health 2 Health 3 Flammability 0 Flammability 0 Reactivity 0 Reactivity 1 MSDS Status: The entire MSDS has been revised October 22,2001. To the best of our knowledge,the information contained herein is accurate. However,neither PVS Chemicals,Inc.,nor any of its subsidiaries,assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein,we cannot guarantee that these are the only hazards which exist. Consult the manufacturer for further Document Number.: Page 8 of 9 Revision No.: Revision Date: 1 5/2006 MATERIAL SAFETY DATA SHEET PVS TECHNOLOGIES,INC. DATE PREPARED: May,2006 FERRIC CHLORIDE,ANHYDROUS Product Number.None information. I Document Number.: page 9 of 9 Revision No.: Revision Date: 1 5/2006 `) Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet Chemical: Hydrofluoric acid NFPA: H=4 F=0 1=0 S=None HMIS: H=4 F=0 R=1 PPE=Supplied by user, dependent on conditions �— MSDS Number. HF70-0505 Effective Date: 5 May 2005 O Issued by: Solvay Chemicals,Inc.Regulatory Affairs Department Not valid three years after effective date or after issuance of superseding MSDS,whichever Is earlier.French or Spanish translations of this MSDS may be available.Check www.solvaychemicals.us or call Solvay Fluorides,LLC to verify the latest version or translation availability. Material Safety Data Sheets contain country-specific regulatory information.Therefore,the MSDS's provided are for use only by customers of Solvay Fluorides,LLC in North America.If you O are located in a country other than Canada,Mexico or the United States,please contact the Solvay Group company in your country for MSDS information applicable to your location. 1.1 Product Name: Hydrofluoric acid,70%(aqueous solution) Chemical Name: Hydrofluoric acid Synonyms: Fluorimydric acid,70% HF,Aqueous HF Chemical Formula: HF Molecular Weight: 20 CAS Number. 7664-39-3 EINECS Number. 231-634-8 1.2 Recommended Uses: Metallurgy-,Glass industry,Chemical industry,Fuel additives, Intermediates 1.3 Supplier. Solvay Fluorides, LLC PO BOX 27328 Houston,TX 77227-7328 3333 Richmond Ave. Houston,Texas 77098 1.4 Emergency Telephone Numbers Emergencies(USA):1-800-424-9300(CHEMTRECIJ Transportation Emergencies ONTERNATIONAL/MARMME):1-703-527-3887(CHEMTRECI) Transportation Emergencies(CANADA):1-613-996-6666(CANUTEC) Transportation Emergencies(MEXICO-SETIQ): 01-800-00-214-00(MEX.REPUBLIC) 525-559-1588(Mexico City and metro area) NETALIS TESTING C OMI P RE MEWED BY Aj— T f Solvay / on MSDS No.HF70-0505 Revised 05 05 05 Fluorides SOLVAY Rasponsi6k�' Copyright 2005,Solvay Fluorides,LLC G.dcr�ryocWork A subsidiary of Solvay chemicals,Inc. All Poghia Reserved. A Subsidiary of Solvay Chemicals Inc. Page 1/15 www.solvaychem 80 icals.us 1. 0.785.82g2 f Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet INGREDIENTS FORMULA WT.PERCENT CAS# Hydrogen Fluoride HF >_70 7664-39-3 Water H2O balance 7732-18-5 Emergency Overview: 3.1 Route of Entry: Inhalation:Yes Skin:Yes Ingestion:Yes O 3.2 Potential Effects of exposure: • Danger!Corrosive and toxic product,very hazardous to human health and Lthe environment. • Causes severe bums to eyes,skin,and respiratory tract. • Bums may not be immediately painful or visible.Onset can be delayed up to 24 hours. • Can be absorbed through the skin in fatal amounts. pot • Risk of cardiac and nervous disorders. • Presents hazards from its ionized fluorine which binds with calcium in the body and can result in hypocalcemia(possible life-threatening lowering of serum calcium). • Chronic exposure to the product can cause bone or dental fluorosis. • Reactions with certain metals can generate flammable and potentially explosive hydrogen gas. Inhalation: • Severe irritation of the nose and the throat. • Spasmodic cough and d'Ifficulty in breathing. • Risk of chemical pneumonitis(jung irritation)and pulmonary edema(fluid in lungs). • At high concentrations,risk of hypocalcemia(possible life-threatening lowering of serum calcium)with nervous problems(tetany)and cardiac arrhythmia(heart irregularity). • In case of repeated or prolonged exposure;risk of sore throat,nose bleeds,chronic bronchitis,emphysema and erosion of teeth. Eyes: • Also possible hazard by simultaneous inhalation of the product • Bums may not be immediately painful or visible for up to 24 hours. • Severe eye irritation,watering,redness and swelling of the eyelids. • Bums. • Risk of serious or permanent eye lesions or comea damage and blindness. I MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay chemicals,Inc. All Rights Reserved. Page 2/15 www.solvaychemicals.us 1.800.765.8292 _� ■a Hydrofluoric acid, 70% ■� (aqueous solution) Matedal Safety Data Sheet Skin contact: • Also possible hazard by simultaneous inhalation of the product. • Bums may not be immediately painful or visible for greater than 8 hours. The product can be absorbed through the skin causing destruction of the deep tissue layers including the bone tissue. O Painful irritation, redness and swelling of the skin. • Severe bums,slow healing. • Risk of shock. • If contact with the fingernails,severe pain after several hours. • Risk of hypocalcemia(possible life-threatening lowering of serum calcium)depending on the extent of the lesions. Ingestion: • Severe irritations,bums,perforation of the gastrointestinal tract accompanied by shock. • Risk of edema(fluid in lungs)and suffocation. • Nausea,vomiting(bloody),abdominal cramps and diarrhea(bloody). • Cough and difficulty breathing. • Risk of chemical pneumonitis(lung irritation)and pulmonary edema(fluid in lungs) from product inhalation. • Risk of hypocalcemia(possible life-threatening lowering of serum calcium)with nervous problems(tetany)and cardiac rhythm disorders. • Risk of convulsions, loss of consciousness,deep coma and cardiopulmonary arrest. • Risk of general symptoms having a severe or fatal prognosis. Carcinogenicity:See section 11.3 111112111111111 General Recommendations: • Consult physician immediately in all cases. • Personal protective equipment(respirator,gloves,etc.)required for rescuers of victims (See section 8). • In case of product splashing into eyes and face,treat eyes first. • Decontaminate the victim first. • Maintain an adequate supply of antidote gel(calcium gluconate). (HANDLE PATIENT AND ALL CONTAMINATED CLOTHING WITH HF RESISTANT GLOVES.) Note:The effect of HF,i.e.the onset of pain,particularly in dilute solutions, may not be felt for up to 24 hours.It is important that workers have immediate access to the antidote(calcium gluconate)both on and off the worksite in order to apply it as soon as possible.Instructions should be given for the worker not to use the gel in the eye and the worker to still seek medical attention regardless of how minor the contact.The calcium combines with the fluoride to form the insoluble calcium fluoride thus preventing the fluoride from entering the intact skin and causing tissue damage.HF antidote gel(calcium gluconate)is available through Pharmascience of Montreal,Canada[(800)207-4477]and your local pharmacist. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 3/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■�. (aqueous solution) Material Safety Data Sheet 4.1 Inhalation: • Remove the subject from the contaminated area as soon as possible.Transport subject lying down,with the head higher than the body,to a quiet,uncontaminated and ■� well-ventilated location. • Administer oxygen(2.5%calcium gluconate if available,can be oxygen-nebulized with O trained personnel)or cardiopulmonary resuscitation if necessary and as soon as possible. If patient is unconscious,give artificial respiration. Note:Mouth to mouth resuscitation is not recommended. • Keep warm(blanket). - Consult physician in all cases. • Take to a hospital. Eyes: • Flush eyes with running water for 5 minutes,while keeping the eyelids wide open. • Rinse the eyes with a calcium gluconate 1%solution in physiological serum (10 ml of calcium gluconate 10% in 90 ml of physiological serum)for 10 minutes. (Continue a calcium gluconate drip into eyes...Then drop wise while transporting.) If 1%calcium gluconate is not available continue flushing with water. • In the case of difficulty opening the lids,administer an analgesiceye wash.Do not use oily drops,ointment,or HF skin bum treatments. • Consult an ophthalmologist or eye specialist and physician immediately in all cases. • Take to a hospital immediately. Skin: • Immediately bring the clothed subject under the shower. • Remove contaminated shoes,socks and clothing,while washing the affected skin with running water for 5 minutes.Double-bag all contaminated clothing for disposal. • Immediately apply calcium gluconate gel 2.5%and massage into the affected area using rubber gloves;continue to massage while repeatedly applying gel until 15 minutes after pain is relieved(see section 16). • Apply water longer(15 minutes)if calcium gluconate is not available. • Alternately,immerse the burned area in a solution of 0.2%iced aqueous Hyamine 1622 (a quaternary ammonium made by Rohm&Haas)or 0.13% iced aqueous Zephiran Chloride(a benzalkonium chloride sold by Sanofi-Synthelabo). • If finger/fingemails are touched,even If there is no pain,dip them in a bath of 5%calcium gluconate for 15 to 20 minutes. • Keep warm(blanket);provide clean clothing. • Consult a physician immediately in all cases of skin contact no matter how minor. • Take to a hospital immediately. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 015 www.solvaychemicals.us 1.800.765.8292 -) Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet Ingestion: • Consult a physician immediately in all cases. • Take to a hospital. ■� if the subject is completely conscious: • Rinse mouth with fresh water. O Do not induce vomiting. • When directed by physician,give orally either 1%aqueous calcium gluconate solution, milk or calcium/magnesium containing anti-acid.Such solutions can be beneficial but also may be problematic if they induce vomiting. • If the subject presents nervous,respiratory or cardiovascular disorders, administer oxygen. If the subject is unconscious: • Administer classical resuscitation measures. • Do not give anything by mouth to an unconscious person. 4.2 Medical Treatment/Notes to Physician:(HANDLE PATIENT AND ALL CONTAMINATED CLOTHING WITH HF-RESISTANT GLOVES.) Note:For bums of moderate area(greater than 8 square inches on a normal adult),significant inhalation exposure,and ingestion,systemic effects may occur,and a critical care unit should be considered for the patient to monitor for hypocalcemia,cardiac arrhythmias, hypomagnesemia, and hyperkalemia and possible dialysis.Hypocalcemia may need to be monitored for bums of greater than two square inches and may require systemic administration of calcium gluconate. EKG can be monitored indirectly for effectiveness of treatment for hypocalcemia. Excess calcium can cause heart irregularities. Inhalation: • Pulmonary resuscitation(oxygen therapy). • If necessary,tracheal intubation and positive pressure ventilation. • Treat as soon as possible.Give a 2.5 to 3%calcium gluconate solution by nebulizer in the first 12 to 24 hours. • Prevention or treatment of pulmonary edema and bacterial secondary Infection. • Surveillance of cardiac(EKG),respiratory,renal and hepatic functions. • In case of hypocalcemia,I.V.perfusion of 10 ml of a 10%calcium gluconate solution diluted in 1 liter of physiological serum. • Surveillance of hyperfluoremia and possible treatment with hemodialysis. • Do not give stimulants.Patient must remain inactive for at least 24 hours. Eye Contact: • Initiate irrigation with 500 to 1,000 cc of a 1% calcium gluconate solution in normal saline using local anesthetic.Administration by an ocular irrigator is desirable. • Consult an ophthalmologist. • Follow up with 1%calcium gluconate eyedrops as required and ophthalmic steroid solution,as indicated by ophthalmologist. • In addition,medical surveillance as specified for inhalation. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 5/15 www.solvaychemicals.us 1.800.785.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet Skin Contact: • Prevention or treatment for shock. • Apply and massage calcium gluconate gel(2.5%)until pain subsides or 20 minutes have elapsed for 4-6 times a day. • If the exposed surface is larger than 2 in2,administer(in 1,000 cc of Hartman or saline O solution)20 cc of 10%calcium gluconate at a slow rate(60-70 drops/minute). • For second and third-degree bums,or if the pain does not subside within 20 minutes,or bums wfth concentrated HF(greater than 50%),consider sub-cutaneous microinjections of 2.5%calcium gluconate at a distance of 5 mm around the affected area using a small - gauge needle(#30 stainless). Do not use more than 0.5 ml per cm2 of affected skin surface. • Severe digital bums:slow antra-arterial infusion(over a 4-hour period)of 10 ml of a 10%calcium gluconate solution diluted in 40 ml of physiological serum. • For HF contact on nails,consider splitting the nail and application of calcium gluconate on the nail bed. • Blisters and necrotic tissue should be debrided(Warning:The liquid contained in the blister is corrosive). pit • Do not use local anesthetics.Resolution of pain is a means to determine effective medical treatment • In addition,medical surveillance as specified in"inhalation"section. Ingestion: • Oxygen therapy via intra-tracheal intubation. • If necessary,tracheotomy. • Careful gastric lavage after administration of 10 vials of calcium gluconate (to be repeated as frequently as needed). • In case of intense pain,inject an I.M.morphomimetic analgesic drug(piritramide) before taking to hospital. • Prevention or treatment of shock and pulmonary edema. • Digestive endoscopy in all cases. • Treatment of gastrointestinal tract burns and resulting effects. • Surveillance and treatment of hypocalcemia.In case of hypocalcemia,I.V.perfusion of 20 ml of a 10%calcium gluconate solution diluted in 1 liter of physiological serum. • Surveillance of hyper luoremla and possible treatment with hemodialysis. • Surveillance of cardiac(EKG)and nervous system functions. 5.1 Flash point:Not applicable. 52 Auto-ignition Temperature: Non-flammable. 5.3 Flammabaity Limits:Non-flammable. 5.4 Unusual Fire and Explosion Hazards:See section 10. / MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 6/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Matelial Safety Data Sheet 5.5 Extinguishing Methods Common:Use means appropriate for surrounding fire. Inappropriate extinguishing means:None. 6.6 Fire Fighting Procedures Specific hazards: O Non-combustible/non-flammable but may produce dangerous fumes if involved in fire. • Formation of dangerous gas in contact with water or humid air. • Formation of flammable gas on contact with certain metals(see section 10). _ Protective measures in case of intervention: • Evacuate all non-essential personnel. • Intervention only by capable personnel who are trained and aware of the hazards of the product. LD • In all cases wear self-contained breathing apparatus. • When intervention in close proximity,wear full protective acid-resistant suit. • Protect Intervention team with water spray when approaching the fire. • After intervention,proceed to clean the equipment used in intervention(remove clothing carefully,double-bag contaminated clothing and dispose of properly and shower thoroughly). Other precautions: • Cool containers exposed to fire. • Depending on wind direction,warn people of danger of inhalation,close doors and windows and get ventilation stopped. • Approach from upwind. • Absorb gas/vapors with water spray. • After the fire,proceed rapidly to clean the surfaces exposed to the fumes in order to limit the damage to the equipment. • As for any fire,ventilate and clean the rooms before reentry. 6.1 Precautions: • Follow the protective measures given in sections 5 and 8. • Isolate area. • Approach from upwind. • Ventilate the premises. • Eliminate all sources of ignition,and do not generate flames or sparks. • Keep away materials and products which are incompatible with the product (see section 10). • Disperse gas/vapor with water spray. • To avoid excessive fuming,do not apply water directly onto the spillage but upstream or on a runoff. • In case of leaking container,try to reposition it to get the leak in gaseous phase. • Protect intervention team with water spray. • Use bagged lime to form containment. • If safe to do so with proper personal protective equipment,attempt to stop or minimize l the leak. / MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 7115 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Matelial Safety Data Sheet 6.2 Cleanup methods: • Prevent the product from entering sewers or confined spaces. • Knock-down water is dangerous for the environment and should be diked for ■� containment and later disposal(see section 13). ;recautions Neutralize product with alkali(sodium carbonate,lime,...6.3 for protection of the environment: O • Immediately notify the appropriate authorities in case of significant discharge. • Do not discharge into the environment(atmosphere, ...). 7.1 Handling: • Cary out industrial operations in closed,but vented,piping circuits and equipment. —0 • Handle small quantities under a lab hood. • Operate in a well-ventilated area. • Use only equipment and materials which are compatible with hydrogen fluoride. • Keep away from reactive products(see section 10). • Preferably transfer by pump or gravity. 7.2 Storage: • Keep in ahermetically-sealed container. • Store in a ventilated,cool area. • Keep away from heat sources. • Keep away from reactive products(see section 10). • Use containment dike around storage containers and transfer installation. 7.3 Specific Uses:See section 1.2. 7A Other precautions: • Provide tight electrical equipment,well protected against corrosion. • Follow the protective measures given in section 8. • Warn people about the dangers of the product. 7.5 Packaging: • Steel+PE. • PE. &I Exposure Limit Values: Authorized limit Values ACGIH•-USA(2005) OSHA HIOSH Hydrogen fluoride(as F) TWA 0.5 ppm-TLV PEL 3 ppm IDLH 30 ppm TWA 0.38 mg/ms-TLV STEL 6 ppm(15m1n) TWA 2 ppm-ceiling 1.5 mg/m'-ceiling AIHA Emergency Response Planning Guidelines ERPG-1 ERPG-2 ERPG-3 2 ppm 20 ppm 50 ppm ` ACGIH•and TLV•are registered trademarks of the American Conference of Governmental Industrial Hygienists. i MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 8f15 www.soivaychemicals.us 1.800.765.8292 l Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet 8.2 Exposure Controls: • Maintain employee exposures to levels below the applicable exposure limits. • Follow the protective measures given in section 7. ■� 82-1 Occupational Exposure Controls: O 8.2.1.1 Ventilation:Provide local ventilation suitable for appropriate emission control. 8.2.1.2 Respiratory protection: • Use only NIOSH-approved respirators. • Comply with OSHA respiratory protection requirements. Use self-contained breathing apparatus in medium confinementrn insufficient oxygen environmentsfin case of large uncontrolled emissions/in all circumstances when the mask and cartridge do not give adequate protection. 8.2.1.3 Hand protection: • Use Protective gloves-HF chemically-resistant;recommended materials:butyl rubber. 82.1.4 Eye protection:Chemical-proof goggles/full face shield obligatory. 8.2.1.5 Skin protection: • HF acid-resistant clothing. 11 HF chemically-resistant boots if risk of splashing, l.J 8.3 Other precautions: • Provide shower and eyewash stations. • Wash soiled equipment. • Take off contaminated clothing immediately after exposure.Double-bag and dispose of properly. • Avoid contact with any leather object. • Consult the industrial hygienist or the safety manager for the selection of personal protective equipment suitable for the working conditions. 9.1 Appearance:Liquid. Color:Colorless. Odor:Pungent 9.2 Important Health,Safety and Environmental information: pH:<i;10 mg HFA:pH=3.15; 100 mg HF/I: pH=2.65. Change of state: Melting point:-700C(-940F). Boiling point:670C(152°F)at atm. Decomposition Temperature: No data. Flash Point:Not applicable. Flammability:Non-flammable. Explosive Properties:With certain materials(see section 10). J MSDS No.HF70-0505 Revised 05-05-05 copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 9/15 www.solvaychemlcals.us 1.800.765.8292 ■� Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet Oxidizing Properties:Not applicable. Vapor Pressure:176 mbar(132 mmHg)at 20°C(680F). ■� Relative Density- Specific gravity:1.25 at 20°C(680F). Solubility: Water.Very Soluble. Fat:No data. Partition coefficient:Not applicable. Viscosity:No data. Vapor Density(alml):2.4 at 20°C(681). Evaporation Rate:No data. Stability:Unstable under certain conditions(see below). 10.1 Conditions to avoid:Negligible. 10.2 Materials and substances to avoid: • Metals:yield hydrogen gas. • Glass:dissolves. • Strong Bases:violent reaction. • Alkalines:violent reaction. 10.3 Hazardous decomposition products:Hydrogen. 10A Hazardous Polymerization:Will not occur. 10.5 Other Information: • Exothermic reaction when mixed in water. • Corrosive action on some metals when moisture exists. • Contact with strong bases or alkaline materials may provoke violent reactions or explosions. • In presence of humidity,contact with metals releases hydrogen. 11.1 Acute toxicity: Inhalation:LC.,O, 1 hour(s),rat,850 to 1070 ppm. Oral:LD100,guinea pig,80mg/kg(2%solution). Dermal:No data. Irritation: • Corrosive. • Reacts with mucous membranes. MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Ruorldes,LLC A subsidiary of Solvay Chemicals,Inc. AI Rights Reserved. Page 10/15 www.solvaychemicals us 1.800.765.8292 �) Hydrofluoric acid, 70% ■■� (aqueous solution) Material Safety Data Sheet Sensitization:No data. Comments: . • Corrosive effect for the skin,eyes and respiratory tract. C • Chronic exposure may entail dental or skeletal fluorosis. • Risk of effect on the liver and the kidney. O The carcinogenic effect found in animals is not demonstrated in humans. • Risk of toxic effect on reproductive systems. 11.2 Chronic toxicity: - • Inhalation,after prolonged exposure,rat,target organ:respiratory system/eyes/kidney, liver,observed effect(Sodium fluoride). • Oral route,after prolonged exposure,rat/mouse,target organ:skeleton/thyroid/testes/ kidney,liver,ca. 1 mg/kg.observed effect(Sodium fluoride). • Ambiguous carcinogenic effect(Sodium fluoride). • Fetotoxic and fertility effects(Sodium fluoride). • Ambiguous mutagenic effect(Sodium fluoride). 11.3 Carcinogenic Designation:None 12.1 Acute ecotoxicity: - Fish,Salmo gairdneri,LC50,96 hour(s),51 mg/I(Fluorides). • Crustaceans, Daphnia magna,ECG,48 hour(s), 97 mgA. • Conditions:Fresh water(Fluorides). Crustaceans, Mysidopsis bahia,EC50,96 hour(s),10.5mgA. • Conditions:Salt water(Fluorides). Algae,Scenedesmus sp.ECw,96 hour(s),43 mg/I(Fluorides). 12.2 Chronic ecotoxicity. • Fish,Salmo gardneri,LC5(),21 day(s),3.7 mgA(Fluorides). • Crustaceans, Daphnia magna,NOEC,21 day(s),3.7 mgA(Fluorides). 12.3 Mobility.- Air-mobility in aerosol form. • Water-considerable solubility and mobility. • Soil/sediments-adsorption on mineral soil constituents. • Conditions:slightly acid pH(Fluorides). 12.4 Degradation Abrotic. • Air-neutralization by natural alkalinity. • Water/soil-ionization/neutralization of inorganic and organic materials. • Water/soil-complexation/precipitation of inorganic materials. Degradation products:aluminumAron/calcium/phosphate complexes and/or precipitates as a function of pH(Fluorides). Biotic:Not applicable(inorganic compound). / MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides.LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 11116 www.solvaychemicals.us 1.800.765.8292 :� ■� Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet 12.5 Potential for bioaccumulation: Bioconcentration:log Po/w-Not applicable(ionizable inorganic compound). Accumulation into vegetable leaves(Fluorides). ■� 12.6 Other adverse effects/Comments: • Harmful for aquatic organisms. O Nevertheless,hazard for the aquatic environment is limited due to product properties: low chronic toxicity. • Product fate is highly dependent on environmental conditions:pH,temperature, oxidoreductive potential,mineral and organic content of the medium,... 13.1 Waste treatment: • Dispose in compliance with local,state and federal regulations. • Contact the producer for recycling/recovery suggestions. • Absorb the product in a KOH solution. Possible residual solution.Vapors may be released.Good ventilation is required. • Use lime or,preferably,calcium hydroxide or calcium carbonate to precipitate the fluoride ion in the form of CaF2. 13.2 Packaging treatment: • To avoid treatments,use dedicated containers. Do not rinse containers. • Dispose of the containers in compliance with local,state and federal regulations. 13.3 RCRA Hazardous Waste:Listed; RCRA Waste Number:U134. Mode DOT IMDG IATA UN Number UN 1790 UN 1790 UN 1790 Class 8 8 8 Proper Shipping Name Hydrofluoric acid Hydrofluoric acid Hydrofluoric acid Hazard label(Subsidiary) Corrosive(Toxic) Corrosive+toxic Corrosive+toxic Subsidiary risk 6.1 Toxic Toxic Placard Corrosive(toxic) 1790 Subsidiary Placard Poison Packing Group it 11 II Reportable Quantity 100 Ibs. MFAG 750 EmS ERG:157 EMS:8-03 ERG code:813 J MSDS No.HF70-0505 Revised 05-D5-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 12/15 www.solvaychamicals.us 1.800.765.8292 -� Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet National Regulations(US) ■� TSCA Inventory 8(b):Yes. SARA Title III Sec.3021303 Extremely Hazardous Substances(40 CFR 355):Yes. OSARA Tide III Sec.311/312(40 CFR 370):Yes. Threshold planning quantity.100 lbs. SARA Title III Sec.313 Toxic Chemical Emissions Reporting(40 CFR 372):Yes. CERCLA Hazardous Substance(40 CFR Part 302) O listed waste:Yes;(U134)Reportable quantity-100 lbs. Unlisted waste:Yes. Characteristic:D002(Corrosive). Other.Occupational Safety and Health Administration(OSHA)requirements for process safety management must be followed anytime at least 1,000 lbs.of hydrofluoric acid is used or stored. Refer to 29CFR 1910.119 for specific details. Environmental Protection Agency(EPA)requirements for a Risk Management Plan(RMP)must be followed anytime at least 1,000 lbs.of hydrofluoric acid>50%is used or stored. Refer to 400FR68.150 for specific details. State Component Listing: State Comment CA Airborne Contaminants&Emissions Inventory CA Hazardous Substance List CT Hazardous Material Safety IL Chemical Safety Act IL Toxic Substances Disclosure to Employees Act IN Occupational Health&Safety Standards-Air KY Occupational Health&Safety Standards-Air LA Right to Know List LA Spill Reporting MA Oil and Hazardous Materials List MA Right to Know Substance List MN Hazardous Substance List NJ Right to Know Substance List NJ Spill Tax List NJ Toxic Catastrophe Prevention Act NC Exposure Limits for Air Contaminants NY Release Reporting List of Hazardous Substances PA Right to Know RI Right to Know Act J MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 13/16 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Mateliai Safety Data Sheet National Regulations(Canada) Canadian DSL Registration:DSL. ■_ WHMIS Classification: D1A-Very toxic material. E-Corrosive. O This product has been classified in accordance with the hazard criteria of the ConboAed Products Reguk0orm and the MSDS contains all the information required by the Controlled Products Regulations Labeling according to Directive 1999/45/EC. Category ID Phrase Symbols T+ Very toxic. C Corrosive. Phrases R 26/27/28 Very toxic by Inhalation,in contact with skin and if swallowed. 35 Causes severe bums. Phrases S (1/2) (Keep locked up and out of the reach of children.) 7/9 Keep container tightly closed and in a well-ventilated place. 26 In case of contact with eyes,rinse immediately with plenty of water and seek medical advice. 36/37 Wear suitable protective clothing and gloves. 45 In case of accident or if you feel unwell,seek medical advice \ immediately(show the label where possible). 16.1 Ratings: NFPA(NATIONAL FIRE PROTECTION ASSOCIATION) Health=4 Flammability=0 Instability=0 Special=None HMIS(HAZARDOUS MATERIAL INFORMATION SYSTEM) Health=4 Fire=0 Reactivity=1 PPE=Supplied by User,dependent on local conditions 16.2 Other Information: For additional information on handling,storage and packaging see HFIPI:Recommended Practices for the Hydrogen Fluorides Industry.Copies can be purchased through American Chemistry Council at(703)741-5611. The previous information is based upon our current knowledge and experience of our product and is not exhaustive.It applies to the product as defined by the specifications.In case of combinations or mixtures,one must confirm that no new hazards are likely to exist. In any case,the user is not exempt from observing all legal,administrative and regulatory procedures relating to the product, personal hygiene,and integrity of the work environment(Unless noted to the contrary,the technical information applies only to pure product). To our actual knowledge,the information contained herein is accurate as of the date of this document. However, neither Solvay Fluorides, LLC nor any of its affiliates makes any warranty, express or implied,or accepts any liability in connection with this information or its use.This information is for use by technically skilled persons at their own discretion and risk and does not relate to the use of this product in combination with any other substance or any other process.This is not a license under any patent or other proprietary right.The user alone must MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 14/15 www.solvaychemicals.us 1.800.765.8292 Hydrofluoric acid, 70% ■� (aqueous solution) Material Safety Data Sheet finally determine suitability of any information or material for any contemplated use,the manner of use and whether any patents are infringed.This information gives typical properties only and is not to be used for specification purposes.Solvay Chemicals, Inc.reserves the right ■� to make additions,deletions or modifications to the information at any time without prior notification. O Trademarks and/or other Solvay Fluorides,LLC products referenced herein are either trademarks or registered trademarks of Solvay Fluorides, LLC or its affiliates, unless otherwise indicated. - M3 Reason far revision: Supersedes edition:Solvay Fluorides,LLC MSDS HF70-0704 dated 07/15/2004. Purpose of revision: Update ACGIH levels(section 8). MSDS No.HF70-0505 Revised 05-05-05 Copyright 2005,Solvay Fluorides,LLC A subsidiary of Solvay Chemicals,Inc. All Rights Reserved. Page 15/15 www.soivaychemicais.us 1.800.765.8292 a , a Ja aterial Safety ta Sheet. Material Safety Data Sheet Emergency phone: CHEMTREC Number Flammability (800)424-9300 Health 0 Instability "yoI Special Personal protection C Section 1. Chemical product and company identification Product name : ENPREP®576E Product code : 202091 Material uses : Specialty chemicals for the electronics and surface finishing industries. Manufacturer : Enthone Inc Enthone OMI deMe)aco S.A.de C.V. 350 Frontage Road Norte 59 No.896 l West Haven, CT 06516 Col.Industrial Vallejo J Me)aco,D.F.02300 Phone: (203) 799-4917 Me)aco Fax: (203) 799-8179 Phone:52 55 5078 3904 www.cooksonelectronics.com Fax 52 555 567 6326 www.cooksonelectronics.com Tel.local de emergenciesa:080 Tel.de emergencies en transportacion:01 800 0021 400; (55)55591588 Validation date 3/8/2005. Supersedes Date 4/30/1998 Prepared by Robyn Hescock Section 2. Composition, Information on Ingredients Name CAS number %by weight sodium carbonate 497-19-8 40-50 sodium hydro)ade 1310-73-2 30-40 2-(2-butoxyethoxy)ethanol 112-34-5 5-10 sodium sulfite 7757-83-7 1-5 Any component not listed in Section 2 is non-regulated or present in the product in concentrations below legal disclosure limits All ingredients comply with applicable rules or orders under United States TSCA and Canadian CEPA regulations. esq i mETALS TESTING iEWED .0 OAT JA Continued on next page Enthone is a subsidiary of ENPREP 578E Page:2/7 Cookson Group PLC Section 3. Hazards identification Physical state Solid.(Powder.) Odor Pungent. Emergency overview Danger! CAUSES RESPIRATORY TRACT,EYE AND SKIN BURNS. HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED. MAY CAUSE ALLERGIC RESPIRATORY REACTION. CONTAINS MATERIAL WHICH MAY CAUSE DAMAGE TO THE FOLLOWING ORGANS: BLOOD,KIDNEYS,LUNGS,LIVER,GASTROINTESTINAL TRACT, RESPIRATORY TRACT,SKIN,CENTRAL NERVOUS SYSTEM,EYE,LENS OR CORNEA POSSIBLE CANCER HAZARD CONTAINS MATERIAL WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA. Do not ingest. Do not get in eyes,on skin or clothing. Do not breathe dust Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Risk of cancer depends on duration and level of wposure. Routes of entry Dermal contact Eye contact. Inhalation. Ingestion. Potential acute health effects Eye contact Corrosive to eyes. Skin contact Toxic in contact with skin. Corrosive to the skin. Inhalation Corrosive to the respiratory system. May cause sensitization by inhalation. Ingestion Toxic if swallowed. May cause burns to mouth,throat and stomach. Potential chronic health effects Target organs Contains material which may cause damage to the following organs:blood,kidneys, lungs,liver,gastrointestinal tract,upper respiratory tract,skin,central nervous system (CNS),eye,lens or comea. Over-exposure 242-Butoxyethoxy)ethanol:INHALATION: coughing,breathing difficulty-shortness of signs/symptoms breath and chest tightness/wheezing and pain. INGESTION: Narcotic effect;may cause nervous system disturbances. nausea/vomiting,headache,dizziness/vertigo and drowsinessffatigue. EYES: blinking,redness or swelling.Risk of serious damage to eyes.Skin:Absorbed through skin. sodium sulfite(2:1):Ingestion:discomfort(gastrointestinal), diarrhea,blood pressure elevation May cause allergic reactions to certain individuals.Eyes:Irritating to eyes, mucosa and skin and may cause bums. Sodium carbonate:If large quantities of this material are swallowed:Causes bums., nauseatvomiting,circulatory collapse,death Sodium hydroxide:Corrosive to eyes and skin.Corrosive on ingestion.Inhalation of aerosol may cause lung oedema. Carcinogenicity Classified 3(Not classifiable for human.)by IARC[sodium sulfite(2:1)]. See toxicological Information(section 11) Section 4. First aid measures First aid Eye contact Provide a readily accessible eyewash facility and quick drench safety shower. Immediately flush eyes with running water for at least 15 minutes,keeping eyelids open. Get medical attention immediately. Skin contact Evacuate the victim to a safe area as soon as possible. Ensure that eyewash stations and safety showers are proximal to the work-station location. In case of contact,immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing jbefore reuse. Thoroughly clean shoes before reuse. Get medical attention. Continued on next page Enthone is a subsidiary of ENPREP 576E Page.317 Cookson Group PLC Use NIOSH approved respirator when air concentration is greater than the TLV or PEL. Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Employers must ensure that employees are properly fitted and trained in the use of respiratory and other personal protection equipment. Employers must assure through industrial hygiene monitoring,engineering control and the selection of proper personel protection equipment that employees working with or around this product are not exposed to contaminant levels above those allowed by OSHA 29 CFR 1910. Inhalation If inhaled,remove to fresh air. If exposed person is not breathing,give artificial respiration or oxygen applied by trained personnel. Get medical attention. Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention immediately. Neoprene gloves. Natural rubber gloves. Protection of first-alders No action shall be taken involving any personal risk or without suitable training. If fumes are still suspected to be present,the rescuer should wear an appropriate mask or a self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing,or wear gloves. Wear suitable protective clothing. Section 5. Fire fighting measures NFPA Hazard identification 0 number Flammability Auto-ignition temperature Not applicable. Flash point Not applicable. l Flammable limits Not applicable. Products of combustion These products are carbon oxides(CO,CO2),sulfur oxides(SO2,S03...). Some metallic oxides. Explosion hazards in Not available. presence of various substances. Special remarks on Not available. explosion hazards Fin:fighting media and Use an extinguishing agent suitable for surrounding fires. Instructions Special protective Fire fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus(SCBA)with a full facepiece operated in positive pressure mode. Section 6. Accidental release measures Personal precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment(Section 8). Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and sewers. Methods for cleaning up Do not clean-up or dispose except under supervision of a specialist. Keep unnecessary and unprotected personnel from entering. Follow your company's spill procedures. Avoid contact with eyes,skin and clothing. Wear suitable protective clothing. Do not breathe dust. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Avoid creating dusty conditions and prevent wind dispersal. Vacuum or sweep up material and place in a designated labeled waste container. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Dispose of according to all federal,state and local applicable regulations. Continued on next page Enthone is a subsidiary of ENPREP 576E Page 417 Cookson Group PLC Section 7. Handling and storage Handling Do not ingest. Do not get in eyes,on skin or on clothing. Keep container closed. Use only with adequate ventilation. Do not breathe dust. Wash thoroughly after handling. Storage Keep container tightly closed. Keep container in a cool,well-ventilated area. Incompatibility with various Reactive with oxidizing agents,organic materials,metals,acids. substances: Conditions of instability Not available. Section 8. Exposure Controls, Personal Protection Engineering controls Use only with adequate ventilation. If user operations generate dust,fumes,vapor or mist,use process enclosures,local exhaust ventilation,or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Personal protection Eyes Avoid contact with eyes. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes,mists or dusts. Skin Avoid contact with skin and clothing. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Respiratory Use a properly fitted,particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Hands Avoid contact with skin. Chemical-resistant,impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Personal protection in case Do not clean-up or dispose except under supervision of a specialist.Keep unnecessary of a large spill and unprotected personnel from entering.Follow your company's spill procedures. Avoid contact with eyes,skin and clothing.Wear suitable protective clothing and eyetface protection. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Avoid breathing vapors of this product.Be sure to use a MSHA/NIOSH approved respirator or equivalent.Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator. Ingredient name CAS number Exposure limits sodum hydrobde 131 D-73-2 ACGIH TLV(United States,912004). CEIL•2 mg/r& Form:AQ forms MOSH REL(United States,6/2001). CEIL 2 mg/m' Form:All fours OSHA PEL(United States,611993). TWA 2 mgW 8 hour(s).Form:AI!forms OSHA PEL 1989(United States,311989). CEIL 2 mg/m3 Form All fans Consult local authorities for acceptable exposure limits. Continued on next page Enthone is a subsidiary of ENPREP 576E Page:5/7 1 Cookson Group PLC l Section 9. Physical and chemical properties Physical state Solid.(Powder.) Color Tan. Odor Pungent. pH Basic. Boiling/condensation point Not available. MeltingMreezing point 851.01°C(1563.8°F)based on data for:Sodium carbonate.Weighted average:595.74°C (1104.3°F) Specific gravity Weighted average:2.08(Water=1) Vapor pressure Not available. Vapor density The highest known value is 0.8 to 1 (Air=1) (d-gluconic acid,monosodium salt). Odor threshold Not available. Evaporation rate Not available. lonicity(in water) Not available. Dispersion properties See solubility in water. Solubility Soluble in cold water,hot water. Section 10. Stability and reactivity Incompatibility with various Reactive with obdizing agents,organic materials,metals,acids. substances: Hazardous polymerization Will not occur. Section 11. Toxicological information Toxicity data Ingredient name CAS number Test Result Route Species sodium carbonate 497-19-8 LD50 4090 mg/kg Oral Rat LD50 6600 mg/kg Oral Mouse LDLo 714 mg/kg Oral man sodium hydro:ade 1310-73-2 LDLo 500 mg/kg Oral Rabbit 2-(2-butoxyethoxy)ethanol 112-34-5 LD50 5660 mg/kg Oral Rat LD50 2200 mg/kg Oral Rabbit LD50 2400 mg/kg Oral Mouse LD50 2700 mg/kg Dermal Rabbit sodium sulfite 7757-83-7 LD50 3560 mg/kg Oral Rat LD50 820 mg/kg Oral Mouse LDLo 2825 mg/kg Oral Rabbit IDLH Not available. Chronic effects on humans CARCINOGENIC EFFECTS:Classified 3(Not classifiable for human.)by IARC[sodium sulfite(2:1)]. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.[sodium sulfite(2:1)]. Contains material which may cause damage to the following organs:blood,kidneys, lungs,liver,gastrointestinal tract,upper respiratory tract,skin,central nervous system (CNS),eye,lens or cornea. Continued on next page Enthone is a subsidiary of ENPREP 576E Page:617 Cookson Group PLC California prop.65 WARNING:This product contains chemical(s)known to the state of California to cause cancer,birth defects or other reproductive harm:propylene oxide;Ethylene oxide; 1,4-dioxane WARNING:This product contains chemical(s)known to the state of California to cause reproductive harm(female):Ethylene oxide California prop.65(no significant risk level):Ethylene oxide; 1,4-dioxane California prop.65(acceptable daily intake level): Ethylene oxide WARNING:This product contains chemical(s)known to the state of California to cause cancer.:propylene oxide;Ethylene oxide; 1,4-dioxane Enthone has not conducted specific studies on the toxicity of this product. Section 12. Ecological information Ecotoxicity data Ingredient name Species Period Result sodium carbonate Lepomis macrochirus(LC50) 96 hour(s) 300 mgA Lepomis macrochirus(LC50) 96 hour(s) 320 mgA Pimephales promelas(LC50) 96 hour(s) <850 mg/l 2-(2-butoxyethoxy)ethanol Lepomis macrochirus(LC50) 96 hour(s) 1300 mgA Enthone has not conducted specific studies on the ecotoxicity or enviromental fate of this product. Section 13. Disposal considerations Waste disposal Waste must be disposed of in accordance with federal,state and local environmental control regulations. Consult your local or regional authorities. Section 14. Transport information Regulatory UN number Proper shipping Class Packing group Label Additional information name Information DOT Classification UN1823 SODIUM HYDROXIDE, 8 II Not available. SOLID,MIXTURE(Sodium hydrodde) ERG#154 Section 16. Regulatory information United States U.S.Federal regulations All ingredients comply with applicable rules or orders under United States TSCA and Canadian CEPA regulations. TSCA 12(b)annual export notification: No products were found. TSCA 12(b)one time export:No products were found. Clean air act(CAA)112 accidental release prevention:propylene oxide;Ethylene oxide Clean air act(CAA)112 regulated flammable substances:No products were found. Clean air act(CAA)112 regulated toxic substances:propylene oxide;Ethylene oxide Continued on next page Enthone is a subsidiary of ENPREP 576E Page:7/7 Cookson Group PLC Product name CAS number Concentration SARA 313 2-(2-butoxyethoxy)ethanol 112-34-5 5-10 State regulations WARNING:This product contains chemical(s)known to the state of California to cause cancer,birth defects or other reproductive harm:propylene oxide;Ethylene oxide; 1,4-dioxane WARNING:This product contains chemical(s)known to the state of California to cause reproductive harm(female):Ethylene oxide California prop.65(no significant risk level):Ethylene oxide;1,4-dioxane California prop.65(acceptable daily intake level):Ethylene oxide WARNING:This product contains chemical(s)known to the state of California to cause cancer.:propylene oxide;Ethylene oxide; 1,4-dioxane WHNBS(Canada) Class D-2A:Material causing other toxic effects(VERY TOXIC). Class E:Corrosive solid. All ingredients in this product are found on the CEPA DSL. Section 16. Other information Definition of Terms ACGIH American Conference of Governmental Industrial Hygienists Ceiling Maximum exposure limit defined by OSHA CAS Chemical Abstract Service [ARC International Agency for Research on Cancer NIOSH National Institute for Occupational Safety and Health NTP National Toxicology Program OSHA Occupational Safety and Health Administration PEL Permissible Exposure Limit REL Recommended Exposure Limit RTK Right to Know SARA Superfund Amendments and Reauthorization Act STEL Short Term Exposure Limit TLV ACGIH Threshold Limit Value TLV C ACGIH Threshold Limit Value,Ceiling TRADE SECRET Claimed as allowed under 29CFR§1910.1200 TSCA Toxic Substances Control Act PPE Personal Protection Equipment CEPA Canadian Environmental Protection Act DSL Domestic Substance List NDSL Non-Domestic Substance List NSN New Substance Notification Rules Disclaimer This Material Safety Data Sheet may be used to comply with OSFWs Hazard Communication Standard, 29CFR§1910.1200. This Material Safety Data Sheet may also be used to comply with the requirements of Workplace Hazardous Materials Information System,of the Controlled Products Regulations,under the Hazardous Products Act. Enthone furnishes the data contained herein in good faith at customer's request without liability or legal responsibility for same whatsoever,and no warranty or guarantee,express or implied,is made with respect to such data;nor does Enthone grant permission,recommendation,or inducement to infringe any patent whether owned by Enthone or others.The data is offered solely for your information and consideration.Since conditions of use are beyond Enthone's control,user assumes all responsibility and risk. C Cookson Electronics C C1 REAGENT Material Safety Data Sheet F REAGENT CHEMICAL&RESEARCH, INC. ' May be used to comply with I!, E 115 US Hwy 202 Ringoes,NJ 08551 SHA's Hazard Communication Standard �- -- 9 CFR 1910.1200.Standard must be 'CHEMICAL consulted forspecific requirements. REVISED DATE: 1/1/2006 VALID UNTIL 1/1/2011 IDENTITY Note:Blank spaces are not permitted if any item is not applicable,or no Hydrochloric Acid, 2 0" Baume information is available,the space must be marked to indicate that. Section 1 - Product Information Product Name CAS# Distributed by HUBBARD-HALL INC. Hydrochloric Acid .7647-01-0 ._. i Synonym ---'Chemical Formula Wnan,SC c0349 hours-Ml Muriatic Acid HCl i�� a esm47aaa8t W.Sprigfield,llA O1009 419A47.07s6 - Wdninplon.MA 91857 978R9s.0077 Chemical Name ;dhemicel F=;:i,ily - - Hydrochloric Acid Solution ;Inorganic Acid Section li - Manufacturers Information Manufacturers Name :Address Reagent Chemical k Research, Inc. 124 River Road Middlesex, NJ 08846 Emergency Contact .. _ Country .----- Robert Dritschel United States Emergency Telephone Em ergency Te!ephone#2 ' 1-409-962-5769 iCHEMTREC 1-800-424-9300 Section III - Ingredients/Regulatory Information Substance Description Percent CAS# Y__ . ._..............._.....:.. ._. ..._........................................ ...-......._..._._...._......................_....._........................._-...._........ . ................._.........__ H drog en Chloride 31 45 33.30 7647-01-0 Water 66.70 - 68.55 7732-18-5 i3EPOSDRE LIMITS/REGULATORY INFORMATION ubstance PEL TLV STEL -WA CEILING Aydrogen Chloride C-7 mg/m3 C-5 npzr. 50 ppm N/D 5 ppm Water N/D N/D N/D N/D N/D N/D Not Determined C Ceiling Level Section IV - Hazards Identification Appearance&Odor Statement a°Hazards Clear/Pale Yellow Liquid/Pungent Odor Severe and painful burns upon contact Primary Route of E�osure Skin, eye and inhalation contact are the pri-mary routes of exposure to this product Inlialauon Acute E)4�osure Effects Inhalation of excessive concentrations of Hydrogen Chloride vapors immediately produces severe irritation of the upper respiratory tract; resulting in coughing, burning of the throat, and a choking sensation. Reactions encountered in man have usually been limited to inflammation occasional ulceration of the nose, throat and larynx. If inhaled deeply, edema of the lungs may occur. Skin Contact Acute Exposure Effects Concentrated solutions are destructive to clothing and on contact with skin, causes severe burns unless promptly washed off. Repeated skin contact with dilute solutions may lead to the development of dermatitis. Exposure to the concentrated vapors of Hydrogen Chloride may also result in burns and dermatitis. .� � AW TAWS TESSTII~:GQItP Page 1 of 7 REVIEWED SY .�. - - — — DAT Section IV - Hazards Identification (continued) Eye Contact Acute Exposure Effects ontact of the eyes with Hydrogen Chloride, either as a gas or in solution, rapidly causes severe irritation and painful burns of the eyes and eyelids. If the acid is not quickly removed by thorough irrigation with water, there may be prolonged or permanent visual impairment or total loss of sight. In estion-Acute(c g !Exposure Effects - When concentrated Hydrochloric Acid is swallowed, it causes severe burns of the mucous membranes of the mouth, esophagus and stomach. The lips and mouth usually turn white, and later brown. There is pain in the throat and stomach, difficulty in swallowing, intense thirst, nausea and in severe cases, collapse and unconsciousness. ——and- . Fre and _..... .. . ._. ._ Explosion Hazards - Non-flammable, but Hydrochloric Acid reacts with all metals, except gold and platinum, with rapid evolution of Hydrogen which is flammable and explosive in air. Firefighters exposed to Hydrochloric Acid vapors should wear Scott Air-Pak, or equivalent. Hydrogen Chloride vapors are extremely irritating to the respiratory tract and may cause breathing difficulty. --•-•-i—no.__... ic it y.. Carc .-- ... .._. .. .._..� IARC -No OSHA ...No ACGIH ..No Section V - First Aid Measures General If a known exposure occurs or is suspected, immediately initiate the recommended procedures below. Simultaneously contact a physician, or the nearest Poison Control Center. Inform the person contacted of the type and extent of exposure, describe the victim's symptoms and follow the advice given. For additional information, call day or night, Reagent Chemical (405) 962-5769 or Chemtrec (800) 424-9300. 16halado6 ...__ Remove from contaminated atmosphere. Tf breathing has ceased, clear the victim's airway and start mouth-to-mouth artificial respiration, which may be supplemented by the use of a bag-mask respirator, or a manually-triggered, oxygen supply capable of delivering 1 liter/second or more. If the victim is breathing, oxygen may be administered from a demand-type or continuous-flow inhalator, preferably with a physician's advice. Contact a physician immediately. Eye Contact - .... _ . Immediately flush the eyes with large quantities of running water for 15 minutes. Hold the eyelids apart during the flushing :o er4ure _-•insing of the entire surface of the eyes and lids with water. DO NOT attempt: to -.eutralize with chemical agents. Obtain medical attention as soon as possible. Oi_'_s of ointments should not be used. Continue the flushing for an additional 15 minutes if the physician is not available. I ?ag 2 of 7 Section V - First Aid Measures (continued) m Contact -)mmediately remove contaminated clothing under a safety shower. Flush all affected areas with large amounts of water for 15 minutes. DO NOT attempt to neutralize with chemical agents. Obtain medical advice. ..._--•----._.__... _..--• ---- DO NOT induce vomiting. Immediately give large quantities of water or milk, if available. If vomiting does occur, give fluids again. Never give anything by mouth to an unconscious person. Call a physician of the nearest Poison Control Center. Medical ti Condions Generally Aggravated by Exposure _ __.... --.----------.- -- . -------.--.. Hydrogen Chloride will aggravate breathing disorders Note to Physician _. -—- - -- - Attending Physician should treat exposed patients symptomatically Section VI - Fire Fighting Measures Flash Point -Flash Method N.A. 'N.A. Exti L - nguis-- h-in- Method� - • Not Applicable Unusual Fire and Explosion Hazards Non-flammable, but Hydrochloric Acid reacts with metals. Special F iit6hting Procedures' - - -- - Non-flammable, but Hydrochloric Acid reacts with all metals, except gold and platinum, with rapid evolution of Hydrogen which is flammable and explosive in air. Firefighters exposed to Hydrochloric Acid vapors should wear Scott Air-Pak, or quivalent. Hydrogen Chloride vapors are extremely irritating to the respiratory -tract and may cause breathing difficulty. Section VII - Accidental Release Measures Steps to be Taken in Case Material is Released or Spilled Spills or discharges into the environment involving large quantities of Hydrochloric Acid should be controlled and cleaned-up according to a pre-determined, affirmative written Spill Prevention and Control Program. For assistance in developing a SPCP contact your nearest Reagent Saes Office. Spills should be handled immediately by neu=ralization and dilution of the spilled product by the use of Soda Ash (Sodium Carbonate) , Lime (Calcium Hydroxide), or Limestone (Calcium Carbonate) witn large amounts of water. For an interior (inside a closed space) spill be aware that the use of Soda Ash, Lime and Limestone will evolve heat and carbon diox-Ide and that ample ven:_ilation must be provided. Waste Disposal Under Federal RCRA, it is the responsibility of the user of products to determine, at the time of disposal, w'cether the product falls under RCRA as a hazardous waste. This is because product uses, transfornaticna, mixtures, etc. may render the resulting end-product hazar-'ous. Containers should be cleaned of residual p ot:ac_ before disposal. Empty containers �hould be disposed of in ac.=darce with all applicable laws and regulations. Page 3 0 7